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HomeMy WebLinkAboutContract 40631CITY SECRETARY , I'" (o 3 \ CONTRACT NO. ~ .-, CONTRACT Between CITY OF FORT WORTH and EASTERN RESEARCH GROUP, INC. For Professional Services for an Assessment of the Air Quality Impacts Related to Natural Gas Production Facilities (Air Quality Study) DEM 10-05: NGAQS Environmental Management Department July 2010 OFFICIAL RECORD CITY SECRETARY FT. WORTH, TX 07-29-10 P04 :54 IN ,.~ Page I of 2 City of Fort Worth, Texas Mayor and Council Communication COUNCIL ACTION: Approved As Corrected on 7/20/2010 -Correction Highlighted in Yellow, Ord. No. 19236-07-2010 & 19237-07-2010 DATE: Tuesday, July 20 , 2010 LOG NAME: 062040 AIR QUALITY STUDY SUBJECT: REFERENCE NO.: C-24354 Aut~or_ize the Execution of a Contrac~ with ~astern Research Group , Inc ., in the Amount of $50 ,000 .00 for Prel_1minary Background Work Associated with the Fort Worth Air Quality Study and Adopt Appropriation Ordinances (ALL COUNCIL DISTRICTS) RECOMMENDATION: It is recommended that the City Council : 1. Suspend the Financial Management Policy Statements that limit the expenditure of gas lease revenue to one-time capital items; and , 2. Adopt the attached appropriation ordinance increasing estimated receipts and appropriations in the Capital Projects Reserve Fund -General Unrestricted Gas Lease Revenue Fund by $50,000.00 from available funds ; and, 3. Authorize the transfer of $50,000 .00 from the Capital Projects Reserve Fund -General Unrestricted Gas Lease Revenue Fund to the General Fund ; and, 4 . Adopt the attached supplemental appropriation ordinance increasing estimated receipts in the General Fund by $50,000 .00 from available funds ; and, 5. Authorize the City Manager to execute a contract in the amount of $50 ,000 .00 with Eastern Research Group, Inc ., for preliminary background work associated with the Fort Worth Air Quality Study . DISCUSSION: The City Council established the Air Quality Committee on March 9, 2010 (Resolution No . 3866-03-2010). This committee was tasked with identifying the study objectives, evaluating qualifications of consultants , reviewing the scope of work with candidate consultants , and recommending a consultant and study framework to the City Council. After reviewing the written submittals and conducting interviews , the Committee has recommended Eastern Research Group , Inc. (ERG) for the Air Quality Study . City staff are currently negotiating with ERG regarding final contract terms and conditions . A future Mayor and Council Communication will address the overall contract. In order to facilitate field work during August 2010 the Consultant needs to begin preliminary background work during July 2010. The scope of work for this initial phase of work will include ambient air monitoring network design and point source test plan development. Focus w ill be on existing data regarding gas well sites and operations within Fort Worth as well as the scientific information regarding sampling design , analysis methods and the quality assurance/quality control procedures to be adhered to during the work . The current Financial Management Policy Statements limit the usage of the gas lease revenues to one- time capital expenses . However, staff recommends suspending the rules in order to allow the use of the funds for the purposes of an air quality study that is directly related to the production of minerals. http ://apps.c fwnet.org/ e council/printmc .asp ?id= 13 8 96&print=true&Doc T y pe= Print 7/2 4/2 010 Page 2 of2 Eastern Research Group, Inc., is in compliance with the City's M/WBE Ordinance by committing to 10 percent M/WBE participation for this project which covers this interim contract and subsequent contracts . This work will affect ALL COUNCIL DISTRICTS . FISCAL INFORMATION/ CERTIFICATION: The Financial Management Services Director certifies that upon approval of the above recommendations and adoption of the attached supplemental appropriation ordinances, funds will be available in the current operating budget, as appropriated of the General Fund . FUND CENTERS: TO Fund/Account/Centers GC10 446100 006060001000 GG01 472010 0062040 GG01 539120 0062040 CERTIFICATIONS: Submitted for City Manager's Office by: Originating Department Head: Additional Information Contact: ATTACHMENTS FROM Fund/Account/Centers $50 ,000 .00 GC10 539120 006060001000 $50,000 .00 GG01 539120 0062040 $50,000.00 Fernando Costa (6122) Susan Alanis (8180) Rick Trice (7959) 1. 062040 A IR QUALITY STUD AO Rec4 .doc (Public) 2. 062040 AIR QUALITY STUD AO .doc (Public) 3. ERG Compliance Memorandum_,_p_gf (CFW Internal) 4 . fundingverification .doc (CFW Internal) 5. RE MC 062040 AIR QUALITY STUDY.msg (CFW Internal) http :// apps. cfwnet. org / ecouncil/printmc . asp ?id = 13 8 96&print=true&Doc Ty pe = Print $50,000 .00 $50 ,000 .00 7/24/2010 STATE OF TEXAS COUNTY OF TARRANT § § § KNOWN ALL BY THESE PRESENTS: CONTRACT FOR PROFESSIONAL SERVICES CITY OF FORT WORTH NATURAL GAS AIR QUALITY STUDY This Contract is entered into by and between the City of Fort Worth ("City"), a home-rule municipality located within Tarrant, Denton, Parker, and Wise Counties, Texas, acting through Fernando Costa , its duly authorized Assistant City Manager, and Eastern Research Group, Inc., a Massachusetts corporation ("Contractor"), acting through John Eyraud, its duly authorized Vice President. City and Contractor may be referred to herein individually as a Party, or collectively as the Parties. WITNESS ETH: That for and in consideration of mutual covenants and agreements herein contained, the Parties hereto mutually agree as follows: ARTICLE 1. DEFINITIONS City means the City of Fort Worth. Change Order means an officially authorized and executed written amendment to this contract or to a Task Order, issued by the City. Contract Documents shall consist of the written , printed, typed and drawn instruments which comprise and govern the performance of the work. Said Contract Documents include, but are not limited to, the Request for Qualifications (RFQ), addenda to the RFQ, the Statement of Qualifications, the work plan, the fee schedule, proposals, other plans, specifications, maps, blueprints, notice of award, general conditions, special conditions , supplementary conditions, general provisions, special provisions, task order(s), work order(s), change orders, this Contract and the payment, performance, and maintenance bonds . The Contract Documents shall also include any and all supplemental agreements approved by the City which may be necessary to complete the work in accordance with the intent of the plans and specifications in an acceptable manner, and shall also include the additional instruments bound herewith. Contractor means Eastern Research Group, Inc. Professional Services Contract OFFICIAL RECORD CITY SECRETARY FT. WORTH, TX Page 1 of 32 Fort Worth Natural Gas Air Quality Study -Eastern Research Group , Inc Notice to Proceed means the official letter issued by the City , pursuant to the Code of the City of Fort Worth and City ordinances and policies that authorizes Contractor to begin work. Task Order means an officially authorized and executed written description and sp ecification directing the Contractor to perform specific services within the scope of this contract, issued by the City. ARTICLE 2. SERVICES Contractor hereby agrees to perform as an independent contractor the services set forth in the Scope of Work attached hereto as Attachment "A". This contract is to provide the City of Fort Worth with professional services for an assessment of the air quality impacts related to natural gas production facilities (Air Quality Study). This contract is contemplated as covering the initial phases of work to be performed for the Air Quality Study as described in the City of Fort Worth Council Resolution Number 3866 and City of Fort Worth Request for Qualifications DEM 10-05:NGAQS. However the parties agree that any additional work beyond the scope of this initial contract is not guaranteed and that this contract confers no rights on the Contractor or any obligation on the part of the City for additional work or compensation. Nothing in this contract is to be construed as an exclusive agreement with the contractor to provide the City with professional services of this type or as an agreement by the City to guarantee the Contractor any specific projects or quantities of work. THERE IS NO MINIMUM GUARANTEE OF ANY WORK UNDER THIS CONTRACT OR ANY GUARANTEE OF ADDITIONAL FUTURE WORK OTHER THAN AS STRICTLY DEFINED BY THIS CONTRACT. Individual projects will be authorized on a Task Order basis when the City elects to proceed with each specific effort. City shall not pay for any work performed by Contractor or its subcontractors, subcontractors and/or suppliers that has not been specifically ordered by the City in writing on a duly executed Task Order or Change Order. Contractor shall not be compensated for any work that is verbally ordered by any person and shall rely only upon written authorization to conduct work. ARTICLE 3. COMPENSATION Section 1. Fee Schedule. City and Contractor agree to the unit prices, employee labor rates, and other costs as specified in this contract. Contractor shall be compensated in accordance with the Fee Schedule shown in Attachment "B". Payment shall be considered full compensation for Professional Services Contract Page 2 of 32 Fort Worth Natural Gas Air Quality Study -Eastern Research Group, Inc all labor, materials, supplies , and equipment necessary to complete the services described in Attachment "A". However the total fee paid by the City shall not exceed a total of forty nine thousand nine hundred fifty four dollars ($49,954.00) and the City will not be liable for any Contractor fees, costs, or other remuneration in excess of this amount unless the City has signed and issued a formal and duly authorized modification , amendment, or change order to this contract. Section 2. Task Orders. City will issue a Task Order to Contractor that details the work to be performed by the Contractor. Task Orders will include at a minimum a unique Task Order Number, scope of work , date to commence work , time period to complete work and the not to exceed payment amount for the task . Section 3. Invoice and Payment. The Contractor shall provide monthly invoices to the City. All invoices must reflect the City Task Order number. Invoices shall contain a detailed breakdown to include: labor including employee name , functional title , date and hours of work performed ; internal supplies and services provided; and external supplies and services provided. Payment for services rendered shall be due within thirty (30) days of the uncontested performance of the particular services so ordered and receipt by City of Contractor's invoice for payment of same. In the event of a disputed or contested billing, only that portion so contested may be withheld from payment, and the undisputed portion will be paid. No interest will accrue on any contested portion of the billing until mutually resolved. City will exercise reasonableness in contesting any billing or portion thereof. The Contractor shall also provide the City with quarterly updates showing the total and itemized costs incurred to the City for each task ordered and the amount remaining in the contract not-to-exceed amount. Contractor shall receive no additional compensation for work delays or hindrances except when direct and unavoidable extra costs to the Contractor are caused by the City's gross negligence . ARTICLE 4. TERM Unless terminated pursuant to the terms herein , this Agreement shall be for a term of one year, beginning upon the date of its execution. Professional Services Contract OFFICIAL RECORD CITY SECRETARY FT. WORTH, TX t-'age 3 of 32 Fort Worth Natural Gas Air Quality Study -Eastern Research Group , Inc ARTICLE 5. INDEPENDENT CONTRACTOR Contractor shall operate hereunder as an independent contractor, and not as an officer, agent, servant, or employee of the City . Contractor shall have exclusive control of and the exclusive right to control the details of its work to be performed hereunder and all persons performing same, and shall be solely responsible for the acts and omissions of its officers, agents, employees, contractors and subcontractors . The doctrine of respondeat superior shall not apply as between City and Contractor, its officers, agents, employees, contractors , and subcontractors, and nothing herein shall be construed as creating a partnership or joint venture between City and Contractor. ARTICLE 6. PROFESSIONAL COMPETENCE AND INDEMNIFICATION Work performed by Contractor shall comply in all aspects with all applicable local, state and federal laws and with all applicable rules and regulations promulgated by the local, state and national boards, bureaus and agencies. Approvals issued by the City or another entity shall not constitute or be deemed to be a release of the responsibility and liability of Contractor or its officers, agents , employees , contractors and subcontractors for the accuracy and competency of its services performed hereunder, which shall be performed in accordance with the applicable professional standard of care. In accordance with Texas Local Government Code Section 271.904 , the Contractor shall indemnify, hold harmless, and defend the City against liability for any damage caused by or resulting from an act of negligence , intentional tort, intellectual property infringement, or failure to pay a subcontractor or supplier committed by the Contractor or Contractor's agent, contractor under contract, or another entity over which the Contractor's exercises control. ARTICLE 7. INTELLECTUAL PROPERTY Section 1. Rights in data. The City shall have unlimited rights in all data delivered under this contract, and in all data first produced in the performance of this contract. Section 2 . Intellectual property rights and ownership. A ll intellectual property work product developed by Contractor under this contract shall be the sole property of the City and the City shall have unlimited rights in such work product. All intellectual property work product developed by Contractor under this contract shall be considered "work for hire" and rights , title , and interests to all Professional Services Contract Page 4 of 32 Fort Worth Natural Gas Air Quality Study -Eastern Research Group, Inc intellectual property shall vest in the City. Contactor affirmatively, by executing this contract, disclaims all such intellectual property interests in favor of the City. In the event that any rights, title, or interest shall by operation of law or otherwise fail to vest in the City or become void or voidable, Contractor shall a) transfer all rights, title, and interest to intellectual property to the City; or alternatively and at the discretion of the City the Contractor shall b) grant an unlimited and exclusive license for publication, sale, reproduction , or use by the City and its authorized sublicensees of all intellectual property developed under this contract. Contractor agrees to timely execute any documents or take any other actions as may reasonably be necessary, or as the State may reasonably request, to perfect the State's ownership, license, or other rights to any work product. Contractor shall not use, sell, transfer, or authorize a third party to use any work product, copyrights, trademarks, or other intellectual property (or derivatives thereof) of the work product developed under this contract without the express written consent of the City. ARTICLE 8. INDEMNIFICATION Section 1. Definitions. In this paragraph, the following words and phrases shall be defined as follows: Environmental Damages shall mean all claims, judgments, damages, losses, penalties , fines, liabilities (including strict liability), encumbrances, liens costs, and expenses of investigation and defense of any claim, whether or not such claim is ultimately defeated, and of any good faith settlement of judgment, of whatever kind or nature, contingent or otherwise, matured or unmatured, foreseeable or unforeseeable, including without limitation reasonable attorney's fees and disbursements and consultant's fees, any of which are incurred as a result of the existence of a violation of environmental requirements pertaining to work performed under this contract or by the operations of the Contractor and Subcontractors, and including without limitation: a. Damages for personal injury and death, or injury to property or natural resources; b. Fees incurred for the services of attorneys , consultants, contractors , experts, laboratories and investigation or remediation of the monitoring wells or any violation of environmental requirements including , but not limited to, the preparation of any feasibility studies or reports of the performance of any cleanup, remediation, removal , response, abatement, containment, closure , restoration or monitoring work required by any federal, state or local governmental agency or political subdivis· thmwtsl xpended in OFFICIAL RECORD . . cm~~n~ Professional Services Contract a e of 32 Fort Worth Natural Gas A ir Quality Study-Eastern Research Grou , l rn J. WORTH , T connection with the existence of such monitoring wells or violations or environmental requirements, and including without limitation any attorney's fees, costs and expenses incurred in enforcing this contract or collecting any sums due hereunder; and c. Liability to any third person or governmental agency to indemnify such person or agency for costs expended in connection with the items referenced in subparagraph (b) herein. Environmental requirements shall mean all applicable present and future statutes, regulations, rules, plans, authorizations, concessions, franchises, and similar items, of all governmental agencies, departments, commissions , boards, bureaus , or instrumentalities of the United States, states, and political subdivisions thereof and all applicable judicial, administrative , and regulatory decrees, judgments, and orders relating to the protection of human health or the environment, including without limitation: a. All requirements, including, but not limited to, those pertaining to reporting, licensing, emissions , discharges, releases, or threatened releases of hazardous materials, pollutants, contaminants or hazardous or toxic substances, materials, or wastes whether solid, liquid, or gaseous in nature, into the air, surfacewater, groundwater, stormwater, or land , or relating to the manufacture , processing , distribution, use, treatment, storage, disposal , transport, or handling of pollutants, contaminants , or hazardous or toxic substances, materials, or wastes , whether solid , liquid, or gaseous in nature; and b. All requirements pertaining to the protection of the health and safety of employees or the public. Section 2. General Indemnification. CONTRACTOR DOES HEREBY RELEASE, INDEMNIFY, REIMBURSE, DEFEND , AND HOLD HARMLESS THE CITY , ITS OFFICERS, AGENTS , AND EMPLOYEES , FROM AND AGAINST ANY AND ALL LIABILITY, CLAIMS, SUITS , DEMANDS, OR CAUSES OF ACTIONS WHICH MAY ARISE DUE TO ANY LOSS OR DAMAGE TO PERSONAL PROPERTY, OR PERSONAL INJURY, AND/OR DEATH, OCCURRING AS A CONSEQUENCE OF THE CONTRACTOR'S OPERATIONS UNDER THIS AGREEMENT, WHEN SUCH INJURIES , DEATH, OR DAMAGES ARE CAUSED BY THE SOLE NEGLIGENCE OF CONTRACTOR, ITS OFFICERS, AGENTS , EMPLOYEES, OR CONTRACTORS , OR THE JOINT NEGLIGENCE OF CONTRACTOR , ITS OFFICERS, AGENTS, EMPLOYEES, OR CONTRACTORS AND ANY OTHER PERSON OR ENTITY. Professional Services Contract Page 6 of 32 Fort Worth Natural Gas Air Quality Study -Eastern Research Group, Inc Section 3. Environmental Indemnification. CONTRACTOR DOES HEREBY RELEASE, INDEMNIFY, DEFEND, REIMBURSE, AND HOLD HARMLESS THE CITY, ITS OFFICERS, AGENTS, AND EMPLOYEES, AGAINST ANY AND ALL ENVIRONMENTAL DAMAGES AND THE VIOLATION OF ANY AND ALL ENVIRONMENTAL REQUIREMENTS RESULTING FROM CONTRACTOR'S OPERATIONS UNDER THIS AGREEMENT WHEN SUCH ENVIRONMENTAL DAMAGES OR VIOLATION OF ENVIRONMENTAL REQUIREMENTS ARE CAUSED BY THE ACT OR OMISSION OF CONTRACTOR, ITS OFFICERS, AGENTS, EMPLOYEES, OR CONTRACTORS, OR THE JOINT ACT OR OMISSION OF CONTRACTOR, ITS OFFICERS, AGENTS, EMPLOYEES, OR CONTRACTORS AND ANY OTHER PERSON OR ENTITY AND WHICH ARE DIRECTLY RELATED TO EITHER (i) NEGLIGENCE; OR (ii) INTENTIONAL OR WILLFUL MISCONDUCT .. Section 4. The obligations of the Contractor under this Article shall include, but not be limited to, the burden and expense of defending all claims , suits and administrative proceedings (with counsel reasonably approved by the City), even if such claims, suits or proceedings are groundless, false, or fraudulent, and conducting all negotiations of any description, and paying and discharging, when and as the same become due , any and all judgments, penalties or other sums due against such indemnified persons. Upon learning of a claim , lawsuit, or other liability which Contractor is required hereunder to indemnify, City shall provide Contractor with reasonable timely notice of same. All Contractors under this contract agree that they assume joint and several liability for any claim by the City or for a third party claim against the City for general or environmental damages caused by any of the Contractors herein. The obligations of the Contractor under this paragraph shall survive the expiration or termination of this Agreement and the discharge of all other obligations owed by the parties to each other hereunder. ARTICLE 9. INSURANCE AND BONDS The Contractor certifies it has, at a minimum, current insurance coverage as detailed below and will maintain it throughout the term of this Contract. Prior to commencing work, the Contractor shall deliver to City, certificates documenting this coverage. The City may elect to have the Contractor submit its entire policy for inspection. A . Insurance coverage and limits: OFFICIAL RECORD CITY SECRETARY FT. WORTH , TX Professional Services Contract L------~gie 7 of 32 Fort Worth Natural Gas Air Qual ity Study-Eastern Research Group , Inc 1 . Commercial General Liability o $1,000 ,000 each occurrence o $2 ,000 ,000 aggregate 2. Automobile Liability 3 . 4 . 5. o $1,000 ,000 each accident , or o $250 ,000 property damage/ $500 ,000 bodily injury per person per accident A commercial business auto policy shall provide coverage on "any auto," defined as autos owned , hired and non-owned during the course of this project. The named insured and employees of Contractor shall be covered under this policy. The City of Fort Worth shall be named an Additional Insured, as its interests may appear. Liability for damage occurring while loading , unloading and transporting materials collected under the Contract shall be included under this policy. Worker's Compensation o Coverage A: statutory limits o Coverage B: $100 ,000 each accident Professional Liability $500 ,000 disease -policy limit $100,000 disease -each employee o $1,000 ,000 each claim o $2,000,000 aggregate The retroactive date shall be coincident with or prior to the date of this contract and the certificate of insurance shall state that the coverage is claims-made and the retroactive date. The insurance coverage shall be maintained for the duration of this contract and for five (5) years following completion of the contract (Tail Coverage). Th is provision shall survive the one year term of this contract. An annual certificate of insurance shall be submitted to the City for each year following completion of this contract. Environmental Impairment Liability and/or Pollution Liability o $2 ,000 ,000 per occurrence. Ell coverage(s) must be included in policies listed in the professional liability insurance above ; or such insurance shall be provided under a separate policy or policies. If no in-field work is to be performed under th is contract (i.e. no individual under the Contractor's control or direction will enter any oil and gas site) the City shall not require Environmental Impairment Liability insurance. Professional Serv ices Contract Page 8 of 32 Fort Worth Natural Gas A ir Qual ity Study -Eastern Research Group , Inc B. Certificates of Insurance evidencing that the Contractor has obtained all required insurance shall be delivered to the City prior to Contractor proceeding with the Contract. 1. Applicable policies shall be endorsed to name the City an Additional Insured thereon, as its interests may appear. The-term City shall include its employees, officers, officials, agents, and volunteers as respects the Contracted services .. 2. Certificate(s) of Insurance shall document that insurance coverage specified herein are provided under applicable poli.cies documented thereon. 3. Any failure on part of the City to request required insurance documentation shall not constitute a waiver of the insurance requirements. 4. A minimum of thirty (30) days notice of cancellation or material change in coverage shall be provided to the City. A ten (10) days notice shall be acceptable in the event of non-payment of premium. Such terms shall be endorsed onto Contractor's insurance policies. Notice shall be sent to Department of Risk Management, City of Fort Worth, 1000 Throckmorton Street, Fort Worth, Texas 76102. 5. Insurers for all policies must be authorized to do business in the state of Texas or be otherwise approved by the City; and, such insurers shall be acceptable to the City in terms of their financial strength and solvency. 6. Deductible limits, or self-insured retentions, affecting insurance required herein shall be acceptable to the City in its sole discretion; and, in lieu of traditional insurance, any alternative coverage maintained through insurance pools or risk retention groups must be also approved. Dedicated financial resources or Letters of Credit may also be acceptable to the City. 7. Applicable policies shall each be endorsed with a waiver of subrogation in favor of the City as respects the Contract. 8. The City shall be entitled, upon its request and without incurring expense, to review the Contractor's insurance policies including endorsements thereto and, at the City's discretion; the Contractor may be required to provide proof of insurance premium payments. 9. The Commercial General Liability insurance policy shall have no exclusions by endorsements unless the City approves such exclusions. 10. The City shall not be responsible for the direct payment of any insurance premiums required by the contract. It is understood that insurance cost is an allowable component of Contractor's overhead. OFFICIAL RECORD CITY SECRETARY FT. WORTH , TX Professional Services Contract Page 9 of 32 Fort Worth Natural Gas Air Quality Study -Eastern Research Group , Inc 11. All insurance required above shall be written on an occurrence basis in order to be approved by the City. 12. Subcontractors to the Contractor shall be required by the Contractor to maintain the same or reasonably equivalent insurance coverage as required for the Contractor. When subcontractors maintain insurance coverage, Contractor shall provide City with documentation thereof on a certificate of insurance. Notwithstanding anything to the contrary contained herein, in the event a subcontractor's insurance coverage is canceled or terminated, such cancellation or termination shall not constitute a breach by Contractor of the contract. 13. Payment and Performance Bonds. Before beginning the work, the Contractor shall be required to execute to the City of Fort Worth a payment bond if the contract is in excess of $25,000 and a performance bond if the contract is in excess of $100,000. The payment bond is solely for the protection and use of payment bond beneficiaries who have a direct contractual relationship with the Contractor or subcontractor to supply labor or material; and in 100% the amount of the Contract. The performance bond is solely for the protection of the City of Fort Worth, in 100% the amount of the Contract, and conditioned on the faithful performance by Contractor of the work in accordance with the plans, specifications, and contract documents. Contractor must provide the payment and performance bonds, in the amounts and on the conditions required, within 14 calendar days after Notice of Award. 14. Requirements for Sureties. The bonds shall be issued by a corporate surety duly authorized and permitted to do business in the State of Texas that is of sufficient financial strength and solvency to the satisfaction of the City. The surety must meet all requirements of Article 7.19-1 of the Texas Insurance Code. All bonds furnished hereunder shall meet the requirements of Chapter 2253 of the Texas Government Code, as amended. In addition , the surety must (1) hold a certificate of authority from the United States Secretary of the Treasury to qualify as a surety on obligations permitted or required under federal law; or (2) have obtained reinsurance for any liability in excess of $100,000 from a reinsurer that is authorized and admitted as a reinsurer in the state of Texas and is the holder of a certificate of authority from the Untied States Secretary of the Treasury to qualify as a surety on obligations permitted or required under federal law. Satisfactory proof of any such reinsurance shall be provided to the City upon request. The City, in its sole discretion, will determine the adequacy of the proof required herein. No sureties will be accepted by the City that are at the time in default or delinquent on any bonds or wh ich are interested in any litigation against the City. Should any surety on the Contract be determined unsatisfactory at any time by the City, notice will be given to the Contractor to that effect and the Contractor shall immediately provide a new surety satisfactory to the City . Professional Services Contract Page 10 of 32 Fort Worth Natural Gas Air Qual ity Study -Eastern Research Group , Inc ARTICLE 10. LICENSES AND PERMITS Contractor certifies and warrants that on the day any work is to commence under this contract and during the duration of the contract it shall have and maintain all of the current, valid , and appropriate federal, state, and local licenses and permits necessary for the provision of services under this contract. Contractor also certifies that if it uses any subcontractor i n the performance of this contract, that such subcontractor shall have and maintain all of the current, valid, and appropriate federal , state, and local licenses and permits necessary for the provision of services under this contract. ARTICLE 11. TRANSFER OR ASSIGNMENT City and Contractor each bind themselves, and their lawful successors and assigns , to this Agreement. Contractor has been engaged as a consequence of Contractor's specific and unique skills; Assignment will only be granted under unusual circumstances and at the sole discretion of the City. Contractor, its lawful successors and assigns, shall not assign, sublet or transfer any interest in this Agreement w ithout prior written consent of the City. ARTICLE 12. RIGHT TO AUDIT (a) Contractor agrees that the City shall, until the expiration of three (3) years after final payment under this Agreement, have access to and the right to examine any d irectly pertinent books, documents, papers and records of Contractor involving transactions relating to this Agreement. Contractor agrees that the City shall have access during normal working hours to all necessary facilities and shall be provided adequate and appropriate workspace in order to conduct audits in compliance with the provisions of this section. C ity shall give Contractor reasonable advance notice of i ntended audits. A City initiated audit of indirect costs shall be conducted by review of an appropriate existing audit by recognized federal agency if such data is made available for review to the City. (b) Contractor further agrees to include in all its subcontracts hereunder, a provision to the effect that the subcontracting contractor agrees that the City shall, until the expiration of three (3) years after final payment under the subcontract, have access to and the right to examine any directly pertinent books, documents, papers and records of such subcontractor, involving transactions to the subcontract , and further, that City shall have access during normal working hours to all subcontractor facilities, and shall be provided adequate and appropriate work space in order to conduct audits in compliance with the provisions of this article. City shall give Contractor and any subcontractor reasonable advance notice of intended audit. OFFICIAL RECORD Profess ional Services Contract CITY SECRETA 11 of 32 Fort Worth Natural Gas Air Quality Study -Eastern Research Gr ou ~, • ORTH, X ( c) Contractor and subcontractors agree to photocopy such documents as may be requested by the City. The City agrees to reimburse Contractor for the cost of copies at the rate published in the Texas Administrative Code in effect as of the time copying is performed . ARTICLE 13. MINORITY AND WOMAN BUSINESS ENTERPRISE (M/WBE) PARTICIPATION In accordance with City Ordinance No. 15530 , the City has goals for the participation of minority business enterprises and woman business enterprises ("M/WBE") in City contracts. Contractor agrees to a minimum M/WBE participation of ten percent (10%) in accordance with its proposal and the aforementioned ordinance. Contractor acknowledges the M/WBE goal established for this Agreement and its commitment to meet that goal. For the purposes of determining M/WBE participation the full 10% M/WBE participation is calculated using the combined total work performed under this contract and a future anticipated contract for work on the Air Quality Study. Any misrepresentation of facts (other than a negligent misrepresentation) and/or the commission of fraud by the Contractor may result in the termination of this Agreement and debarment from participating in City contracts for a period of time of not less than three (3) years. ARTICLE 14. NON-DISCRIMINATION During the performance of this contract, Contractor shall not discriminate in its employment practices and shall comply with all applicable provisions of Chapter 17, Article Ill of the Code of the City of Fort Worth. Contractor agrees not to discriminate against any employee or applicant for employment because of because of age, race, color, religion, sex, disability, national origin , sexual orientation, transgender, gender identity or gender expression in any manner involving employment, including the recruitment of applicants for employment, advertising, hiring, layoff, recall, termination of employment, promotion, demotion, transfer, compensation, employment classification, training and selection for training or any other terms, conditions or privileges of employment. Contractor agrees to post in conspicuous places, available to employees and applicants for employment, notices setting forth the provisions of the non-discrimination clause. Contractor also agrees that in all solicitations or advertisements for employees placed by or on behalf of this contract, that Contractor is an equal opportunity employer. Notices, advertisements, and solicitations placed in accordance with federal law, rule or regulation shall be deemed sufficient for the purpose of meeting the requirements of this section. Professional Serv i'ces Contract Page 12 of 32 Fort Worth Natural Gas Air Quality Study -Eastern Research Group , Inc ARTICLE 15. OBSERVE AND COMPLY Contractor shall at all times observe and comply with all federal, state, and local laws and regulations and with all City ordinances and regulations which in any way affect this Agreement and the work hereunder, and shall observe and comply with all orders, laws ordinances and regulations which may exist or may be enacted later by governing bodies having jurisdiction or authority for such enactment. No plea of misunderstanding or ignorance thereof shall be considered. Contractor agrees to defend, indemnify and hold harmless City and all of its officers, agents and employees from and against all claims or liability arising out of the violation of any such order, law, ordinance, or regulation, whether it be by itself or its employees. ARTICLE 16. DEFAULT If Contractor fails to begin work or to complete work within the time specified in a Task Order City shall have the right to take charge of and complete the work in such a manner as it deems appropriate. If the City exceeds the costs detailed herein or in the Task Order, City may deliver to Contractor a written itemized statement of the excess costs and Contractor shall reimburse the City for such excess costs without delay. If at any time during the terms of this contract, the work of the Contractor fails to meet the specifications of the Contract Documents or to meet the standards of duty, care, or proficiency of a reasonable and competent Contractor, City may notify the Contractor of the deficiency in writing. Failure of the Contractor to correct such deficiency and complete the work required under this contract or a Task Order to the satisfaction of the City within ten ( 10) days after written notice shall constitute default, and shall result in termination of this contract. Contractor shall not be deemed to be in default because of any failure to perform under this contract if the failure arises solely from causes beyond the control of the Contractor and without any fault or negligence by the Contractor. Such causes shall include acts of God, acts of war or terrorism, fires, floods, epidemics, quarantine restrictions, labor strikes, freight embargoes, and events of unusually severe weather. ARTICLE 17. TERMINATION City may terminate this contract without cause by giving thirty (30) days written notice to Contractor. In the event of termination, any work in progress will continue to completion unless otherwise specified in the notice of termination. If the City terminates this contract under this provision, City shall pay Contractor for all services performed prior to the termination. Termination shall be without prejudice to any other remedy the City may have. OFFICIAL RECORD CITY SECRETARY Professional Services Contract FT. WORT 1 · of 32 Fort Worth Natural Gas Air Quality Study -Eastern Research Grou "'""""l.._nc _______ --.J All data and completed or partially completed documents prepared under this contract shall be promptly turned over to the City upon termination of this contract. ARTICLE 18. VENUE AND JURISDICTION If any action, whether real or asserted , at law or in equity , arises on the basis of any provision of this Agreement, venue for such action shall lie in state courts located in Tarrant County, Texas or the United States District Court for the Northern District of Texas -Fort Worth Division. This Agreement shall be construed in accordance with the laws of the State of Texas. ARTICLE 19. CONTRACT CONSTRUCTION The Parties acknowledge that each party and, if it so chooses, its counsel have reviewed and revised this Agreement and that the normal rule of construction to the effect that any ambiguities are to be resolved against the drafting party must not be employed in the interpretation of this Agreement or any amendments or exhibits hereto. ARTICLE 20 . HEADINGS The headings contained herein are for the convenience in reference and are not intended to define or limit the scope of any provision of this Agreement. ARTICLE 21. COUNTERPARTS This Agreement may be executed in one or more counterparts and each counterpart shall, for all purposes, be deemed an original, but all such counterparts shall together constitute but one and the same instrument. ARTICLE 22 . SEVERABILITY The prov1s1ons of this Agreement are severable, and if any word, phrase, clause, sentence, paragraph , section or other part of this Agreement or the application thereof to any person or circumstance shall ever be held by any court of competent jurisdiction to be invalid or unconstitutional for any reason, the remainder of this Agreement and the application of such word, phrase, clause , sentence, paragraph, section, or other part of this Agreement to other persons or circumstances shall not be affected thereby and this Agreement shall be construed as if such invalid or unconstitutional portion had never been contained therein. Professional Services Contract Page 14 of 32 Fort Worth Natural Gas Air Quality Study -Eastern Research Group , Inc ARTICLE 23. RIGHTS AND REMEDIES NOT WAIVED In no event shall the making by the City of any payment to Contractor constitute or be construed as a waiver by the City of any breach of covenant, or any default which may then exist, on the part of Contractor, and the making of any such payment by the City while any such breach or default exists shall in no way impair or prejudice any right or remedy available to the City with respect to such breach or default. Any waiver by either party of any provision or condition of the contract shall not be construed or decreed to be a waiver of any other provision or condition of this Contract, nor a waiver of a subsequent breach of the same provision or condition, unless such waiver be expressed in writing by the party to be bound . All costs and attorneys fees incurred by the City in the enforcement of any provision of this contract shall be paid by the Contractor. The remedies provided for herein are in addition to any other remedies available to the City elsewhere in this contract and by law. ARTICLE 24. NOTICES Notices to be provided hereunder shall be sufficient if forwarded to the other Party by hand-delivery or via U.S. Postal Service certified mail return receipt requested, postage prepaid, to the address of the other Party shown below: If to the City: If to the Contractor: City of Fort Worth Environmental Management Department Attn: Brian K. Boerner, CPM, CHMM, Director 1000 Throckmorton Street Fort Worth, Texas 76102-6311 Eastern Research Group, Inc. Attn: Mike Pring 110 Hartwell Avenue Boston, MA 02421 ARTICLE 25. WARRANTY Contractor warrants that it understands the currently known hazards and suspected hazards which are presented to persons, property and the environment by the types of work which are to be performed under this contract. OFFICIAL RECORD CITY SECRE TARY I FT. WORTH , TX Professional Services Contract Pa e 15 of 32 Fort Worth Natural Gas Air Quality Study -Eastern Research Group, Inc Contractor further warrants that it will perform all services under this Contract in a safe, efficient and lawful manner using industry accepted practices , and in full compliance with all applicable state and federal laws governing its activities and is under no restraint or order which would prohibit performance of services under this Contract. ARTICLE 26. NO THIRD-PARTY BENEFICIARIES This Agreement shall inure only to the benefit of the parties hereto and third persons not privy hereto shall not, in any form or manner, be considered a third party beneficiary of this Agreement. Each party hereto shall be solely responsible for the fulfillment of its own contracts or commitments. ARTICLE 27. ENTIRETY This contract and the other contract documents are incorporated by reference herein, are binding upon the parties and contain all the terms and conditions agreed to by the City and Contractor, and no other contracts , oral or otherwise, regarding the subject matter of this contract or any part thereof shall have any validity or bind any of the parties hereto. In the event of any conflict between this contract and any other contract documents, then firstly the terms of this contract shall govern, secondly the work plan and fee schedule shall govern, and thirdly the other contract documents shall govern. This portion of page left intentionally blank. Professional Services Contract Page 16 of 32 Fort Worth Natural Gas Air Quality Study -Eastern Research Group, Inc ATTACHMENT A SCOPE OF WORK OFFICIAL RECORD CITY SECRETARY FT. WORTH , TX ATTACHMENT A. SCOPE OF WORK THERE IS NO GUARANTEE OF ANY WORK UNDER THIS CONTRACT, however the types of work which the Contractor will perform upon specific written authorization by the City shall include the following , and related environmental and engineering consulting services : This scope is intended to be illustrative and not exhaustive , and similar or related services may be ordered subject to the terms of this contract and as authorized by the City. The Scope of Work is detailed in the document entitled "Final Work Plan -Natural Gas Air Quality Study Planning " prepared by Eastern Research Group, Inc. and dated July 21, 2010. Professional Services Contract Fort Worth Natural Gas Air Quality Study -Eastern Research Group , Inc OFFICIAL RECORD CITY SECRETARY FT. WORTH, TX Page 17 of 32 FINALWORKPLAN Natural Gas Air Quality Study Planning Prepared by: Eastern Research Group, Inc . 1600 Perimeter Park Drive Suite 200 Morrisville , NC 27560 Prepared for: M r. Brian Boerner Director, Department of Environmental Management City of Fort Worth Professional Services Contract l 000 Tirrockmorton Street Fort Worth, Texas 76102-6311 July 21 , 2010 Fort Worth Natural Gas Air Quality Study -Eastern Research Group, Inc Page 18 of 32 TABLE OF CO NTENTS P age No. Introduction ...................................................................................................................................... 1 1.0 Contractor's Project Manager .............................................................................................. ! 2 .0 Task 1 -Ambient Air Monitoring Network Design ............................................................ 2 3.0 Task 2 -Point Source Test Plan Development ................................................................... .4 4.0 Task 3 -Communication and Outreach ................................................................................. 7 5 .0 Timeline ............................................................................................................................... 7 6.0 Cost Estimate ....................................................................................................................... 8 LIST OF TABLES P age No. Project Milestones and Schedule for Fort Worth Natural Gas Air Quali ty Study Planning .7 2 Estimated Costs to Perform Fort Worth Natural Gas Air Quality Study Planning ............... 8 3 List of Staff Members for Fort Worth Natural Gas Air Quality Study Planning .................. 9 ii Professional Services Contract Fort Worth Natural Gas Air Quality Study -Eastern Research Group, Inc OFFICIAL RECORD CITY SECRETARY FT. WORTH , TX Page 19 of 32 INTRODUCTION TI1is document contains Eastern Research Grnup 's (ERG's) final work plan for conducting the initial plaru1ing and preparatory Work needed to perform the tasks and activities specified in Project DEM 10-05 (Natural Gas Air Quality Study). The primary objectives of this project are to answer these fundamental questions : • What quantity of emissions, is coming from the sites on a volume and mass basis ? • Do the sites comply with applicable reg11latory limits ? • Wha.t effect do these emissions h ;lVe on ambient air quality at the fenceline? • Are the City's setbacks for Wells, tan)cs , and compressors adequate to protect public health? This work plan addresses the logistical and technical planning tasks that must b e completed in order to be mobilized and conducting point source testing and ambient air monitoring in the City of Fort Worth during the month of August. U nder this work plan, we will be preparing the Ambient Air Monitoring Network Design as well as the Point Source Testing Plan. 1.0 CONTRACTOR'S PROJECT MANAGE R The overall Project Manager (PM) for ERG for this Task Order is Mr. Mike Pring. In this role, he will be responsible for directing this project 's day-to-day activities. He will also maintain overall re s ponsibility for the successful completion of the project. Contact information for Mr. Pring is as follows: Telephone : Fax: Email: Professional Services Contract 919-468-7840 9 19-468-7801 Mike.Pring@erg.com Fort Worth Natural Gas Air Quality Study -Eastern Research Group, Inc Page 20 of 32 2.0 TASK 1 -AMBIENT AIR MONITORING NETWORK DESIGN In order to produce a scientifically accurate and defensible ambient monitoring study that will be ready for implementation in August , ERG will de sign the Ambient Monitoring Network under this task. As part of the Ambient Monitoring Network development process, E RG will perform a variety of analyses which must be completed prior to initiation of ambient monitoring. While there are short-tenn needs for this data as described b elow, much of this data will be used throughout the project for other tasks and for end-use data analysis. All analyses will feed into our recommendations for situating runbient monitoring sites across the Fort Worth Area. Th.e following data will be retrieved by ERG, and used in this task: 1) Existing Monitoring Sites and Ambient Monitoring Data: ERG wi ll review and evaluate existing monitoring sites in Fort Worth for possible co -location. ERG will query EPA's Air Quality Subsy stem (AQS) to identify all monitoring sites (both active and inactive) within the City of Fort Worth 's boundaries, as well as any existing Texas Commission on Environmental Quality (TCEQ) s ites . Active s ites may offer the opportunity for co-location of monitors, and inactive si tes may be re-tooled to house proposed monitoring sites. 2) Existing Emission Inventory Data: ERG will retrieve emission inventory data from E PA's 2005 National Emissions Inventory (the most recent publicly available dataset) and the 2005-2008 Toxic Release Inventories. Additionall y , the Texas Commission on Environmental Quality recently finished the statewide 2008 base year emission inventory, and we may be requesting that data. This data will be used to identify existing, non-natural gas related sources of air toxic emissions such as industrial or commercial manufacturing facilities. 3) Existing Meteorological Data: ERG will retrieve National Weather Service (NWS) data from Dallas-Fot1 Worth International Airport, as well as sutrnunding NWS stations. Additionally, there may be meteorological data housed in AQS that we will extract. 2 OFFICIAL RECORD CITY SECRETARY FT. WORTH , TX Professional Services Contract Page 21 of 32 Fort Worth Natural Gas Air Quality Study -Eastern Research Group, Inc 4) Permit Data: Another source of data which may be useful is air quality permits for existing facilities , which may contain information on emission unit characteristics and emissions. We will ask the City and TCEQ for that da1a. 5) GIS Data : We understand that the City contains GIS files of all oil and natural gas activity sites, in addition to city boundary and council district lines. 6) Texas Railroad Commission Data: The Texas Railroad Commission (TRC) database will be queried to obtain natural gas and cond.ensate production data for each well in the study area. We may also find pem1it applications and other relevant information for natural gas drilling activities in the City of Fort Worth . 7) 8) Population Statistics: We will obtain 2001-2010 census-level population statistics from the U .S. Census Bureau or from the City . This data will be useful in identifying areas in the City with high population densities. NATA05/NAT A02 Results: EPA recently performed risk exposure modeling analyses for the entire country at the census-tract level based on the 2005 National-scale Air Toxics A5sessment (NATA) Inventory. The census-tract results for the City of Fort Worth can be extracted, and used to identify areas which have high cancer and /or noncancer risk, with specific focus on benzene risk. The level of information from the NAT A model includes estimated contributions from point, area, onroad, and nonroad sources, as well as background concentrations. Because of this , this data will be useful as another tool in helping identify potential monitoring sites. We will use the wind observations to develop wind rose plots (multi-year, annual, monthly) from meteorological stations in and around the City of Fort Worth. Using these wind rose plots, we will determine typical wind flow patterns for the City. Knowing the typical wind flow for the City is important in placing monitoring sites in their appropriate locations. One site will likely be located in a remote setting, upwind of typical air flow, and will serve as the background site . We will also propose other sites located across the city with monitor pµrposes of population exposure and/or downwind of targeted sources. 3 Professional Services Contract Page 22 of 32 Fort Worth Natural Gas Air Quality Study-Eastern Research Group, Inc Population ell.'Posure sit es would typically be located n ear schools , community centers and/or parks (Protected Use s ites as defined in Ordinance No. 18449-02-2009). We also propose exploring existing monitoring sites that are in the City to use as possible locations, or as s uppl ements to the additional monitoring si tes. Using the permit data, the City's GIS data, and emission inventory d ata, we will develop overlays, such that a visu al observati on of natural gas we ll clusters and sensitive areas (schools, community centers, parks) might identify areas for targeted and/or fenceline monitoring. Finally, ERG will develop a project-specific Quality Assurance Project Plan (QAPP) under this task which will provide specifics on the data quality o bj ectives (DQOs ), sampling methods and schedul e, QA/QC protocol, and d ata reporting. The QAPP prepared for this study will ensure that high quality, scientifically d efensible data wi ll be collected. Because of the high profile of this study, we will base the project-specific QAPP on the QAPP currently being used under o ur National Monitoring Programs contract, w hicb is a Level l QAPP (the highest required by EPA). (Note: additional Ambient Monitoring s ites may be identified as a result of the point source testing task, but these sites will not be identified until after the point source testil1g has begun. Additionall y, we antic ip ate conducting monitoring at pre-production sites during the drilling and fractu ring steps. However, given the short notification periods prior to these activities commencing, these sites can not be determined at this time .) 3.0 TASK 2 -POINT SOURCE TEST PLAN DEVELOPMENT To ensure timely commencement of the point source testing activities in A ug ust, there are several planning and preparation activities that need to be completed beforehand. 111ese activities are included in the fo llowing sub-tasks : Task 2.1: Sample Point Identification. 4 Professional Services Contract Fort Worth Natural Gas Air Quality Study -Eastern Research Group, Inc OFFICIAL RECORD CITY SECRETARY FT. WORTH , TX Page 23 of 32 Task 2.2: Development of Data Collection Forms. Task 2.3 : Equipment Acquisition and Sampling Logistics. Task 2.4: Development of the Point Source Test Plan. Task 2.1: Sample Point Identification This task is essential to de veloping a practical work schedule as well as a reali stic point so urce testing budget. Using information provided principally by the City of Fort Worth, but supplemented with data from the TRC, TCEQ, and websites concerned with natural gas production issues , Sage will identify each point so urce that is to be surveyed for emissions. Us ing GiS mapping capabilities, each s ite will be located on an ove rlay of the City together with embedded street address and GPS coordinate information . Th e map will s ubsequently be div ided into sectors so that individual monitoring routes can be created for the two field team s . Task 2.2: Field Data Collection QA/QC Forms Task 2 will focus on developing project-specific electronic field data collection forms for use with hand-held data loggers to record information about each well, well pad, compressor site , processing site, or disposal site visited. This information will include site characterization data, emission measurement results, and information necessary to the modeling effort. [dentifying the data need s up front will assist in Quality Ass urance/Quality control (QNQC) by ensuring that all infonnation needed for sub sequent data interpretation and di spersion modeling efforts will be co llected in a consistent manner and transferred accurately to project fil es. Us ing hand-held fi e ld computers with pre-formatted electronic data forms will eliminate the errors associated with hand-written forms , while helping to guarantee that data collection will be complete and consistent. Task 2.3: Equipment Acquisition and Sampling Logistics Some equipment will have to be either leas ed or purchased for the point so urce surveying effort . Most of this will be sampling support equipment such as calibration gases, gas regul ators , 5 Professional Services Contract Page 24 of 32 Fort Worth Natural Gas Air Quality Study -Eastern Research Group, Inc data Joggers , and data storage media. Due to sometimes lengthy delivery times, it is essential that acquisition of this equipment begin well in advance of the scheduled field start date so that there are no delays due to equipment shortages or long delivery times . This task covers only the labor needed to select and order sampling equipment and supplies. It does not include any equipment purchase or leasing expenses. In addition to equipment acquisition, a myriad of support issues will have to be resolved prior to the project startup in order for the field activities to proceed smoothly and without delays. Examples include: • Selection of a field support office; • Creation of monitoring grids and sampling schedules for each point source team; • Assignment of sampling task responsibilities ; • Establishment of standard operating procedures ; • Standardization of data archival protocols; and • Communication and coordination between sampling teams. Work on resolving these issues well in advance of the field testing is necessary and important to a smooth on-time start and to efficient field operations . Task 2. 4: Development of a Point Source Test Plan The development of the point source section of the Project Test Plan will be a critical project element, and extensive time, thought, discussion, and peer review will go into it. In carrying out this task, the following point source issues will be defined: • • • • Scope of Work -Identification of the point source sites to be surveyed for emissions with the IR Camera and the development of a sampling matrix defining the proposed emission rate measurements, screening measurements, and canister sampling activities. Quality Control activities -a discussion of the various procedures that will be used to define the quality of the collected point source data and field measurements . Sample Analysis -a description of the analytical methods to be used by TestAmerica in the analyses of the point source canister samples. Point Source Testing Schedule - a detailed time line indicating proposed site visit dates for the duration of the project. 6 OFFICIAL RECORD CITY SECRETARY FT. WORTH , TX Professional Services Contract Page 25 of 32 Fort Worth Natural Gas Air Quality Study -Eastern Research Group, Inc • Reporting -a discussion of the point source e lements to be included in the draft report with an anticip ated sch edule for the submission of the final report. Two single day trips to Fort Worth are included in this task. These may be needed, for example, to meet with City staff to refine the project scope, discuss efficient sampling strategies, or to work out project logistics. 4.0 TASKJ -COMMUNICATlON AND OUTREACH Thi s task involves the development of a memo presenting proposals for the City to consider in developing a formal community outreach and communications plan. To build trust within the community that this project will meet the committee's objectives, address the concerns oflhe citizens of Fort Worth, and be conducted in a scientifically defensible fashion, up-front outreach efforts are critical. Under this task, ERG will present options and make specific recommendations as to how these goals may be achieved. It is anticipated that the formal community outreach and communications plan will be developed under the primary contract. 5.0 TIMELINE The proposed schedule for this project is shown in Table 1 below. The dates for final products are projected based on the Fort Worth review and approval of the associated draft deliverable within 3 days of receipt. If situations arise su ch that Fort Worth review takes longer than indicated, subsequent project milestone dates will have to be re-evaluated to ensure they can still be met. As necessary, ERG will propose revised milestone dates . Table 1. Projected Deliverable Schedule for Fort Worth Natural Gas Air Quality Study Planning Milestones Planned Date• Task 1-Ambient Air Monitoring Network Design 1.1 : Draft Ambient Air Monitoring Network De sign for Fort Worth approval August 9, 2010 1.2 : Final Ambient Air Monitoring Network Design August 16, 2010 1.3: Draft QAPP for Fort Worth approval August 9, 2010 7 Professional Services Contract Page 26 of 32 Fort Worth Natural Gas Air Quality Study -Eastern Research Group , Inc 1.4 : Final QAPP August 16, 20 10 Task 2 -Point Source Testing Plan Development 2.1: Draft Point Source Lis ting Augusi 9, 20 10 2.2 : Final Point Source Listing August 16, 2010 2.3: Draft Data Coll ecti on Form s August 2, 2010 2.4 Fi n al Da ta Collection Forms Augus t 9, 20 10 2.5 Point So urce Testing Equipment List August 2, 2010 2.6 Draft Point So urce Test Plan August 2, 2010 2.7 Final Point Source Test Plan Aug ust 9, 2010 Task 3 -Co mmunication and Outreach 3.1: Draft Communication and Outreach Memo August 2, 2010 3.2 : Final Communication and Outreach Memo Augu~t 9, 20 10 'Submittal of final deliverables under Tasks 1.2, 2.2, 2.4, 2.7, and 3.2 is based upon receipt of City 's comments within 3 days of receipt of associated draft deliverable. 6.0 COST ESTIMATE This section of the work plan presents the cost estim ate to complete the Natural Gas Air Quality Study Planning. Table 2 provides a breakdown of lab or costs for the project on a task- by-task basis . Table 3 shows the staff proposed for the project and an estimate of their t otal hours on the project. Table 2. Estimated Costs to Perform Fort Wol'th Natuml Gas Ail'Quality Study Planning Task 1. Ambi ent Air Monitoring Network Design 2. Point Source Test Plan Development 3. Communication and Outreach TOTAL 8 Professional Services Contract Total Costs HQUnr 255 121 30 406 Dolliu's $26 ,676 $18,388 $4,890 $49,954 OFFICIAL RECORD CITY SECRETARY FT. WORTH , TX Fort Worth Natural Gas Air Quality Study -Eastern Research Group, Inc Table 3. List of Staff Members for Fort Worth Natural Gas Air Quality Study Planning Staff Member Labor CJassiftcation Total Hours Art Bedrosian Consulting Engineer/Scientist 3 Dave Dayton Prinoioal Engineer/Scientist 20 Melita Elmore Principal Engineer/Scientist, 15 Stacie Enoch Associate Engineer/Scientist 5 Karla Faught Associate Engineer/Scientist 48 Katie Ferguson Staff Engineer/Scientist 13 Jamie Hauser Associate Engineer/Scientist 5 Chris Lehman Mid-level Engineer/Scientist 17 Regi Oommen Mid-level Engineer/Scientist 34 Heather Perez Associate .Engineer/Scientist 60 Mike Pring Senior Staff Engineer/Scientist 43 David Ranum Principal Engi11eer/Scientist 84 JodyTisano Staff/Technician Support 10 Stephen Treimel Associate Engineer/Scientist 30 Tom Van Zandt Consulting Engineer/Scientist 4 John Wilhelmi Principal Engineer/Scientist 15 TOTAL 406 9 Professional Services Contract Page 28 of 32 Fort Worth Natural Gas Air Quality Study -Eastern Research Group, Inc - ATTACHMENT B FEE SCHEDULE OFFICIAL RECORD CITY SECRETARY FT. WORTH, TX ATTACHMENT 8. FEE SCHEDULE Prices for professional services rendered under this contract will be as specified in the schedule provided in the following attachment entitled "Eastern Research Group, Inc. and City of Fort Worth Contract Fee Schedule -Air Quality Study, Natural gas Air Quality Study, First Contract" dated July 21 , 2010 and only as consistent with the terms of this contract and subject to the not-to-exceed amount. Professional Services Contract Fort Worth Natural Gas Air Quality Study -Eastern Research Group , Inc OFFICIAL RECORD CITY SECRETARY FT. WORTH , TX Page 29 of 32 Eastern Research Group, Inc and City of Fort Worth Contract F88 Schedule • Air Quality Study Natural Gas Air Quality Study, First Contract July 21 , 2010 This Is a Um• and materlll• (T&M) proposal Prime and subcontract labor wm be lnvok:MI to Ft W.onh at burdenMt hourty rat•, below. Non-labor costs wlll be Invoiced at cost whh no l nd lroct burden&. LABOR Category Consu11ing Eng lnN1'/Sdentlst Principal Eng ineer/Sdentlst Senior Staff Englneet"!Scientlst Mid-level Eng iMer/Sdentist Staff Engineer/Scien1is t Associate Engineer/Sci entist Staff/Technician Sl.4)p(lrt Intern Engine&f/Sdentist Ill.OJI 10-12/31 /10 Rate R-,,,. .. ntattve Personnel or Equtvalent• 201 Art Bedrosian (Sage), Tom Van Zandt (Hicks) 163 Dav e Dayton (ERG), Ray MenHI (ERG), Oint Bur1dio (ERG), John Wil helmi (ERG), Pali& Fle1ds (ERG), David Ranum {Sage), Andrew Poth (Hicks), Melita Elmore (Hicks) 126 Mike Pring (ERG) $ 117 Regi Oommen (ERG), Arney Stackangast {ERG ) Steve Mendenhall (ERG), Chris Lehman (Sage) $ 100 Scott Rnch"' (ERG), Jason Renzaglia (ERG) Katie FMguson {Sage) $ 89 Rajney Williams (ERG), Scott Sholar (ERG), Heather Perez {ERG), Stephen Treimel (ERG), Stacie Enoch (ERG), Jamie. Haus"' (ERG), T,acy Parham (ERG), Karla Faught (ERG i, Jefod McOeland (Hicks) 70 Anita White (ERG}, Jodie Tisano (ERG.}, Matt O'Nelii (1-ick,), Erik Epple (1-icks), PatM Van Zandt (1-icks) 46 Sarah Roystar (E RG) ·ERG team may subS1itute equ ivalent personnel aft8f consultation with the City witho.J t modification to the resulting contrad . NON-LABOR COSTS Provided at cost to Pf lme or subcontractor without burden Professional Services Contract Fort Worth Natural Gas Air Quality Study -Eastern Research Group, Inc Page 30 of 32 Estimate for Task 1: Ambl•nt Monito ring Ne twork O.slgn (ERG) Consulting Englneer/Scien1ist Principal Englneer/Sdent/st Senior Staff Engine8f/Scientist Mid-level Engineer/Scientist Staff Engine81'1Scientist Associate Engineer/Scientist StaffITechnldan Support Intern Engineer/Scientist Total Hours Rate 0 $ 20 $ 43 S 34 $ 0 $ 148 $ 10 $ 0 $ 255 Price 201 $ 163 $ 126 $ 117 $ 100 $ 90 $ 70 $ 46 $ s Est imate f o r Task 2 : Point Source Test Pla n D.w.topment (Sag, and Hick•) Hours Rate Price Consulting Engineer/Scientist 7 $ 201 $ Principal En gineer/Sdentist 84 $ 183 $ Senior Staff Engfleer/Scientist 0 $ 126 $ Mid-level Engineer/Scientist 17 $ 117 $ Staff Englne8f1Sci8fltis1 13 $ 100 $ Associate Englneer/Sc1 en1ist 0 $ 90 $ Staff/Technician Sc..pport 0 $ 70 $ Intern Engin991'/Scientist 0 $ 46 $ Total 12 1 $ Estimate fo r Task 3: Communicat ion and OutrHc h Hours Rate Price Consulting Engineer/Scientist $ 201 $ Principal Engineer/Scientist 30 $ 163 $ Sailor Staff Engineer!Scienist $ 126 s Mid~evel Engineer/Scientist $ 117 $ Staff Engine81'/Scientist $ 100 $ Associate Engineer/Scientist $ 90 $ Statf/T echnldan Sl4)P0rt $ 70 $ $ 46 $ Total 30 s TOTAL COST FOR CONTRACT 1 408 Personnel 3 ,280.00 Oayton-20 5,-418.00 Pri ng-43 3 ,978.00 Oommen-34 13,320.00 Perez-60 , Faught-4B, Enoch-5, Traimel-30 , Hauser-5 700.00 T lsanc> 10 26,676.00 Personn11.f 1,407 Bedrosian (Sage)-3 , Van Zandt (Hlcks)-4 13,692 Ranum (Sage)-84 1,989 Lehman ($age)-17 1,300 Fe,g.ison (Sage)-13 18,388 Personnel "' , 4 ,890 Elmore IHick•)-15, John Wilhelmi (ERG)-15 4,SIIO 49,954.00 • These prices ~n2S. lndude costs for pollution 1iablllty lnsu,ance for th e prime and subconttactors or performance and payment bonds. _._ ....... I t\.- ,;. • .1... .. • .. ~ .... ·l Professional Services Contract Fort Worth Natural Gas Air Quality Study -Eastern Research Group , Inc OFFICIAL RECORD CITY SECRETARY FT. WORTH, TX Page 31 of 32 SIGNATURE PAGE FOR CONTRACT FOR PROFESSIONAL SERVICES CITY OF FORT WORTH NATURAL GAS AIR QUALITY STUDY IN WITNESS THEREOF , the parties hereto have made and executed this Agreement in multiple originals the day and year first above written , in Fort Worth , Tarrant County, Texas . CITY OF FORT WORTH: . Q_ ·-" Fernando Costa Assistant City Manager RECOMMENDED: C Brian Boemer, CHMM, Director APPROVED AS TO FORM AND LEGALITY: a:;t__.11. ;3 ~ Arthur N. Bashor Assistant City Attorney EASTERN RESEARCH GROUP , INC. ~~ Wtness Seal: ®~ GAIL SCHUBERT Notary Publle COMMONWEAi.TH OF MASSACHUSETTS My Comm1u1on lxpt1e1 March 21 , 2014 ~~-c).~35y contract Authorl'zatioa 1f~D}it:i -~ -- Date Page 32 of 32 INSURANCE .. CONTRACTOR COMPLIANCE WITH WORKERS' COMPENSATION LAW Pursuant to V.T.C.A. Labor Code §406 .96 (2000), as amended, Contractor certifies that it provides workers' compensation insurance coverage for all of its employees employed on City of Fort Worth Department of Environmental Management Project DEM 10-05: NGAQS . CONTRACTOR EASTERN RESEARCH GROUP, INC. By ~~ /}1 A 5 SAC l + u. .5 CTT5 STATE OF "ffi:X:A6 § vV'l I I) i) u.;-5 ey § COUNTY OF "fAR~AN T § me , the undersigned authority , on this day personally appeared ....-"""-""'-='---=---.f-'1~~~~~-,1 known to me to be the person whose name is subscribed to the r;rn;~t , and 9-icknowled,9ed to me that he executed the same as the act and V I C<:.... f' res,· d l'AJ r for the purposes and consideration therein expressed and in the capacity therein stated . Given Under My Hand and Seal of Office this c:)1,, day of Jk-' J , 20 / 0 ~~ Public in and for the State of ~ @~ GAIL SCHUBERT Notary Public COMMONWEALTH OF MASSACHUSETTS MY Co1T1ml111on hplres March 21. 2014 Mee ss A.Ju...se.it_j ..... REQUEST FOR QUALi FiCA TIONS '-ERG Eastern Research Group, Inc. PROPOSAL IN RESPONSE TO REQUEST FOR QUALIFICATIONS PACKAGE (RFQ) NO. DEM 10-05: NGAQS AIR QUALITY STUDY Submitted to : City of Fort Worth Department of Environmental Management 1000 Throckmorton Street Fort Worth , TX 76102-6311 Submitted by: Eastern Research Group, Inc. 1600 Perimeter Park Drive , Suite 200 Morrisville , NC 27560 with Sage Environmental Consulting, LP 4611 Bee Caves Road, Suite 100 Austin , TX 78746 June 2 , 2010 .ERG www.erg.com ERG No . 0023 .00 .002 .119 PROPOSAL IN RESPONSE TO REQUEST FOR QUALIFICATIONS PACKAGE (RFQ) NO. OEM 10-05: NGAQS AIR QUALITY STUDY Submitted to : City of Fort Worth Departm ent of Enviro nmental Management 1000 Throckmorto n Stre et Fort Worth , TX 76102-6311 Submitted by: Eastern Research Group Inc. 1600 Perimeter Park Driv e , Su ite 200 Morrisville , NC 27560 with Sage Environmental Consulting , LP 4611 Bee Ca v es Road , S u ite 100 Austin , TX 787 46 June 2 , 2010 'l'iOO ~·irr,tti!1 p~, :it ,t. ', ••• ,'.' ,-,,, ',1'.""i»Hc NC 27550 P~Lt 919 ~63-• 1,., 0d,. ,!~·468·7!\Qi 111 ,1,gl®. VA Af ,,,·~ ::;:. .:..,, ~. "' %StJr '/A Ch,mtih Vil Cl' '.~·;C !L C>.: ' o•,. OH • Mei,hcy, PA Air Quality Study June 2, 2010 CONTENTS Section Page 1.0 QUALIFICATIONS DOCUMENTS 2.0 ACKNOWLEDGEMENT OF RECEIPT OF ADDENDA 3.0 MINORITY AND WOMEN BUSINESS ENTERPRISES (M/WBE) UTILIZATION REQUIREMENTS 4.0 QUALIFICATIONS OF THE PROVIDER ....................................................................... I A. COMPANY INFORMATION .................................................................................... l B. ST A TEMENT OF QUALIFICATIONS .................................................................... 2 B . l Ambient Air Sampling, and Related Laboratory Analysis and QA/QC Ex perience ......................................................................................................... 2 B .2 Point Source and Equipment Emissions Testing, and Related Laboratory Analysis and QA/QC Experience ..................................................................... 4 B.3 Clean Air Act Ex perience Related to Natural Gas Production ......................... 5 B.4 Dispersion Modeling Experience ...................................................................... 5 B .5 Project Organization and Management ............................................................. 8 B .6 Personnel Qualifications ................................................................................. 11 B.7 Laboratories and Accreditations ..................................................................... 15 B.8 Disclosures ...................................................................................................... 15 C. SCOPE OF SERVICES: METHODOLOGY AND WORK PLAN ......................... 16 Task A: Measure and Analyze Emissions ................................................................ 17 Task B: Conduct Dispersion Modeling ..................................................................... 21 Task C: Conduct Ambient Sampling ........................................................................ 22 Task D: Develop Communication Plan .................................................................... 24 5 .0 LIST OF SUBCONTRACTORS 6 .0 INSURANCE CERTIFICATES 7 .0 PROVIDER 'S LICENSES AND CERTIFICATES 8 .0 NONDJSCRIMINA TION 9 .0 CONFLICT OF INTEREST AFFIDAVIT ATTACHMENT A: KEY STAFF RESUMES A TT A CHM ENT B: SAMPLE DOCUMENTS Air Quality Study June 2, 2010 CONTENTS (Continued) Tables Page l Selected Ambient Air Sampling, and Related Laboratory Analysis and QA/QC Experience 3 2 Selected Point Source and Equipment Emissions Testing, and Related Laboratory Analysis and QA/QC Experience ............................................................................................ 6 3 Selected Clean Air Act Natural Gas Production Experience ................................................... 7 4 Selected Dispersion Modeling Experience .............................................................................. 9 5 Summary of ERG Team Key Personnel Qualifications ........................................................ 11 6 Project Milestones and Planned Schedule ............................................................................. 18 7 Example Point Source Sample Matrix ................................................................................... 20 Figures Page ERG Team Project Organization ........................................................................................... 10 II 1.0 QUALIFICATIONS DOCUMENTS QUALIFICATIONS DOCUMENT CHECKLIST All Qualifications Documents, including this Checklist. must. be completed in full and submitted in a s~aled envelope, in the requested order, or the Qualifications Package may be consider-ed as a non-"responsive submittal. Qualifications Documents Initial if Included 1 . 2 . 3 . 4 . 5 . 6 . 7. 8 . 9 . QUALIFICATIONS DOCUMENT CHECKLIST ACKNOWLEDGEMENT OF RECEIPT OF ADDENDA MINORITY and WOMEN BUSINESS ENTERPRISES QUALIF I CATIONS OF PROVIDER LIST OF SUBCONTRACTO RS 1NSURANCE CERTIFICATES PROVIDER 'S LICENSES & CERTIFICATES NONDISCRIMINATION CONFLICT OF INTEREST AFFADAVIT f1r I understand that failure to submit all of these items may cause my submittal to be conslderec! non-responsive . Name Title Paula G. Fields Principal Engineer Company __ ...;E=a=ste=· m'-'-'--'-R=e=se=arc==-h'-'G=r-=o=up=· =ln=~"-'(=E"--'R=G"-) _ 2.0 ACKNOWLEDGEMENT OF RECEIPT OF ADDENDA 2.2.1 Check if applicable _X_ The undersigned acknowledges the rece ipt of the following addendum (a} to the Request for Qualifications , and has attached all addenda following this page. (Add lines if necessary}. Addendum Number 1 ____ -=5/-'-14/..:.:....:..:10=------ (Date received) Addendum Number 2 ________ 5=/2=5/=-1.:..::0C.J(.:..::re=v..:..:. 5/2=-=·=6/:.:...1:..=0CL.) _ (Date received) _ Addendum Number3 ___________ _ (Date received) Addendum Number4 ___________ _ (Date rece lved ) 2.2.2 Check if applicable_ The unders igned acknowledges the receipt of no addenda to the Request for Qualifications. PROVIDER: Eastern Research Group, Inc. Company Name 8950 Cal Center Dr.. #348 Address Sacramento, CA 95826 City, State , Zip BY: Paula G. Fields (print or type name of signatory) ~~.~ {Signature Principal Eng ineer Tille (print or type) 3.0 MINORITY AND WOMEN BUSINESS ENTERPRISE (MIWBE) UTILIZATION REQUIREMENTS An M/WBE goal of 10% has been established for this project. The Provider sha ll make a good faith effort to sub-consult with or purchase suppli es from M/WBE firm s . The Prov i der must meet or e xc eed th e stated goat or submit documentation of a good faith effort for all appll cable contracts to permit a determination of compliance with the specificati ons. Beca use this is a Request for Qualifications for professional seivices defined In Chapter 2254 of th e Texas Government Code, the Provide r's initi al response to t he Request for Qualifications shall not include a response to the req ui rements of the C ity's M/WBE ordinance . The C ity shall rank the Provi der on the b asis of demo nstrated competence and qualificati ons. During contract negotiations , t he Provi der shall respond to this ordinance in the m anner specified below: (1) An M/WBE Utilization Plan, hereinafter referred to as the utilization plan , must be submitted. The utilization plan must detail the steps taken to ach ieve M/WBE participation in c lu ding but not limited to firm s contacted, type of work d iscussed , crite ri a for sub-contractor selection , etc. The utilization plan must address each subcontracting opportunity avail ab le that m ay in c lu de professi onal s e ivices, subsurface drilling/boring , courier serv ice , outside printin g, equ ipm ent suppliers , etc. (2) The utilizati on plan mu st a l so i nclude the point of contact (i ncluding name and title) that will be designated as respons ible for imp lementing the utilizatio n plan . reporting on the statu s of utilization plan (monthly and a nnua lly), and performing lia ison duties t o the City as it relates t o all M/WBE issues during the contract term . (3) The Provid er may utilize a joint venture arrangement with an MIWBE firm . In a joint v enture , th e Provid e r may count the M/WBE portion of t he joint venture t oward meet ing the utilization plan commitment (L e., proposed goal is 40% and j oi nt venture is 20% then separate M/WBE must be use d f or the remaining 20% n ot for the entire 40%). If a j oint venture is proposed , the Joint Venture E li g i bility Form must be completed and submitted. (4) All M/WBE firm s must be currently certified or i n the process of bein g ce rtified by the North Central Texas Reg ional Certification Agency (NCTRCA), or Texas Department of T ransportati on (TI<Don. Highway Division a nd located in the nine county marketplace . For th e purpose of determ i ning contract compliance under the M/WBE ordinance , busi nesses list ed as MBE or W BE within the utilization pl an must be certifi ed as such prior to a recommendation for award being made to the City Counci l. If during the course of work un der the contract a change of any of the MBE or WBE firm s id en tifi ed in the orig i nal utilization plan is needed th en a Change Requ est mu st be submitted t o the C ity of Fort W orth -M/WBE Office a nd the change approved by same. (5) All subcontracting and supplier opportunities directly attributed to this Contract from M/WBE firms , inclusive of 1st, 2nd , 3rd tiers , etc. s ub-co ntractors and suppliers may be included in the util ization plan commitment. It is the sole respons ibility of the Provider to report and document all M/WBE participation dollars irrespective of t ier leveL The Provider will be given credit toward the M/WBE plan when the M/WBE performs a commercially useful functi on . The successful Provider will be requ ired to submit executed contractual agreements (i.e., Master Serv ice Agreements) or letters of intent prior to receiving the Contract Documents. ·--------------------.. -----.... ·-·-··---.............................. ____ .. ______ _ The undersig ned acknowledges the City's M/WBE requirements as stated above , and if selected as the most highly qualified provider, wJII comply with the requ irement to submit a utilization plan during contract negotiations. PROVIDER: Eastern Research Group, Inc. Company Name 8950 Cal Center Dr,, #348 Address Sacramento. CA 95826 City. State, Zip BY: Paula G. Fields (print or type name of signatory) (~~.~ (Signaiu Principal Engineer Title (print or type) Air Quality Study June 2, 2010 4.0 QUALIFICATIONS OF THE PROVIDER A. COMPANY INFORMATION This proposal is submitted by the team of Eastern Research Group , Inc . (ERG) and Sage Environmental Consulting, LP (Sage). Addresses and contact information follow: Headquarters: Key Contact 110 Hartwell Ave., Lexington, MA 02421 Person: "-ERG Key Contributing Offices: Mike Pring • 3508 Far West Blvd ., Suite 210, Austin, TX 78731 Project Manager • 1600 Perimeter Park Dr., Suite 200, Morrisville, NC 919-468-7840 27560 Mike.Pring@,erg.co • 8950 Cal Center Dr., Suite 348, Sacramento , CA 95826 m Headquarters: Key Contact 720 W. Arapaho Road , Richardson, TX 75080 Person: Key Contributing Offices: David Ranum SAGE •4611 Bee Caves Rd., Suite 100, Austin , TX 78746 Senior Technical C"VllllOfrt.l"NT,\1,. Cotl.vl.nl'KI "~~._"'•.fwJ,ruul" • 12727 Featherwood Dr., Suite 210, Houston , TX 77034 Specialist • 1401 South County Rd. 1140, Midland, TX 79706 512-327-0288 davi dr@sagee nviro nmental. com ERG is a Massachusetts Corporation that provides environmental , engineering, economic, and laboratory services to primarily federal , state, and local government agencies. ERG 's clients include: the U.S. Environmental Protection Agency (U.S. EPA); and the Departments of Labor and Department of Energy. We work for many state and local air agencies, including the states of Texas, Louisiana, and Arkansas; and organizations in Houston, Austin , Sacramento, and elsewhere. Our clients also include regional organizations such as the Western Regional Air Partnership (WRAP), and the Western Climate Initiative (WCI). ERG has extensive knowledge of the natural gas exploration and production industry from our regulatory development, air toxics, and air permitting projects for government agencies. We have performed air quality studies comprising all of the elements involved in the City of Fort Worth 's (City's) natural gas air quality study (NGAQS): source sampling and characterization, dispersion modeling, emissions estimating , ambient air sampling, laboratory analyses, and health risk assessments. Sage Environmental Consulting, L.P. (Sage) is an environmental engineering and consulting company with expertise in regulatory compliance and permitting. Sage provides services across a wide spectrum of environmental programs and media such as air quality , hazardous and solid waste, water quality , hazardous materials, and petroleum storage activities. While Sage provides a broad range of services, its specialty is the air quality aspects of heavy process industries especially petroleum refining , chemical manufacturing, and upstream and midstream oil and gas operations. As a subcontractor, Sage will evaluate point source and equipment emissions generated from natural gas facilities in Fort Worth. Sage will provide input to all tasks related to source testing and analysis , and may assist with dispersion modeling of selected sites. Also, ERG has identified a properly accredited and highly qualified Minority/Woman Owned Business Enterprise (M/WBE), with an office in Fort Worth , and with whom Sage has a strong working relationship in the areas of source sampling and public outreach. We will quickly add ~RG Air Quality Study June 2, 2010 them to our team during negotiations and commit no less than 10% of the project budget to their efforts, anticipated to be in the source sampling and communications planning areas . 8. STATEMENT OF QUALi FiCA TIONS The ERG/Sage team collectively has the best technical and communications skills to successfully plan and implement the NGAQS for the City: • Availability -We are strong in numbers and deep in experience. Our key staff are available to kick off the project and begin source testing in August. • Natural gas sector experience -We are experienced in characterizing, sampling, and modeling emissions from the range of gas field sources . Our staff work within these indu stries on behalf of regulators , including those located within the Barnett Shale. We have demonstrated our abilities to communicate effectively under these conditions . • No conflict of interest -As a company , ERG does not conduct any environmental , regulatory , or permit application support work for private industrial companies. While Sage does have direct industry experience, natural gas producers represent less than 5% of Sage revenues over the last three years. The ERG/Sage team has the ability to objectively perform the project activities while holding the best interests of the City and its citizens paramount. • Reputation for high quality and technical knowledge -Just ask our clients! We regularly work for federal , state, local , and regional government agencies to address a wide range of air quality issues. Our technical skills have earned us a reputation for meeting technical challenges, producing high quality reports , and delivering on time and within budgets. Most of our clients are repeat customers. The remainder of this section describes the qualifications of our team within the main areas necessary for this project: ambient sampling, emissions testing, dispersion modeling, and communications/outreach. This experience is all primarily focused on air toxics emissions emitted by the gas or related industries. 8.1 Ambient Air Sampling, and Related Laboratory Analysis and QA/QC Experience The ERG team supports clients' measurements and monitoring programs from design and planning, through execution , to the interpretation and effective presentation of results. Table 1 presents selected examples of past experience of ERG in the area of ambient air sampling of toxic pollutants and related laboratory analyses and QA/QC activities. Our team includes chemists, environmental scientists, mechanical engineers , and highly trained technicians. We have designed , managed , and operated national monitoring networks , and prepared associated technical assistance documents for the U.S. EPA. We provide a tum-key approach to network design beginning with the determination of data quality objectives (DQOs) continuing through to data characterization and reporting. For more than 20 years, the ERG team has sampled and analyzed millions of hazardous air pollutant measurement records for federal , state, local, and tribal agency clients. As the prime contractor for U.S. EPA 's Urban Air Toxics Monitoring Program (UATMP), ERG staff gained unparalleled experience in collecting, analyzing, and characterizing air toxics measurements. 2 ~ Table 1. Selected Ambient Air Sampling, and Related Laboratory Analysis and QA/QC Experience ;;ti .--------------------~----~ G1 Client Contact, Value, Pro.iect Scope National Monitoring Programs (ERG). ERG is the prime contractor for U.S. EPA 's National Monitoring Programs, a position held since the contract 's inception in 1984. Over the last 26 years, ERG staff ha ve supported U.S . EPA, state , local , and tribal agencies in network de sign , s iting , methods de ve lopment, sampling, analysi s, and reporting of air toxics . Major program s include : the Urban Air Toxics Monitoring Program (UATMP); Non-Methane Organic Compound s (NMOC); Speciated NMOC (SNMOC); National Air Tox ics Trends Sites (NA ITS); Community-Scale Air Toxics Ambient Monitoring Program (CSA TAMP); and the Photochemical Assessment Monitoring Stations (P AMS) support. In total , several hundred monitoring sites across the country have participated in these programs. In the last five years, U.S. EPA has used this contract for emergency response/time-sensitive applications for U.S. EPA, federal , and state/lo cal/tribal agencies, such as for monitoring after Hurricane Katrina. ERG is supporting U .S. EPA in its School Air Toxics Monitoring Initiative, a program designed to address whether children at schools are being disproportionatel y impacted from air toxic emission sources from nearby large manufacturing facilities. Currently, ERG is assisting U.S. EPA and affected states in analyzing air toxic samples in response to a recent oil spill in the Gulf of Mexico . Agency for Toxic Substances and Disease Registry (ATSDR). ERG is the prime contractor for ATSDR's air monitoring programs in a wide range of technical , scientific, and logistical areas of expo s ure a s sessment, toxicological evaluation s, public health evaluations, community outreach activities, training support, and other scientific evaluations . ERG has provided assistance to ATSDR in all phases of planning and implementing ex posure investigation environme ntal monitoring programs resulting in the design of efficient and representative ambient air monitoring approaches. Sampling ofVOCs; carbonyl compounds ; TSP mass ; TSP trace metals; continuous PM 10 and PM25 ; and continuous S02, H2S, and/or NH3 to support agenc y ex posure investigation efforts have occurred in several locations around the country for intensive 2-3 month studies. Stationary Sources Audit Program. Under this project, ERG manages the development and distribution of QA performance evaluation and audit samples to states and regions for use in stationary source compliance test evaluation projects. Al so under this project, ERG staff have developed and improved sampling and analy sis methods for toxic compounds on U.S. EPA 's high priority list of 33 to x ic chemical s. Location, Period of Performance (POP) Mike Jones , U.S. EPA (919) 541-0528 Value: $18 ,629 ,589 POP : 4/2009-9/2013 Debra Gable , A TSDR (404) 498-0489 Va lue : $8 ,965 ,843 POP: 8/2005-8/2010 Jeffrey Curry, U.S. EPA (919) 541-4018 Value : $500 ,000 POP: 12/2005-9/2010 c.... § Cl) .N N 0 ..... 0 Air Quality Study June 2, 2010 This experience has been critical in responding to emergency response/time-sensitive applications for federal and state/local/tribal agencies, such as for monitoring after Hurricane Katrina. Within one month of this devastating hurricane, ERG helped U.S. EPA , federal, and affected state agencies design and implement a monitoring network of over 30 sites to address potential health impacts during cleanup and recovery. ERG is currently assisting the U.S. EPA and affected states in analyzing air toxic samples in response to the oil spill in the Gulf of Mexico. ERG has also supported the Agency for Toxic Substances and Disease Registry (A TSDR) air monitoring programs in a wide range of technical , scientific, and logistical areas of exposure assessment, toxicological evaluations, public health evaluations, community outreach activities, training support, and other scientific evaluations. Currently , ERG is supporting U.S. EPA in its School Air Toxics Monitoring Initiative, a program designed to address whether children at schools are being disproportionately impacted by air toxic emissions from nearby manufacturing facilities. For this program, ERG collects and analyzes selected air toxics for 59 schools, participates in stakeholder's meetings, and prepares technical reports on the measurements, meteorology, and sources of interest. 8.2 Point Source and Equipment Emissions Testing, and Related Laboratory Analysis and QA/QC Experience ERG team member Sage offers technical expertise in the use of gas monitoring equipment for the implementation of point source sampling programs. Sage understands oil and gas regulations, has exceptional sampling and monitoring capacity and experience, and a hands-on knowledge of the industry. To characterize emissions from natural gas facilities and equipment, Sage provides: • [nfrared (IR) cameras to help quickly identify major leaks; • Toxic vapor analyzers (TV As) to provide direct concentration measurements; and • Hi Flow samplers to provide direct on-site emission rate measurements. Sage's experience related to oil and gas exploration and gas production has been in the major producing regions of Texas, Louisiana, New Mexico, Colorado, Wyoming, and Montana. Over 20% of Sage's historic and current workload has involved the measurement of benzene emissions, and another 20% has involved measurement of fugitive emissions. For the City of Corinth, Texas, Sage provided technical support to help the environmental staff understand the TCEQ Effects Screening Levels (ESLs) and how they could impact residents near gas well drilling operations. Sage's expertise with air quality sampling and monitoring spans a period of 40 years. A few examples of Sage staffs relevant sampling and monitoring experience follows: • Sampling to support natural gas plant emission factor development; • Sampling of wellhead emissions from steam enhanced secondary recovery operations; • Design and installation of a vapor well monitoring system; • [mplementation and management of a natural gas plant fugitive emission program ; • Set up and operation of LOAR program for a West Virginia gas plant; • Compound specific sampling methods using gas chromatographs; • Ambient and source level sampling using FTlR (Fourier Transform Infra-Red) analyses; • Numerous gas canister sampling programs in ambient and source level applications ; and • Gas plant facility emissions surveys using the [R cameras and TVA 10008 analyzers. 4 Air Quality Study June 2, 2010 • Evaluation of the IR camera as a fugitive leak detector in a Texas refinery. • Sampling to measure mass emissions from barges in transport. • Design of sampling methods and led the sampling field work for the 14 refinery Characteriz ation of Atmospheric Emiss ions.from P e troleum Refineries , which developed the prototype for U.S. EPA Method 21 and the format for the fugitive emissions correlation equations and emission factors used today. Table 2 presents selected examples of Sage 's past experience with oil and gas issues , including data reporting , data management system preparation , sampling, and several other pertinent types of projects for various facilities. Analysis of samples collected by Sage will be conducted by TestAmerica, Austin Laboratory. Information on TestAmerica is provided in Section B.7 , below. 8.3 Clean Air Act Experience Related to Natural Gas Production The ERG team has supported federal , state, and local air pollution control agencies in implementing the provisions of the Clean Air Act (CAA) for over 28 years. Our experience in this area includes directly supporting the U.S. EPA in implementing Title I of the CAA by developing New Source Performance Standards (NSPS) and National Emission Standards for Hazardous Air Pollutants (NESHAP), by compiling the National Emissions Inventory (NEI) and the urban air toxics inventories required by Sections l 12(k) and 112(c)(6), and by developing county-specific air to x ics hot spot emission inventories under the National Air Toxics Assessment (NA TA) program. ERG has worked with numerous state and local agencies in implementing the permitting provisions of Title I (New Source Review) and Title V (Operating Permits) of the CAA in issuing over 1,700 air quality permits, many of which were for natural gas exploration , production , and processing facilities. In addition , team member Sage, has relevant experience in natural gas production federal regulatory issues. For example, Sage performed a SIP and nonattainment evaluation study for sulfur dio x ide (S02) in Oklahoma. The project required compiling the emissions inventory and performing dispersion modeling to successfully avoid a proposed S02 nonattainment designation request by U.S. EPA. Also , Sage has performed numerous permitting projects for oil and gas companies. Table 3 presents several relevant examples of projects performed by the ERG team for implementing provisions of the CAA for natural gas production sources. 8.4 Dispersion Modeling Experience The ERG team includes expert meteorologists , engineers, and computer scientists who employ state-of-the-art modeling procedures for complex, unique air pollution situations including atmospheric photochemical reactions , health effects evaluations, hazardous pollutant releases , and complex meteorological phenomena. With more than 30 years of combined expert dispersion modeling experience, ERG staff have conducted numerous studies of source impacts in complex terrain , shoreline environments, and other areas where complicated dispersion situations can be expected. ERG modeling staff have also developed computer programs and procedures for processing large amounts of raw meteorological data in support of dispersion -.ERG 5 Table 2. Selected Point Source and Equipment Emissions Testing, and Related Laboratory Analysis and QA/QC Experience Project Scope Oil and Gas Technical Support/or the City of Corinth TX (Sage). Sage personnel provided technical support to help the environmental staff to better understand the air quality implications of the TCEQ Effects Screening Levels and how they could impact residents near gas well drilling operations. Sage also prepared SCREEN modeling to calculate from known emission rates of benzene the ground level concentrations that could be expected at residential areas. This information was provided to the city staff so they could better inform their City Council. Infrared Imaging SEP (Sage). Sage staff performed a two part study using the infrared camera to detect refinery process equipment leaks in Port Arthur, TX . ln the first part of the study all regularly monitored components in the refinery LOAR program were surveyed with the camera. 1n the second part, equipment outside of the LOAR program was surveyed for leak emissions. The study took 9 months to complete and resulted in the development of several practical camera screening methodologies and produced informative conclusions regarding number of components that could be effectively surveyed by the camera on a daily basis. The study also looked at the effect of environmental factors such as wind, cloud cover, ambient temperature, % relative humidity, barometric pressure, and types of imaging backgrounds on imaging quality. IR Camera Survey at Natural Gas Liquid Separator Plant (Sage). Sage recently completed an infrared camera survey of a liquid separator plant operated by Enterprise Products, in response to odor complaints from a nearby neighbor. The survey was conducted by David Ranum and included all equipment at the 400 million scfm facility . Several emission points were detected with the camera by Mr. Ranum . Measurement and Modeling of BTEX Emissions from Glycol Dehydrators for Gas Research Institute (Sage). Sage staff led a project to develop new test methods for the measurement of benzene/toluene/ethylbenzene/xy lene (BTEX) emissions from glycol dehydrators. Assisted in the development of the program with the GRI advisory review committee. Several methods were tested in trials and the most favorable , (i.e ., is the easiest to use and most accurate) methods were further refined through extensive field testing. The final methods were documented through the ASTM method development process. Client Contact, Value, Location, Period of Performance (POP) Bruce Hanson, City of Corinth (940) 321-1484 Value :$ 10 ,000 POP : 4/20 I 0-5 /20 l 0 Jannetta Bowden Ned, Total Petrochemicals USA. ( 409) 963-6972 Value : $800 ,000 POP: 09 /2007-10/2008 Farah Ullah, Enterprise Products (713) 381 -6500 Value : $4 ,000 POP: 3/2010 Gas Research Institute (GRI) Value : $100,000 POP: 1992 '-§ CD ,"-> I\.) C ...... C Table 3. Selected Clean Air Act Natural Gas Production Experience Client Contact, Value, Location, Period of Proiect Scope Performance (POP) Texas Upstream Oil and Gas Emissions Inventory (ERG). ERG is developing a state-wide Greg Lauderdale, TCEQ emissions inventory of upstream oil and gas sources associated with the onshore exploration and (512) 239-1433 production of oil and natural gas in Texas. First, we estimated criteria pollutant and HAP Valu e : $338 ,000 (2 contracts) emissions from drilling rig engines . Currently, we are conducting surveys to collect emissions POP : 2/2009-8/2010 data from upstream oil and gas dehydrators , compressor engines, wellheads , oil/gas well completions, pneumatic devices, turbines , storage tanks , equipment leaks , and loading racks. Emissions estimates to include benzene, toluene , ethylbenzene, xylene , and formaldehyde. Indiana Air Permit Review and Preparation Support (ERG). ERG supported the Indiana Duane Van Laningham, IDEM Department of Environmental Management (IDEM) in air permit application reviews and (317) 233-6878 preparation of permits to address application of federal and state requirements . Prepared over Valu e : $9 ,400,000 (2 contracts) 1,400 draft permits for a many industries and emission sources including natural gas compressor POP: 5/2000-12/2008 stations and processing plants , boilers, and reciprocating and internal combustion engines . Alaska Air Permit Technical Assistance (ERG). ERG reviewed permit applications and drafted Debra Dalcher, Alaska Title V Operating permits for 10 facilities (including 6 oil and gas platforms). ERG prepared one Department of Environmental major NSR PSD permit for an oil and gas facility , and three BACT analyses for major NSR Conservation (ADEC) permits for fuel gas souring on oil and gas platforms. Prepared statement of basis and final (907) 269-7562 decisions regarding applicability of state and federal regulations. Developed permit language and Value : $3,225 ,000 (2 Contracts) reporting requirements to ensure compliance with all applicable state and federal air regulations. POP : 5/2006-6/2010 Draft Air Quality Installation/Operating Permits Support (ERG). ERG is reviewing permit Sandra Etzel, Allegheny County applications and drafting Minor Source Operating permits for over 150 individual sources, Health Department (ACHD) including several natural gas compressor stations. ERG conducted on-site inspections of each (412) 578-8116 facility to confirm compliance with all applicable provisions of the Clean Air Act, and to obtain Valu e : $1 ,000,000 the data needed to prepare the emissions inventory. Conducted completeness reviews and POP: 4/2008-6/2010 prepared letters to the source to collect information not obtained durimz the site visit. Permit Preparation for the Navajo Nation (ERG). ERG staff prepared seven Title V Permits for Charlene Nelson , Navajo Nation the Navajo Nation EPA including four El Paso Natural Gas Company Compressor Stations, the (928) 729-4247 APS Four Corners Steam Electric Station (FCSES), the SRP Navajo Generating Station (NGS), Value: $93 ,000 (3 Contracts) and the Peabody Western Coal Company Black Mesa Complex. POP: 9/2006 -3 /2009 c... § CD .N N C .... C Air Quality Study June 2, 2010 modeling efforts . We also have extensively worked to develop, enhance, and apply air dispersion models and modeling techniques to solve a multitude of air quality issues throughout the U.S., as well as in Canada, Australia, Great Britain , Taiwan , Thailand , Azerbaijan , Argentina, Morocco, Qatar, and Saudi Arabia. To demonstrate the range of our capabilities, ERG staff have: • Conducted dispersion modeling compliance assessments for hundreds of facilities throughout the U.S., leading to the approval ofrequired state and federal operating air permits; • Performed deposition and air dispersion modeling in support of several public health assessments , as well as assessments of proprietary diesel fuel additives, hazardous waste incinerators, and trace element emissions by electric utilities ; • Assessed health risks of populations exposed to potentially harmful air emissions; and • Determined optimal site locations and design for new facilities to minimize air quality impacts. The ERG team has experience using many different dispersion models including: AERMOD, ISCST3 , ISCL T3 , [SC-PRIME , CALPUFF, VISCREEN , OZIPM, RPMTI , and RPMJISS. ERG staff have also worked extensively with models specialized for dealing with complex terrain (CTSCREEN , CTDMPLUS), mobile source impacts (CALINE/CAL3QHC), offshore impacts (OCD), and accidental hazardous releases (CHARM). ERG 's expertise in air quality modeling includes modeling wet and dry deposition , visibility and regional haze, emergency response and hazardous chemical releases, atmospheric chemistry, fugitive dust, offshore and coastal dispersion, and long-range transport. Many of our team's modeling activities were in support of national emission standards for hazardous air pollutants (NESHAPs), and state air quality permitting efforts, as well as ambient monitor siting and exposure analyses. The ERG team has performed these modeling projects for a variety of different facility types, including natural gas processing plants , crude oil processing plants, power plants, refineries , and chemical manufacturing plants. Table 4 presents examples of past modeling analyses performed by the ERG team. 8.5 Project Organization and Management ERG 's project management plan is based on strong leadership in our project manager, Mr. Mike Pring, and continual communications within the ERG team and between the team, the City, and stakeholders throughout the contract term. We will convene team calls once every two weeks (at minimum) and stay in close touch with the City . ERG has conducted government agency contracts for nearly 25 years. We have in place the structure of experienced program managers, contract administrators, administrative staff, and accounting systems needed to implement the proposed contract from day one. Two important project considerations are meeting the interim a nd overall deadlines, and ensuring high quality de liverables will be developed through effective monitoring of schedules and quality. Our project organization structure shown in Figure I facilitates effective communication of technical data between the City and ERG , as well as among our Project Manager, Task Leaders and key staff. This integrated approach provides the best combination of project management and technical leadership because we use technical experts in Task Leader roles and a single point-of-contact as our Project Manager. All of these staff have successfully completed similar air quality studies for other clients. Note our commitment to add a properly accredited M/WBE firm to the team , whom we have already identified. 8 Table 4. Selected Dispersion Modeling Experience Project Scope Alaska Air Permit Modeling Assistance (ERG). ERG assisted ADEC by reviewing the source impact modeling analysis for a PSD permit issued for a major crude oil processing facility on the North Slope of Alaska. ERG reviewed the applicant 's AERMOD modeling demonstration to verify that the proposed facility would be in compliance with the Alaska Ambient Air Quality Standards and federal National Ambient Air Quality Standards for NOx, CO, S02, and PM 10. Dispersion Modeling in Support of Indirect Risk Assessments of Hazardous Waste Combustors at Six Industrial Facilities (ERG) ERG staff conducted air dispersion modeling for stack and fugitive sources using ISCST3 in accordance with U .S. EPA's guidance "Human Health Risk Assessment Protocol for Hazardous Waste Combustion Facilities". The air modeling included air concentration of vapors and particulate, wet and dry deposition for particulate, and wet deposition of vapors. Deliverables included ISCST3 input and output files; spreadsheets and software tools used to determine input parameters; and, reports with modeling results and QA/QC findings. Regional Air Quality Modeling for Ras La/fan Industrial City (ERG) ERG staff conducted a regional air quality evaluation and planning for Ras Laffan Industrial City, Qatar, in conjunction with the proposed expansion of a large, liquefied natural gas (LNG) plant. As well as other subsequent expansions by Qatargas and International Power, activities included performing air dispersion modeling selection, data gathering, and model application, as part of a comprehensive Environmental Assessment (EA). Follow-on activities included a model evaluation study , comparing modeling results obtained with ISCST3 and AERMOD. Independent Third-Party Review of the ASARCO El Paso Smelter, Regulatory Assistance for the Panda Gila River Cogeneration Project (ERG) ERG staff conducted an independent audit of ASARCO Incorporated's air quality analysis performed in support of the renewal ofTCEQ Air Permit 20345 for the El Paso Smelter. Served as an independent expert as part of an Interim Agreed Order between ASARCO and TCEQ. Analysis included evaluating modeling techniques using the AERMOD dispersion model, emission and meteorological data development , and interpretation of results. Compounds consisted of criteria pollutants (S02, PM10, NOx, CO), and air toxic emissions subject to TCEQ Effects Screening Levels (ESLs). Client Contact, Value, Location, Period of Performance (POP) Debra Dalcher, ADEC (907) 269-7562 Value : $35 ,000 POP : 4/2008-10/2008 Dr. Laurie C. Haws, TCEQ (UT /CEER as Prime) (512) 239-1789 Value : $48,400.00 POP: 11/2002-9/2003 Mr. Michael Snakard, URS (713) 299-9149 Value : $46 ,000 POP: 08 /2002-05/2005 Robert Opiela, TCEQ (Radian/URS as Prime) (512) 239-1147 Value: $15,000 POP: 01/2007-06/2007 § Cl> _"-> I\.) 0 ..... 0 Figure 1. ERG Team Project Organization FORT WORTH ~ Mike Pring (ERG) ERG Project Manager, M/WBE Monitor Clint Burk/in, PE (ERG) Regi Oommen (ERG) Senior Peer Reviewer QA/QC Coordinator ,. ' ,, ,, 0 David Ranum (Sage) Arney Srackengast (ERG) Dave Dayton (ERG) John Wilhelmi (ERG) Task A Lead: Measure and Task B Lead: Task C Lead: TaskD Lead: Analyze Emissions Dispersion Modeling Ambient Sampling Communication Plan -t Key Support Staff: Key Support Staff: Key Support Staff: Art Bedrosian (Sage) Art Bedrosian (Sage) Ray Merrill , Ph.D . (ERG) Jennifer Parras (Sage) Scott Fincher (ERG) Regi Oommen (ERG) Harish Badrinarayanan (Sage) ' ' ' • ' I !-------------------------------j~~~M/~WB~E~Fi~rm~~~l-------------------------------j § (l) _I\) I\) C) ..... C) Air Quality Study June 2, 2010 8.6 Personnel Qualifications Table 5 summarizes the credentials and key areas of expertise for the key ERG team members. Short biographies for each key staff follow below, and I-page resumes are in Attachment A. Table 5. Summary of ERG Team Key Personnel Qualifications Key Areas of Expertise Related to Gas 1, Industry and Air Toxics Studies I' ~ ~ ~ 52 ~ ~ r,J n ~-~ n = r,J "'I Q r,, r,, (JQ Name, Role Degree(s) a = a C. "= ii ~ ;-~ "= = = .... c:r n n r,, r,, _.., Q -· 5' ~-a :ii:-.... "'I -· t') .., n ~-= n -· -· = n (JQ = = .... (JQ ~ = = (JQ (JQ .... r,, Mike Pring, B.S., Environmental • • • Project Manager Engineering Clint Burklin, B.S., Chemical • • • Sr. Peer Reviewer Engineering John Wilhelmi , B.S., M.S., Chemical • • Communications Lead Engineering Arney Srackangast, B.S., Meteorology • • Modeling Lead Regi Oommen, M.S., Atmospheric QA/QC Coordinator Sciences; B.S., • • Meteorology; B.A., Chemistry Scott Fincher, B.S ., Meteorology • • Modeling Support Ray Merrill, Ph.D., Ph.D., Analytical Sr. Advisor Sampling Chemistry; B.S., • Chemistry Dave Dayton, Mechanical Sampling Lead Engineering • David Ranum, M.A., English; A.S., • • • Measurements Lead Electronics Art Bedrosian , B.S., Physics • • • • • Sr. Advisor Measurements Jennifer Parras, B.S., Environmental • • • Measurements Support Engineering Harish Badrinarayanan, M.S., Environmental Measurements Support Engineering; M.B.A.; • • • • B.S., Chemical Engineering ~RG 11 Air Quality Study June 2, 2010 Mike Pring (ERG) is a Senior En v ironmental Engineer specializing in air quality issues , including emissions inventories, Clean Air Act implementation , air to x ics , and regulatory co mpliance. He is the proposed ERG project manager for the City 's NGAQS. As project manager, he will also have the responsibility of ensuring compliance with the M/WBE requirements for the contract. Mr. Pring is supporting on-going efforts of the TCEQ to characterize emissions from upstream oil and gas emissions sources, including drilling engines , compressor engines, dehydrators, wellheads, oil/gas well completions, pneumatic devices, storage tanks , equipment leaks , and loading racks. Mr. Pring has ten years experience supporting state and local air pollution agencies in reviewing permit applications and writing construction and operating permits for oil and gas production sources. He provided technical leadership and overall project management for the preparation of Prevention of Significant Deterioration (PSD), Title V, and Minor Source Air Quality Permits for large offs hore oil and gas ex ploration and production platforms, natural gas compressor stations , and natural gas storage facilities. Mr. Pring has experience with the Toxics Release [nventory (TR£) and the Emergency Planning and Community Right-to-Know Act of 1986 (EPCRA) reporting requirements. Clint Burk/in (ERG) is a Principal Engineer and Vice President with over 35 years of experience characterizing emissions from combustion and fugitive sources, including those within the natural gas industry. He is a licensed Professional Engineer in North Carolina (see Section 7.0 for a copy of his license.) He will be a Senior Peer reviewer of all work products. Most of his work has been in the form of technical assistance to national , state, and local air control agencies, as well as direct technical assistance to electric utilities , energy companies, the Electric Power Research Institute , the American Petroleum lnstitute and the Gas Research Institute. Mr. Burklin's ex perience spans the full range of air pollutants including the criteria pollutants, toxic air pollutants, ozone precursors, and greenhouse gases . Currently, he supports projects for the Western Climate Initiative and the State of New Mexico to develop a GHG reporting protocol for oil and gas ex ploration and gas production facilities. John Wilhelmi (ERG) is a Senior Chemical Engineer and Vice President with 16 years of experience. He will lead the development of the Communications Plan, and provide useful insights related to health risk for this project. Mr. Wilhelmi has devoted his professional career to characterizing releases from industrial facilities , evaluating the fate and transport of these releases , and assessing the human health risks that result from exposures to pollutants in these releases. Mr. Wilhelmi has researched and reviewed the manufacturing processes, unit operations, and pollution control s in a wide range of chemical manufacturing and materials process ing industries, including many related to the production and refining of petroleum products. He has conducted various types of risk assessment: cancer and non-cancer, acute and chronic, and direct and indirect. Also , he has prepared and delivered presentations of ranging technical content at public meetings, scientific conferences, and training courses. Arney Srackangast (ERG) is a Mid-Level Scientist with 24 years experience in managing, performing, and peer reviewing atmospheric modeling studies in support of federal and state air quality evaluations. He will lead the dispersion modeling work for this project. Mr. Srackangast is a recognized expert on the development, applicat ion , and use of atmospheric dispersion models, as well as other air quality topics , including ambient monitoring, emission inventory development and meteorological data processing. Mr. Srackangast routinely interacts with both state and federal regulatory agencies to develop thorough modeling methodologies which yield representative results. Mr . Srackangast has led over 100 air quality analyses in support of various 12 Air Quality Study June 2, 2010 state and federal programs including Prevention of Significant Deterioration (PSD), State Implementation Plans (SIPs), National Emissions Standards for Hazardous Air Pollutants (NESHAPs) and state air quality permitting efforts, as well as ambient monitor siting and exposure analyses (i.e., health risk assessments). Regi Oommen (ERG) is a Senior Scientist and has over 14 years of air quality and emissions inventory experience. He will serve as overall QA/QC manager, and will work closely with the ERG lab on ambient data analysis. Mr. Oommen 's areas of experience include: database development and management; data collection and analysis ; air quality modeling; emissions estimation guidance ; quality assurance/quality control (QA/QC); planning/meeting support; and technical writing. For the last several years, Mr. Oommen has been supporting various oil and natural gas projects for TCEQ and for the Minerals Management Services (MMS) in emissions estimations and data formatting and management for air quality modeling. For TCEQ, Mr. Oommen led efforts to estimate 2005 base year criteria air pollutant emissions from selected exploration activities, such as drilling , degassing , pneumatic pumps, and wellhead completions. For MMS , Mr. Oommen compiled activity data (e.g., fuel usage , fugitive equipment counts, etc.) from thousands of offshore oil and natural gas platforms to estimate air emissions . For the past 14 years , he has supported U.S. EPA 's development of the 1990, 1996, 1999, 2002 , and 2005 National Emissions Inventory (NEI) and the Urban Air Tox ics Monitoring Program. Mr. Oommen was also the lead data analyst for five Agency for Toxic Substances and Disease Registry (ATSDR) E x posure Investigations, which summarized air toxics , criteria pollutants, and harmful sulfur compounds in communities affected by oil and natural gas wells. Scott Fincher (ERG) is a Staff Scientist with 12 years of air quality experience . He will assist with the dispersion modeling work for this project. Mr. Fincher has served as a task leader on a variety of air dispersion modeling projects. He works with environmental agency staff of various states to ensure use of representative modeling methodologies. Mr. Fincher 's areas of experience include dispersion modeling for several petrochemical , pulp and paper, electrical generation , and U.S . military facilities . In addition, he has provided deposition and dispersion modeling in support of indirect risk assessments. He also has experience with the retrieval , analysis, and processing of meteorological data when necessary. In recent years, he has assisted various state agencies with review of dispersion modeling results submitted as part of the permitting process. Ray Merrill, Ph.D. (ERG) is an internationally recognized environmental chemist with over 33 years of experience managing and performing environmental measurements, methods development and evaluation, and QA/QC programs. He is experienced in a broad range of applications chemistry, including routine chemical analysis procedures through complex instrumental analysis , such as optical remote and mobile monitoring. Dr. Merrill is the QA Manager for ERG 's laboratory and manages laboratory quality certification under U.S. EPA 's National Environmental Laboratory Accreditation Conference (NELAC). Dr. Merrill is active in ASTM, NELAC Institute and ISO standard development and consults internationally on environmental laboratory quality issues , good laboratory practice, and application of ISO 25 to environmental laboratories. Dave Dayton (ERG) is a Senior Environmental Engineer with 35 years of experience. He will be the ambient monitoring task lead. Mr. Dayton has been involved with U.S. EPA 's National Monitoring Programs since their inception in 1984, with expertise in field sample collection , sample analysis, and reporting . He developed procedures for analysis of air canister samples to demonstrate the total nonmethane organic compound content of the canisters (now U.S. EPA '-ERG 13 Air Quality Study June 2, 2010 Method T0-12). Mr. Dayton designed and fabricated numerous equipment items, which have become integral to the continued operation of air monitoring networks, such as for U.S . EPA and ATS DR. He was manager of numerous programs involving sampling and analysis, such as a program to provide HAPs monitoring at multiple sites comprising two separate networks in the southern Gulf Coast Region of the country. Mr. Dayton has also served as the Project Director on si x exposure investigations for A TSDR in v olving collection and analysis of samples for VOC , carbonyl compounds, and metals, and continuous monitoring for H2S, NH3, S02, inhalable PM IO, respirable particulate (PM25 ), and meteorology. David Ranum (Sage) is a Senior Technical Specialist with 25 years of experience in environmental consulting. Mr. Ranum will lead the point and equipment source emissions measurements task. His experience includes instrumentation system design, air toxics monitoring, auditing of environmental systems, water monitoring, fugitive emissions monitoring, stack testing using CEMs (Continuous Emission Monitors), design and installation of CEM sy stems and ambient air monitoring using conventional analyzer systems as well as with FTIR (F ourier Transform Infrared Spectroscopy) technologies. Mr. Ranum 's skills include instrumentation operation , maintenance, calibration , and repair , environmental sampling, technical writing, data processing, report writing, project management, and the auditing of ambient air monitoring systems and LDAR (Leak Detection and Repair) programs . He brings to the oil and gas industry many years of data collection experience. Art Bedrosian, QEP (Sage) is a Key Executive Advisor and Client Service Manager with 40 years experience as an air quality professional. He w i ll be an advisor to Sage staff during this project, and will contribute expertise and guidance to the dispersion modeling task . Mr. Bedrosian has provided the overall leadership, scheduling, and QA/QC for hundreds of environmental and engineering projects for almost all types of industries. He has performed compliance audits for oil and gas production facilities both on and off-shore. He has also prepared NSR permit applications for gas processing facilities , refineries , chemical plants , and electric power generating facilities. He has performed atmospheric dispersion modeling for all types of facilities and for mobile sources as well. In addition to NSR, his permitting ex perience includes federal Title V and PSD permits. He has served for the past 15 years on the Board of Directors for the Central Texas Clean Air Force to direct ozone monitoring and compliance efforts. He was selected by Mayor Howard Peak of San Antonio to serve on a small , select blue ribbon panel tasked with the goal of developing San Antonio 's first air quality policy programs . Jennifer Parras (Sage) is a Sage Project Manager with more than 12 years of experience in the oil and gas industry. She will provide technical support for the point and equipment source sampling. Ms. Parras was an environmental manager for Duke Energy Field Services, Midland , TX where she was responsible for environmental compliance of 18 gas plants and 300 compressor stations located in New Mexico and Tex as. She managed all compliance for air quality, water, and waste issues, and was lead auditor for internal corporate environmental audits. For Alnon , she ensured environmental compliance with all state and federal rules and for the implementation and completion of all air compliance issues including permitting, recordkeeping, monitoring, and reporting. She was also responsible for the LOAR program, submitting periodic compliance reports for regulated air emissions, developing compliance of the applicable units for MACT and NSPS regulations, developing and submitting the annual emissions inventory and TRI reports , management of Title V compliance, daily transmission of ~RG 14 Air Quality Study June 2, 2010 reportable emissions to the proper agencies, and environmental guidance on any environmental issues within the process units. Harish Badrinarayanan (Sage) is a Technical Specialist (chemical engineer) who has spent most of the past few years working for Sage on site at upstream and midstream facilities , such as DCP Midstream , Eagle Rock Energy, and BP North America. He will provide technical support for the point and equipment source sampling. He has managed and prepared Excess Emissions and Emission Event reports for natural gas booster stations and gas processing facilities in New Mex ico and Texas. He has managed the preparation of Affirmative Defense (AD) documents in consultation with field personnel and attorneys. Harish has supported preparation of Permit By Rule , Standard Permits, and case-by-case NSR permit applications to accurately permit compressor stations and gas processing plants; calculated emissions from combustion sources , blowdown operations, condensate flashing , miscellaneous VOC storage tanks , truck loading, dehydration units , and fugitive sources. He has prepared emission inventories for natural gas compressor facilities located in the states of Kansas, New Mexico, and Colorado and a natural gas liquid facility in Washington; and prepared annual compliance certifications and semi-annual monitoring reports for facilities in Colorado. B. 7 Laboratories and Accreditations ERG maintains a NELAP-certified laboratory that conforms fully to all associated quality requirements (see Section 7.0 for Texas NELAP certification). ERG 's approach for laboratory analysis is based on more than 26 years experience supporting U.S. EPA 's national monitoring programs. Our laboratory facilities , analytical capacity, and proven approach allows ERG to achieve a sample completeness rate of 95 percent. We analyze these approximate numbers of samples annually for various programs: • Air toxics method TO-l 5A: 3,000 samples • SNMOC: 1,000 samples • Metals (Method [0-3.5): 1,000 samples • Carbonyl compounds (Method T0-1 lA): 3,500 samples • PAHs (Method T0-13A): 1,500 samples • EPA/ERG Hexavalent Chromium: 1,500 samples In addition to ERG 's in-house laboratory for ambient data analysis , Sage will use the services of TestAmerica's Austin laboratory, for analysis of source samples . TestAmerica's Austin laboratory, has provided environmental chemical analyses to government and commercial clients for over 30 years. TestAmerica has 9 state certifications including NELAP certification in Texas (see Section 7.0 for Texas NELAP certification). 8.8 Disclosures For the past three years , ERG has had no current contracts or financial interests with natural gas producers. Sage 's contracts and revenues with natural gas producers covering the last three years are listed in the table below. Note that none of these projects were conducted for work on the Barnett Shale, and the total revenues comprise less than approximately 5% of Sage 's annual 3- year revenues. 15 Air Quality Study June 2, 2010 + . + Sa2eClieot 3-Y ear Revenues Work Product D American Petroleum [nstitute $41 ,641 TRI training Anadarko Petroleum $611 ,677 Auditing program setup DCP Midstream LP General on-site services (e.g., Title V deviation report, $385 ,385 LOAR services, etc.) Eagle Rock Energy Partners, L.P. $297,525 EMIS data entry EGF Energy Partners LLC $23 ,146 TCEQ registrations El Paso Ex ploration and Production Environmental compliance $105 ,656 evaluations Enbridge CAM applicability , emissions $344 ,227 inventories Enerplus Resources Corporation $1 ,883 Air compliance support Enterprise NSPS Kb audit, HRVOC $71 ,617 audit, standard permitting Hardin F uels , Inc. $13 ,645 TCEQ NOV Response Noble Energy, Inc . RMP update , permitting $5 ,811 support Patriot Operating Company, LLC $14 ,194 Initial design PHA Prism Gas $101 ,997 Pipeline removal Questar Market Resources Regulatory review (MACT, $17,783 SSM Plans) Schneider Energy Services Flash emission factor analysis, $15 ,407 SPCCp Stanley Energy, Inc. $4 ,994 Air quality issues support TEC Inc . $10 ,232 Beaver Creek EIS Tennessee Gas Pipeline & Affiliates $32 ,480 GHG data collection U .S. Liquids of LA, LP $11 ,340 SWPPP VexaPak $13 ,498 SPCC-SWPPP plan Western Operating Company Semi-annual monitoring reports , general compliance $8 ,223 assistance Whiting Oil and Gas Corporation $170,734 Regulatory review/assistance Williams Production RMT Co . Water facilities permit, GHG $17,184 emission inventory C. SCOPE OF SERVICES: METHODOLOGY AND WORK PLAN The City of Fort Worth is seeking an independent evaluation of emissions generated from equipment and processes associated with the exploration and production of natural gas. Due to the rapid increase in the number of natural gas wells drilled and producing in the Barnett Shale over the last five years , the citizens of the City have become increasingly concerned that they are being exposed to harmful chemicals emitted from drilling and fracturing equipment used to drill wells and bring them into production , and from the natural gas processing and handling ~RG 16 Air Quality Study June 2, 2010 equipment used to collect the natural gas and prepare it for market. ERG understands the issues the City is dealing with , and is well-prepared to answer these fundamental questions: • What quantity of emissions is coming off of the sites on a volume and mass basis? • Do the sites comply with applicable regulatory limits? • What effect do these emissions have on ambient air quality at the fenceline? • Are the City 's setbacks for wells , tanks , and compressors adequate to protect public health? In order to answer the first question , the ERG team is fully equipped and experienced to conduct point source testing to determine the quantity of emissions emitted from drilling and fracturing operations, from well site equipment (i.e., dehydrators, storage tanks, and leaking pipes and valves), from natural gas processing equipment (i.e ., compressors, dehydrators , and pipelines), and from by-product handling (i.e., Chesapeake 's Brentwood saltwater evaporation and disposal facility). ERG can quantify emissions of any pollutants of concern, but will focus this effort on benzene, methane, ethane, VOC , sulfur-containing organics, formaldehyde , NOx, and PM. Task A, below provides more details on our site-specific sampling methodology. In order to assess if the City 's setback provisions for wells, tanks , and compressors are adequate to protect public health , ERG will conduct ambient monitoring at locations throughout Fort Worth , with an emphasis on sensitive receptor locations such as schools, hospitals, and recreational areas. Ambient monitoring may also be conducted at locations identified as potential "hot spots" as a result of the point source testing task. Additionally, ERG will use the site-specific sampling results to conduct dispersion modeling to determine ambient air quality at the fenceline of potential high emitters. For locations where multiple s ites are in close proximity, the ERG team will include emissions from all nearby sites in making this determination. Task B, below, describes our approach to dispersion modeling, and Task C, below, describes our approach to ambient monitoring. The results of this project will be communicated to the citizens of Fort Worth in language that is easily understandable, and in a format that is easily accessible and visually informative. ERG provides outreach services for many of our clients, and Task D , below, provides a description of how ERG can assist the City in relaying the information gained under this study to its citizenry. Table 6 provides a tentative schedule of planned dates for project milestones. Task A: Measure and Analyze Emissions According to information provided in the pre-qualification meeting on May 20, 20 IO there are approximately 1,650 natural gas well sites and approximately 600 pads of varying size and complex ity containing natural gas processing and transmission equipment within the municipal boundaries of the City of Fort Worth , Texas. Since it is important for public health and safety reasons to identify all sources of emissions associated with natural gas collection and processing, Sage will perform an initial infrared (IR) camera survey at each accessible gas well pad and processing facility operating within the City's 17 Air Quality Study June 2, 2010 Table 6. Project Milestones and Planned Schedule Planned Completion Milestone Date 8 Proiect KickoffMeetin2 and Work Plan 2na Week in August Task A -Measure and Analyze Point Source Emissions A. I: Identification of well pads and pipelines within the City August 13 , 2010 A.2: Commence IR screening of well pads and pipelines Augu st 16 , 2010 A.3: Commence point source testing based on results of IR screening August 30, 2010 A.4: Preparation of point source emissions report December 30, 2010 Task B -Conduct Dispersion Modelin2 b 8.1: Complete facility plot plan review November 26, 2010 B.2: Complete valuation of source locations and release parameters November 26, 2010 B.3: Complete review of receptor placement and classification November 26 , 2010 B.4: Meteorological data analysis (if necessary) December 30, 2010 B.5: Model execution and review of results January 28 , 2011 B.6: Preparation of dispersion modeling report February 25, 2011 Task C -Conduct Ambient Samplin2 c C.1: Network design August 23 , 2010 C.2: Sampling and analysis November 24, 20 I 0 C.3: Preparation of ambient sampling report December 30 , 2010 Task D -Communication and Outreach Plan D.I: Communication and outreach plan December 30, 2010 D .2: Communication and outreach materials February 25 , 2011 a Schedule predicated on receipt of Notice to Proceed by A ugust 9, 20 l 0 . b It is anticipated that the dispersion modeling will not start un t il the point source testing is completed . c Assumes sampling to be conducted August -October with sample analysis concluding by November 24 . boundaries. The IR camera provides a quick and effective means of surveying large areas for equipment leaks. While the [R camera can not quant ify emissions , the extent and density of the IR image does provide the experienced operator with an indication of the magnitude of the leak. Leaks identified by the IR camera will be ranked in order of potential magnitude to focus the sampling program on obtaining actual emission quantities from statistically representative s ites. This two-step approach is important to the statistical validity of the data as well as its spatial representativeness. Moreover, by prioritizing the sampling process according to the results of the IR camera surveys, the cost of unnecessary sampling that would occur with a more random approach can be avoided, providing the City with the best value for its dollar. Sage will field two [R camera teams in order to complete the survey of natural gas point source emitters within a reasonable timeframe. [n addition , by surveying all possible point source emission locations, we can more effectively identify the larger emitters and thereby focus the site specific sampling efforts, the ambient air monitoring, and the dispersion modeling on any potential "worst case" problem areas that exist. All equipment leaks detected with the IR camera will be video recorded and documented both with a digital camera and with descriptions recorded in electronic spreadsheets. All equipment leaks that are accessible to the field crew will be measured with the TV A 1 OOOB to determine the leaking concentration. 18 Air Quality Study June 2, 2010 Following the IR camera surveys, emission rates for a selected number of accessible leaks will be measured directly using the Hi Flow Sampler. Emission rates for leaks found by the camera on equipment inaccessible to the field crew will be evaluated using average production based emission factors. Each facility visited by the point source inspection teams will be documented with photographs as well as by a detailed inventory of major on-site equipment. Particular attention will be paid to the following point sources as they are frequent sources of emissions: flares , pipelines, compressors, and condensation tanks. Flare combustion efficiency can be quickly gauged with the IR camera by viewing the flare plume as it dissipates into the atmosphere. Quick dissipation is an indication of good combustion efficiency while a long, cohesive plume indicates just the opposite. Sage will view all flares and a video recording will be taken of any apparent instances of incomplete flare combustion. Natural gas pipelines can be the source of very large leaks depending on the age of the pipeline and the materials of construction . Once the size of the pipeline network has been determined , Sage, in conjunction with the City of Fort Worth , will determine a representative sample size. A third IR camera-equipped field team will be assigned to survey the selected pipelines, to determine leak concentrations with the TV A , to collect canister samples, and to make direct emission measurements, where possible, with the Hi Flow Sampler. Leaks from compressor seals and vents are also fairly common. Typically, these leak areas are not readily accessible; however, every effort will be made when encountering a compressor-related leak to quantify both its pollutant concentration and emission rate. Condensation knock out tanks at natural gas facilities are usually equipped with a closed vent system leading to a control device (flare). The integrity of the closed vent system can quickly be determined with the IR camera as can high probability leak areas such as poorly sealed thief hatches, unseated pressure relief valves, and failed conservation vents. Note, that while leaks from these components are readily detectable with the IR camera, they may not always be accessible to measurement by the TV A or the Hi Flow Sampler or to canister sample collection. In order to develop speciation information from point source leaks, a representative number of canister samples will be collected. The number of canister samples taken will be developed as details of the testing scheme are worked out. However, this number will most likely be calculated as a percentage of the number of leaks found for each equipment type. For example, a 10% rate for compressors would mean collection of a canister sample at every l 0th compressor leak detected with the IR camera. Sage will collect a statistically representative number of canister samples from each of the following equipment categories: Wet gas wells Tanks Dry gas wells Other major equipment (e.g., process heaters, boilers, etc.) Compressor stations Automatic control valves Pipelines Manual valves Dehydrators Connectors Completed canisters will be delivered , along with the appropriate Chain-of-Custody documentation, to TestAmerica laboratories in Austin, TX. The primary analytical target compounds will be benzene and carbon disulfide. Additional secondary compounds of interest are expected to be the same as used by TCEQ for their Barnett Shale monitoring. An emission rate test will be made with the Hi Flow Sampler in conjunction with each canister sample, in order to derive compound-specific emission rates for each equipment type sampled. 19 Air Quality Study June 2, 2010 It is important to characterize emissions from natural gas equipment that either has no detectable emissions, or that is leaking, but at levels below the det ection limit of the IR camera. To accomplish this , direct emission rate measurements wi th the Hi Flow Sampler will be made on valves and connectors that I) have a TV A reading between 100 and I 0,000 ppm or 2) have only background readings (i.e. default zeros). The number of valves and connectors to be sampled will be determined as the scope of work is developed. Based upon Sage 's experience with over 200 fugitive emission-related projects, the following scheme is offered as a starting point. • Valves 10,000 ppm <> 100 ppm -1 valve/five pads • Valves O ppm or background -1 valve/IO pads • Connectors 10 ,000 ppm < > 100 ppm -I connector/five pads • Connectors O ppm or background -1 connector/IO pads An example of a point source sampling matrix is provided in Table 7. Table 7. Example Point Source Sample Matrix IR Point Source Leaks Camera TVA Canister 1 Hi Flow 1 Well Heads • 10% per equip. leak I 0% per equip. leak Compressors • 10% per equip. leak Flares • Check with the IR camera for combustion efficiency Pipelines • Sample size to be determined Dehydrators • 10% per equip. leak Tanks • I 0% per equio. leak Other Major Equipment • 10% per equio. leak Automatic Control Valves • 10% per equio. leak I 0% oer equip. leak Manual Valves • 10% per equio. leak I 0% oer equip . leak Connectors • I 0% per equip. leak 10% per equip. leak Valves 10 ,000< > 100 ppm • I per 5 pads Valves = 0 ppm • I oer 10 oads Connectors I 0 ,000 < > 100 ppm • 1 per 5 pads Connectors = 0 ppm • 1 per 10 pads I For 11lustrat10n only. The actual number of canister collect10ns and H1 Flow sampling events will be determined with the City of Fort Worth during scope of work development. All testing and sample analysis will be conducted us ing standard quality control procedures and within guidelines and practices accepted by federal and state regulators. For example, prior to use , the IR camera's sensitivity will be validated daily through the following procedures: 1. Following power on and cool down , and after the camera has equilibrated to outside temperatures, a non-uniformity correction (NUC) will be performed several times. 2 . A flow of propane gas approximately equal to 5 grams/hour will be established and the furthest distance from which the camera operator can reliably detect the gas flow will be documented and a video record saved. 3. The gas flow will then be increased to 25 grams/hour and Step 2 repeated. 20 Air Quality Study June 2, 2010 4. The following meteorological conditions will be recorded along with the timestamp and measured distances: ambient temperature, wind speed ,% relative humidity, barometric pressure, % cloud cover, and degree of ambient light. The TV A l OOOB will be calibrated daily prior to use with zero air and three upscale certified span gas concentrations: Low (-500 ppm CH4), Mid (-1000 ppm CH4) and High (-10 ,000 ppm CH4). An acceptance criterion of ±10% accuracy will be required for each span calibration point. Canister quality control procedures will consist of the following: • Initial and final canister vacuums will be checked and recorded; • Canisters will not be filled to less than l O inches Hg vacuum ; • To avoid dilution of the canister sample by ambient air, the canister sample will be pulled from as close to the leak interface as possible and will be pulled over a 2 minute period ; • A duplicate sample and field blank will be collected for every ten canister field samples ; and • All required Chain-of-Custody documents will be shipped with each canister sample. Calibration checks will be performed on the Hi Flow sensor each day prior to use with a 2.5% CH4 certified compressed gas standard . Once every 30 days (per the manufacturer) the Hi Flow Sampler will be calibrated with zero air, 2.5% CH4, and l 00% CH4 certified compressed gas standards. Task B: Conduct Dispersion Modeling Once testing has been completed, modeling will be conducted to determine the impact emissions from gas facilities have on air quality at the facility fenceline, and at sensitive receptors in close proximity to the facility. [n addition to modeling conducted at current conditions, ERG will consider the effect that full build-out of natural gas exploration and production in Fort Worth will have on future impacts. The following activities will be performed to carry out this analysis: • Facility plot plan review; • Evaluation of source locations and release parameters; • Review of receptor placement and classification; • Review of model runtime options ; • Meteorological data analysis (if necessary); and • Model execution. First, the ERG team will review the plot plans for the facilities to be modeled. From these plot plans , we will derive appropriate property boundaries and fencelines , and uniquely identify all emissions sources and downwash structures of interest. Before modeling can proceed , sources must be correctly classified as either point, volume, or in some cases, area. Sources must also be located in an appropriate fashion to reflect where on the property emissions actually occur. Source classification and placement will conform to all TCEQ and U.S. EPA modeling guidance. A listing of all necessary source parameters input to the model will be developed, to include emission rates, Universal Transverse Mercator (UTM) coordinates, base elevation , source height, stack exit velocity and temperature, and source dimensions , as applicable to each source type. Locations, dimensions, and heights of structures on the property that could contribute to building downwash will also be clearly presented. 21 Air Quality Study June 2, 2010 ERG will meticulously check the source input parameters developed to ensure that they conform to all state and federal air quality modeling guidance . If sources with similar parameters are combined into one source, justification will be provided . Effective plume heights for volume sources will be calculated appropriately, and volume source dimensions will be divided by a factor of 2.15 according to U.S. EPA guidance . "Pseudo-point" sources ( e.g., rain capped or horizontal stacks) will be modeled with an exit velocity of 0.1 meters per second. Area sources will maintain an aspect ratio of no greater than I O-to-1 , and no sources will extend off property. The receptor grid developed for the facility will consist of both appropriate fenceline receptor spacing, as determined by the area of the facility , and downwind receptor spacing. ERG expects that most receptor grid spacing will increase as receptors are located further from the well pad , pipeline, or processing facility , but the receptor spacing must still be dense enough to identify maxima and develop concentration isopleths. Receptors will include terrain heights, and local land use information will be used to classify receptors as residential , commercial or sensitive. Acceptable model runtime options have been clearly set forth in TCEQ and the U.S. EPA guidance. These will be verified for consistency. Notable among the options are that all analyses should use appropriate dispersion coefficients, as determined by a land-use analysis. Properly processed meteorological data will be input to the model. TCEQ provides a number of pre-processed , approved data sets to choose from. Generally, the station closest to the facility will be used. If not , justification for use of alternate stations will be presented. In the event that other meteorological data is proposed , at least one complete year of surface observations and mixing heights must be available, and a description of the methodology and software used to process the data will be presented . Having carefully reviewed all modeling input files for completeness, ERG will recommend that the modeling be executed. As part of the submitted modeling analysis, summaries of model outputs will be clearly presented. Annual average , maximum hourly , and other short-term averaging period concentrations for the pollutants of interest in this study will be reported. Also , summary plots of the modeled receptor grid , along with pollutant isopleths, will be included. Task C: Conduct Ambient Sampling Ambient sampling will be conducted throughout Fort Worth at a variety of locations to obtain a statistically representative cross-section of ambient exposure to emissions from natural gas exploration and production sites. ERG will be ready to work with the City at contract initiation to design the sampling network, including monitor locations and sampling durations. Although the network will be specific to the scope defined by the City , our approach will consist of three main activities: network design ; sampling and analysis; and data characterization. Network Design. The ambient monitoring network will be designed to produce high quality, representative data. To effectively plan this effort, extensive technical expertise, innovation , and an in-depth understanding of the intended use of the resulting data are required. Our approach to the network design for Fort Worth will be as follows: • Define the problem and/or the goals of the study (e.g., benzene exposure); • Establish the Data Quality Objectives (DQOs); • Determine the appropriate measurement methodologies ; • Survey the study area; • Identify and address any/all potential limitations to executing the study; 22 Air Quality Study June 2, 2010 • Develop a Quality Assurance Project Plan (QAPP) at the appropriate level of detail; and • Implementation , which includes: training and development of operational procedures, pre- deployment staging, and field deployment. For the NGAQS , we will use our extensive field and laboratory experience to efficiently set up the network design. Prior to the initiation of any field work, ERG staff routinely develops historical and seasonal "windrose " graphs , and prepares a climatological summary of the study area. These are particularly useful in identifying appropriate locations and objectives for the monitoring sites, as well as identifying unusual wind patterns that need to be considered in network design. Monitoring objectives include, but are not limited to source-oriented exposure, population ex posure, background/remote concentrations, and trends. We ex pect to also refine the DQOs to meet the specific objectives of the study. For example, typical canister sampling of VOCs via U.S. EPA Method T0-15 is for a duration of24-hours (daily). However, during intensive studies, sub-daily measurements can be taken to develop a diurnal concentration profile that may be more appropriate in understanding the behavior of the target compounds, such as for BTEX (benzene, toluene , ethylbenzene, and xylenes), and their potential sources. The City may wish to conduct a combination of] -hour, 3-hour, 6-hour, 8- hour, and/or 12-hour canister sampling throughout the study to accomplish this. Specifically, these time period measurements (sub-daily and daily) are useful for: • Understanding the influence of mobile sources. Samples taken during morning and afternoon rush hour commutes can be represented effectively using 3-hour samples, and are useful in understanding contributions from mobile sources . Also , ERG has developed BTEX signature ratios to help identify concentrations predominantly from mobile sources. • Understanding non-chronic risk exposure. Samples conducted every hour can be compared to reference exposure concentrations, such as TCEQs 1-hour ESL for benzene or U.S. EPA 's ]-hour and 8-hour Acute Exposure Guideline Levels (AEGL) for mild and moderate effects. Sampling conducted every 6 hours can be compared to California EPA's Reference Exposure Level (REL). 24-hour samples can be compared to U.S. EPA's individual sample comparison levels and/or ATSDR 's acute and intermediate minimal risk levels (MRLs). • Understanding chronic risk exposure. If the City is interested in developing estimates of chronic risk, then our sampling schedule would be designed in a manner to ensure enough concentrations needed to develop an annual average. The annual average would then be used to calculate chronic risk exposures, such as for cancer and/or noncancer. Sampling and Analysis . ERG maintains a NELAC-certified laboratory that conforms fully to all associated quality requirements. As part of our Quality Systems, prior to performing laboratory analyses, ERG will work with the City to ensure the following: • The analysis method requested is appropriate for the target analytes; • The analysis requested will meet the DQOs associated with the corresponding data use; and • The City understands data turn-around times , and any convoluting elements that may exist. ERG 's technical approach in performing laboratory analyses is well proven , based on more than 26 years experience supporting U.S. EPA 's National Monitoring Programs, and is widely 23 Air Quality Study June 2, 2010 accepted by state and federal regulators. The analysis will be conducted under the following six activities : • Catalogue of Sample Receipt/Chain-of-Custody fo rms. • Review the accompanying field sample collection fo rms. • Logging the sample into our Laboratory Information Management System (LIMS) database. • Sample Preservation and Preparation -ERG preserves and prepares the samples in accordance with the applicable recognized method , as they are received. • Analyze samples in accordance with the applicable recognized method. • Prepare and Distribute Preliminary Data -After analyses have been completed , ERG will prepare a compiled data report and certificate of analysis for the City . This LIMS system combines central storage of sample data with multiple access points to the data throughout the laboratory and associated offices. Information stored in the LIMS covers all as pects of the life of a sample from receipt to reporting of results. All samples, or sample components, are tracked by the LIMS. The LIMS system also automatically captures and stores analytical results directly from the laboratory instruments. This eliminates any potential source of errors in transcribing raw analytical data. Data Characterization. There are several data characterization products that the City may want generated and are generally lumped into two types : statistical and non-statistical. Fundamental statistical characterization includes calculating the central tendency (e.g., mean , median , geometric mean , mode, etc.), data distribution (e.g ., percentiles, standard deviation , variability, frequency , confidence intervals, etc.), and correlations of the dataset. A wide range of non- statistical data visualization products can be constructed using visual plotting software and GIS information. Non-statistical characterization includes visual plots, pollution roses, and back trajectories, and may provide more insight than data presented in a tabular form. Integration of ambient monitoring data and other data sources can yield interesting conclusions. Examples include: • Integration with meteorological data may include Pearson correlation statistics, construction of wind and pollution roses, and construction of back trajectories; • Integration with emissions data may include: data validation between ambient monitoring data and emissions inventory, emissions tracing to specific facilities /sources, and toxicity- weighting of emissions and comparison to ambient monitoring data; • Integration with air regulations data may include: evaluation of federal , state, or local regulations , pre-and post-implementation ; and anticipated reduction in ambient concentrations due to on-the-books and beyond on-the-books regulations ; • Integration with site locations: land use/location setting of monitors, daily traffic patterns, nearby population and car registration , topography maps, and climate summaries; and • Integration with risk factors may include: individual sample comparison levels , theoretical cancer risk using Unit Risk Estimate (URE) factors and /or theoretical noncancer risk using Reference Concentration (RfC) factors , and comparison of measured concentration risk and NATA-modeled risk Task D: Develop Communication Plan The ERG team has extensive experience working with its government clients to communicate complex technical , scientific, and policy issues to various audiences, including scientific review boards, environmental regulators , community groups, and the public. We have a proven track 'fRG 24 Air Quality Study June 2, 2010 record of creating effective and engaging outreach and technical materials , which have been packaged into reports , fact sheets, websites, journal articles, speeches, and presentations. Our scientists and engineers work closely with technical writers and editors to maximize the impact of each product by customizing its presentation, content, and language style to the targeted users. When developing a communications plan , ERG will first coordinate with the City to establish the community 's information needs and identify the issues of greatest concern (e.g., cancer, non- cancer effects, exposure to odors and irritants , etc .). ERG will coordinate with the City to characterize the intended audience in terms of educational background , languages spoken , access to computers and the internet, and their most trusted sources of information. ERG can make recommendations for how best to actively engage interested community members. Three specific communications issues raised in the RFQ will be addressed as follows : Methods used to establish screening levels used by TCEQ. Environmental and public health agencies use different screening levels and guidelines to place environmental measurements into perspective. Until recently , TCEQ evaluated air monitoring data using a single paradigm: agency-derived "Effects Screening Levels" (ESLs). ERG has gained extensive experience using these ESLs through its ongoing work assisting A TSDR with public health evaluations of air quality in Corpus Christi and Midlothian, TX. ERG has already drafted text for use in A TSDR documents to explain these concepts to the public. More importantly, ERG is also aware of a recent shift in TCEQ methodologies for screening air pollution levels. Earlier this year, the agency expanded its evaluation approach to use ESLs primarily for permitting purposes and a new set of screening values-"Air Monitoring Comparison Values" (or AMCVs)--derived specifically for health-based screening of ambient air monitoring data. ERG has tracked the development of this new screening paradigm and has become well-versed on how AMCVs differ from ESLs. A firm knowledge of the difference between AMCV s and ES Ls is critical for evaluations of ambient air monitoring data in Texas. Finally, ERG has already researched the methodologies that TCEQ used to derive its AMCVs and ESLs and is prepared to comment on the various factors that come into play to ensure that these values are adequately protective (e.g., application of uncertainty factors). Comparison of different agencies ' health-based screening levels. Earlier in 2010, ERG performed this exact task. Specifically, we compiled health-based screening levels published by ATSDR, U.S. EPA , and TCEQ for more than 150 different air pollutants and provided our client (A TSDR) with detailed information on the similarities and differences between the agency values. ERG 's risk assessors and environmental health scientists can easily expand upon this previous work to include health-based screening values published by other entities, including international environmental and health organizations. Consideration of special exposure limits. Through its work for U.S. EPA , ATSDR, and other agencies, ERG has a proven track record of identifying all screening limits that might be applicable to a given exposure scenario, including any derived for susceptible populations . For this project, ERG will first work with the City of Fort Worth to clarify what is meant by "special exposure limits ," as many can potentially apply (e.g., screening values specific to children or the elderly, screening values based on potential exposures via vapor intrusion from groundwater plumes, soil vapor screening values , screening values to protect livestock from exposures in oilfield settings). ERG will then access all relevant literature to inform the issues of concern and communicate the significance of the screening values. 25 5.0 LIST OF SUBCONTRACTORS Providers shall complete the following information and submit it with the Qualifications Documents to permit the City of Fort Worth to more fully evaluate the submittal's quality prior to awarding the contract. Subcontractor's Subcontractor's Subcontractor's Subcontractor's Proposed Tasks Name Address Telephone No. FAX Number on the Project 14611 Bee Caves Road, Lead role for Task A (Measure and Sage Environmental Suite 100 , Austin , TX 512-327-0288 512-327-4972 Analyze Emissions), and contributions to K.:onsultants , LP 78746 all other tasks for purposes of integrating knowledge of source sampling and analysis. 7.0 PROVIDER'S LICENSES AND CERTIFICATES NELAP-Reeognized Laboratory Accreditation is hereby awarded to EASTERN RESEARCH GROUP, INC. 601 KEYSTONE PARK DRIVE, SUITE 700 MORRISVILLE, NC 27560-6363 in accordance with Texas Water Code Chapter 5, Subc'hapter R, Title 30 Texas Administrative Code Chapter 25, and the National Environmental Laboratory Accreditation Program. The laboratory's scope of accreditation includes the fields of accreditation that accompany this ce,rtificate. Continued accreditation depends upon successful ongoing participation in the program. The Texas Commlssion on Environmental Quality urges customers to verify the laboratory's current accreditation status for particular methods and analyses. Certificate Number: T104704426-09-TX Effective Date: 07/01/2009 Expiration Date: 06/30/2010 Texas Commission on Environmental Quality Texas Commission on Environmental Quality NELAP -Recognized Laboratory Fields of Accreditation Ea stern Research Group , Inc. 601 Keystone Park Drive, Suite 700 Morrisville, NC 27560-6363 Certificate Issue Date: Expiration Date: T104704426-09-TX 7/1/2009 6/30/2010 These fie lds of accred itation supercede all previous fields . The Texas Commission on Environmental Qual ity urges custome rs to verify the laboratory 's current accreditation status for particular methods and analyses . ·------------·--··---·----····-·----··----·---·-··-··--..... _. __ Matrix: Air and Emissions -"----··---·--- Category I Method: EPA T0-15 Analytes: Code AA Analytes: Code AA 1 1 1-Trichloroethane 5160 FL 1 1 2 2-Tetrachloroethane 5110 FL 1 1 2-Trichloroethane 5165 FL 1 1-Dichloroethane 4630 FL 1 1-Dichloroethylene 4640 FL 1 2 4-Trichlorobenzene 5155 FL 1 2-Dichlorobenzene 4610 FL 1 2-Dichloroethane 4635 FL 1 3-Dichlorobenzene 4615 FL 1 4-Dichlorobenzene 4620 FL 2-Butanone (Methyl ethyl ketone MEK) 4410 FL Acetonitrile 4320 FL Acrylonitrile 4340 FL Benzene 4375 FL Bromomethane 4950 FL Carbon tetrachloride 4455 FL Chlorobenzene 4475 FL Chloroethane 4485 FL Chloroform 4505 FL Chloromethane 4960 FL Chloroprene 4525 FL cis-1 2-Dichloroethylene 4645 FL cis-1 3-Di ch loropropene 4680 FL Ethylbenzene 4765 FL Methyl isobutyl ketone (Hexane) 4985 FL Methyl methacrylate 4990 FL Methyl tert-butyl ether (MTBE) 5000 FL Methylene chloride 4975 FL Styrene 5100 FL Toluene 5140 FL trans-1 3-Dichlotopropylene 4685 FL Trichloroethene (Trichloroethylene) 5170 FL Vinyl c hloride 5235 FL Xylene (total) 5260 FL Page 1 of 1 Texas C0rnmissiclr7F:O@ ;<E'f'.1virorameata b.f~u :ality . ''.)~:ijt(JrW11t;'! ;iJJJ~ '.\;~~1;Lt~~~i;if;t;}it~[Jt 1 : N ELAP-Re~qgnized.::Laqpratory Accredit~tiorl is >~e-~¢ay ,awc!r9ed to ••• ~·'"-·-··· --~•,..•""'-----~~~ •• ;, ...; .• .:i;...............,L.-,1,;. • _ .. __ .;,...;.._to...c _......,;,~..--,1..--.:.....,:.,'"'c=-• ..-.. ""'-'--"'•'•·.A-.-~"""' •. -~ .. -;.:...,,,.. ·'-""--., ,. .. in accordance with Texas Water Code Chapter 5 , Subchapter R, Title 30 Texas Administrative Code Chapter 25, and the Nationa LEnvironmental Laboratory Acc_r,editation ~~ogr~m . The laboratory's scope of accreditation .im:I Jdes:ftiefields ofa_ccreditation that accompany. this .certificate . Continued accreditation depends upon successful ongoing participaticm ::iri 'ltJe ·prog raili The=T'exasComn,ission on Environmental .Quality urges customers to verify the . laborato,y'si curreht a9ct ~g jtation status for particular~methods :and analyses. Certificate Number: Effective Date: 3/29/2010 Expiration Date: 6/30/201 O ·~" cc'u .,}l!::Yt[i{'/{~{f::rtii_,'._r,:;1'._'._If.g,{/'• ··-. -:~. .. " >.. . ~ .. .:~ i,:·; . ~-----~: ·_;;· · 1 ·M;~u, ·;,:_; :,.-.' >executive. Dir,ctor Texas C ,ss,on on · · .. ,, ... ,.;,, ,:· ... ,, .. ,.,::L, .. ,.s,;,.,,,, ·Environmental Quality ·::·'·, Texas Commission on Environmental Quality NELAP -Recognized Laboratory Fields of Accreditation TestAmerica Laboratories, Inc. -Austin 14050 Summit Drive, Suite A100 Austin, TX 78728-7149 Certificate: Expiration Date: Issue Date: ---------, T104704217 -10-5 6/30/2010 3/29/2010 These fields of accreditation supercedeall previous fields. The Texas Commission on Environmental Quality urges customers to verify the laboratory's current accreditation status for particular methods and analyses. Matrix: Air Method 40 CFR 50, App. J Analyte AB Analyte ID Method ID Particulates <10 um TX 3950 40 CFR 50 App J Method ASTM D1946 Analyte AB Analyte ID Method ID Carbon dioxide TX 3755 ASTM 01946-90 Carbon monoxide TX 3780 ASTM 01946-90 Methane TX 4926 ASTM O 1946-90 Nitrogen TX 1843 ASTM O 1946-90 Oxygen TX 3895 ASTM O 1946-90 Method EPA 6010 Analyte AB Analyte ID Method ID Arsenic TX 1010 10155201 Chromium TX 1040 10155201 Lead TX 1075 10155201 Method EPA T0-12 Analyte AB Analyte ID Method ID Non-methane hydrocarbons TX 3855 10248201 Method EPA T0-14A Analyte AB Analyte ID Method ID 1, 1, 1-Trichloroethane TX 5160 10248609 1, 1,2 ,2-Tetrachloroethane TX 5110 10248609 1, 1,2-Trichloro-1,2 ,2-trifluoroethane TX 5195 10248609 1, 1,2-Trichloroethane TX 5165 10248609 1, 1-Dichloroethane TX 4630 10248609 1 , 1-Dich loroethylene ( 1, 1-D ichloroethene) .TX 4640 10248609 1,2,4-Trichlorobenzene TX 5155 10248609 1,2,4-Trimethylbenzene TX 5210 10248609 1,2-Dibromoethane (EDB , Ethylene dibromide) TX 4585 10248609 1,2-Dichloro-1, 1,2,2-tetrafluoroethane TX 4695 10248609 1,2-Dichlorobenzene TX 4610 10248609 Page 1 of41 Texas Commission on Environmental Quality NELAP -Recognized Laboratory Fields of Accreditation TestAmerica Laboratories, Inc •• Austin 14050 Summit Drive, Suite A100 Austin, TX 78728-7149 Certificate: Expiration Date: Issue Date: T104704217-10-5 6/30/2010 3/29/2010 These fields of accreditation supercedeall previous fields. The Texas Commission on Environmental Quality urges customers to verify the laboratory's current accreditation status for particular methods and analyses. Matrix: Air 1,2-Dichloroethane TX 4635 10248609 1,2-Dichloropropane TX 4655 10248609 1,3,5-Trimethylbenzene TX 5215 10248609 1,3-Dichlorobenzene TX 4615 10248609 1,4-Dichlorobenzene TX 4620 10248609 Benzene TX 4375 10248609 Benzyi chloride TX 5635 10248609 Bromomethane (Methyl bromide) TX 4950 10248609 Carbon tetrachloride TX 4455 10248609 Chlorobenzene TX 4475 10248609 Chloroethane TX 4485 10248609 Chloroform TX 4505 10248609 Chloromethane (Methyl chloride) TX 4960 10248609 cis-1 ,2-Dichloroethylene TX 4645 10248609 cis-1 ,3-Dichloropropylene TX 4680 10248609 Dichlorodifluoromethane TX 4625 10248609 Ethylbenzene TX 4765 10248609 Hexachlorobutadiene TX 4835 10248609 Methylene chloride TX 4975 10248609 Styrene TX 5100 10248609 Tetrachloroethylene (Perchloroethylene) TX 5115 10248609 Toluene TX 5140 10248609 trans-1 ,2-Dichloroethylene TX 4700 10248609 trans-1,3-Dichloropropylene TX 4685 10248609 Trichloroethane (Trichloroethylene) TX 5170 10248609 Trichlorofluoromethane TX 5175 10248609 Vinyl chloride TX 5235 10248609 Xylene (total) TX 5260 10248609 Method EPA T0-15 Analyte AB Analyte ID Method ID 1, 1, 1-Trichloroethane TX 5160 10248803 Page 2 of41 Texas Commission on Environmental Quality NELAP -Recognized Laboratory Fields of Accreditation TestAmerica Laboratories, Inc. -Austin 14050 Summit Drive, Suite A100 Austin, TX 78728-7149 Certificate: Expiration Date: Issue Date: T104704217-10-5 6/30/2010 3/29/2010 These fields of accreditation supercedeall previous fields. The Texas Commission on Environmental Quality urges customers to verify the laboratory's current accreditation status for particular methods and analyses. Matrix: Air 1 , 1 ,2,2-Tetrachloroethane TX 5110 10248803 1, 1,2-Trichloroethane TX 5165 10248803 1, 1-Dichloroethane TX 4630 10248803 1, 1-Dichloroethylene (1, 1-Dichloroethene) TX 4640 10248803 1 ,2,3-Trimethylbenzene TX 5182 10248803 1,2,4-Trichlorobenzene TX 5155 10248803 1,2,4-Trimethylbenzene TX 5210 10248803 1 ,2-Dibromoethane (EDB, Ethylene dibromide) TX 4585 10248803 1 ,2-Dichlorobenzene TX 4610 10248803 1,2-Dichloroethane TX 4635 10248803 1,2-Dichloropropane TX 4655 10248803 1,3,5-Trimethylbenzene TX 5215 10248803 1,3-Butadiene TX 9318 10248803 1,3-Dichlorobenzene TX 4615 10248803 1,4-Dichlorobenzene TX 4620 10248803 1,4-Dioxane (1,4-Diethyleneoxide) TX 4735 10248803 1-Butene TX 4917 10248803 1-Pentene TX 4833 10248803 2,2,4-Trimethylpentane TX 5220 10248803 2,2-Dimethylbutane TX 4666 10248803 2 ,3,4-Trimethylpentane TX 4667 10248803 2,3-Dimethylbutane TX 4669 10248803 2,3-Dimethylpentane TX 4671 10248803 2,4-Dimethylpentane TX 4672 10248803 2-Butanone (Methyl ethyl ketone, MEK) TX 4410 10248803 2-Methyl-2-butene TX 10236 10248803 2-Methylheptane TX 4939 10248803 2-Methylhexane TX 10235 10248803 2-Methylpentane (lsohexane) TX 4941 10248803 3-Methyl-1-butene TX 10238 10248803 Page 3 of 41 Texas Commission on Environmental Quality NELAP -Recognized Laboratory Fields of Accreditation TestAmerlca Laboratories, Inc. -Austin · 14050 Summit Drive, Suite A100 Austin, TX 78728-7149 Certmcate: Expiration Date: Issue Date: T104704217-10-5 6/30/2010 3/29/2010 These fields of accreditation supercedeall previous fields. The Texas Commission on Environmental Quality urges customers to verify the laboratory's current accreditation status for particular methods and analyses. Matrix: Air 3-Methylheptane TX 4532 10248803 3-Methylhexane TX 4533 10248803 3-Methylpentane TX 4534 10248803 4-Methyl-1-pentene TX 10242 10248803 Acetaldehyde TX 4300 10248803 Acetonitrile TX 4320 10248803 Acetylene TX 4323 10248803 Acrylon itrile TX 4340 10248803 Benzene TX 4375 10248803 Benzyl chloride TX 5635 10248803 Bromochloromethane TX 4390 10248803 Bromodichloromethane TX 4395 10248803 Bromoform TX 4400 10248803 Bromomethane (Methyl bromide) TX 4950 10248803 Carbon tetrachloride TX 4455 10248803 Chlorobenzene TX 4475 10248803 Chloroethane TX 4485 10248803 Chloroform TX 4505 10248803 Chloromethane (Methyl chloride) TX 4960 10248803 Chloroprene TX 4525 10248803 cis-1,2-Dichloroethylene TX 4645 10248803 cis-1 ,3-Dichloropropylene TX 4680 10248803 cis-2-Butene TX 4602 10248803 cis-2-Hexene TX 10244 10248803 cis-2-pentene TX 4603 10248803 Cyclohexane TX 4555 10248803 Cyclopentane TX 4562 10248803 Cyclopentene TX 10247 10248803 Dibromochloromethane TX 4575 10248803 Dichlorodifluoromethane TX 4625 10248803 Page 4 of 41 Texas Commission on Environmental Quality NELAP -Recognized Laboratory Fields of Accreditation TestAmerlca Laboratories, Inc. -Austin 14050 Summit Drive, Suite A100 Austin, TX 78728-7149 Certificate: Expiration Date: Issue Date: T104704217-10-5 6/30/2010 3/29/2010 These fields of accreditation supercedeall previous fields. The Texas Commission on Environmental Quality urges customers to verify the laboratory's current accreditation status for particular methods and analyses. Matrix: Air Dichlorotetrafluoroethane TX 4652 10248803 Ethane TX 4747 10248803 Ethylbenzene TX 4765 10248803 Ethylene TX 4752 10248803 Hexachlorobutadiene TX 4835 10248803 Hexane TX 4850 10248803 lsobutane (2 -methylpropane) TX 4942 10248803 lsopentane (2-Methylbutane) TX 4938 10248803 lsoprene (2-Methylbutadiene) TX 4937 10248803 lsopropylbenzene TX 4900 10248803 m+p-xylene TX 5240 10248803 m-Diethylbenzene TX 10252 10248803 Methanol TX 4930 10248803 Methyl isobutyl ketone (Hexane) TX 4985 10248803 Methyl methacrylate TX 4990 10248803 Methyl tert-butyl ether (MTBE) TX 5000 10248803 Methylcyclohexane TX 4965 10248803 Methylcyclopentane TX 4966 10248803 Methylene chloride TX 4975 10248803 m-Ethyltoluene TX 10253 10248803 n-Butane TX 5007 10248803 n-Decane TX 5875 10248803 n-Heptane TX 4825 10248803 n-Nonane TX 5026 10248803 n-Octane TX 5027 10248803 n-Pentane TX 5028 10248803 n-Propylbenzene TX 5090 10248803 n-Undecane TX 10261 10248803 o-Ethyltoluene TX 10254 10248803 a-Xylene TX 5250 10248803 Page 5 of 41 Texas Commission on Environmental Quality NELAP -Recognized Laboratory Fields of Accreditation TestAmerlca Laboratories, Inc. -Austin 14050 Summit Drive, Suite A100 Austin, TX 78728-7149 Certificate: Expiration Date: Issue Date: T104704217-10-5. 6/30/2010 3/29/2010 These fields of accreditation supercedeall previous fields. The Texas Commission on Environmental Quality urges customers to verify the laboratory's current accreditation status for particular methods and analyses . Matrix: Air p-Diethylbenzene TX 10262 10248803 p-Ethyltoluene TX 10255 10248803 Propane TX 5029 10248803 Propylene TX 4836 10248803 Styrene TX 5100 10248803 Tetrachloroethylene (Perchloroethylene) TX 5115 10248803 Toluene TX 5140 10248803 trans-1 ,2-Dichloroethylene TX 4700 10248803 trans-1,3-Dichloropropylene TX 4685 10248803 trans-2-Butene TX 4607 10248803 trans-2-Hexene TX 10264 10248803 trans-2-pentene TX 4608 10248803 Trichloroethene (Trichloroethylene) TX 5170 10248803 Trichlorofluoromethane TX 5175 10248803 Trichlorotrifluoroethane TX 5185 10248803 Vinyl acetate TX 5225 10248803 Vinyl bromide TX 5230 10248803 Vinyl chloride TX 5235 10248803 Xylene (total) TX 5260 10248803 Page 6 of 41 Texas Commission on Environmental Quality NELAP -Recognized Laboratory Fields of Accreditation TestAmerica Laboratories, Inc. -Austin 14050 Summit Drive, Suite A100 Austin, TX 78728-7149 Certificate: Expiration Date: Issue Date: T104704217-10-5 6/30/2010 3/29/2010 These fields of accreditation supercedeall previous fields. The Texas Commission on Environmental Quality urges customers to verify the laboratory's current accreditation status for particular methods and analyses. Matrix: Non Potable Water Method CA HML 939-M Analyte AB Analyte ID Method ID Lead, Organ ic TX 10329 CAHML939-M Method EPA 1020 Analyte AB Analyte ID Method ID lgnitability TX 1780 10117007 Method EPA 120 .1 Analyte AB Analyte ID Method ID Conductivity TX 1610 10006403 Method EPA 130 .2 Analyte AB AnalytelD Method ID Total hardness as CaC03 TX 1755 10007202 Method EPA 150.1 Analyte AB Analyte ID Method ID pH TX 1900 10008409 Method EPA 160 .1 Analyte AB Analyte ID Method ID Res idue-filterable (TDS) TX 1955 10009208 Method EPA 160.2 Analyte AB Analyte ID Method ID Residue-nonfilterable (TSS) TX 1960 10009606 Method EPA 160 .3 Analyte AB Analyte ID Method ID Residue-total TX 1950 10010001 Method EPA 160.5 Analyte AB Analyte ID Method ID Residue-settleable TX 1965 10010807 Method EPA 1664 Analyte AB Analyte ID Method ID n-Hexane Extractable Material (O&G) TX 1803 10127409 Method EPA 200.7 Analyte AB Analyte ID Method ID Page 7 of 41 Texas Commission on Environmental Quality NELAP -Recognized Laboratory Fields of Accreditation TestAmerica Laboratories, Inc. -Austin 14050 Summit Drive, Suite A100 Austin, TX 78728-7149 Certificate: Expiration Date: Issue Date: ---·--------·---- T104704217-10-5 6/30/2010 3/29/2010 These fields of accreditation supercedeall previous fields. The Texas Commission on Environmental Quality urges customers to verify the laboratory's current accreditation status for particular methods and analyses. Matrix: Non Potable Water Aluminum TX 1000 10013806 Antimony TX 1005 10013806 Arsenic TX 1010 10013806 Barium TX 1015 10013806 Beryllium TX 1020 10013806 Boron TX 1025 10013806 Cadmium TX 1030 10013806 Calcium TX 1035 10013806 Chromium TX 1040 10013806 Cobalt TX 1050 10013806 Copper TX 1055 10013806 Iron TX 1070 10013806 Lead TX 1075 10013806 Magnesium TX 1085 10013806 Manganese TX 1090 10013806 Molybdenum TX llOO 10013806 Nickel TX ll05 10013806 Phosphorus , total TX 1910 10013806 Potassium TX 1125 10013806 Selenium TX 1140 10013806 Silica-dissolvl:!d TX 1995 10013806 Silver TX 1150 10013806 Sodium TX ll55 10013806 Strontium TX 1160 10013806 Thallium TX 1165 10013806 Tin TX 1175 10013806 Titanium TX 1180 10013806 Vanadium TX 1185 10013806 Zinc TX 1190 10013806 Method EPA 200.8 Analyte AB Analyte ID Method ID Page 8 of41 Texas Commission on Environmental Quality NELAP -Recognized Laboratory Fields of Accreditation TestAmerica Laboratories, Inc. -Austin 14050 Summit Drive, Suite A100 Austin, TX 78728-7149 Certificate: Expiration Date: Issue Date: T104704217-10-5 6/30/2010 3/29/2010 These fields of accreditation supercedeall previous fields. The Texas Commission on Environmental Quality urges customers to verify the laboratory's current accreditation status for particular methods and analyses. Matrix: Non Potable Water Aluminum TX 1000 10014605 Antimony TX 1005 10014605 Arsenic TX JOJO 10014605 Barium TX 1015 10014605 Beryllium TX 1020 10014605 Cadmium TX 1030 10014605 Calcium TX 1035 10014605 Chromium TX 1040 10014605 Cobalt TX 1050 10014605 Copper TX 1055 10014605 Iron TX 1070 10014605 Lead TX 1075 10014605 Magnesium TX 1085 10014605 Manganese TX 1090 10014605 Molybdenum TX 1100 10014605 Nickel TX 1105 10014605 Potassium TX 1125 10014605. Selenium TX I 140 10014605 Silver TX 1150 10014605 Sodium TX 1155 10014605 Strontium TX 1160 10014605 Thallium TX 1165 10014605 Tin TX 1175 10014605 Titanium TX 1180 10014605 Vanadium TX 1185 10014605 Zinc TX 1190 10014605 Method EPA 245 .1 Analyte AB Analyte ID Method ID Mercury TX 1095 10036609 Method EPA 300 .0 Analyte AB Analyte ID Method ID Page 9 of41 Texas Commission on Environmental Quality NELAP -Recognized Laboratory Fields of Accreditation TestAmerica Laboratories, Inc. -Austin 14050 Summit Drive, Suite A100 Austin, TX 78728-7149 Certificate: Expiration Date: Issue Date: T104704217-10-5 6/30/2010 3/29/2010 These fields of accreditation supercedeall previous fields. The Texas Commission on Environmental Quality urges customers to verify the laboratory's current accreditation status for particular methods and analyses. Matrix: Non Potable Water Bromide TX 1540 10053006 Chloride TX 1575 10053006 Fluoride TX 1730 10053006 Nitrate as N TX 1810 10053006 Nitrite as N TX 1840 10053006 Orthophosphate as P TX 1870 10053006 Sulfate TX 2000 10053006 Method EPA 310.1 Analyte AB Analyte ID Method ID Alkalinity as CaC03 TX 1505 10054805 Method EPA 335 .1 Analyte AB Analyte ID Method ID Amenable cyanide TX 1510 10060001 Method EPA 335.3 Analyte AB Analyte ID Method ID Total cyanide TX 1645 10061004 Method EPA 335 .4 Analyte AB Analyte ID Method ID Total cyanide TX 1645 10061402 Method EPA 340 .2 Analyte AB Analyte ID Method ID Fluoride TX 1730 10062201 Method EPA 350 .1 Analyte AB Analyte ID Method ID Ammonia asN TX 1515 10063408 Method EPA 353 .2 Analyte AB Analyte ID Method ID Nitrate-nitrite TX 1820 10067400 Method EPA 365 .1 Analyte AB Analyte ID Method ID Phosphorus, total TX 1910 10069804 Page 10 of 41 Texas Commission on Environmental Quality NELAP -Recognized Laboratory Fields of Accreditation TestAmerica Laboratories, Inc. -Austin 14050 Summit Drive, Suite A100 Austin, TX 78728-7149 Certificate: Expiration Date: Issue Date: 1104704217-10-5 6/30/2010 3/29/2010 These fields of accreditation supercedeall previous fields. The Texas Commission on Environmental Quality urges customers to verify the laboratory's current accreditation status for particular methods and analyses. Matrix: Non Potable Water Method EPA 376.1 Analyte AB Analyte ID Method ID Sulfide TX 2005 10074201 Method EPA 410.4 Analyte AB Analyte ID Method ID Chemical oxygen demand TX 1565 10077200 Method EPA415.1 Analyte AB Analyte ID Method ID Total organic carbon TX 2040 10078407 Method EPA 420.2 Analyte AB Analyte ID Method ID Total phenolics TX 1905 10079808 Method EPA 420.4 Analyte AB Analyte ID Method ID Total phenolics TX 1905 10080203 Method EPA 6010 Analyte AB Analyte ID Method ID Aluminum TX 1000 10155609 Antimony TX 1005 10155609 Arsenic TX 1010 10155609 Barium TX 1015 10155609 Beryllium TX 1020 10155609 Boron TX 1025 10155609 Cadmium TX 1030 10155609 Calcium TX 1035 10155609 Chromium TX 1040 10155609 Cobalt TX 1050 10155609 Copper TX 1055 10155609 Iron TX 1070 10155609 Lead TX 1075 10155609 Magnesium TX 1085 10155609 Page 11 of41 --------- Texas Commission on Environmental Quality NELAP -Recognized Laboratory Fields of Accreditation TestAmerlca Laboratories, Inc. -Austin 14050 Summit Drive, Suite A100 Austin, TX 78728-7149 Certificate: Expiration Date: Issue Date: T104704217-10-5 6/30/2010 3/29/2010 These fields of accreditation supercedeall previous fields. The Texas Commission on Environmental Quality urges customers to verify the laboratory's current accreditation status for particular methods and analyses. Matrix: Non Potable Water Manganese TX 1090 10155609 Molybdenum TX 1100 10155609 Nickel TX 1105 10155609 Phosphorus, total TX 1910 10155803 Potassium TX 1125 10155609 Selenium TX 1140 10 155609 Silica-dissolved TX 1995 10155609 Silver TX 1150 10155609 Sodium TX 1155 10155609 Strontium TX 1160 10155609 Thallium TX 1165 10155609 Tin TX 1175 10155609 Titanium TX 1180 10155609 Vanadium TX 1185 10155609 Zinc TX 1190 10155609 Method EPA 6020 Analyte AB Analyte ID Method ID Aluminum TX 1000 10156204 Antimony TX 1005 10156204 Arsenic TX 1010 10156204 Barium TX 1015 10156204 Beryllium TX 1020 10156204 Cadmium TX 1030 10156204 Calcium TX 1035 10156204 Chromium TX 1040 10156204 Cobalt TX 1050 10156204 Copper TX 1055 10156204 Iron TX 1070 10156204 . Lead TX 1075 10156204 Lithium TX 1080 10156204 Magnesium TX 1085 10156204 Page 12of41 Texas Commission on Environmental Quality NELAP -Recognized Laboratory Fields of Accreditation TestAmerica Laboratories, Inc. -Austin 14050 Summit Drive, Suite A100 Austin, TX 78728-7149 Certificate: Expiration Date: Issue Date: T104704217-10-5 6/30/2010 3/29/2010 These fields of accreditation supercedeall previous fields. The Texas Commission on Environmental Quality urges customers to verify the laboratory's current accreditation status for particular methods and analyses. Matrix: Non Potable Water Manganese TX 1090 10156204 Molybdenum TX 1100 10156204 · N ickel TX 1105 10156204 Potassium TX 1125 10156204 Selen ium TX 1140 10156204 Silver TX 1150 10156204 Sodium TX 1155 10156204 Strontium TX 1160 10156204 Thallium TX 1165 10156204 Tin TX 1175 10156204 Titanium TX 1180 10156204 Vanadium TX 1185 10156204 Zinc TX 1190 10156204 Method EPA 608 Analyte AB Analyte ID Method ID Aroclor-1016 (PCB-1016) TX 8880 10103603 Aroclor-1221 (PCB-1221) TX 8885 10103603 Aroclor-1232 (PCB-1232) TX 8890 10103603 Aroclor-1242 (PCB-1242) TX 8895 10103603 Aroclor-1248 (PCB-1248) TX 8900 10103603 Aroclor-1254 (PCB-1254) TX 8905 10103603 Aroclor-1260 (PCB-1260) TX 8910 10103603 Method EPA 624 Analyte AB Analyte ID Method ID 1, 1, 1-Trichloroethane TX 5160 10107207 1, 1,2,2-Tetrachloroethane TX 5110 10107207 1, 1,2-Trichloroethane TX 5165 10107207 1, 1-Dichloroethane TX 4630 10107207 1, 1-Dichloroethylene (1 , 1-Dichloroethene) TX 4640 10107207 1,2-Dibromoethane (EDB , Ethylene dibromide) TX 4585 10107207 1,2-Dichlorobenzene TX 4610 10107207 Page13of41 Texas Commission on Environmental Quality NELAP -Recognized Laboratory Fields of Accreditation TestAmerlca Laboratories, Inc. -Austin 14050 Summit Drive, Suite A100 Austin, TX 78728-7149 Certificate: Expiration Date: Issue Date: T104704217-10-5 6/30/2010 3/29/2010 These fields of accreditation supercedeall previous fields. The Texas Commission on Environmental Quality urges customers to verify the laboratory's current accreditation status for particular methods and analyses. Matrix: Non Potable Water 1,2-Dichloroethane TX 4635 10107207 1,2-Dichloropropane TX 4655 10107207 1,3-Dichlorobenzene TX 4615 10107207 1,4-Dichlorobenzene TX 4620 10107207 2-Butanone (Methyl ethyl ketone, MEK) TX 4410 10107207 2-Chloroethyl vinyl ether TX 4500 10107207 Acetone TX 4315 10107207 Acrolein (Propenal) TX 4325 10107207 Acrylonitrile TX 4340 10107207 Benzene TX 4375 10107207 Bromodichloromethane TX 4395 10107207 Bromoform TX 4400 10107207 Bromomethane (Methyl bromide) TX 4950 10107207 Carbon tetrachloride TX 4455 10107207 Chlorobenzene TX 4475 10107207 Chloroethane TX 4485 10107207 Chloroform TX 4505 10107207 Chloromethane (Methyl chloride) TX 4960 10107207 cis-1,2-Dichloroethylene TX 4645 10107207 cis-1,3-Dichloropropylene TX 4680 10107207 Dibromochloromethane TX 4575 10107207 Ethylbenzene TX 4765 10107207 m+p-xylene TX 5240 10107207 Methyl tert-butyl ether (MTBE) TX 5000 10107207 Methylene chloride TX 4975 10107207 Naphthalene TX 5005 10107207 a-Xylene TX 5250 10107207 Tetrachloroethylene (Perchloroethylene) TX 5115 10107207 Toluene TX 5140 10107207 trans-1,2-Dichloroethylene TX 4700 10107207 Page 14 of 41 Texas Commission on Environmental Quality NELAP -Recognized Laboratory Fields of Accreditation TestAmerica Laboratories, Inc. -Austin 14050 Summit Drive, Suite A100 Austin, TX 78728-7149 Certificate: Expiration Date: Issue Date: T104704217-10-5 6/30/2010 3/29/2010 These fields of accreditation supercedeall previous fields. The Texas Commission on Environmental Quality urges customers to verify the laboratory's current accreditation status for particular methods and analyses. Matrix: Non Potable Water trans-1,3-Dichloropropylene TX 4685 10107207 Trichloroethane (Trichloroethylene) TX 5170 10107207 Trichlorofluoromethane TX 5175 10107207 Vinyl chloride TX 5235 10107207 Xylene (total) TX 5260 10107207 Method EPA 625 Analyte AB Analyte ID Method ID 1,2,4,5-Tetrachlorobenzene TX 6715 10107401 1,2,4-Trichlorobenzene TX 5155 10107401 1,2-Dichlorobenzene TX 4610 10107401 1,3-Dichlorobenzene TX 4615 10107401 1,4-Dichlorobenzene TX 4620 10107401 2 , 3,4 ,6-T etrachlorophenol TX 6735 10107401 2,4, 5-Trichlorophenol TX 6835 10107401 2,4,6-Trichlorophenol TX 6840 10107401 2,4-Dichlorophenol TX 6000 10107401 2,4-Dimethylphenol TX 6130 10107401 2,4-Dinitrophenol TX 6175 10107401 2,4-Dinitrotoluene (2,4-DNT) TX 6185 10107401 2 ,6-Dinitrotoluene (2 ,6-DNT) TX 6190 10107401 2-Chloronaphthalene TX 5795 10107401 2-Chlorophenol TX 5800 10107401 2-Methyl-4,6-dinitrophenol TX 6360 10107401 2-Methylphenol (o-Cresol) TX 6400 10107401 2-Nitrophenol TX 6490 10107401 3,3'-Dichlorobenzidine TX 5945 10107401 4-Bromophenyl phenyl ether TX 5660 10107401 4-Chloro-3-methylphenol TX 5700 10107401 4-Chlorophenyl phenylether TX 5825 10107401 4-Methylphenol {p-Cresol) TX 6410 10107401 4-Nitrophenol TX 6500 10107401 Page 15 of 41 Texas Commission on Environmental Quality NELAP -Recognized Laboratory Fields of Accreditation TestAmerica Laboratories, Inc. -Austin 14050 Summit Drive, Suite A100 Austin, TX 78728-7149 Certificate: Expiration Date: Issue Date: T104704217-10-5 6/30/2010 3/29/2010 These fields of accreditation supercedeall previous fields. The Texas Commission on Environmental Quality urges customers to verify the laboratory's current accreditation status for particular methods and analyses. Matrix: Non Potable Water Acenaphthene TX 5500 10107401 Acenaphthyiene TX 5505 10107401 Anthracene TX 5555 10107401 Benzidine TX 5595 10107401 Benzo(a)anthracene TX 5575 10107401 Benzo(a)pyrene TX 5580 10107401 Benzo(b )fluoranthene TX 5585 10107401 Benzo(g, h, i)perylene TX 5590 10107401 Benzo(k)fluoranthene TX 5600 10107401 bis(2-Chloroethoxy)methane TX 5760 10107401 bis(2-Chloroethyl) ether TX 5765 10107401 bis(2-Chioroisopropyl) ether TX 5780 10107401 bis(2-Ethylhexyl) phthalate (DEHP) TX 6255 10107401 Butyl benzyl phthalate TX 5670 10107401 Chrysene TX 5855 10107401 Dibenz(a,h) anthracene TX 5895 10107401 Diethyl phthalate TX 6070 10107401 Dimethyl phthalate TX 6135 10107401 Di-n-butyl phthalate TX 5925 10107401 Di-n-octyl phthalate TX 6200 10107401 Fluoranthene TX 6265 10107401 Fluorene TX 6270 10107401 Hexachlorobenzene TX 6275 10107401 Hexachlorobutadiene TX 4835 10107401 Hexachlorocyclopentadiene TX 6285 10107401 Hexach loroethane TX 4840 10107401 lndeno(1,2,3-cd) pyrene TX 6315 10107401 lsophorone TX 6320 10107401 Naphthalene TX 5005 10107401 Nitrobenzene TX 5015 10107401 Page 16of41 Texas Commission on Environmental Quality NELAP -Recognized Laboratory Fields of Accreditation TestAmerica Laboratories, Inc. -Austin 14050 Summit Drive, Suite A100 Austiri, TX 78728-7149 Certificate: Expiration Date: Issue Date: T104704217-10-5 6/30/2010 3/29/2010 These fields of accreditation supercedeall previous fields. The Texas Commission on Environmental Quality urges customers to verify the laboratory's current accreditation status for particular methods and analyses. Matrix: Non Potable Water n-Nitrosodiethylamine TX 6525 10107401 n-Nitrosodimethylamine TX 6530 10107401 n-Nitroso-di-n-butylamine TX 5025 10107401 n-Nitrosodi-n-propylamine TX 6545 10107401 n-Nitrosodiphenylamine TX 6535 1010740 1 Pentachlorobenzene TX 6590 10107401 Pentachlorophenol TX 6605 10107401 Phenanthrene TX 6615 10107401 Phenol TX 6625 10107401 Pyrene TX 6665 10107401 Pyridine TX 5095 10107401 Method EPA 7196 Analyte AB Analyte ID Method ID Chromium VI TX 1045 10162400 Method EPA 7470 Analyte AB Analyte ID Method ID Mercury TX 1095 10165807 Method EPA 8015 Analyte AB Analyte ID Method ID Diesel range organics (ORO) TX 9369 10173601 Ethanol TX 4750 10173601 Ethylene glycol TX 4785 10173601 Gasoline range organics (GRO) TX 9408 10173601 lsobutyl alcohol (2-Methyl-1-propanol) TX 4875 10173601 lsopropanol TX 4885 10173601 Methanol TX 4930 10173601 n-Butyl alcohol TX 4425 10173601 n-Propanol TX 5055 10173601 Propylene Glycol TX 6657 10173601 tert-Butyl alcohol TX 4420 10173601 Page 17 of41 --------------· Texas Commission on Environmental Quality NELAP -Recognized Laboratory Fields of Accreditation TestAmeri ca Laboratories, Inc. -Austin 14050 Summit Drive, Suite A100 Austin, TX 78728-7149 Certificate: Expiration Date: Issue Date: T104704217-10-5 6/30/2010 3/29/2010 These fields of accreditation supercedeall previous fields . The Texas Comm ission on Environmental Quality urges customers to verify the laboratory's current accreditation status for particular methods and analyses. Matrix: Non Potable Water Method EPA 8082 Analyte · AB Analyte ID Method ID Aroclor-1016 (PCB-1016) TX 8880 10179007 Aroclor-1221 (PCB -1221) TX 8885 10179007 Aroclor-1232 (PCB-1232) TX 8890 10179007 Aroclor-1242 (PCB -1242) TX 8895 10179007 Aroclor-1248 (PCB-1248) TX 8900 10179007 Aroclor-1254 (PCB-1254) TX 8905 10179007 Aroclor-1260 (PCB-1260) TX 8910 10179007 Method EPA 8260 Analyte AB Analyte ID Method ID 1, 1, 1,2-Tetrachloroethane TX 5105 10184802 1, 1, 1-Trichloroethane TX 5160 10184802 1, 1,2,2-Tetrachloroethane TX 5110 10184802 1, 1,2-Trichloroethane TX 5165 10184802 1, 1-Dichloroethane TX 4630 10184802 1, 1-Dichloroethylene (1 , 1-Dichloroethene) TX 4640 10184802 1, 1-D ichloropropene TX 4670 10184802 1,2, 3-T rich lorobenzene TX 5150 10184802 1,2,3-Trichloropropane TX 5180 10184802 1,2,4-Trichlorobenzene TX 5155 l0184802 1,2,4-Trimethylbenzene TX 5210 10184802 1,2-Dibromo-3-chloropropane (DBCP) TX 4570 10184404 1,2-Dibromoethane (EDB , Ethylene dibromide) TX 4585 10 184802 1,2-Dichlorobenzene TX 4610 1018 4802 1,2-Dichloroethane TX 4635 10184802 1,2-Dichloropropane TX 4655 10184802 1,3 ,5-Trimethylbenzene TX 5215 10184802 1,3-Dichlorobenzene TX 4615 10184802 1,3-Dichloropropane TX 4660 10184802 1,4-Dichlorobenzene TX 4620 10184802 Page 18 of 41 Texas Commission on Environmental Quality NELAP -Recognized Laboratory Fields of Accreditation TestAmerica Laboratories, Inc. -Austin 14050 Summit Drive, Suite A 100 Austin, TX 78728-7149 Certificate: Expiration Date: Issue Date: T104704217-10-5 6/30/2010 3/29/2010 These fields of accreditation supercedeall previous fields. The Texas;.Commlssion on Environmental Quality urges customers to verify the laboratory's current accreditation status for particular methods and analyses. Matrix: Non Potable Water 1,4-Dioxane (1,4-Diethyleneoxide) TX 4735 10184802 1-Chlorohexane TX 4510 10184802 2 ,2-Dichloropropane TX 4665 10184802 2-Butanone (Methyl ethyl ketone, MEK) TX 4410 10184802 2-Chloroethyl vinyl ether TX 4500 10184802 2-Chlorotoluene TX 4535 10184802 2-Hexanone TX 4860 10184802 2-Nitropropane TX 5020 10184802 4-Chlorotoluene TX 4540 10184802 4-1 sopropyltol uene TX 4915 10184802 4-Methyl-2-pentanone (MIBK) TX 4995 10184802 Acetone TX 4315 10184802 Acetonitrile TX 4320 10184802 Acrolein (Propenal) TX 4325 10184802 Acrylonitrile TX 4340 10184802 Allyl chloride (3-Chloropropene) TX 4355 10184802 Benzene TX 4375 10184802 Benzyl chloride TX 5635 10184802 Bromobenzene TX 4385 10184802 Bromochloromethane TX 4390 10184802 Bromodichloromethane TX 4395 10184802 Bromoform TX 4400 10184802 Bromomethane (Methyl brom ide) TX 4950 10184802 Carbon disulfide TX 4450 10184802 Carbon tetrachloride TX 4455 10184802 Chlorobenzene TX 4475 10184802 Chloroethane TX 4485 10184802 Chloroform TX 4505 10184802 Chloromethane (Methyl chloride) TX 4960 10184802 Chloroprene TX 4525 10184802 Page 19 of 41 Texas Commission on Environmental Quality NELAP -Recognized Laboratory Fields of Accreditation TestAmerica Laboratories, Inc. -Austin 14050 Summit Drive, Suite A100 Austin, TX 78728-7149 Certificate: Expiration Date: Issue Date: T104704217-10-5 6/30/2010 3/29/2010 These fields of accreditation supercedeall previous fields. The Texas Commission on Environmental Quality urges customers to verify the laboratory's current accreditation status for particular methods and analyses . Matrix: Non Potable Water cis-1 ,2-Dichloroethylene TX 4645 10184802 cis-1 ,3-Dichloropropylene TX 4680 10184802 Dibromochloromethane TX 4575 10184802 Dibromomethane TX 4595 10184802 Dichlorodifluoromethane TX 4625 10184802 Diethyl ether TX 4725 10184802 Epichlorohydrin (1-Chloro-2,3-epoxypropane) TX 4745 10184802 Ethanol TX 4750 10184802 Ethyl methacrylate TX 4810 10184802 Ethyl benzene TX 4765 10184802 Ethylene oxide TX 4795 10184802 Hexachlorobutadiene TX 4835 10184802 lodomethane (Methyl iodide) TX 4870 10184802 lsobutyl alcohol (2-Methyl-1-propanol} TX 4875 10184802 lsopr?PYI ether TX 4905 10184802 lsopropylbenzene TX 4900 10184802 m+p-xylene TX 5240 10184802 Methacrylonitrile TX 4925 10184802 Methyl acetate TX 4940 10184802 Methyl methacrylate TX 4990 10184802 Methyl tert-butyl ether (MTBE) TX 5000 10184802 Methylene chloride TX 4975 10184802 Naphthalene TX 5005 10184802 n-Butyl alcohol TX 4425 10184802 n-Butylbenzene TX 4435 10184802 . n-Propylbenzene TX 5090 10184802 a-Xylene TX 5250 10184802 Pentachloroethane TX 5035 10184802 Propionitrile (Ethyl cyanide) TX 5080 10184802 sec-Butylbenzene TX 4440 10184802 Page 20 of41 Texas Commission on Environmental Quality NELAP -Recognized Laboratory Fields of Accreditation TestAmerica Laboratories, Inc. -Austin 14050 Summit Drive, Suite A100 Austin, TX 78728-7149 Certificate: Expiration Date: Issue Date: T104704217-10-5 6/30/2010 3/29/2010 These fields of accreditation supercedeall previous fields. The Texas Commission on Environmental Quality urges customers to verify the laboratory's current accreditation status for particular methods and analyses. Matrix: Non Potable Water Styrene TX 5100 10184802 tert-Butyl alcohol TX 4420 10184802 tert-Butylbenzene TX 4445 10184802 Tetrachloroethylene (Perchloroethylene) TX 5115 10184802 Toluene TX 5140 10184802 trans-1 ,2-Dichloroethylene TX 4700 10184802 trans-1,3-Dichloropropylene TX 4685 10184802 trans-1 ,4-Dichloro-2-butene TX 4605 10184802 Trichloroethane (Trichloroethylene) TX 5170 10184802 Trichlorofluoromethane TX 5175 10184802 Trichlorotrifluoroethane TX 5185 10184802 Vinyl acetate TX 5225 10184802 Vinyl chloride TX 5235 10184802 Xylene (total) TX 5260 10184802 Method EPA 8270 Analyte AB Analyte ID Method ID 1,2,4,5-Tetrachlorobenzene TX 6715 10185805 1,2,4-Trichlorobenzene TX 5155 10185805 1,2-Dichlorobenzene TX 4610 10185805 1,2-Diphenylhydrazine TX 6220 10185805 1,3,5-Trinitrobenzene (1,3 ,5-TNB) TX 6885 10185805 1,3-Dichlorobenzene TX 4615 10185805 1,3-Dinitrobenzene (1,3-DNB) TX 6160 10185805 1,4-Dichlorobenzene TX 4620 10185805 1,4-Dinitrobenzene TX 6165 10185203 1,4-Naphthoquinone TX 6420 10185805 1,4-Phenylenediamine TX 6630 10185601 1-Naphthylamine TX 6425 10185805 2 , 3 ,4, 6-T etrachlorophenol TX 6735 10185805 2,4 ,5-Trichlorophenol TX 6835 10185805 2 ,4,6-Trichlorophenol TX 6840 10185805 Page 2 1 of 41 Texas Commission on Environmental Quality NELAP -Recognized Laboratory Fields of Accreditation TestAmerica Laboratories, Inc. -Austin 14050 Summit Drive, Suite A100 Austin, TX 78728-7149 Certificate: Expiration Date: Issue Date: T104704217-10-5 6/30/2010 3/29/2010 These fields of accreditation supercedeall previous fields. The Texas Commission on Environmental Quality urges customers to verify the laboratory's current accreditation status for particular methods and analyses. Matrix: Non Potable Water 2,4-Dichlorophenol TX 6000 10185805 2,4-Dimethylphenol TX 6130 10185805 2,4-Dinitrophenol TX 6175 10185805 2,4-Dinitrotoluene (2,4-DNT) TX 6185 10185805 2,6-Dichlorophenol TX 6005 10185805 2,6-Dinitrotoluene (2 ,6-DNT) TX 6190 10185805 2-Acetylaminofluorene TX 5515 10185805 2-Chloronaphthalene TX 5795 10185805 2-Chlorophenol TX 5800 10185805 2-Methyl-4,6-dinitrophenol TX 6360 10185805 2-Methylnaphthalene TX 6385 10185805 2-Methylphenol (o-Cresol) TX 6400 10185805 2-Naphthylamine TX 6430 10185805 2-Nitroaniline TX 6460 10185805 2-N itrophenol TX 6490 10185805 2-Picoline (2-Methylpyridine) TX 5050 10185805 3,3'-Dichlorobenzidine TX 5945 10185805 3,3'-Dimethylbenzidine TX 6120 10185805 3-Methylcholanthrene TX 6355 10185805 3-Nitroaniline TX 6465 10185805 4,4'-Methylenebis(2-chloroaniline) TX 6365 10185805 4-Aminobiphenyl TX 5540 10185805 4-Bromophenyl phenyl ether TX 5660 10185805 4-Chloro-3-methylphenol TX 5700 10185805 4-Chloroaniline TX 5745 10185805 4-Chlorophenyl phenylether TX 5825 10185805 4-Dimethyl aminoazobenzene TX 6105 10186002 4-Methylphenol (p-Cresol) TX 6410 10185805 4-Nitroaniline TX 6470 10185805 4-Nitrophenol TX 6500 10185805 Page 22 of41 .. Texas Commission on Environmental Quality NELAP -Recognized Laboratory Fields of Accreditation TestAmerica Laboratories, Inc. -Austin 14050 Summit Drive, Suite A100 Austin, TX 78728-7149 Certificate: Expiration Date: Issue Date: T104704217-10-5 6/30/2010 3/29/2010 These fields of accreditation supercedeall previous fields. The Texas Commission on Environmental Quality urges customers to verify the laboratory's current accreditation status for particular methods and analyses. Matrix: Non Potable Water 5-N itro-o-toluidine TX 6570 10185805 7 , 12-Dimethylbenz(a) anthracene TX 6115 10185805 a-a-Dimethylphenethylamine TX 6125 10185805 Acenaphthene TX 5500 10185805 Acenaphthylene TX 5505 10185805 Acetophenone TX 5510 10185805 Aniline TX 5545 10185805 Anthracene TX 5555 10185805 Aramite TX 5560 10186002 Benzidine TX 5595 10185805 Benzo( a )a nth racene TX 5575 10185805 Benzo(a)pyrene TX 5580 10185805 Benzo(b )fluoranthene TX 5585 10185805 Benzo(g, h, i)perylene TX 5590 10185805 Benzo(k)fluoranthene TX 5600 10185805 Benzoic acid TX 5610 10185805 Benzyl alcohol TX 5630 10185805 Biphenyl TX 5640 10185601 bis(2-Chloroethoxy)methane TX 5760 10185805 bis(2-Chloroethyl) ether TX 5765 10185805 bis(2-Chloroisopropyl) ether TX 5780 10185805 bis(2-Ethylhexyl) phthalate (DEHP) TX 6255 10185805 Butyl benzyl phthalate TX 5670 10185805 Carbazole TX 5680 10185805 Chlorobenzilate TX 7260 10185805 Chrysene TX 5855 10185805 Diallate TX 7405 10185805 Dibenz(a,h) anthracene TX 5895 10185805 Dibenzo(a,e) pyrene TX 5890 10185805 Dibenzofuran TX 5905 10185805 Page 23 of41 i 1 Texas Commission on Environmental Quality NELAP -Recognized Laboratory Fields of Accreditation TestAmerica Laboratories, Inc. -Austin 14050 Summit Drive, Suite A100 Austin, TX 78728-7149 Certificate: Expiration Date: Issue Date: T104704217-10-5 6/30/2010 3/29/2010 These fields of accreditation supercedeall previous fields. The Texas Commission on Environmental Quality urges customers to verify the laboratory's current accreditation status for particular methods and analyses. Matrix: Non Potable Water Diethyl phthalate TX 6070 10185805 Dimethoate TX 7475 10185601 Dimethyl phthalate TX 6135 10185805 Di-n-butyl phthalate TX 5925 10185805 Di-n-octyl phthalate TX 6200 10185805 Dinoseb (2-sec-butyl-4,6-dinitrophenol, DNBP) TX 8620 10185805 Disulfoton TX 8625 10185203 Ethyl methanesulfonate TX 6260 10185805 Famphur TX 7580 10186002 Fluoranthene TX 6265 10185805 Fluorene TX 6270 10185805 Hexachlorobenzene TX 6275 10185805 Hexachlorobutadiene TX 4835 10185805 Hexachlorocyclopentadiene TX 6285 10185805 Hexachloroethane TX 4840 10185805 Hexachloropropene TX 6295 10185805 lndeno(1,2,3-cd) pyrene TX 6315 10185805 lsodrin TX 7725 10185805 lsophorone TX 6320 10185805 lsosafrole TX 6325 10185805 Kepone TX 7740 10185805 Methapyrilene TX 6345 10185805 Methyl methanesulfonate TX 6375 10185805 Naphthalene TX 5005 10185805 Nitrobenzene TX 5015 10185805 Nitroquinoline-1-oxide TX 6515 10185805 n-Nitrosodiethylamine TX 6525 10185805 n-Nitrosodimethylamine TX 6530 10185805 n-Nitroso-di-n-butylamine TX 5025 10185805 n-Nitrosodi-n-propylamine TX 6545 10185805 Page 24 of 41 Texas Commission on Environmental Quality NELAP -Recognized Laboratory Fields of Accreditation TestAmerica Laboratories, Inc. -Austin 14050 Summit Drive, Suite A100 Austin, TX 78728-7149 Certificate: Expiration Date: Issue Date: T104704217-10-5 6/30/2010 3/29/2010 These fields of accreditation supercedeall previous fields. The Texas Commission on Environmental Quality urges customers to verify the laboratory's current accreditation status for particular methods and analyses. Matrix: Non Potable Water n-Nitrosodiphenylamine TX 6535 10185805 n-Nitrosomethylethylamine TX 6550 10185805 n-Nitrosomorpholine TX 6555 10185805 n-Nitrosopiperidine TX 6560 10185805 n-Nitrosopyrrolidine TX 6565 10185805 o,o ,o-Triethyl phosphorothioate TX 8290 10185805 o-Toluidine TX 5145 10185805 Parathion, ethyl TX 7955 10185601 Parathion , methyl (Methyl parathion) TX 7825 10185203 Pentachlorobenzene TX 6590 10185805 Pentachloronitrobenzene TX 6600 10185805 Pentachlorophenol TX 6605 10185805 Phenacetin TX 6610 10185805 Phenanthrene TX 6615 10185805 Phenol TX 6625 10185805 Phorate TX 7985 10185203 Pronamide (Kerb) TX 6650 10185805 Pyrene TX 6665 10185805 Pyridine TX 5095 10185805 Safrole TX 6685 10185805 Sulfotepp TX 8155 10186002 Thionazin (Zinophos) TX 8235 10185805 Method EPA 9012 Analyte AB Analyte ID Method ID Amenable cyanide TX 1510 10193405 Total Cyanide TX 1635 10193405 Method EPA 9034 Analyte AB Analyte ID Method ID Total sulfides TX 2010 10196006 Method EPA 9040 Analyte AB Analyte ID Method ID Page 25 of 41 Texas Commission on Environmental Quality NELAP -Recognized Laboratory Fields of Accreditation TestAmerica. Laboratories, Inc. -Austin 14050 Summit Drive, Suite A100 Austin, TX 78728-7149 Certificate: Expiration Date: Issue Date: T104704217-10-5 6/30/2010 3/29/2010 These fields of accreditation supercedeall previous fields. The Texas Commission on Environmental Quality urges customers to verify the laboratory's current accreditation status for particular methods and analyses. Matrix: Non Potable Water pH TX 1900 10197203 Method EPA 9050 Analyte AB Analyte ID Method ID Conductivity TX 1610 10198808 Method EPA 9056 Analyte AB Analyte ID Method ID Bromide TX 1540 10199209 Chloride TX 1575 10199209 Fluoride TX 1730 10199209 Nitrate as N TX 1810 10199209 Nitrite as N TX 1840 10199209 Orthophosphate as P TX 1870 10199209 Sulfate TX 2000 10199209 Method EPA 9060 Analyte AB Analyte ID Method ID Total organic carbon TX 2040 10200201 Method EPA 9066 Analyte AB Analyte ID Method ID Total phenolics TX 1905 10200609 Method Iowa OA-1 ; GRO Analyte AB Analyte ID Method ID Volatile Petroleum Hydrocarbons TX 10330 90016403 Method Iowa OA-2 ; DRO Analyte AB Analyte ID Method ID Extractable Petroleum Hydrocarbons TX 10331 90016607 Method QuickChem 10-204-00-1-X Analyte AB Analyte ID Method ID Total Cyanide TX 1635 60030800 Method RSK 175 Analyte AB Analyte ID Method ID Carbon dioxide TX 3755 RSK 175 Page 26 of41 Texas Commission on Environmental Quality NELAP -Recognized Laboratory Fields of Accreditation TestAmerlca Laboratories, Inc. -Austin 14050 Summit Drive, Suite A100 Austin, TX 78728-7149 Certificate: Expiration Date: Issue Date: T104704217-10-5 6/30/2010 3/29/2010 These fields of accreditation supercedeall previous fields. The Texas Commission on Environmental Quality urges customers to verify the laboratory's current accreditation status for particular methods and analyses. Matrix: Non Potable Water Ethane TX 4747 RSK 175 Ethylene TX 4752 RSK 175 lsobutane (2-methylpropane) TX 4942 RSK 175 Methane TX 4926 RSK 175 n-Butane TX 5007 RSK 175 Propane · TX 5029 RSK 175 Method SM 2320 B Analyte AB Analyte ID Method ID Alkalin ity as CaC03 TX 1505 20003003 Method SM 2340 B Analyte AB Analyte ID Method ID Total hardness as CaC03 TX 1755 20003401 Method SM 2340 C Analyte AB Analyte ID Method ID Total hardness as CaC03 TX 1755 20003605 Method SM 2510 B Analyte AB Analyte ID Method ID Conductivity TX 1610 20003809 Method SM 2540 B Analyte AB Analyte ID Method ID Residue-total TX 1950 20004608 Method SM 2540 C Analyte AB Analyte ID Method ID Residue-filterable (TDS) TX 1955 20004404 Method SM 2540 D Analyte AB Analyte ID Method ID Residue-nonfilterable (TSS) TX 1960 20004802 Method SM 2540 F Analyte AB Analyte ID Method ID Residue-settleable TX 1965 20005009 Method SM 3500 Cr D Anatyte AB Analyte ID Method ID Page 27 of41 , Texas Commission on Environmental Quality NELAP -Recognized Laboratory Fields of Accreditation TestAmerica Laboratories, Inc. -Austin 14050 Summit Drive, Suite A100 Austin, TX 78728-7149 Certificate: Expiration Date: Issue Date: 1104704217-10-5 6/30/2010 3/29/2010 These fields of accreditation supercedeall previous fields. The Texas Commission on Environmental Quality urges customers to verify the laboratory's current accreditation status for particular methods and analyses . Matrix: Non Potable Water Chromium VI TX 1045 20009001 Method SM 4500 CN E Analyte AB Analyte ID Method ID Total Cyanide TX 1635 20021209 Method SM 4500 CN G Analyte AB Analyte ID Method ID Amenable cyanide TX 1510 20021607 Method SM 4500 F-C Analyte AB Analyte ID Method ID Fluoride TX 1730 20012800 Method SM 4500 H+ 8 Analyte AB Analyte ID Method ID pH TX 1900 20016404 Method SM 4500 N03 F Analyte AB Analyte ID Method ID Nitrate-nitrite TX 1820 20024402 Method SM 4500 P F Analyte AB Analyte ID Method ID Phosphorus , total TX 1910 20026000 Method SM 4500 S2-F Analyte AB Analyte ID Method ID Sulfide TX 2005 20126209 Method SM 5220 D Analyte AB Analyte ID Method ID Chemical oxygen demand TX 1565 20027809 Method SM 5310 C Analyte AB Analyte ID Method ID Total organic carbon TX 2040 20028200 Method TCEQ 1005 Analyte AB Analyte ID Method ID Total Petroleum Hydrocarbons (TPH) TX 2050 90019208 Page 28 of 41 Texas Commission on Environmental Quality NELAP -Recognized Laboratory Fields of Accreditation TestAmerica Laboratories, Inc. -Austin 14050 Summit Drive, Suite A 100 Austin, TX 78728-7149 Certificate: Expiration Date: Issue Date: T104704217-10-5 6/30/2010 3/29/2010 These fields of accreditation supercedeall previous fields. The Texas Commission on Environmental Quality urges customers to verify the laboratory's current accreditation status for particular methods and analyses. Matrix: Non Potable Water Method Tennessee EPH Analyte AB Analyte ID Method ID Extractable Petroleum Hydrocarbons TX 10331 Tennessee EPH Method Tennessee GRO Analyte AB Analyte ID Method ID Gasoline range organics (GRO) TX 9408 Tennessee GRO Page 29 of 41 Texas Commission on Environmental Quality NELAP -Recognized Laboratory Fields of Accreditation TestAmerica Laboratories, Inc; -Austin 14050 Summit Drive, Suite A100 Austin, TX 78728-7149 Certificate: Expiration Date: Issue Date: T104704217 -10-5 6/30/2010 3/29/2010 These fields of accreditation supercedeall previous fields. The Texas Commission on Environmental Quality urges customers to verify the laboratory's current accreditation status for particular methods and analyses. Matrix: Solid & Hazardous Material Method CA HML 939-M Analyte AB Analyte ID Method ID Lead , Organic TX 10329 CAHML939-M Method EPA 1020 Analyte AB Analyte ID Method ID lgnitability TX 1780 10117007 Method EPA 1311 Analyte AB Analyte ID Method ID TCLP TX 849 10118806 Method EPA 1312 Analyte AB Analyte ID Method ID SPLP TX 850 10119003 Method EPA 350.1 Analyte AB Analyte ID Method ID Ammonia asN TX 1515 10063408 Method EPA 6010 Analyte AB Analyte ID Method ID Aluminum TX 1000 10155609 Antimony TX 1005 10155609 Arsenic TX 1010 10155609 Barium TX 1015 10155609 Beryllium TX 1020 10155609 Boron TX 1025 10155609 Cadmium TX 1030 10155609 Calcium TX 1035 10155609 Chromium TX 1040 10155609 Cobalt TX 1050 10155609 Copper TX 1055 10155609 Iron TX 1070 10155609 Lead TX 1075 10155609 Magnesium TX 1085 10155609 Page 30of41 -I I Texas Commission on Environmental Quality NELAP -Recognized Laboratory Fields of Accreditation TestAmerica Laboratories, Inc. -Austin 14050 Summit Drive, Suite A100 Austin, TX 78728-7149 Certificate: Expiration Date: Issue Date: T104704217-10-5 6/30/2010 3/29/2010 These fields of accreditation supercedeall previous fields. The Texas Commission on Environmental Quality urges customers to verify the laboratory's current accreditation status for particular methods and analyses. Matrix: Solid & Hazardous Material Manganese TX 1090 10155609 Molybdenum TX 1100 10155609 Nickel TX 1105 10155609 Phosphorus , total TX 1910 10155609 Potassium TX 1125 10155609 Selenium TX 1140 10155609 Silica as Si02 TX 1990 10155609 Silver TX 1150 10155609 Sodium TX 1155 10155609 Strontium TX 1160 10155609 Thallium TX 1165 10155609 Tin TX 1175 10155609 Titanium TX 1180 10155609 Vanadium TX 1185 10155609 Zinc TX 1190 10155609 Method EPA 6020 Analyte AB Analyte ID Method ID Aluminum TX 1000 10156204 Antimony TX 1005 10156204 Arsenic TX 1010 10156204 Barium TX 1015 10156204 Beryllium TX 1020 10156204 Cadmium TX 1030 10156204 Calcium TX 1035 10156204 Chromium TX 1040 10156204 Cobalt TX 1050 10156204 Copper TX 1055 10156204 Iron TX 1070 10156204 Lead TX 1075 10156204 Lithium TX 1080 10156204 Magnesium TX 1085 10156204 Page 31 of41 Texas Commission on Environmental Quality NELAP -Recognized Laboratory Fields of Accreditation TestAmerica Laboratories, Inc. -Austin 14050 Summit Drive, Suite A100 Austin, TX 78728-7149 Certificate: Expiration Date: Issue Date: T104704217-10-5 6/30/2010 3/29/2010 These fields of accreditation supercedeall previous fields. The Texas Commission on Environmental Quality urges customers to verify the laboratory's current accreditation status for particular methods and analyses. Matrix: Solid & Hazardous Material . Manganese TX 1090 10156204 Molybdenum TX 1100 10156204 Nickel TX 1105 10156204 Potassium TX 1125 10156204 Selenium TX 1140 10156204 Silver TX 1150 10156204 Sodium TX 1155 10156204 Strontium TX 1160 10156204 Thallium TX 1165 10156204 Tin TX 1175 10156204 Titanium TX 1180 10156204 Vanadium TX 1185 10156204 Zinc TX 1190 10156204 Method EPA 7196 Analyte AB Analyte ID Method ID Chromium VI TX 1045 10162400 Method EPA 7471 Analyte AB Analyte ID Method ID Mercury TX 1095 10166208 Method EPA 8015 Analyte AB Analyte ID Method ID 2-Propanol (lsopropyl alcohol) TX 4895 10173601 Diesel range organics (ORO) TX 9369 10173601 Ethanol TX 4750 10173601 Ethylene glycol TX 4785 10173601 Gasoline range organics (GRO) TX 9408 10173601 lsobutyl alcohol (2-Methyl-1-propanol) TX 4875 10173601 Methanol Tx · 4930 10173601 n-Butyl alcobol TX 4425 10173601 n-Propanol TX 5055 10173601 Propylene Glycol TX 6657 10173601 Page 32 of41 Texas Commission on Environmental Quality NELAP -Recognized Laboratory Fields of Accreditation TestAmerica Laboratories, Inc. -Austin 14050 Summit Drive, Suite A100 Austin, TX 78728-7149 Certificate: Expiration Date: Issue Date: T104704217-10-5 6/30/2010 3/29/2010 These fields of accreditation supercedeall previous fields. The Texas Commission on Environmental Quality urges customers to verify the laboratory's current accreditation status for particular methods and analyses. Matrix: Solid & Hazardous Material tert-Butyl alcohol TX 4420 10173601 Method EPA 8082 Analyte AB Analyte ID Method ID Aroclor-1016 (PCB-1016) TX 8880 10179007 Aroclor-1221 (PCB-1221) TX 8885 10179007 Aroclor-1232 (PCB-1232) TX 8890 10179007 Aroclor-1242 (PCB-1242) TX 8895 10179007 Aroclor-1248 (PCB-1248) TX 8900 10179007 Aroclor-1254 (PCB-1254) TX 8905 10179007 Aroclor-1260 (PCB-1260) TX 8910 10179007 Method EPA 8260 Analyte AB Analyte ID Method ID 1, 1, 1,2-Tetrachloroethane TX 5105 10184802 1, 1, 1-Trichloroethane TX 5160 10184802 1, 1,2,2-Tetrachloroethane TX 5110 10184802 1, 1,2-Trichloroethane TX 5165 10184802 1, 1-Dichloroethane TX 4630 10184802 1, 1-Dichloroethylene (1 , 1-D ichloroethene) TX 4640 10184802 1, 1-Dichloropropene TX 4670 10184802 1,2,3-Trichlorobenzene TX 5150 10184802 1,2 ,3-Trichloropropane TX 5180 10184802 1,2,4-Trichlorobenzene TX 5155 10184802 1,2,4-Trimethylbenzene TX 5210 10184802 1,2-Dibromo-3-chloropropane (DBCP) TX 4570 10184802 1,2-Dibromoethane (EDB , Ethylene dibromide) TX 4585 10184802 1,2-Dichlorobenzene TX 4610 10184802 1,2-Dichloroethane TX 4635 10184802 1,2-Dichloropropane TX 4655 10184802 1,3 ,5-Trimethylbenzene TX 52 15 10184802 1,3-Dichlorobenzene TX 4615 10184802 1,3-Dichloropropane TX 4660 10184802 Page 33 of41 Texas Commission on Environmental Quality NELAP -Recognized Laboratory Fields of Accreditation TestAmerica Laboratories, Inc. -Austin 14050 Summit Drive, Suite A100 Austin, TX 78728-7149 Certificate: Expiration Date: Issue Date: T104704217-10-5 6/30/2010 3/29/2010 These fields of accreditation supercedeall previous fields. The Texas Commission on Environmental Quality urges customers to verify the laboratory's current accreditation status for particular methods and analyses. Matrix: Solid & Hazardous Material 1,4-Dichlorobenzene TX 4620 10184802 1,4-Dioxane (1,4-Diethyleneoxide) TX 4735 10184802 1-Chlorohexane TX 4510 10184802 2,2-Dichloropropane TX 4665 10184802 2-Butanone (Methyl ethyl ketone , MEK) TX 4410 10184802 2-Chloroethyl vinyl ether TX 4500 10184802 2-Chlorotoluene TX 4535 10184802 2-Hexanone TX 4860 10184802 2-Nitropropane TX 5020 10184802 4-Chlorotoluene TX 4540 10184802 4-lsopropyltoluene TX 4915 10184802 4-Methyl-2-pentanone (MIBK) TX 4995 10184802 Acetone TX 4315 10184802 Acetonitrile TX 4320 10184802 Acrolein (Propenal) TX 4325 10184802 Acrylonitrile TX 4340 10184802 Allyl chloride (3-Chloropropene) TX 4355 10184802 Benzene TX 4375 10184802 Benzyl chloride TX 5635 10184802 Bromobenzene TX 4385 10184802 Bromochloromethane TX 4390 10184802 Bromodichloromethane TX 4395 10184802 Bromoforrn TX 4400 10184802 Bromomethane (Methyl bromide) TX 4950 10184802 Carbon disulfide TX 4450 10184802 Carbon tetrachloride TX 4455 10184802 Chlorobenzene TX 4475 10184802 Chloroethane TX 4485 10184802 Chloroform TX 4505 10184802 Chloromethane (Methyl chloride) TX 4960 10184802 Page 34 of 41 Texas Commission on Environmental Quality NELAP -Recognized Laboratory Fields of Accreditation TestAmerica Laboratories, Inc. -Austin 14050 Summit Drive, Suite A100 Austin, TX 78728-7149 Certificate: Expiration Date: Issue Date: T104704217-10-5 6/30/2010 3/29/2010 These fields of accreditation supercedeall previous fields. The Texas Commission on Environmental Quallty urges customers to verify the laboratory's current accreditation status for particular methods and analyses. Matrix: Solid & Hazardous Material Chloroprene TX 4525 10184802 cis-1,2-Dichloroethylene TX 4645 10184802 cis-1,3-Dichloropropylene TX 4680 10184802 Dibromochloromethane TX 4575 10184802 Dibromomethane TX 4595 10184802 Dichlorodifluoromethane TX 4625 10184802 Diethyl ether TX 4725 10184802 Epichlorohydrin (1-Chloro-2,3-epoxypropane) TX 4745 10184802 Ethanol TX 4750 10184802 Ethyl acetate TX 4755 10184802 Ethyl methacrylate TX 4810 10184802 Ethylbenzene TX 4765 10184802 Ethylene oxide TX 4795 10184802 Hexachlorobutadiene TX 4835 10184802 lodomethane (Methyl iodide) TX 4870 10184802 lsobutyl alcohol (2-Methyl-1-propanol) TX 4875 10184802 lsopropylbenzene TX 4900 10184802 m+p-xylene TX 5240 10184802 Methacrylonitrile TX 4925 10184802 Methyl methacrylate TX 4990 10184802 Methyl tert-butyl ether (MTBE) TX 5000 10184802 Methylene chloride TX 4975 10184802 Naphthalene TX 5005 10184802 n-Butyl a lcohol TX 4425 10184802 n-Butylbenzene TX 4435 10184802 n-Propylbenzene TX 5090 10184802 o-Xylene TX 5250 10184802 Pentach loroethane TX 5035 10184802 Propionitrile (Ethyl cyanide) TX 5080 10184802 sec-Butylbenzene TX 4440 10184802 Page 35 of 41 Texas Commission on Environmental Quality NELAP -Recognized Laboratory Fields of Accreditation TestAmerica Laboratories, Inc. -Austin 14050 Summit Drive, Suite A100 Austin, TX 78728-7149 Certificate: Expiration Date: Issue Date: T104704217-10-5 6/30/2010 3/29/2010 These fields of accreditation supercedeall previous fields. The Texas Commission on Environmental Quality urges customers to verify the laboratory's current accreditation status for particular methods and analyses. Matrix: Solid & Hazardous Material Styrene TX 5100 10184802 tert-Butyl alcohol TX 4420 10184802 tert-Butylbenzene TX 4445 10184802 Tetrachloroethylene (Perchloroethylene) TX 5115 10184802 Toluene TX 5140 10184802 trans-1 ,2-Dichloroethylene TX 4700 10184802 trans-1 ,3-Dichloropropylene TX 4685 10184802 trans-1,4-Dichloro-2-butene TX 4605 10184802 Trichloroethene (Trichloroethylene) TX 5170 10184802 Trichlorofluoromethane TX 5175 10184802 Trichlorotrifluoroethane TX 5185 10184802 Vinyl acetate TX 5225 10184802 Vinyl chloride TX 5235 10184802 Xylene (total) TX 5260 10184802 Method EPA 8270 Analyte AB Analyte ID Method ID 1,2,4,5-Tetrachlorobenzene TX 6715 10185805 1,2,4-Trichlorobenzene TX 5155 10185805 1,2-Dichlorobenzene TX 4610 10185805 1,2-Diphenylhydrazine TX 6220 10185805 1,3,5-Trinitrobenzene (1,3,5-TNB) TX 6885 10185805 1,3-Dichlorobenzene TX 4615 10185805 1,3-Dinitrobenzene (1 ,3-DNB) TX 6160 10185805 1,4-Dichlorobenzene TX 4620 10185805 1,4-Naphthoquinone TX 6420 10185805 1-Naphthylamine TX 6425 10185805 2,3,4,6-Tetrachlorophenol TX 6735 10185805 2,4,5-Trichlorophenol TX 6835 10185805 2,4 ,6-Trichlorophenol TX 6840 10185805 2,4-Dichlorophenol TX 6000 10185805 2,4-Dimethylphenol TX 6130 10185805 Page 36 of 41 Texas Commission on Environmental Quality NELAP -Recognized Laboratory Fields of Accreditation TestAmerica Laboratories, Inc. -Austin 14050 Summit Drive, Suite A100 Austin, TX 78728-7149 Certificate: Expiration Date: Issue Date: T104704217-10-5 6/30/2010 3/29/2010 These fields of accreditation supercedeall previous fields. The Texas Commission on Environmental Quality urges customers to verify the laboratory's current accreditation status for particular methods and analyses. Matrix: Solid & Hazardous Material 2,4-Dinitrophenol TX 6175 10185805 2,4-Dinitrotoluene (2,4-DNT) TX 6185 10185805 2 ,6-Dichlorophenol TX 6005 10185805 2,6-Dinitrotoluene (2,6-DNT) TX 6190 10185805 2-Acetylaminofluorene TX 5515 10185805 2-Chloronaphthalene TX 5795 10185805 2-Chlorophenol TX 5800 10185805 2-Methyl-4 ,6-dinitrophenol TX 6360 10185805 2-Methylnaphthalene TX 6385 10185805 2-Methylphenol (o-Cresol) TX 6400 10185805 2-Naphthylamine TX 6430 10185805 2-Nitroaniline TX 6460 10185805 2-Nitrophenol TX 6490 10185805 2-Picoline (2-Methylpyridine) TX 5050 10185805 3,3' -Dichlorobenzidi ne TX 5945 10185805 3,3'-Dimethylbenzidine TX 6120 10185805 3-Methylcholanthrene TX 6355 10185805 3-Nitroaniline TX 6465 10185805 4-Aminobiphenyl TX 5540 10185805 4-Bromophenyl phenyl ether TX 5660 10185805 4-Chloro-3-methylphenol TX 5700 10185805 4-Chloroaniline TX 5745 10185805 4-Chlorophenyl phenylether TX 5825 10185805 4-Methylphenol (p-Cresol) TX 6410 10185805 4-Nitroaniline TX 6470 10185805 4-Nitrophenol TX 6500 10185805 5-Nitro-o-toluidine TX 6570 10185805 7, 12-Dimethylbenz(a) anthracene TX 6115 10185805 a-a-Dimethylphenethylamine TX 6125 10185805 Acenaphthene TX 5500 10185805 Page 37 of41 Texas Commission on Environmental Quality NELAP -Recognized Laboratory Fields of Accreditation TestAmerica Laboratories, Inc. -Austin 14050 Summit Drive, Suite A100 Austin, TX 78728-7149 Certificate: Expiration Date: Issue Date: T104704217-10-5 6/30/2010 3/29/2010 These fields of accreditation supercedeall previous fields. The Texas Commission on Environmental Quality urges customers to verify the laboratory's current accreditation status for particular methods and analyses. Matrix: Solid & Hazardous Material Acenaphthylene TX 5505 10185805 Acetophenone TX 5510 10185805 Aniline TX 5545 10185805 Anthracene TX 5555 10185805 Benzidine TX 5595 10185805 Benzo(a)anthracene TX 5575 10185805 Benzo(a)pyrene TX 5580 10185805 Benzo(b )fluoranthene TX 5585 10185805 Benzo(g , h, i)perylene TX 5590 10185805 Benzo(k)fluoranthene TX 5600 10185805 Benzoic acid TX 5610 10185805 Benzyl alcohol TX 5630 10185805 Biphenyl TX 5640 10185805 bis(~-Chloroethoxy)methane TX 5760 10185805 bis(2-Chloroethyl) ether TX 5765 10185805 bis(2-Chloroisopropyl) ether TX 5780 10185805 bis(2-Ethylhexyl) phthalate (DEHP) TX 6255 10185805 Butyl benzyl phthalate TX 5670 10185805 Carbazole TX 5680 10185805 Chlorobenzilate TX 7260 10185805 Chrysene TX 5855 10185805 Diallate TX 7405 10185805 Dibenz(a,h) anthracene TX 5895 10185805 Dibenzo(a ,e) pyrene TX 5890 10185805 Dibenzofuran TX 5905 10185805 Diethyl phthalate TX 6070 10185805 Dimethyl phthalate TX 6135 10185805 Di-n-butyl phthalate TX 5925 10185805 · Di-n-octyl phthalate TX 6200 10185805 Dinoseb (2-sec-butyl-4,6-dinitrophenol, DNBP) TX 8620 10185805 Page 38 of41 Texas Commission on Environmental Quality NELAP -Recognized Laboratory Fields of Accreditation TestAmerica Laboratories, Inc. -Austin 14050 Summit Drive, Suite A100 Austin, TX 78728-7149 Certificate: Expiration Date: Issue Date: T104704217-10-5 6/30/2010 3/29/2010 These fields of accreditation supercedeall previous fields. The Texas Commission on Environmental Quality urges customers to verify the laboratory's current accreditation status for particular methods and analyses. Matrix: Solid & Hazardous Material Ethyl methanesulfonate TX 6260 10185805 Fluoranthene TX 6265 10185805 Fluorene TX 6270 10185805 Hexachlorobenzene TX 6275 10185805 Hexachlorobutadiene TX 4835 10185805 Hexachloroethane TX 4840 10185805 Hexachloropropene TX 6295 10185805 lndeno(1 ,2 ,3-cd) pyrene TX 6315 10 185805 lsophorone TX 6320 10185805 lsosafrole TX 6325 10185805 Kepone TX 7740 10185805 Methapyrilene TX 6345 10185805 Methyl methanesulfonate TX 6375 10185805 Naphthalene TX 5005 10185805 Nitrobenzene TX 5015 10185805 Nitroquinoline-1-oxide TX 6515 10185805 n-Nitrosodiethylamine TX 6525 10185805 n-Nitrosodimethylamine TX 6530 10185805 n-Nitroso-d i-n-butylamine TX 5025 10185805 n-Nitrosodi-n-propylamine TX 6545 10185805 n-Nitrosodiphenylamine TX 6535 10185805 n-Nitrosomethylethylamine TX 6550 10185805 n-Nitrosomorpholine TX 6555 10185805 n-Nitrosopiperidine TX 6560 10185805 n-Nitrosopyrrolidine TX 6565 10185805 o,o,o-Triethyl phosphorothioate TX 8290 10185805 o-Toluid ine TX 5145 10185805 Pentachlorobenzene TX 6590 10185805 Pentachloron itrobenzene TX 6600 10185805 Pentachlorophenol TX 6605 10185805 Page 39 of 41 Texas Commission on Environmental Quality NELAP -Recognized Laboratory Fields of Accreditation TestAmerica Laboratories, Inc. -Austin 14050 Summit Drive, Suite A100 Austin, TX 78728-7149 Certificate: Expiration Date: Issue Date: 1104704217-10-5 6/30/2010 3/29/2010 These fields of accreditation supercedeall previous fields. The Texas Commission on Environmental Quality urges customers to verify the laboratory's current accreditation status for particular methods and analyses. Matrix: Solid & Hazardous Material Phenacetin TX 6610 10185805 Phenanthrene TX 6615 10185805 Phenol TX 6625 10185805 Pronamide (Kerb) TX 6650 10185805 Pyrene TX 6665 10185805 Pyridine TX 5095 10185805 Safrole TX 6685 10185805 Method EPA 9012 Analyte AB Analyte ID Method ID Amenable cyanide TX 1510 10193405 Total Cyanide TX 1635 10193405 Method EPA 9034 Analyte AB Analyte ID Method ID Total sulfides TX 2010 10196006 Method EPA 9040 Analyte AB Analyte ID Method ID Corrosivity TX 1615 10197203 pH TX 1900 10197203 Method EPA 9045 Analyte AB Analyte ID Method ID pH TX 1900 10198400 Method EPA 9050 Analyte AB Analyte ID Method ID Conductivity TX 1610 10198808 Method EPA 9056 Analyte AB Analyte ID Method ID Bromide TX 1540 10199209 Chloride TX 1575 10199209 Fluoride TX 1730 10199209 Nitrate as N TX 1810 10199209 Nitrate-nitrite TX 1820 10199209 Page 40 of41 Texas Commission on Environmental Quality NELAP -Recognized Laboratory Fields of Accreditation TestAmerica Laboratories, Inc. -Austin 14050 Summit Drive, Suite A100 Austin, TX 78728-7149 Certificate: Expiration Date: Issue Date: T104704217-10-5 6/30/2010 3/29/2010 These fields of accreditation supercedeall previous fields. The Texas Commission on Environmental Quality urges customers to verify the laboratory's current accreditation status for particular methods and analyses. Matrix: Solid & Hazardous Material Nitrite as N TX 1840 10199209 Orthophosphate as P TX 1870 10199209 Sulfate TX 2000 10199209 Method EPA 9066 Analyte AB Analyte ID Method ID Total phenolics TX 1905 10200609 Method EPA 9095 Analyte AB Analyte ID Method ID Paint Filter Test TX 10312 10204009 Method Iowa OA-1 ; GRO Analyte AB Analyte ID Method ID Volatile Petroleum Hydrocarbons TX 10330 90016403 Method Iowa OA-2 ; ORO Analyte AB Analyte ID Method ID Extractable Petroleum Hydrocarbons TX 10331 90016607 Method SSA/ASA Part 3:34 Analyte AB Analyte ID Method ID Carbon, organic (Walkley-Black) TX 10340 SSA/ ASA Pt 3 :34 Method TCEQ 1005 Analyte AB Analyte ID Method ID Total Petroleum Hydrocarbons (TPH) TX 2050 90019208 Method Tennessee EPH Analyte AB Analyte ID Method ID Total Petroleum Hydrocarbons (TPH) TX 2050 Tennessee EPH Method Tennessee GRO Analyte AB Analyte ID Method ID Total Petroleum Hydrocarbons (TPH) TX 2050 Tennessee GRO Page 41 of 41 r BOAR_D OF REGISTRATION FOR.ENGINEERS AND LAND SUJlVEYOR_S Be It Known That Qtliutnu £. llurkl in HAVING GIVEN SATISFACTORY EVIDENCE OF T.HE NECESSARY QUALIFICATIONS WITH REGARD TO CHARACTER, EDUCATION, AND EXPERIENCE AS REQUIRED BY THE CURRENT NORTH CAROLINA ENGINEERING AND LAND SURVEYING ACT, WAS EXAMINED -DULY REGISTERED -AWARDED THIS CERTIFICATE -AND IS HEREBY AUTHORIZED TO PRACTICE AS A PROFESSIONAL ENGINEER IN THE STATE OF NORTH CAROLINA IN TESTIMONY WHEREOF: THE BOARD OF REGISTRATION ISSUES THIS CERTIFICATE UNDER THE SEAL OF THE BOARD AND SIGNATURES OF THE CHAIRMAN AND SECRETARY THIS 3RD DAY OF JULY 1985fy-· . ~~~-~~00:.12:. ~OOili,? 8.0 NONDISCRIMINATION AH C ity contractors are required to comply with C hapter 17, "Human Relations : Article Ill. "Discrimination;' Division 3. "Employment Practices." of the Code of the City of Fort Worth , p ro hi b iti ng discriminati on i n employment practices. Provider agrees that Provider, !ts employees. officers , agents , cont ractors or subcontractors, have fully complied with all prov isions of such Ord inance , and that no employee, participant. app!lcant, contractor or subcontractor has been d iscri m inated aga inst according to the terms of such Ordi nance by Prov ider , its employees , officers . agents, contractor o r subcontractors herein. CONTRACTOR Eastern Research Grouo. Inc. BY Paula G. Fields Compa ny Name (pri nt er type name of signato ry) a,..l.._Fo~ . 8950 Cal Center Dr .. #348 (Sig nature } Address Sacramento. CA 95826 Pri ncipal Eng ineer City. State. Zip Trtl e (pri nt or type) 9.0 CON FLICT OF INTERES T AFFA DA VI T STATE OF TEXAS COUNTY OF TARRANT § § § KNOWN ALL BY THESE PRESENTS : On behalf of ___ J: __ R __ G-"'"-------I swear or affirm : 1. That a ll financial conflicts of interest with any official , employee, or relative of any official or employee have been d isc lo sed in our compan y's or organization 's Statement of Qualifications package submitted to the City of Fort Worth . 2. That all financial interests and prior contracts (with a value in excess of $10 .000 ) with any company whose primary business is Involved in the product ion , process ing , transmission , or sales of natural gas has been d isclosed in our company 's or organ ization 's Statement of Qualifications package submitted to the City of Fort Worth . 3. That the company or organization agre es to comply with the eth i cal standards promulgated as Texas Occupational Code Section §137 .57 stated below in all of its dealings with regards to the City of Fort Worth Air Quality Study, regardless of whether or not the submitting comp any or organi zation is a profess iona l engineering firm : Engineers Shall be Objecllve and Truthful (aJ Engineers shall issue statements only in an objective and truthful manner. Engineers should strive to make affected parti es a ware of the engineers' professional concerns regarding partJcu/ar acti ons or projects, and of the consequences of engineering decisions or Judgments that are overruled or disregarded. (b) The issuance of oral or written assertions in the practice of engineering shall not be: (1) fraudulent, (2) deceitful, or (3) misleading or shall not in any manner whatsoever tend to create a misleading impression. (c) The engineer shall disclose a possible confllcl of i nterest to a potential or current client or employer upon discovery of the possible conflict. (d) A conflict of interest exists wh en an engineer accepts employment when a reasonable probability exists that the engineer's own financial, business, property, or personal interests may affect any professional judgment, decisi ons, or practices exercised on behalf of the client or employer. An engineer may acoept such an employment only if all parties involved in the potential conflict of interest are fully informed in writing and the client or employer confirms the knowledge of the potential conflict in writing. An engineer in a conflict of interest employment shall mainta in the interests of the client and other parties as provided by §137. 61 of this title (relating to Engineers Shall Maintain Confidentiality of Clients) and other rules and statutes. £R(I Company Name 5A"'1'i)E£P l<1s,1 AN \/ P .. Name ofDuly Authorized Officer of the Company or Organization cer of the Company or Organization SUBSCRIBED AND SWORN TO BEFORE ME by the said 5 ,"'4 <<.p \~ S b ~in to which witness my hand and official seal on this \ i 1~ day of {b.a.'f . , 2010. ?~t.~~ Notary Public in and for the State of Texas Seal: PATRICIA S. 8ASKIN IIOfAlt'f~SfAltllftWI 110 .. lltlllJ ln!Ut: __ .22:~~la.. MIKE PRING, Senior Environmental Engineer ,ERG Mike Pring has more than 19 years of experience in the air quality consulting field , specializing in criteria air pollutant (CAP) and hazardous air pollutant (HAP) emission inventories , New Source Review (NSR) permitting, and Title V and Minor Source permitting. EDUCATION B.S., Environmental Engineering , University of Florida, Gainesville, FL, 1991. EXPERIENCE Senior Environmental Engineer, Eastern Research Group, Inc., 1996-Present. Environmental Engineer, Radian International LLC, 1991-1996. Laboratory Technician, U.S. EPA Acid Rain Laboratory, University of Florida, 1988-1991. Laboratory Technician, CH2MHill , 1988. SELECTED RELEVANT WORK EXPERIENCE Development of an Emissions Inventory for Drilling Rig Engines for Texas. Managed ERG project to support the Texas Commission on Environmental Quality (TCEQ) for preparation of a state-wide drilling rig emissions inventory for 2008. Lead a team of engineers and scientists in preparing survey materials, interviewing drilling rig owners and operators, compiling survey results , preparing emission factors using U.S. EPA 's NONROAD model , and estimating state- wide emissions ofNOx, VOC , CO, PM 10, S02, and HAPs. Developed historical and future year projected inventories for 2002 through 2021 based on historical drilling data and forecasted oil and gas production activity. Development of an Emissions Inventory for Upstream Oil and Gas Sources for Texas. Managing ERG 's support to the TCEQ for preparation of an emissions inventory of upstream oil and gas emissions sources including dehydrators, compressor engines, wellheads, oil/gas well completions, pneumatic devices, turbines, storage tanks , equipment leaks, and loading racks. Identification of the best emissions estimation methodology for each source type, preparation and distribution of a survey to industry to collect the data needed to implement the methodology, and development of an emissions inventory for CAPs and benzene, formaldehyde, toluene, ethylbenzene , and xylene from upstream oil and gas production sites. Oil and Gas Air Permitting. Project Manager in ERG 's support to the Alaska Department of Environmental Conservation (ADEC), the Indiana Department of Environmental Management (IDEM), and the Allegheny County Health Department (ACHD) permitting programs. Provided technical leadership and overall project management for the preparation of Prevention of Significant Deterioration (PSD), Title V , and minor source air quality permits for large offshore oil and gas exploration and production platforms, natural gas compressor stations, and natural gas storage facilities. Estimated emissions, performed regulatory analysis, conducted Best Achievable Control Technology (BACT) analysis, and drafted permit language ensuring compliance with all requirements of the Clean Air Act and state air quality rules . Air Toxics. Conducted on-site audits at semiconductor, pulp and paper, organic and inorganic chemical , paint, and furniture manufacturing facilities to assess compliance with the Toxics Release Inventory (TRI) and the Emergency Planning and Community Right-to-Know Act of 1986 (EPCRA) reporting requirements . Updated EPCRA reporting guidance for semiconductor, printing, and presswood/plywood manufacturing operations by evaluating TRI data reported for these industries and working with trade associations to develop source category distinctions, process descriptions, and environmental release estimation methodologies. Updated guidance documents to provide clear regulatory interpretation and reporting guidance for issues problematic to these industries . A-1 CLINTON E. BURKLIN, P.E., Principal Engineer Clint Burklin's career has focused on the characterization of air pollutant emissions, the evaluation of emission control equipment, and the support and development of emission performance standards. This work has been in the form of technical assistance to national , State, and local air control agencies, as well as direct technical assistance to electric utilities , energy companies, the Electric Power Research Institute, the American Petroleum Institute and the Gas Research Institute. Mr. Burklin's experience spans the full range of air pollutants including the criteria pollutants, toxic air pollutants, ozone precursors, and greenhouse gases. EDUCATION B.S., Chemical Engineering, The University of Texas, Austin , TX, 1971. EXPERIENCE Vice President, Eastern Research Group, Inc., 2004-Present. Senior Program Manager, Eastern Research Group, Inc., 1996-2004. Principal Project Manager, Radian International LLC , 1994-1996. Various engineering positions , Radian Corporation, 1971-1993. SELECTED RELEVANT WORK EXPERIENCE Oil and Gas GHG Protocol Development. For The Western Climate Initiative (WCI), Mr. Burki in is leading a task to develop the mandatory GHG reporting protocol for the cap-and-trade program. He works hand-and-hand with the oil and gas committee to establish accurate quantification and monitoring methods, and investigate technical issues associated with complex emission sources such as contractor emissions, storage tanks, field gas combustion , instrument gas vented from pneumatic control devices, and others. He is leading the development of regulatory language that is aligning the WCI reporting requirements with the federal mandatory reporting rule, Subpart W requirements. GasSTAR Program Support. Mr. Burklin directed a study under U.S. EPA's GasSTAR program (promoting voluntary methane reductions in the U.S. natural gas industry) that evaluated the uncertainty in the annual methane reductions reported by the U.S. natural gas industry. The methane emission estimation methodologies reviewed by Mr. Burklin applied to fugitive, exhaust, and direct methane emissions from equipment used by the production , processing, transmission , and distribution sectors of the natural gas industry. Update toAP-42 Emissions Factors/or Industrial Sources. Mr. Burklin has directed a series of more than 10 work assignments to develop and update the emission factors in U.S. EPA's Compilation of Air Pollutant Emission Factors (AP-42). These studies resulted in new factors and updated previous factors for toxic , criteria, and greenhouse gas emissions from petroleum production and refining sources, gasoline storage and marketing, external combustion boilers and heaters , and internal combustion engines and turbines. Field Fuel Gas Combustion in NG Fields/or HARC. For the Houston Advanced Research Center (HARC) and the TCEQ , Mr. Burklin developed detailed inventories for stationary reciprocating engines. In the first study, Mr. Burklin inventoried the natural gas engines used in the gas fields to compress and transport natural gas to gas processing plants in Texas. The inventory included collecting detailed information on over 1000 engines used in the Texas gas fields and conducting site visits to 65 compression facilities to verify their inventory data. Mr. Burklin developed an inventory of Texas gas field compressor engine emissions for the years 1999 , 2000 and 2002 , and forecast emissions for the years 2007 and 20 l 0. A-2 JOHN WILHELMI, Senior Chemical Engineer \\ERG John Wilhelmi is a senior chemical engineer in ERG 's Environmental and Occupational Health practice. He has devoted his professional career ( 16 years) to characterizing air emissions from a wide array of industrial processes, evaluating their transport through the atmosphere, and assessing potential inhalation exposures and health risks. For the past 14 years, Mr. Wilhelmi has provided this service to the federal Agency for Toxic Substances and Disease Registry (A TSDR) for dozens of sites, including some of the agency 's highest visibility projects. EDUCATION B.S ., 1991 , Chemical Engineering, Stanford University . M .S., 1996 , Chemical Engineering, Massachusetts Institute of Technology. EXPERIENCE Senior Chemical Engineer (Vice President), ERG, 1996-Present. Research Assistant, Massachusetts institute of Technology, 1994-1996. Associate Consultant in Air Sciences, ENVIRON Corporation , 1991-1993. SELECTED RELEVANT WORK EXPERIENCE Public Health Evaluation of Air Emissions from Multiple Texas Petroleum Refineries. Manages an ongoing project for the ATS DR to assess the public health implications of exposure to air pollution in neighborhoods along so-called "Refinery Row " in Corpus Christi. Integrated facility emission data from multiple sources, ambient air monitoring data, and dispersion modeling data into a cohesive account of local outdoor air quality issues. Helped the agency respond to community health concerns regarding both acute and chronic exposures to airborne hydrocarbons and other pollutants. Prepared written documents for a wide range of audiences. Public Health Evaluation of an Accidental Release from a Petroleum Refinery. Assisted ATS DR in evaluating the public health implications of inhalation exposure to pollutants released during an accidental release of catalyst from a cracking unit at a petroleum refinery in Wyoming. Submitted detailed evaluations of typical refinery operations, facility-specific emission data, dispersion modeling analyses , and toxicity reviews. Assisted ATSDR with preparing a public health assessment, intended for public distribution later in 20 l 0. Data Quality Reviewer for U.S. EPA 's Toxics Release Inventory (TRI). Helped U.S. EPA assess the accuracy of facility-specific environmental release data submitted to the agency 's Toxics Release lnventory. Conducted site visits to more than 40 industrial facilities-including petroleum refineries in Texas-to assess the quality of air emissions data and waste management data that were disclosed to the public. Exposure Investigations for Oil and Gas Production Activities. Served as senior data reviewer for multiple exposure investigations conducted under contract to A TSDR. All exposure investigations involved ambient air monitoring of pollutants of interest, typically some combination of hydrogen sulfide, sulfur dioxide, and volatile organic compounds. The exposure investigations were conducted to assess air quality impacts from a wide range of industrial operations, including oil and gas production activities , refineries , landfills, and electricity generating facilities. Public Health Evaluation of Cement Kilns. Providing ongoing technical assistance to ATSDR on its evaluation of the public health implications of exposure to air pollutants released by three large cement kilns in Midlothian, Texas. Examined spatial and temporal trends among emission data ( continuous and annual) and conducted an extensive data quality review of ambient air monitoring data. A-3 ARNOLD R. SRACKANGAST, Mid-Level Scientist Mr. Srackangast has 21 years experience in managing, performing, and peer reviewing atmospheric modeling studies in support of federal and State air quality evaluations. Mr. Srackangast is a recognized expert on the development, application , and use of atmospheric dispersion models, as well as other air quality topics, including ambient monitoring, emission inventory development and meteorological data processing. EDUCATION B.S. (Cum Laude), Meteorology , Texas A&M University , 1985. EXPERIENCE Principal Scientist, Eastern Research Group, Inc., 2003-Present. Independent Contractor, AS l MET Services, 2003-Present. URS Corporation I Radian International LLC / Radian Corporation , 1985-2002. SELECTED RELEVANT WORK EXPERIENCE Co-Generation Air Quality Analysis. Lead technical review of the air quality analysis of a 2100 MW natural gas-fired cogeneration project sited near Gila Bend, AZ , for the Maricopa County Environmental Services Department. Performed technical peer review of the modeling protocol and application , including federal Class I and Class II impacts, and participated in public hearing support. Permit Timeline Reduction Initiative Modeling Support. Subcontractor for the University of Texas Center of Energy and Environmental Resources (UT/CEER) on a contract with TCEQ to provide air dispersion modeling support under the Permit Timeline Reduction Initiative. Conducted air dispersion modeling for six facilities in order to expedite the permitting process for RCRA hazardous waste combustion facilities. Performed modeling in accordance with the procedures described in the U.S. EPA 's "Human Health Risk Assessment Protocol." Co-Generation Facility Modeling. Task member for the air quality analysis portion of an Application for Certification of a 320 MW Cogeneration and Power Project. Served as internal technical consultant and peer review on air dispersion modeling and meteorological processing. Provided expert testimony at public hearings before the California Energy Commission (CEC). NAAQS and PSD Modeling. Task leader in charge of performing full NAAQS and PSD analysis for five Tier II Gasoline projects in the Gulf Coast Region. Comprehensive facility information was gathered and compiled, including sitewide building downwash information , as well as developing PSD baseline and current emission rates for increment analyses. Off-site emission retrievals were reviewed for errors and omissions. Ozone Formation and Transport Study. Task leader for a major analysis of the formation and transport of ozone in the Houston , Texas area. Research led to the development of an ozone climatology of the region. Responsibilities included analyzing and correlating meteorological conditions during ozone episodes, performing air quality and meteorological data analyses, designing and development of computer generated graphics for data presentation , and the upgrade and maintenance of a large 5-year air quality database of 33 continuous air monitoring stations in the Houston area. Also developed forward and back trajectories to determine the transport of ozone on individual days. Meteorological Data Collection. Task leader of a project to collect and process annual on-site meteorological data from two 30-meter meteorological towers and National Weather Service observations into the format necessary for air dispersion models, including AERMOD, ISCST3 , andCDM. A-4 REGI OOMMEN, Senior Scientist Regi Oommen is a senior scientist with more than 14 years of experience in the air quality consulting and emission inventory development, specializing in database management, quality assurance/quality control , and data analyses of criteria air pollutants (CAPs) and hazardous air pollutants (HAPs). EDUCATION M.S., 1996 , Atmospheric Sciences, North Carolina State University. B.S ., 1994 , Meteorology, North Carolina State University. B.A., 1994, Chemi stry , North Carolina State University. EXPERIENCE Senior Scientist, Eastern Research Group, [nc., 2006-Present. Environmental Scientist, ERG , l 996-2005 Environmental Chemist, North Carolina 's Division of Air Quality, 1996 SELECTED RELEVANT WORK EXPERIENCE Development of Version 2 of the 2005 NATA National Emissions Inventory. Recently directed the compilation and revision of Version 2 of U.S. EPA 's 2005 NATA National Emissions Inventory (NEI) for point sources emitting HAPs and CAPs. Oversaw a team of scientists and engineers by quality assuring the submitted data; blending and merging data from federal , state, local , and tribal agencies; and preparing emission data records in U.S. EPA 's NEI Output Format (NOF). Managed the development of the final database, which consisted of over 5.3 million emission records. Prepared summary data files for state/local/tribal agency review. Development of the 2005 Oil and Gas Emission Inventory for TCEQ. Developed CAP emission estimates of area source oil and natural gas operations occurring in Texas for base year 2005. Reviewed emission factor , activity data, and control information for exploration processes (e.g., well completions, mud degassing, offshore platforms) relating to oil and natural gas production. Compiled the project database and formatted emissions in U.S. EPA 's NE[ Input Format (NIF) for the 2005 base year, and for projected emissions out to 2020. Exposure Investigations/or ATSDR. Led data analysis tasks for the Agency for Toxic Substances and Disease Registry 's (ATSDR) Exposure Investigations in: Plymouth , NC; Lovington , NM; Overland Park, KS; and Bridgeport, IL. Summarized results from ambient monitoring for air toxics and harmful sulfur compounds, which included: statistical characterization of the measurements from the mon itoring network, evaluating the effect of nearby stationary and mobile emission sources , construction of back trajectories and pollution roses , and correlation to meteorological parameters. Impacted communities were affected by oil and natural gas sources, a pulp and paper mill , and a landfill. Oil and Natural Gas Platforms for Gulf of Mexico Emissions Inventory. Oversaw the development of the 2008 base year emissions inventory of CAPs and greenhouse gas (GHG) from nearly 4 ,000 oil and natural gas platforms. Prepared activity data templates for operators to populate and compiled survey data from the platform operators. Quality assured survey data through identification of missing values; testing submitted data within acceptable range checks ; recalculation of total fuel used ; corrections of the emissions estimation calculation program in Oracle; and checking final emission estimates. Prepared final estimates of over two million emission records in a format compatible for modeling. Performed similar tasks in preparation of baseyear 2005 and 2000 emission inventories. A -5 RAYMOND MERRILL, Senior Analytical Chemist ,ERG Dr . Raymond Merrill is an internationally recognized environmental chemist with more than 33 years of experience managing and performing environmental measurements, methods development, method evaluation, and quality control/quality assurance programs. EDUCATION Ph .D., Analytical Chemistry, Duke University, Durham, North Carolina, 1977. B.S., Cum Laude, Chemistry, Stetson University, Deland, Florida, 1972. EXPERIENCE Senior Program Manager, Eastern Research Group, Inc., 1996-Present. Senior Program Manager, Radian Corporation , 1992-1996. Program Manager, Radian Corporation, 1990-1992. Senior Staff Scientist, Group Leader, Radian Corporation , 1987-1990. Senior Scientist, Radian Corporation, 1986-1987. Research Chemist, GS-14, U.S. Environmental Protection Agency, 1983-1986. Chemist, GS-13 , U .S . Environmental Protection Agency, 1980-1983. Chemist, GS-12 , U.S. Environmental Protection Agency, 1978-1980. Research Associate/Research Fellow, Duke University, 1976-1978. SELECTED RELEVANT WORK EXPERIENCE Stationary Sources Audit Program. Manages development and distribution of QA performance evaluation and audit samples to states and regions for use in compliance test evaluation projects. Manages and serves as peer reviewer for development and improvement of sampling and analysis methods for tox ic compounds on U.S. EPA 's high priority list of33 toxic chemicals. Cement Kiln NOx Reduction Strategies. Managed Ellis County Cement Kiln NOx Reduction Strategies, Composition of Ellis County Raw Materials. Directed chemical analysis team and subcontractors to conduct research to determine the chemical, mineral and elemental composition of limestone and all other raw materials used in clinker production in Ellis county including, sulfur, organic content, calcite, dolomite, aragonite and pyrite Significant differences were identified in raw materials to explain variability in NOx emissions. Estimating VOC Emissions from Animal Waste Lagoons Using the WATER9 Model. Prepared work plan , Quality Assurance Project Plan (QAPP), and special head space protocol for U.S. EPA review. Manages ongoing work to investigate total organic (non-methane/non-ethane) carbon mass ; analyze swine waste sample head space for VOCs and total non-methane/non- ethane carbon mass ; analyze swine waste samples for volatile, semivolatile, and tentatively identified organics using RCRA SW-846 methods; and analyze swine waste samples for selected polar organic compounds (POC) using direct aqueous injection of samples following the research protocol developed by U.S . EPA/NEIC. Cavity Ring Down Spectroscopy (CRDS) Large Area Mobile Monitoring Method Evaluation. Prepared work plan , QAPP, and executed a field test evaluation ofCRDS technology combined with tracer release to estimate emission flux from a large area municipal landfill. Passive Fourier Transform Infrared Spectroscopy (PFTIR)for U.S. EPA. Prepared work plan , QAPP, and prepared for field test to evaluate PFTIR technology at an industrial flare facility scheduled for August 2010. A-6 DAVE DAYTON, Senior Environmental Engineer ,ERG Dave Dayton is a Senior Environmental Engineer and Senior Program Manager. During his 35 years in the environmental field , Mr . Dayton has participated in and directed a wide range of programs, primarily in the areas of modeling analysis, ambient air quality monitoring technologies, monitoring program design, remote sen s ing technologies, instrumentation and systems design , method research and development, gas chromatography , mass spectrometry, and stationary source emissions monitoring. EDUCATION Mechanical Engineering, North Carolina State University. EXPERIENCE Senior Program Manager/Senior Engineer, Eastern Research Group, Inc., 1997-Present. Senior Engineer, Ea stern Research Group, Inc., 1996-Present. Senior Scientist, Radian International , LLC , 1994-1996. Group Leader, Radian Corporation , 1991-1993. Staff Engineer, Radian Corporation , 1988-1991. Engineer, Radian Corporation, 1983-1988. Member of Technical Staff, TRW Corporation , 1980-1983 . Research Assistant, Research Triangle In stitute , 1974-1980 . Environmental Technician , U.S . Environmental Protection Agency, 1972-1974. SELECTED RELEVANT WORK EXPERIENCE U.S. EPA 's National Monitoring Programs. Serves as Contract Manager and Senior Program Manager for multiple U.S. EPA/OAQPS delivery order contracts to support multiple nationwide ambient air networks, such as the Non-Methane Organic Compounds (NMOC), Speciated NMOC (SNMOC), urban air toxics monitoring program (UA TMP), photochemical assessment monitoring stations (PAMS), and the National Air Toxics Trends Stations (NA TIS) monitoring efforts . Support included equipment design and fabrication , installation and operation assistance (i.e., for canister sample and carbonyl compounds collection), training, sample analysis, data reporting, and entry of data into the AQS database . Contracts have spanned 17 years of continuous monitoring network operation. Agency for Toxic Substances and Disease Registry (ATSDR) Exposure Investigations. Served as Senior Program Manager for multiple ambient air monitoring networks in Plymouth , NC , Lovington, NM, Overland Park, KS , Bridgeport, IL , Alexandria, VA , and Thomaston , ME. Developed network design plan, monitoring plan , and data analyses plan for sampling of hydrogen sulfide, ammonia, hazardous air pollutants, and/or criteria air pollutants at locations that could impact public health. San Joaquin Valley Air Quality Study (SJVAQS). Served as Project Director for the SJV AQS. Designed , fabricated , tested , and demonstrated an automated nonmethane organic compound (NMOC) monitoring instrument. The system is semi-continuous and based on U.S. EPA Reference Method TO-I 2. The system was used to collect NMOC data at the Edison , California site during the study. Emissions Sampling -Boiler Industrial Furnaces (BIF). Serves as Program Manager to support network monitoring efforts around two BIF facilities. Data from these networks were used to develop criteria for BTF permitting. Support included equipment installation and operation assistance (i.e., for high-volume particul ate , high-volume semivolatile, volatile organic compounds, total organic compounds, and meteorology), sample analysis, and data reporting. A-7 SCOTT FINCHER, Staff Scientist Mr. Fincher is a Staff Scientist. He assists with processing and analysis of data in support of air quality projects. Mr. Fincher 's areas of ex perience included dispersion modeling for several petrochemical , lumber, electrical generation , and U.S. military facilities. In addition , he provided deposition and dispersion modeling in support of indirect risk assessments . He has also assisted in retrieval , analysis, and processing of meteorological data when necessary. Mr. Fincher currently uses his background in dispersion modeling to review and comment on modeling analyses submitted in support of permit applications for a number of state agencies. EDUCATION B.S ., Meteorology, Texas A&M Uni versity, College Station , TX., 1998. EXPERIENCE Staff Scientist, Eastern Research Group, Inc., 2008-Present. Scientist, Eastern Research Group, Inc., 2003-2008. Meteorologist, URS Corporation , Austin , TX, 2000-2003. Associate Meteorologist, Radian International, Austin , TX, 1998-2000. SELECTED RELEVANT WORK EXPERIENCE For both the Arizona Department of Environmental Quality (ADEQ) and the Alaska Department of Environmental Conservation (ADEC), Mr. Fincher performed reviews of modeling protocols and modeling report submitted to the respective states. He conducted completeness reviews , evaluated AERMOD model inputs and outputs for conformance with state modeling regulations , and prepared memos for state use summarizing findings. Deposition and Air Dispersion Modeling. Performed modeling that conformed to U.S . EPA guidance , in support of se ven indirect risk assessments for various hazardous waste incinerator and electric utilities. He also revised an indirect risk assessment work plan to comply with the U.S. EPA "Human Health Risk Assessment Protocol " for hazardous waste combustion facilities. Permit Modeling. Modeling task leader for an air permit for a major Gulf Coast client. He performed SCREEN3 and ISCST3 modeling, and w as responsible for full task documentation. Additionally, he provided follow-up technical assistance as this permit went to hearing before the TNRCC. Air Quality Modeling Support. Mr. Fincher served as a modeling task leader or team member for more than thirty additional projects in the States of Texas, Louisiana, Mississippi , New Mexico, Nebraska, Wyoming, Tennessee, and Ohio. These include electrical cogeneration facilities and power plants, U.S. military facilities , several Gulf Coast petrochemical clients, and various lumber processing facilities in support of Federal and State permitting efforts. He was responsible for SCREEN3 , OCD, ISCST3 , and AERMOD modeling, full task documentation , and QC of modeling inputs. Model Training. Provided training to a U.S. Government contractor in the setup and use of the NASA Chemical Equilibrium with Applications (CEA) model. He also provided subsequent support to the contractor as the CEA model was used in open burning/open detonation (OB /OD) applications . A-8 SAGE ENVIRONMENTAL CONSULTING DAVID RANUM, Senior Technical Specialist "Friendly Service, No Surprise,!" David has over 27 years experience in a variety of area s within the environmental field , including instrumentation system design , air toxics monitoring, auditing of environmental systems, water monitoring, fugitive emi ss ions monito r ing, stack testing using CEMs (Continuous Emission Monitors) and , design and installation of CEM systems and ambient air monitoring using conventional analyzer systems and FTIR (Fourier Transform Infrared Spectroscopy) technologies. His skills include instrumentation operation , maintenance, calibration, and repair , environmental sampling, technical writing, data processing, project management, and the auditing of ambient air monitoring systems and LOAR (Leak Detection and Repair) programs. Mr. Ranum provided repair and field service support of microprocessor-based data acquisition systems for Radian Corporation (now part of URS Corporation). He later transferred to Radian's Air Monitoring Department where he provided instrumentation, quality control , reporting and auditing support on a wide variety of projects associated with both ambient and process level emission measurements. Before leaving URS , David worked with the FTIR group in the application of this new technology to environmental measurements as well as participating in numerous U.S. EPA Consent-Decree mandated LOAR audits. David moved to Sage Environmental Consulting in December 2005 where he continues to work on LOAR projects as well as extend Sage's expertise and capabilities in the areas of ambient air and source level monitoring. David's recent activitie s have included performing LOAR audits, conducting IR camera surveys at both off-shore and on-shore facilities , designing and conducting Level 1 Thermography Certification training, conducting direct emission testing (bagging), and support of a meteorological system he installed at a landfill site in Oregon. Experience Summary • Performed an IR camera survey of a Gulf Coast natural gas facility in response to odor complaints in early 2010. • Installed a meteorological system at a landfill site in Oregon in 2009-20 l 0. Provided operator training and continued support. • Conducted an IR camera survey for 1-3 butadiene emissions at a Gulf Coast refinery in 2009. • Performed an IR camera survey for leaking equipment at two Shell-owned off-shore platforms in 2009. • Project Manager and lead auditor in numerous Consent Decree LOAR audits. • Project Manager for a nine-month IR camera study at a mid-sized Texas refinery in 2007-2008. • Conducted direct emission testing (bagging) in support of IR camera studies in 2009-20 l O for Battelle Memorial Institute as well as several similar bagging studies . • Provided instrumentation support for numerous source level and ambient air monitoring programs. • Conducted flux chamber emission testing on both land farms and surface impoundments. • Provided technical support in numerous FTTR-based source and ambient level monitoring programs. Education Electronics Technician Diploma, Southwest School of Electronics, Austin , TX 1978. Secondary Education Diploma, the University of Victoria, Victoria, British Columbia 1975. M.A . English Literature, the University of Washington , Seattle, WA. 1972. B.A. Honors, English Literature, the University of Victoria, Victoria, British Columbia, 1971. A-9 SAGE ENVIRONMENTAL CONSULTING ARTHUR V. BEDROSIAN, Key Executive Advisor "Friendly Service, No Surprise.!" With 39 years experience in the environmental profession, Art Bedrosian has served as a meteorology officer in the U.S. Air Force, has worked for the Texas Air Control Board, and has been an engineering and environmental consultant for more than 30 years. As a member of the Board of Directors of the Central Texas Clean Air Force and Chair of the Technical Advisory Committee, Mr. Bedrosian has and continues to work closely with business leaders, elected officials, and regulators. He has provided community leadership in the evaluation of air quality impacts, as well as point and area source emissions reductions methods to reduce ozone levels in Texas. Since the regional efforts began in 1995, he has been actively engaged in shaping the direction of the technical efforts to develop an accurate emissions inventory database, representative photochemical modeling, and realistic mitigation measures. Experience Summary • Successfully evaluated regional ozone issues for the Texas Air Quality Coalition, a 10-county area north of Dallas. The project goal was to identify and develop mitigation measures aimed at ozone reduction for the Dallas-Fort Worth non-attainment area. • Established and managed an ambient air monitoring project which involved data collection, data reporting , and quality assurance for a six-month long program to develop a carbon monoxide and meteorological data base for two major roadway intersections in New York City. This effort utilized four IO-meter meteorological towers and eight carbon monoxide monitors in two urban canyon settings. • Managed a one-year long PSD air monitoring program to establish a pre-construction ambient air quality baseline for Champion Paper's proposed paper mill in East Texas . This continuous monitoring effort involved five NAAQS parameters plus meteorology. Mr. Bedrosian was responsible for all data reports and quality assurance documentation. • Managed the operation , data reporting, and quality assurance for three one-year long multi- station TSP and meteorological monitoring programs for proposed lignite surface mines in Louisiana and Texas. • While employed by the T ACB (now TCEQ), Mr. Bedrosian was responsible for the management of the data collection and equipment maintenance for twenty-three Texas Air Surveillance Network monitoring sites and four Continuous Air Monitoring Stations. He participated in monitor site selection and used monitored data to assist in control strategy development, State Implementation Plan consistency determinations, and selection of Attainment/Non-attainment determinations. He coordinated TACB monitoring activities with those of contractors during the 1977 Houston Area Oxidant Study. • Performed PSD pre-construction ambient air quality and meteorological monitoring station siting studies for New Mexico Power and Light 's Red Bluff coal-fired generating station and another in West Texas for Texas Utilities. • Designed a sampling program to quantify sulfuric acid emission levels from a large golf cart battery charging facility and a program to quantify methane emissions from a landfill. While with the T ACB , he performed vinyl chloride and benzene sampling at selected industries along the Houston Ship Channel. • Performed source sampling for particulate matter, heavy metals , and sulfur dioxide at oil refineries , petrochemical facilities , foundries , power plants, and manufacturing facilities. Education B.S. in Physics , Stevens Institute of Technology. U.S. Air Force, Meteorology Training, 43 Semester Hours, Texas A&M University. A-10 SAGE ENVIRONMENTAL CONSULTING JENNIFER PARRAS, Project Manager "Friendly Service, No Surprise,!" Jennifer has experience in the environmental field focused on air quality, water and waste compliance, as well as solid waste management. Jenn ifer 's air quality experience includes Title V operating permitting, New Source Review permitting, Flexible Permitting, Permits by Rule, Standard Permits, Title V Compliance Certification reporting , regulatory analysis, state and federal emissions reporting requirements, environmental rule interpretation and general environmental reporting for refineries, natural gas processing facilities , and asphalt manufacturing operations. Her water and waste water experience included the implementation of new Spill Prevention Control and Countermeasure (SPCC) rules , New Mexico Pit and Below Grade Tank Rule , and Stormwater Pollution Prevention Plan (SWPPP) Regulations. Her solid waste experience focused on managing all land disposal units on site and auditing offsite land disposal facilities. Experience Summary • Worked for Sage since June 2005 where she has been responsible for compliance implementation and permitting including various NSR permits, excess emissions auditing, Benzene NESHSAPs third party review and TAB generation , RCRA auditing , & SPCC review and plan corrections . • Worked for Duke Energy Field Services, in Midland , TX (2001 -2005) where her duties included environmental compliance of the Western Division Area (includes 18 Gas Plants and 300 compressor stations located in New Mexico and Texas); management of a staff of 4 environmental professionals and l administrative assistance; compliance with all air, water, and waste issues; consultation with legal; serving as lead auditor for internal corporate environmental audits; and acting interface between management and filed operations personnel. • Served as the Environmental Group Leader for Alon USA LLP , in Big Spring, TX. There she was responsible for the environmental management of all Alon USA facilities including the Big Spring Refinery, 6 terminals, pipelines, and fuels , as well as miscellaneous corporate issues. • Worked as an Environmental Engineer for Fina Oil & Chemical Company (Big Spring Refinery), Big Spring, TX. Her responsibilities included stewarding the LOAR program , submitting periodic compliance reports for regulated air emissions, developing compliance of the applicable units for MACT and NSPS Regulations, developing and submitting the AEI and TRI reports , management of the Title V , report daily reportable emissions to the proper agencies, and providing environmental guidance on any environmental issues within the process units. • Performed emission control sampling of wastewater for analysis of total hazardous air pollutants, and sampling of refinery products for volatile organic compounds. • Developed refinery and gas plant Title V compliance demonstration tools. • Developed Title V permit amendments and annual reports. • Developed maintenance startup and shutdown permit application for refineries. • Provided various permit by rule registrations for oil and gas companies. • Conducted excess emissions rules/regulations and engineering analysis for natural gas facilities in Texas and New Mexico. • Conducted New Mexico excessive emission reporting review and engineering analysis. Education B.S. Environmental Engineering, Montana Tech, Butte, MT, 1995 A-1 1 SAGE ENVIRONMENTAL CONSULTING HARISH BADRINARA YANAN, Technical Specialist "Fri endly Service, No Surprt.e, ! " Harish has over nine years of experience in the environmental consulting focused on air quality compliance . He specializes in providing technical and regulatory support on compliance issues. Harish has assisted oil and gas companies in bringing their sites in Texas into compliance through significant air permitting efforts resulting from voluntary audit disclosures. He has experience in providing on-site support for continuous compliance for upstream and midstream oil and gas facilities. He has prepared emissions inventories and handled various aspects of Title V and NSR air permit applications including emission calculations, rule interpretation, and forms preparation. Experience Summary • Prepared emission inventories for natural gas compressor facilities located in states of Kansas , New Mexico, and Colorado and a Natural Gas Liquids (NGL) facility in Washington . Prepared Annual Compliance Certifications (ACC) and Semi-annual monitoring reports (SAR) for facilities located in Colorado . Prepared Notice oflntent (NOi), portable and stationary Streamline Permit applications for co-located natural gas compression facilities located in New Mexico. Prepared summary of historical Greenhouse Gas (GHG) emissions for all reporting units at the performance unit level. (BP We st Lake). • As part of a voluntary audit disclosure, managed and supported preparation of Permit By Rule (PBR), Standard Permits (SP), and case-by-case New Source Review (NSR) permit applications to accurately permit compressor stations and gas processing plants. Estimated emissions from combustion sources, blowdown operations, condensate flashing , miscellaneous VOC storage tanks, truck loading , dehydration units , and fugitive emissions. Interacted with legal personnel to develop strategies to demonstrate compliance with audit disclosure items. Familiar with the use of software such as E&P TANKS , GRI-GL YCALC, and U.S. EPA TANKS 4 .09 and simple SCREEN3 modeling. (Eagle Rock Energy, D CP Midstream , Enbridge) • Worked extensively in preparing permit by rule and standard exemption applications for authorizing emissions from new sources and for permitting grandfathered sources. Worked on authorizing emissions from sources such as analyzers, flares , fugitive components, diesel engines , surface coating facilities , loading/unloading facilities and adsorption units. He has prepared documents and templates for PBRs and Standard Exemptions (SEs) in order to comply with the record keeping requirements of 30 TAC 106.8. Reviewed all PB Rs and SEs at facilities and developed recordkeeping templates to demonstrate continuous compliance with the requirements of the PBR. (Chevron Phillips Chemical Company-Port Arthur facility, EI DuPont de Nemours , Beaumont Works Facility) • Prepared federal air operating (Title V) permit applications and updates for petrochemical, polymer manufacturing and chlor-alkali facilties. Reviewed potentially applicable federal (NSPS , NESHAP, and MACT standards) and state regulations. Determined applicability of regulations and completed all relevant forms. Prepared relevant Title V application forms using Intelliregs software. (Ch e vron Phillips Chemical Company -Port Arthur and Orange fac ilities, Noltex LLC, Oxy Viny ls Battleground Facility) Education • MBA , University of Houston -Victoria, Texas, December 2009 • M.S. in Environmental Engineering, Texas A&M University-Kingsville, Texas 2001 • B .S . in Chemical Engineering, Madras University , Chennai , India 1999 A-12 Drilling Rig Emission Inventory for the State of Texas Final Report Prepared for: Texas Commission on Environmental Quality Prepared by: Eastern Research Group, Inc. July 15, 2009 Drilling Rig Emission Inventory for the State of Texas Final Report Prepared for: Greg Lauderdale Texas Commission on Environmental Quality P. 0. Box 13087 Austin, TX 78711-3087 Prepared by: Rick Baker Mike Pring Eastern Research Group, Inc. 5608 Parkcrest Drive, Suite 100 Austin, TX 78731 July 8, 2009 Table of Contents LIST OF ACRONYMS ................................................................................................................. iii 1.0 Executi ve Summary ......................................................................................................... 1-1 2 .0 Introduction ...................................................................................................................... 2-1 3 .0 Review of Existing Literature .......................................................................................... 3-1 3.1 Review of Existing Studies .................................................................................. 3-1 3 .2 Re view of Existing Data ...................................................................................... 3-2 3.3 Drilling Rig Overview ......................................................................................... 3-3 4 .0 Data Collection Plan ........................................................................................................ 4-1 4.1 Participant Recruitment ....................................................................................... 4-1 4.2 Phone/Emai l Surveys ........................................................................................... 4-1 4.3 Confidentiality ..................................................................................................... 4-2 5.0 Data Collection Results .................................................................................................... 5-1 5.1 SurveyFindings ................................................................................................... 5-1 5.2 Model Rig Category Deve lopment ...................................................................... 5-3 5.3 Fracturing ............................................................................................................. 5-6 6.0 Emissions Inventory De velopment and Results .............................................................. 6-1 6.1 Activity Data ........................................................................................................ 6-1 6.1.1 2008 Base Year Activity .......................................................................... 6-1 6.1.2 2002 and 2005 Prior Years Activity ........................................................ 6-1 6.1.3 2009 through 2021 Projected Activity ..................................................... 6-3 6.1.4 2002 , 2005, and 2008 through 2021 Activity Summary .......................... 6-6 6 .2 Model Rig Emission Profiles ............................................................................. 6-12 6.2 .1 Model Rig Engine Profiles ..................................................................... 6-12 6.2 .2 Model Rig Emission Factors .................................................................. 6-14 6.3 Emission Estimation Methodology .................................................................... 6-17 6.4 Results ................................................................................................................ 6-19 6.4 .1 Emission Summary ................................................................................ 6-19 6.4 .2 NIF 3.0 Files .......................................................................................... 6-19 7.0 Conclusions and Recommendations ................................................................................ 7-1 8.0 References ........................................................................................................................ 8-1 Appendix A -Approved Data Collection Plan Appendix B -Survey Letter Appendi x C -Drill Rig Survey Form Appendix D -Survey Data Appendix E-Total Drilling Depth by County by Model Rig Well Type Category Appendi x F -Emission Factors Appendix G -Annual and OSD County-Leve l Emission Estimates List of Tables Table 1.1 Drilling Rig Estimate s (tons/year) ............................................................................... 1-2 Table 3 .1 Existing Oil and Gas Exploration Emissions Studies .................................................. 3-1 Table 5.1 Survey Summary Stati stics .......................................................................................... 5-3 Table 5.2 Model Rig Category Statistics ..................................................................................... 5-5 Table 6.1 2002 and 2005 Prior Year Activ ity Scaling Factors .................................................... 6-3 Table 6 .2 Projected Crude Oil Production 2008-2021.. ............................................................... 6-5 Table 6 .3 Projected N atural Gas Production 2008-202 1 ............................................................. 6-5 Table 6-4 Projected Growth Factors 2009-202 1 .......................................................................... 6-7 Ta ble 6 .5 2008 Total Depth by Model Rig Well Type Category (1 ,000 feet) ............................. 6-8 Table 6 .6 Model Rig Engine Parameters ................................................................................... 6-14 Table 6 .7 PM 10 Speciation Factors ............................................................................................ 6-16 Table 6 .8 TOG Speciation Factors ............................................................................................. 6-16 T able 6.9 TxLED Counties ........................................................................................................ 6-17 Table 6 .10 Tex as Drilling Rig Estimates (tons/year) ................................................................. 6-20 Table 6.11 2008 Annual and OSD County-Level Cri teria Pollutant Emission Estimates ......... 6-21 List of Figures Figure 5 .1 Counties with Survey Data ......................................................................................... 5-4 F igure 6.1 TRC Di strict Map ....................................................................................................... 6-2 Figure 6 .2 EIA Regions ............................................................................................................... 6-4 11 Acronym API CARB co DOE EIA ERG HAP hp IADC MMBBL NEI NIF NOx OSD PM10 PM2.s sec SIP S02 TCEQ TexAER TIPRO TOG TRC TxLED TXOGA US EPA voe WRAP LIST OF ACRONYMS Definition American Petroleum Institute California Air Resources Board Carbon Monoxide U.S. Department of Energy Energy Information Administration Eastern Research Group Hazardous Air Pollutant Horsepower International Association of Drilling Contractors Million Barrels National Emissions Inventory NEI Input Format Nitrogen Oxides Ozone Season Daily PM with particle diameter less than 10 micrometers PM with particle diameter less than 2.5 micrometers Source Classification Code State Implementation Plan Sulfur Dioxide Texas Commission on Environmental Quality Texas Air Emissions Repository Texas Independent Producers and Royalty Owners Association Total Organic Gases Texas Railroad Commission Texas Low Emission Diesel Texas Oil and Gas Association United States Environmental Protection Agency Volatile Organic Compounds Western Regional Air Partnership 111 1.0 Executive Summary The purpose of this study was to develop a comprehensive emissions inventory for drilling rig engines associated with onshore oil and gas exploration activities occurring in Texas in 2008. Oil and gas exploration and production facili ties are considered some of the largest sources of area source emissions in certain geographical areas , dictating the need for continuing studies and surveys to more accurately depict these activities. A 2005 base year oil and gas emissions inventory developed for the Texas Commission on Environmental Quality (TCEQ) by Eastern Research Group (ERG) in 2007 (TCEQ, 2007) was comprehensive in coverage of all exploration and production facility and equipment types, including drilling rig engines. However, that project relied on data from secondary sources wi th assumptions applied to represent local activities . The Western Regional Air Partnership (WRAP) developed a comprehensive emissions inventory of oil and gas exploration and production facilities for the western states that did not include Texas, although the previous ERG study did make use of the WRAP results in terms of methodology and emis sion factors where practicable . The current inventory effort built off of the previous 2007 study, focusing exclusively on drilling activities . The previous effort was expanded upon by improving both the activity data (well counts , types , and depths) used to estimate emissions, and through the development of updated drilling rig engine emission profiles . The improved well activity data was obtained through acquisition of the "Drilling Permit Master and Trailer" database from the Texas Railroad Commission (TRC), while the improved drilling rig emissions characterization profiles were obtained through a survey of oil and gas exploration and production companies. The activity data and emissions characterization data were then used to develop the drilling rig engine emissions inventory for a 2008 base year. In order to survey drilling rig contractors and oil and gas operators across the state , ERG purchased contact information for companies that were active in well drilling activities that occurred in Texas in 2008 through a commercial vendor (RigData®). Through phone and email surveys, ERG obtained 45 drilling rig profiles representative of over 1,500 wells drilled in Texas in 2008. The survey effort itself focused on collecting the following information from each respondent: • The number of engines on a rig • Engine make , model, model year, and size (hp) • Average load for each engine 1-1 • Engine function (draw works , mud pumps, power) • Actual engine hour data for each well ( total hours) • Actual engine fuel use data for each well (total fuel use) • Total well drilling time (actual number of drilling days) • Total well completion time (number of days needed for well completion activities) • Well depth • Number of wells represented by survey Target pollutants for this inventory include nitrogen oxides (NO x), volatile organic compounds (VOC), carbon monoxide (CO), particulate matter (PM 10 and PM2 .5), sulfur dioxide (S02), and hazardous air pollutants (HAP). Emissions were calculated for each county in Texas where drilling occurred in 2008 and are provided in annual tons per year and by typical ozone season day . For planning purposes , the 2008 base year estimates were used to develop 2002 and 2005 prior year inventories, as well as projected inventories for 2009 through 2021. 2002 and 2005 prior year inventories were based on TRC records of oil and gas well completions during those years , and U .S Department of Energy (DOE), Energy Information Administration (EIA) oil and gas production growth estimates were used to develop the projections for future years 2009 through 2021. Emissions estimates developed from this inventory project may be used for improved input data to photochemical air quality dispersion modeling, emissions sensitivity analyses , State Implementation Plan (SIP) development, and other agency activities. The final 2002, 2005, and 2008 base year inventory estimates are provided in National Emissions Inventory (NEI) Input Format (NIF) 3.0 to facilitate entry of the data into the state's TexAER (Texas Air _gmissions Repository) database, and for the purposes of submittal to US EPA. For purposes of NIF preparation, Source Classification Code (SCC) 23-10-000-220 (Industrial Processes -Oil and Gas Exploration and Production -All Processes -Drill Rigs) was used as provided by TCEQ (TCEQ, 2009). Table 1-1 summarizes the statewide annual emission estimates for 2002 , 2005 , and 2008 through 2021. Table 1.1 Drilling Rig Estimates (tons/year) Year co NOx PMrn PM2.s S02 voe 2002 13 ,305 35 ,828 2,552 2,475 4 ,776 3,631 2005 15,878 42 ,854 3,036 2,945 5 ,977 4 ,337 2008 16 ,721 55 ,238 2,543 2,467 956 4 ,326 2009 16 ,769 55,457 2,550 2,474 961 4 ,340 2010 16 ,336 53,123 2,417 2,344 45 4 ,182 1-2 "' Table 1.1 Drilling Rig Estimates (tons/year) (Continued) Year co NOx PM,o PM2.s S02 voe 2011 15,117 48,462 2,319 2,249 44 3,806 2012 14,748 46,253 2,263 2,196 43 3,665 2013 12,008 39,793 1,378 1,337 38 3,413 2014 11,945 39,461 1,372 1,331 38 3,392 2015 11,755 38,837 1,350 1,310 37 3,349 2016 11,558 36,440 1,320 1,280 37 3,320 2017 8,915 34,771 1,118 1,085 36 2,800 2018 6,114 31,282 811 787 35 2,227 2019 6,073 31,127 805 781 35 2,215 2020 6,035 30,771 800 776 35 2,205 2021 3,299 26,063 448 435 33 1,504 1-3 2.0 Introduction The purpose of this study was to develop a comprehensive emissions inventory for drilling rig engines associated with onshore oil and gas exploration activities occurring in Texas in 2008 . Oil and gas exploration and production facilities are considered some of the largest sources of area source emissions in certain geographical areas, dictating the need for continuing studies and surveys to more accurately depict these activities. A previous study conducted by Eastern Research Group (ERG) in 2007 under TCEQ contract 582-7-84003 , Work Order 01 was comprehensive in coverage of all the exploration and production facility and equipment types , including drilling rig engines, although this project relied on data from secondary sources with assumptions applied to represent local activities (TCEQ , 2007). The Western Air Regional Partnership (WRAP) developed a comprehensive emissions inventory of oil and gas exploration and production facilities for the western states that did not include Texas , although the previous ERG study did make use of the WRAP study in terms of methodology and emission factors where practicable. While drilling activities are generally short-term in duration, typically covering a few weeks to a few months , the associated diesel engines are usually very large, from several hundred to over a thousand horsepower. As such, drilling activities can generate a substantial amount of NO x emissions . While previous studies have focused more intently on quantifying the ongoing fugitive VOC emissions associated with oil and gas production, significant uncertainty remains regarding the shorter term NOx emission levels associated with drilling activity . In order to gain a more accurate understanding of emissions from drilling rig engines, data regarding typical rig profiles (number of engines, engine sizes , and engine load factors) were collected through phone and email surveys for drilling operations for the 2008 base year. These data were used to develop well drilling emissions profiles using US EPA's NONROAD emissions model. 1 To develop the statewide emissions inventory, the drilling rig emissions profiles developed as a result of the survey were applied to well drilling activity data for 2008 obtained from the Texas Railroad Commission (TRC). The activity and drilling rig engine emissions profiles developed under this study were used to develop emissions estimates of volatile organic compounds (VOC), nitrogen oxide (NO x), carbon monoxide (CO), particulate matter (PM10 and PM2.s ), sulfur dioxide (S02), and 1 While the NONROAD model was used to calculate drilling activity emi ssions (in order to more accurately capture emission standard phase in impacts), the se emissions are actually classified as area sources emissions and reported as such to the TCEQ . 2-1 hazardous air pollutants (HAP) for drilling rig engines across the state. Emissions are calculated on a county-level basis and provided in annual tons per year and by typical ozone season day. For planning purposes , the 2008 base year estimates were used to develop 2002 and 2005 prior year inventories, as well as projected inventories for 2009 through 2021 . Section 3.0 of this report provides the results of a review of existing literature as well as currently available data that could be used to develop the inventory. This discussion also provides an overview of the drilling process and identifies the types of activities and equipment that are commonly associated with drilling activity. Section 4.0 provides an overview of the data collection plan and the subsequent survey that was used to obtain the information needed to develop the model drilling rig emissions profiles. Section 5 .0 presents the results of the survey, including a discussion of how the data was broken down into distinct "model" drilling rigs by well type and depth. Section 6 .0 describes the development of the emissions inventory including how the activity data was compiled, how the model drilling rig emission profiles were developed , and how these model drilling rig emission profiles were combined with the activity data to develop the 2002, 2005 , and 2008 through 2021 emission inventories. 2-2 3.0 Review of Existing Literature At the start of this study ERG conducted a review of relevant literature, current studies , and available data that could be used in the development of a drilling rig engine emissions inventory for Texas. The results of this research are discussed below in Sections 3.1 through 3.3. Section 3 .1 discusses the review of existing studies concerning estimating emissions from oil and gas drill rig operations, Section 3 .2 covers the results of the review of existing Texas data available from government and industry websites and publications, and Section 3.3 includes a discussion of drilling rigs and the types of engines and activities occurring during a drilling operation. 3.1 Review of Existing Studies Over the last several years numerous studies have been conducted in the western states to develop area source emission estimates for oil and gas exploration and production sources, with subsequent studies improving upon the data collection methodology and emission estimation approaches. Most of these studies addressed emissions from drilling rig engines to some degree. The relevant studies ERG identified are listed in Table 3-1. Table 3.1 Existing Oil and Gas Exploration Emissions Studies Report Title Geographic Publication Date Covera2e Oil and Gas Emission Inventories for the Western WRAP States December, 2005 States (Russell, et al., 2005) Ozone Precursors Emission Inventory for San San Juan and Rio Arriba Juan and Rio Arriba Counties, New Mexico Counties , August, 2006 (Pollack, et al., 2006) New Mexico Emissions from Oil and Gas Production Facilities Texas August, 2007 (TCEQ , 2007) WRAP Area Source Emissions Inventory Projections and Control Strategy Evaluation WRAP States September, 2007 Phase II (Bar-Ilan , et al., 2007) Development of Baseline 2006 Emissions from Denver- Oil and Gas Activity in the Denver-Julesburg Julesburg April , 2008 Basin (Bar-Ilan, et al., 2008) Basin , Colorado Recommendations for Improvements to the CENRAP CENRAP States' Oil and Gas Emissions States November, 2008 Inventories (Bar-Ilan, et al., 2008a) 3-1 Table 3.1 Existing Oil and Gas Exploration Emissions Studies (Cont.) Report Title Geographic Publication Date Covera2e Development of Baseline 2006 Emissions from Piceanc e Oil and Gas Activity in the Piceance Basin (Bar-Basin, January, 2009 Ilan, et al., 2009) Colorado Based on a re view of these studies, ERG developed a series of survey questions to obtain the types of data that would be needed to develop the 2008 base year emissions inventory. The resultant survey was developed using example survey questions and forms from several of these ex isting studies . The studies identified in Table 3-1 were comprehensive in nature , inclusive of all emission sources found at oil and gas exploration and production locations . While drilling rig engines were typically included in these studies, this source category was not the primary focus of these efforts , as these inventories addressed emissions sources associated with both the exploration and production sides of the oil and gas industry. As such, many of the surveys used in these studies were sent to the oil and gas producers themselves, and not directly to the owners and operators of the drill rigs , who are typically contracted by the producers to drill the well. As described below in Section 5, ERG focused this survey effort on the drilling contractors themselves , who are most familiar with drilling equipment and activities , with less emphasis on the production companies. 3.2 Review of Existing Data All exploratory oil and gas drilling in Texas requires a permit. These permits are processed and maintained through the TRC . The drilling permits are available for review through the TRC website , and include well-specific data such as approval date, location (county), well profile (vertical, horizontal, directional), well depth , start or "spud-in" date, and well completion date . On March 10 , 2009 , ERG obtained this data in electronic format through acquisition of the "Drilling Permit Master and Trailer" database . This database formed the basis of the activity data used to develop the 2008 base year emissions inventory. In addition to the drilling permit data obtained through the TRC, many of the larger drilling contractors provide information about their drilling rig fleets in their on-line websites. Examples of these websites are provided in the approved Data Collection Plan, which is included as Appendix A of this report. ERG reviewed this on-line information in an effort to gain a better understanding of typical drilling rig engine profiles , including the size , number, and type of 3-2 engines used on typical rigs. Additional information provided included make and model of the engines. Engine manufacturer websites were also reviewed and proved useful as a resource to obtain engine specifications and fuel usage data that could be used to gapfill the data obtained during the survey and needed to complete the emissions inventory . For example , engine fuel usage data could be used to determine load percentages for engines where the operator provided fuel use data but did not provide load estimates. 3.3 Drilling Rig Overview Air pollutant emissions from oil and gas drilling operations originate from the combustion of diesel fuel in the drilling rig engines . The main functions of the engines on an oil and gas drilling rig are to provide power for hoisting pipe , circulating drilling fluid , and rotating the drill pipe. Of these operations , hoisting and drilling fluid circulation require the most power. There are two common types of rigs currently in use -mechanical and electrical. In general , mechanical rigs have three independent s ets of engines. The first set of eng ines ( draw works engines) are used to provide power to the hoisting and rotating equipment, a second set of engines (mud pump engines) are dedic ated to circulating the drilling fluid which is commonly referred to as "mud", and a third Draw Works engines - used to power hoisting and rotating equipment Mud Pump engines -used to circulate drilling fluid Generator engines -used to power auxiliary equipment set of engines (generator engines) are used to provide power to auxiliary equipment found on the drill site such as lighting equipment and heating and air conditioning for crew quarters and office space . There may be one, two , or more draw works engines , depending on the input power required. There are typically two mud pumps for land rigs, with each mud pump independently powered by a separate engine . The mud pump engines are typically the largest engines used on a mechanical rig. Finally , there are typically two electric generator engines per mechanical rig , with one running continuously and the second serving as a stand by unit. Electrical rigs are typically comprised of two to three large, identical diesel-fired engine- generator sets that prov ide electricity to a control house called a silicon controlled rectifier (SCR) house. E lectricity from the SCR house is then used to provide power to separate motors on the rig . In this configuration, there are dedicated electric motors used for the draw works/hoisting operations, the mud pumps , and other ancillary power needs (such as lighting). The generator engines are loaded as required to meet fluctuating power demands, with one unit typically designated for standby capacity. The trend in new rig design is almost exclusively towards electric rigs , except perhaps for the smallest rigs. This is probably due to the relative expense of 3-3 engines versus motors , both in terms of initial cost and maintenance. Today, electrical rigs are common, especially for larger rigs (Bommer, 2008). After drilling and casing a well , it must be "completed." Completion is the process in which the well is enabled to produce oil or gas . Once the desired well depth is reached, the geological formation must be tested and evaluated to determine whether the well will be completed for production, or plugged and abandoned. To complete the well production, casing is installed and cemented and the main drilling rig is dismantled and moved to the next site. A smaller rig, called a completion rig (also known as a workover rig), is then moved on site to bring the well into production, to perforate the production casing and run production tubing to complete the well. Typically, the completion rig is a carrier-mounted arrangement and may be on-site for several days to a week or more depending on well depth and other factors. The completion rigs hoist smaller loads and pump at lower rates than the drilling rigs, and therefore require much smaller engine capacity. Increasingly, reservoir productivity is enhanced by the application of a stimulation technique called hydraulic fracturing. In this process, the reservoir rock is hydraulically overloaded to the point of rock fracture. The fracture is induced to propagate away from the well bore by pumping hydraulic fracturing fluid into the well bore under high pressure . The fracture is kept open after the end of the job by the introduction of a solid proppant (sand, ceramic, bauxite, or other material), by eroding the sides of the fracture walls and creating rubble by high injection rates, or for carbonate formations , by etching the walls with acid . The fracture thus created and held open by the proppant materials becomes a high conductivity pathway to the well bore for reservoir fluid. In vertical wells a single fracture job per reservoir is commonly done. In high angle or horizontal wells, it is common to perform multiple fracturing jobs (multi stage fracturing) along the path of the bore hole through a reservoir. Fracturing jobs are often high rate, high volume, and high pressure pumping operations. They are accomplished by bringing very large truck- mounted diesel-powered pumps (e.g., 2,000 hp or more) to the well site to inject the fracturing fluids and material, and to power the support equipment such as fluid blenders. The measure of the power required is based on the hydraulic horsepower necessary to fracture the well. Although very short in duration (typically less than a day), fracturing activities may result in substantial NOx emissions due to the very high horsepower requirements. Oil and gas wells are commonly classified as vertical, directional, or horizontal wells , depending on the direction of the well bore . Vertical wells are the most common, and are wells 3 -4 that are drilled straight down from the location of the drill rig on the surface. Directional wells are wells where the well bore has not been drilled straight down, but has been made to deviate from the vertical. Directional wells are drilled through the use of special tools or techniques to ensure that the well bore path hits a particular subsurface target, typically located away from (as opposed to directly under) the surface location of the well . Horizontal wells are a subset of directional wells in that they are not drilled straight down, but are distinguished from directional wells in that they typically have well bores that deviate from vertical by 80 -90 degrees. Horizontal wells are commonly drilled in shale formations. Once the desired depth has been reached (the well bore has penetrated the target formation), lateral legs are drilled to provide a greater length of well bore in the reservoir. 3-5 4.0 Data Collection Plan ERG's Data Collection Plan identified the proposed approach for collecting the information needed to develop a comprehensive emis s ions inventory for land -based drilling rig engines in the state of Texas in 2008 . The primary focus of the data collection survey was to obtain engine operating data from rig operators who were actively drilling in Texas in 2008. The goal of this survey was to obtain sufficient data to allow for the development of a series of "model" drilling rig emission profiles for different well types and/or depths to apply to the corresponding subsets of the TRC well activity data. Details of the Data Collection Plan were subject to external peer review and appro ved by TCEQ . ERG conducted the data collection as per the approved Data Collection P lan , which is included as Appendix A . 4 .1 Participant Recruitment In order to encourage survey response rates, stakeholder support for the study was sought. In addition to consulting with contacts at the University of Texas , Southern Methodist University , and the Texas Railroad Commission for suggestions on implementing the survey and soliciting participants , the following trade associations were contacted to help encourage participation in the study: • International Association of Drilling Contractors (IADC) • Texas Independent Producers and Royalty Owners Association (TIPRO) • Texas Oi l and Gas Association (TXOGA) ERG provided the trade associations with a draft copy of the survey materials and requested they distribute them to their membership for feedback. In addition , ERG requested these trade groups lend their support to the project through a letter of introduction about the study to be sent to their constituents . While these as sociations were supportive of the goals and appreciated the need for this study , ERG did not receive any feedback on the draft survey materials. However, both TIPRO and TXOGA recognized the importance of the project and agreed to allow ERG to reference their support in the survey transmittal letter (see Appendix B). 4.2 Phone/Email Surveys Once the survey was developed , ERG obtained contact information for oil and gas well operators and drilling contractors in order to distribute the survey. The primary source of data used to identify target respondents was the commercial RigData® database . This database 4 -1 contains information for over 24,000 drilling permits issued in Texas between January 1, 2008 and March of 2009. For over 14,000 of these records, drilling contractor contact information was provided. The RigData® database used to develop the target respondent list has been provided to the TCEQ in electronic format ERG attempted to contact each of the drilling contractors included in this listing through phone and/or email surveys. The survey effort itself focused on collecting the following information from each respondent: • The number of engines on a rig • Engine make , model, model year, and size (hp) • Average load for each engine • Engine function (draw works, mud pumps, power) • Actual engine hour data for each well (total hours) • Actual engine fuel use data for each well (total fuel use) • Total well drilling time (actual number of drilling days) • Total well completion time (number of days needed for well completion activities) • Well depth • Number of wells represented by survey An example of the data collection form used to compile the results of the survey is presented in Appendix C . For those respondents who were contacted via email, an Excel file containing similar information was provided as an email transmittal. The results of the survey effort are described in Section 5.0. 4.3 Confidentiality Confidentiality was stressed to survey participants, as evidenced in the survey letter. ERG is particularly sensitive to the privacy of individuals and businesses. Therefore all interviews and data collection efforts began with a guarantee of privacy, anonymity, and confidentiality. To ensure survey respondent's rights to privacy, respondents were informed of the research purpose, the kinds of questions that would be asked, and how the TCEQ may use the results of the study. Confidentiality was maintained by eliminating respondent names from the study datasets before provision to the TCEQ. 4-2 5.0 Data Collection Results 5.1 Survey Findings Using the contact information in the RigData® dataset , ERG began implementation of the Data Collection Plan on April 30, 2009 and collected data through June 16 , 2009. Initially, contacts were attempted with many of the oil and gas well operators themselves . As a rule , the operators were knowledgeable concerning general information about the drilling process including average depth , drilling days , number of engines used and gallons of fuel used per day. However, they typically did not have the specific information about the characteristics of the rig engines (model year, engine size , and load factors) needed to estimate emissions . During phone interviews it was discovered that several of the operators also drilled their own w ells. Based on the se interviews , the strategy for the remainder of the data collection phase of the project was refined. In particular, factors such as depth of the well , the engine configurations used , the individual preferences of drilling superintendents to idle engines or to tum them off, and the difficulty of estimating load and operating hours over the entire drilling period made it difficult to collect the data via email or fax without being able to discuss the needed data directly with the respondent. The complexity of the drilling process and the lack of response from the operators to anything other than a v erbal interview informed the collection process for the drilling contractors . Therefore to obtain the information needed, a verbal interview with the actual drilling contractors was determined to be preferable in order to carefully walk the respondent through the survey questions. The RigData® dataset included approximately 225 unique contact profiles for drilling contractors . However, many of these contacts were regional contacts for the same company, several had gone out of business , and others had recently consolidated into a single company. As a result, the final number of unique contacts for the drillers was approximately 190. ERG attempted to contact each of the drilling companies at least four times , by phone a nd/or email. Based on the experience with contacting the operators , verbal contact was attempted with each respondent before distribution of the surv ey through email or fax. The strategy was designed to increase participation by explaining the purpose of the survey, to explain the data being requested, and thus avoid recei ving incomplete or inaccurate surveys. For each targeted survey respondent, three attempts were made v ia phone to find someone to speak 5-1 with before a voicemail was left or an email was sent. This strategy was intended to eliminate dead-end contacts such as unreturned voicemails or emails. Because smaller companies generally had fewer administrative and management personnel , contact for companies with less than 50 wells generally consisted of a phone call answered by a receptionist who either took a message , transferred the call to a voicemail , or establi shed direct contact with someone who could answer the survey questions. If there was no answer, a return call was scheduled. After three attempts without response , a short voice message was left. If no reply was received to this message, no further attempt was made to contact the respondent. For the larger drilling companies (those that drilled over 100 wells in 2008), an enhanced contact strategy was used . Because some of the companies are quite large and represent a significant percentage of the wells drilled in the state, more extensive efforts were made to increase their participation. For several of these companies, an effort was made to encourage response by providing them with tailored Excel spreadsheets identifying their wells and asking about specific well types and locations . In addition, attempts were made to contact the company through multiple avenues , either through multiple contacts provided in the RigData® dataset , or through contact information available on-line. In one case, ERG collected data from one of the top 25 drilling contractors after an initial refusal from one drilling superintendent by requesting data through other contacts at the company. Generally speaking, at least ten contacts through phone calls and emails were attempted for the larger companies , the medium sized companies required from 5 to 7 contacts, and the smaller companies required 3 to 4 contacts before identifying the appropriate person to talk to. At the completion of the survey effort, 45 completed surveys with sufficient data to estimate emissions had been obtained from 39 different drilling rig contractors and/or oil and gas well operators. This figure reflects approximately a 15 % response rate for complete surveys from the attempted contacts . One additional survey was received after the submittal cutoff date , but it was not received in time for incorporation into the inventory. The surveys that were received and used in the inventory were representative of over 1,500 wells drilled in Texas in 2008 and covered 121 counties and all of the major oil and gas basins in the state (Andarko, East Texas, Ft. Worth/Bend Arch, Permian, and Western Gulf). An additional 17 survey responses were obtained, but the respondents for these surveys did not provide sufficient information to be used in the final model drilling rig emission profile de v elopment. Typically, these incomplete responses were those received from the oil and gas 5-2 well operators and not the drilling contractors. Considering both the complete and incomp lete survey responses , the overall response rate for the survey effort was approximately 21 %. Table 5-1 presents the summary results for the survey effort. Table 5.1 Survey Summary Statistics Survey A c tivity/Results -Number of Res pondents Attempted Company Contacts 295 Refusal to Participate 24 Soft Refusal ( did not return attempted contacts via phone calls or email) 209 Respondent Interviewed and provided sufficient data for inclu sion in inventory dataset 45 Respondent Interviewed , but insufficient data provided for inclusion in inventory dataset 17 Figure 5-1 provides a county-level map of Texas providing a graphical representation of the geographic coverage of the survey results. 5.2 Model Rig Category Development Upon completion of the survey and data collection task, the survey results were compiled into a spreadsheet database for evaluation in order to disaggregate the survey data into sub- categories for model drilling rig profile development. As each completed survey was received from the surveyor, identifying information for that survey was entered into a tracking spreadsheet, and the survey was prepared for data entry and forwarded to data entry personnel. Upon receipt of the survey , data entry personnel transferred the data in the survey form into the spreadsheet database, and updated the survey tracking spreadsheet with date of data entry and their initials. A QA check was then performed on the data entered into the spreadsheet database, and the tracking spreadsheet was updated to indicate the date of QA and the initials of the personnel performing the QA. 5-3 Figure 5.1 Counties with Survey Data Survey results for vertical, directional, and horizontal well types were reviewed as described below. A review of the 32 surveys completed for vertical drilling, representing 1,261 wells, provided a clear distinction between the engine profiles (number and size of engines) used to drill shallow vertical wells relative to deeper vertical wells . In particular, by separating the 5-4 survey results into those representing wells at 7,000 feet of depth or less , and those representing wells deeper than 7,000 feet, the following differences were observed: • The average drilling duration for the shallower wells was 8 days , with a maximum of 14 days; • The average drilling duration for deeper wells was 27 days , with a maximum of 84 days; • Only 1 of the 16 profiles for shallow wells was for an electrical rig, compared to 6 electrical rig profiles out of the 16 profiles for the deeper wells; • The engine sizes were significantly different for the shallow and deep wells, with the survey results for the shallow wells containing no engines over 700 hp , while the engine population for surveys received for the deeper wells contained approximately 25 engines rated at over 1,000 hp . For horizontal and directional wells, a total of 13 completed surveys were received representative of 288 wells. The average measured well depth of the wells covered under these surveys was approximately 11 ,000 feet, with a minimum of 8,000 feet and a maximum of 17,688 feet. All of the profiles for horizontal and directional wells were either for electrical rigs (6 profiles) with 2 or 3 engines, or for mechanical rigs (7 profiles) with 6 engines . Due to the limited number of surveys received for horizontal and directional wells , and the relative consistency of the profiles for these types of wells, it was determined to consolidate the survey results for horizontal and directional wells into one model rig category. Table 5-2 provides a summary of the final survey statistics for each of the three model rig well type categories. Table 5.2 Model Rig Category Statistics Number Number of Model Rig of surveys respondents Number of Number of Number of Well Type included providing Wells Mechanical Electrical Cate2orv in profile surveys Represented Ri2 Profiles Ri2 Profiles Horizontal and Directional 13 10 288 7 6 Wells Vertical Wells 16 16 900 15 1 <= 7,000 feet Vertical Wells > 16 13 361 10 6 7,000 feet Tables D-1 through D-3 in Appendix D contain the collected survey data for each of the three model rig well type categories. 5-5 5.3 Fracturing During the data collection phase of this project, information was solicited from respondents regarding fracturing activities. While not specifically mentioned in the original work plan or data collection plan, a review of existing literature and studies showed fracturing activity to be increasing in Texas over the past several years. As part of their survey response, the drilling contractors and oil and gas exploration companies occasionally provided some qualitative or quantitative information regarding fracturing, but the responses were highly variable in content and format. In general, the indication was that fracturing was a short-term activity (less than one day in duration), and that pump trucks containing multiple, large diesel-fired engines could be used simultaneously to pump the fracturing fluids into the well. Specific information regarding the frequency of fracturing events and the total hp-hours required per event were not generalizable to the inventory as a whole, however. Further investigation regarding fracturing was made by contacting service companies that provide fracturing services , as well as interviewing personnel at the TRC and researching the availability of fracturing data on-line through the TRC website . Two of the three service companies contacted provided some data for the fracturing activities they performed in 2008 , which varied from the use of five 1,250 hp pump engines for a total duration of 1 hour, to the use of seven 2,500 hp pump engines for a total duration of 12 hours. The third service company contacted did not provide any data as of the time of this draft report . Unlike the drilling permit records obtained through the "Drilling Permit Master and Trailer" database , fracturing data is not compiled by the TRC or otherwise made readily available in any summarized format through any on-line queries or electronic datasets. However, images of individual well completion records (referred to as G-1 forms for gas well completions and W-2 forms for oil well completions) are available on-line through the TRC website . Using American Petroleum Institute (API) numbers from the TRC data, a random on-line search was performed to review the G-1 and W-2 records for approximately 1,200 wells. The G-1 and W-2 forms were only found for approximately one-third of these wells. These forms are frequently completed by hand, with inconsistent data being reported by individual well operators, with much of the data being incomplete . However, based on a review of the records we were able to identify, it appears that approximately 80% of the wells in the sample had some kind of fracturing activity occurring prior to well completion. 5-6 While data is not currently available under this project to provide emission estimates for fracturing activities, due to the large engine sizes used by the pump trucks , this is a source category that may be considered for inclusion in future emission inventory development projects. 5-7 6.0 Emissions Inventory Development and Results The 2008 activity data from the TRC and the model rig emissions profiles developed using the survey results for each model rig well type category were utilized to develop emissions estimates for selected target years as described below. 6.1 Activity Data 6.1.1 2008 Base Year Activity Activity data for the 2008 base year was obtained from the TRC through acquisition of the "Drilling Permit Master and Trailer" database, which contains information on well drilling activities, including American Petroleum Institute (API) number, date approved, location (county), well profile (vertical, horizontal, directional), well depth, spud-in date, and well completion date. The TRC data was combined with data from the RigData® dataset used to identify survey respondents as discussed previously. This combined database was used to compile an initial list of all oil and gas wells that were either completed in 2008 (based on completion date), or that were started in 2008 (based on spud-in date). As many of the wells completed in 2008 were started in 2007, and many of the wells started in 2008 were not completed until 2009, an adjustment was needed to the initial list of wells to determine a representative dataset for 2008. This adjustment was accomplished by including only those wells with spud dates of December 1, 2007 or later (and that were completed in 2008), and only those wells with completion dates of January 31, 2009 or earlier (and that had spud-in dates in 2008). In all, 16,964 oil and gas wells are included in the final 2008 dataset which compares favorably with the 16,569 oil and gas well completions reported by the TRC in 2008 (TRC , 2009c). The slight discrepancy with the total wells included in the 2008 dataset compared to the completion figure from the TRC is due to the fact that the TRC data only includes 2008 completions and does not account for wells started in 2008 that were not completed until 2009. The final 2008 activity dataset contains drilling activity data for 210 of the 254 counties in Texas. 6.1.2 2002 and 2005 Prior Years Activity Once the final 2008 activity dataset was established, activity data scaling factors for 2002 and 2005 were developed based on the ratio of the oil and gas well completions for those years relative to the number of oil and gas well completions in 2008 as reported by the TRC (TRC 6-1 2009a, T R C 2009b , TRC 2009c). This analysis was performed at the TRC district leve l, which allowed geographic variation in drilling trend s across the state from 2002 through 2008 to be reflected in the 2002 and 2005 p rior year datasets . Figure 6-1 provides a county-level map of Texas showing the location and coverage of each of the TR C districts. Oil and Gas Division District Boundaries District Office 1 &2 San AntonJo 3 Houston 4 Corpus Christi 5&6 Kilgore 8 78 Abilene 7C San Ange lo 8&8A Midland RAILROAD COMMlS ION ofTEXAS 9 Wichita Falls Oil Md G~ Di1'i$fo'n 10 Pampa Figure 6.1 TRC District Map 6 -2 For example, in 2008 there were 512 total oil/gas well completions in TRC District 1, and in 2002 there were 165 total oil/gas well completions in District 1. Therefore, the scaling factor from 2002 to 2008 is: 2002 to 2008 scaling factor= 165 wells / 512 wells = 0 .32 Table 6-1 shows the 2002, 2005 , and 2008 oil and gas well completion records and the resultant 2002 and 2005 scaling factors that were developed for each district for this analysis . Table 6.1 2002 and 2005 Prior Year Activity Scaling Factors 2008 Total 2002 Total 2005 Total Oil/Gas Oil/Gas 2002 Scaling Oil/Gas 2005 Scaling TRC District Completions Completions Factor Completions Factor 1 512 165 0 .32 389 0.76 2 687 513 0 .75 672 0 .98 3 699 724 1.04 712 1.02 4 1,351 1,266 0 .94 1,123 0 .83 5 738 618 0 .84 714 0 .97 6 1,973 717 0.36 1,556 0 .79 7B 746 298 0.40 501 0 .67 7C 2,082 887 0.43 1,389 0 .67 8 2 ,641 1,281 0.49 927 0 .35 8A 559 756 1.35 626 1.12 9 3 ,484 1,096 0 .31 1,185 0 .34 10 1,095 419 0 .38 856 0 .78 As can be seen in Table 6-1 , certain areas of the state experienced significant growth in drilling acti vity in 2008 relativ e to 2002, while other areas remained relatively stable. The most dramatic example of this change in activity can be seen in TRC District 9 , which contains the Barnett Shale, an area that has experienced significant growth in drilling activity over the last 6 years . For this District, drilling activity approximately tripled between 2002 and 2008. The scaling factors presented in Table 6-1 were applied to the 2008 base year well depth totals by county for each of the three model rig well types to determine county-level well depth for each model rig type for 2002 and 2005 . 6.1.3 2009 through 2021 Projected Activity 2009 through 2021 projected activity data were developed using the 2008 base year activity data from the TRC and forecasting future activity based on US DOE Energy Information Administration (EIA) projections of oil and gas production for the Southwest and Gulf Coast 6-3 regions from the Annual En ergy Outlook 2009, Upda te d R eference Ca se w ith ARRA (EIA, 2009). The EIA data tables (specifically Tables 113 and 114) present estimated crude oil and natural gas production estimates for the years 2006-2030. The geographic level of the projected data is by EIA Region. Portions of Texas fall into three EIA Regions: Gulf Coast (Region 2); Southwest (Region 4); and Midcontinent (Region 3). The majority of the State is in the Gulf Coast and Southwest EIA Regions . Only a small portion (area to the west of Oklahoma) is in the Midcontinent Region. In addition , because the Midcontinent EIA Region contains six other states , any projections data for the Midcontinent EIA Region may not be reflective of Texas operations . Thus , it was assumed that the Southwest and Gulf Coast EIA Regions are representative of Texas and each region was weighted equally to determine the statewide projections. Figure 6-2 shows the EIA regions and their coverage in Texas . Figure 6.2 EIA Regions Tables 6-2 and 6-3 show projected crude oil and natural gas production for the Gulf Coast and Southwest EIA Regions , as well as the combined total for both regions , from 2008 through 2021 . The total percentage change for each year from 2009 through 2021 is presented relative to the base year of 2008 . This data was then used to calculate a projected growth factor(%) for each year from 2009 through 2021 by weighing the oil and gas percentage growth figures relative to the number of oil and gas wells completed in Texas 2008 . For example , the projected growth factor for 2009 is calculated as follows: 6-4 Table 6.2 Projected Crude Oil Production 2008-2021 Crude Oil Production (MMBBL/day) EIA Region 2008 2009 2010 2011 2012 2103 2014 2015 2016 2017 2018 2019 2020 2021 Gulf Coast 0 .503 0 .505 0 .503 0.483 0.465 0.450 0.438 0.401 0 .3 74 0.347 0.320 0.294 0 .271 0.251 Southwest 0.919 0 .920 0.904 0 .892 0 .890 0.915 0 .956 1.000 1.043 1.082 1.117 1.147 1.167 1.183 Total 1.422 1.425 1.407 1.375 1.355 1.365 1.393 1.402 1.416 1.429 1.436 1.442 1.438 1.434 % change from 2008 0 .2 1% -1.05 % -3.29% -4 .71% -4.01 % -2 .02 % -1.42% -0 .39 % 0 .50% 1.02 % 1.38 % 1.14% 0.86% Table 6.3 Projected Natural Gas Production 2008-2021 Natural Gas Production (trillion cubic feet) EIARegion 2008 2009 2010 2011 2012 2103 2014 2015 2016 2017 2018 2019 2020 2021 Gulf Coast 5.412 5.165 4 .792 4 .606 4.415 4 .326 4 .233 4 .162 4 .086 4 .020 3.959 3.921 3 .903 3.825 Southwest 2.170 2.474 2.623 2.716 2 .713 2.679 2 .659 2.645 2 .627 2 .609 2 .603 2 .591 2.591 2 .564 Total 7 .582 7.639 7.415 7.321 7.128 7 .005 6 .892 6.807 6.713 6.629 6 .563 6.512 6.495 6.388 % change from 2008 0 .76 % -2 .20% -3.44% -5.99 % -7 .61 % -9 .09 % -10 .2% -11.5 % -12 .6% -13.4% -14 .1% -14 .3% -15 .7% 6-5 2009 growth factor =((%change from 2008 to 2009 in Crude Oil Pro duction x number of oi l well completions in 2008) + (% change from 2008 to 2009 in Natural Gas Production x number of gas well completions in 2008)) / (total numb er of oil and gas well completions in 2008) Using the data in Tables 6-2 through 6-4 , the projected growth factor for 2009 is: 2009 growth factor = ((0 .21% x 6,208) + (0 .76% x 10,361)) / (6 ,208 + 10,361) = 0 .55% Table 6-4 shows the growth factors that we re deve loped for each proj ected year as a result of this analysis. These factors were then applied to the 2008 base year well depth totals by county for each of the three mode l rig profile we ll types to determine activity data for 2009 through 2021. It is worth noting that through the first five months of 2009 , the number of well completions in Texas has exceeded the number of well completions for the same period in 2008 . However, during the second half of 2008, there was a dramatic increase in drilling activity in Texas which dropped off significantly by the end of the year due to commodity prices and the effects of the economic recession. Therefore, while Table 6-4 presents projected production data based on the current DOE EIA data, the volatility in drilling activity during 2008 , coupled with the rapidly changing economic climate over the last year, results in a high leve l of uncertainty regarding these ( or any) projections for drilling activity in 2009 and beyond . These projections are based on the best data currently available , but should be revisited once the economic climate and oil and gas prices stabilize in order to more accurately assess future year projected erruss1ons. 6.1 .4 2002 , 2005 , and 2008 through 2021 Act ivity Summary Once the final activity dataset for 2008 was determined , total county-level well depth for each of the three model rig well type categories was calculated by summing the individual well depths in each county by model rig well type category. The total county-level well depth for 2002 , 2005 , and 2009 through 2021 for each model rig well type category was then calculated based on the 2008 summary data using the methodology described above . Tab le 6-5 shows the total depth by model rig well type category for 2008 (blank cells indicate there was no activity in that county for that well type). 6 -6 Table 6-4 Projected Growth Factors 2009-2021 Production % cbane.e from 2008 2008 Well Completions 2009 2010 2011 2012 2103 2014 2015 2016 2017 2018 20 19 2020 2021 Oi l I 6,208 0 .2 1% -1.05 % -3 .29 % -4 .7 1% -4 .01 % -2.02 % -1 .42 % -0 .39% 0.50% 1.02 % 1.38 % 1.14% 0 .86% Natura l Gas I 10 ,361 0.76% -2 .20% -3 .44% -5 .99 % -7.6 1% -9 .09 % -10 .2% -11.5% -12 .6% -13.4% -1 4 .1% -14.3 % -15.7% Projected Growth Factor 0 .55 % -1.77 % -3 .38 % -5 .5 1% -6 .26 % -6.44 % -6 .92 % -7 .3 1% -7 .67 % -8 .02% -8.3 1 % -8 .54% -9 .52 % 6-7 Table 6.5 2008 Total Depth by Model Rig Well Type Category (1,000 feet) County Vertical <= 7 .000 feet Vertical> 7,000 feet Directional/Horizontal Anderson 52.20 113 .70 20.33 Andrews 1,969.19 l ,115 .4 1 46 .30 Angelina 1.32 394 .74 101.70 Aransas 6 .00 45.45 23.30 Archer 221.32 15.50 Atascosa 39.80 38.50 Austin 67.19 28.70 15.02 Bastrop 6.40 74 .60 71.70 Baylor 45 .54 5 .50 Bee 239.20 204.49 240.25 Bell 4 .50 Bexar 0.80 Borden 11.45 166 .10 42.85 Bosque 10.00 15.80 Bowie 9 .00 Brazoria 15 .90 252 .90 103 .39 Braz os 33 .14 214 .89 Briscoe 6 .50 8 .50 Brooks 17 .16 582 .32 103 .96 Brown 41.00 Burleson 208.41 172.77 Caldwell 29.86 8.15 Calhoun 15 .60 112 .60 82 .83 Callahan 81.68 Cameron 9 .50 Carson 6 .50 10.10 Cass 7 .00 Chambers 78 .60 153.46 Cherokee 9.40 886 .08 243.05 Childress 9 .30 Clay 116 .15 23 .00 52.50 Cochran 229.30 25 .00 Coke 121.70 15 .70 Coleman 97 .69 Colorado 122 .71 149.88 25.42 Comanche 3 .00 Concho 167.15 Cooke 161.00 228 .84 17 .90 Coryell 4 .00 Cottle 39.20 106.70 8.00 Crane 602.54 175 .75 43 .26 Crockett 881.48 1,822.74 131.17 Crosby 91.69 Culberson 216 .89 44 .00 Dallas 99.50 6-8 Table 6.5 2008 Total Depth by Model Rig Well Type Category (1,000 feet) (Cont.) County Vertical <= 7,000 feet Vertical > 7,000 feet Directional/Horizontal Dawson 42.70 359 .69 17.50 Denton l l.lO 79 .50 2,491.72 DeWitt 57.40 392.08 568.84 Dickens l 74 .02 123 .70 Dimmit 270.5 l l 78.14 125.64 Duval 68.80 479.83 71.95 Eastland 48.09 Ector 501.36 1,619.73 73.30 Edwards 119.55 206 .10 67.50 Ellis 1.50 269.00 Erath 29.95 97.10 Falls l.80 Fannin 19 .00 Fayette 15.08 22.10 93.80 Fisher 162 .58 68 .30 Foard 25.10 Fort Bend 159.90 74.65 125.04 Franklin 10.90 94.55 Freestone l l.40 2,650.39 484.37 Frio 153 .73 62.80 61.74 Gaines 407 .24 633.81 56 .9 9 Galveston 4.40 51.15 53 .3 7 Garza 189.30 52 .00 3.20 Glasscock 900 .20 19 .20 Goliad 231.61 377.49 76 .04 Gonzales 15.53 21 .26 21.50 Gray 12.15 13 .00 Grayson 12.99 49 .00 37 .6 0 Gregg 503.10 263.25 Grimes 3 .90 169 .6 4 Guadalupe 9 .20 7 .79 Hale 65.00 15 .00 Hansford 62.41 263 .33 50 .20 Hardeman 12.59 96.23 28 .60 Hardin 81.95 284.12 180 .3 5 Harris 19 .20 34.20 85.40 Harrison 60.61 2,900.41 1,836.28 Hartley 17.95 Haskell 63.70 Hemphill 6 .50 3,936.45 685.47 Henderson 233 .25 53 .60 Hidalgo 37.54 1,324 .96 347 .92 Hill 7 .00 1,161.12 Hockley 208.43 123.40 87.44 Hood l ,Oll.19 6-9 Table 6.5 2008 Total Depth by Model Rig Well Type Category (1,000 feet) (Cont.) County Vertical <= 7 .000 feet Vertical > 7 .000 feet Directional/Horizontal Hopkins 4 .50 21.80 Houston 8.30 161.85 56.50 Howard 81.64 779.85 Hudspeth 26.00 22.00 Hutchinson 313 .77 17.10 39.00 Irion 196 .70 1,513 .07 Jack 197.69 137.50 Jackson 205.63 319.66 32.99 Jasper 8 .10 44.50 194.33 Jefferson 24.80 166 .30 300.61 Jim Hogg 9.40 194.13 14.38 Jim Wells 84 .07 52.75 6.11 Johnson 52.00 8,421.16 Jones 221.93 Karnes 21.40 100.90 179.60 Kenedy 7.00 382.44 92.50 Kent 120.99 109.80 36.00 King 203.90 7.40 Kleberg 54 .50 150.10 Knox 54.20 7 .20 La Salle 52.36 691.44 24.00 Lamb 32.80 7 .50 Lavaca 107.69 552.74 216.53 Lee 35.30 24.48 83.01 Leon 68.91 524.00 310.50 Liberty 34.00 330.85 145 .10 Limestone 6.30 1,876.14 451.40 Lipscomb 214.88 1,447 .13 Live Oak 132 .03 342.83 129 .60 Loving 149.10 620.83 33 .00 Lubbock 60.30 Ly nn 46 .25 Madison 36 .31 66.20 Marion 104 .73 66.50 Martin 3,643.04 Matagorda 25.97 590 .09 100.27 Maverick 333.88 27 .00 241.35 McCulloch 1.00 McLennan 1.23 9.50 9 .50 McMullen 128.79 749 .60 49 .50 Medina 30.11 Menard 70 .50 Midland 8.60 2,637 .28 75 .30 Milam 19.29 10.00 Mitchell 640 .83 6-10 Table 6.5 2008 Total Depth by Model Rig Well Type Category (1,000 feet) (Cont.) County Vertical <= 7 .000 feet Vertical > 7 .000 feet Directional/Horizontal Montague 107.08 475.44 365.20 Montgomery 6 .00 51.95 24.52 Moore 126.48 6.30 Motley 5 .00 9.00 Nacogdoches 1.00 2,210.41 761.92 Navarro 36 .15 102.10 6.60 Newton 30 .55 68 .50 Nolan 332.89 37 .70 Nueces 66 .84 339 .36 64 .62 Ochiltree 16 .50 309.88 427 .67 Oldham 45.90 Orange 7 .00 17.00 101.32 Palo Pinto 212.17 135.05 Panola 92 .08 2,693.70 1,652.45 Parker 6.45 880.85 Pecos 224.68 2,667.60 840.55 Polk 60.63 90.83 218.65 Potter 21.20 Reagan 34.05 2,509.42 Real 3.00 Red River 5 .80 8.20 5.80 Reeves 88.15 310.70 374.12 Refugio 588 .28 335.65 Roberts 17.80 1,337.30 361.71 Robertson 2,317.69 438.50 Runnels 375 .57 4.80 Rusk 27.00 3 ,697.44 508.05 Sabine 8.00 San Augustine 52.50 286.91 San Jacinto 3.70 127.95 24.00 San Patricio 29.80 94.07 89.11 Schleicher 117.95 416.02 Scurry 155.28 224.80 96.96 Shackelford 206 .38 Shelby 546.60 881.58 Sherman 274.40 80.60 Smith 6.50 108.75 185.85 Somervell 144.00 Starr 69 .53 1,406.17 178.30 Stephens 469.77 14.40 Sterling 40.42 294.86 9.25 Stonewall 221.08 Sutton 740.80 1,866.84 7 .20 Tarrant 37.45 18 .00 7,630.70 Taylor 69.30 4.00 6-11 Table 6.5 2008 Total Depth by Model Rig Well Type Category (1,000 feet) (Cont.) County Vertical <= 7 .000 feet Vertical > 7 .000 feet Directional/Horizontal Terrell 79 .85 295 .70 92.95 Terrv 26 .89 86 .20 55 .20 Throckmorton 90 .84 Titus 4.60 Tom Green 123.60 16.00 Trinity 4.10 Tyler 23 .11 70.20 329.95 Upshur 11 .77 260 .21 96 .80 Upton 78.50 4 ,699 .94 288.60 Val Verde 3.10 73 .30 Van Zandt 8.20 35.20 Victoria 296 .15 207 .20 33.03 Walker 4 .90 Waller 82.71 61.80 10 .00 Ward 460 .51 161.91 482.33 Washington 6.00 42 .00 Webb 262.53 1,689 .96 305 .77 Wharton 239.83 586.42 114 .77 Wheeler 3,839.70 482.40 Wichita 366 .76 9 .00 Wilbarger 126 .99 Willacy 301.75 25 .50 Wilson 4.45 Winkler 20.50 294 .95 148 .92 Wise 93.50 121 .00 2,032.78 Wood 17 .70 37 .86 32 .00 Yoakum 462 .25 195 .22 171.10 Young 259 .30 Zaoata 6.00 2,031.18 500 .35 Zavala 16 .05 60 .20 Statewide Total 20 ,746 82 ,337 48 ,121 Appendix E contains a summary of the total well depth by county and year for each model rig well type category. 6.2 Model Rig Emission Profiles 6.2.1 Model Rig Engine Profiles As described in Section 5.2, the survey data was disaggregated into three model rig categories for the following well types and depths based on the results of the data collection survey: • Vertical wells less than or equal to 7,000 feet ; 6-12 • Vertical wells greater than 7,000 feet; and • Horizontal/Directional wells. For each of these rig categories, a model rig engine profile was developed. In order for the model rig engine profile data to be applied consistently to the TRC activity data, the survey results were normalized to a 1,000 foot drilling depth. This was accomplished by dividing the total drilling hours for each engine included in each survey by the well depth for that survey to obtain the hours of operation per engine per 1,000 feet of drilling depth. As the engine profiles and functions for engines used on mechanical rigs and electrical rigs are distinctly different as described in Section 3.3, separate engine profiles for mechanical and electrical rigs were developed for each model rig well type category. The following average engine parameters were calculated for each model rig well type category using a weighted average for each parameter based on the number of wells associated with each survey: • Number of engines by rig type (i.e., mechanical draw works, mud pumps, and generators; electrical rig engines; and completion engines). • Engine age • Engine size (hp) • Engine on-time (hours/1,000 feet drilled) • Overall average load(%) Surveys with missing data parameters were excluded from the weighted average calculation. The weighted averaged engine parameters developed for each model rig category by rig type are summarized in Table 6-6. 6-13 Table 6.6 Model Rig Engine Parameters Model Rig Rig Type Engine #of Average Engine Hours/1,000 Average Cateeorv Type En2ines A2e (:vrs) Size (hp) ft drilled Load(%) Vertical <= Mechanical Draw Works 1.60 7 442 30 .8 51.8 7,000 ft 1 Mud Pumps 1.69 6 428 29.4 45 .9 Generator 0 .9 7 4 330 28.3 70.4 Vertical Mechanical Draw Works 2.01 25 455 35.9 47.4 > 7,000 ft Mud Pumps 1.62 18 761 33.2 46.0 Generator 2.00 10 407 19.3 78.7 Electrical 2.15 2 1,381 62.6 48 .5 Horizontal/ Mechanical Draw Works 2.00 15 483 50.1 41.l Directional Mud Pumps 2 .00 6 1,075 36.4 42 .6 Generator 2 .00 10 390 26.8 69.0 Electrical 2.03 2 1,346 47.3 52 .5 All All Completion 1.00 Default 350 10 .0 43 .0 1 The one electrical rig surveyed for vertical we ll s <= 7,000 fee t represents less than 0.5 % of the total wells m this model rig well type category and was considered to have a negligible contribution to the emissions profile. As can be seen in Table 6-6, the expected tr end toward larger engine sizes and more hours required per 1,000 feet for the deeper vertical wells and the horizontal/directional wells is verified. The older engine ages for the mechanical rigs used on the deeper vertical wells and the horizontal/directional wells are based on several surveys received for these well types that covered a large number of wells drilled by rigs with older engines . However, as noted in Section 3.3, the future trend for these types of wells is towards the use of electrical rigs , and the average age of the engines used on the electrical rigs for these well types is only two years. 6.2.2 Model Rig Emission Factors Once the final mechanical and electrical rig engine profiles were established for each model rig well type category, US EPA's NONROAD model was used to develop criteria pollutant emission factors for each rig type for each year of the inventory (2002 , 2005, and 2008 -2021). Use of the NONROAD model allowed for expected reductions in emissions over time due to the phasing in of EPA 's emissions standards for nonroad diesel engines. Using the engine parameters summarized in Table 6-6, NONROAD model input files were developed (U.S. EPA, 2005). In particular, the NONROAD Activity file was modified using the hours per 1,000 feet drilled and average lo ad, while the Population files were modified using the engine size. In addition , the population for a particular engine type was adjusted to a unit value of 1 for ease in calculation. The modified NONROAD files used in the emission factor calculation have been provided to the TCEQ in electronic format. 6-14 A total of 16 years were modeled -the base year of 2008, the prior years of 2002 and 2005 , and 13 projected years from 2009 to 2021. For each year modeled, the engine model age was kept constant. For instance, the 7 year old mechanical draw works engine for vertical wells< 7,000 feet was modeled as a 2001 model year engine for the 2008 base year, as a 1995 model year engine for 2002, and as a 2014 model year engine for the future year of 2021. The model year-specific emissions output from the NONROAD model (i.e., based on the model year fraction of the unit engine population specified by the NONROAD population file) was then ratioed up to the number of engines in each rig type. 2 For mechanical rigs, the draw works, mud pump, and generator engine emissions were aggregated together. For both mechanical and electrical rig types, a single completion engine of 350 hp running 10 hours per 1,000 feet drilled was also included to model completion activities . A composite model rig emissions profile was developed by aggregating the mechanical and electrical rig types together based upon the percentage of wells associated with each rig type. For example, for the horizontal/directional model rig well type, approximately two-thirds of the wells were represented by electrical rigs, so the resultant emission factors are weighted two-thirds by the NONROAD electrical rig emission factors, and one-third by the mechanical rig emission factors. S02 emissions are based on fuel sulfur content profiles for Texas obtained from historical fuel sampling data performed for the TCEQ. The average diesel sulfur content(% weight) for a particular analysis year was developed using the county-level fuel parameter data contained in TCEQ's TexN model, weighted by the number of wells in each county. The statewide average diesel sulfur content values calculated were 0.2995% for 2002 and 2005, 0.0316% for 2008 and 2009 , and 0.0015% for 2010 through 2021, reflecting the reduced sulfur requirements over time. Total hydrocarbon (THC) exhaust emissions from the NONROAD model were converted to VOC and TOG using ratios of 1.053 and 1.070, respectively (U.S. EPA, 2005a). Crankcase THC emissions were assumed to be equivalent to both VOC and TOG (U.S. EPA, 2005b). For diesel nonroad engines, PM10 is assumed to be equivalent to PM, while the PM25 fraction of PM10 is estimated to be 0.97 (U.S. EPA, 2005a). Hazardous air pollutant (HAP) emission factors were then developed by applying speciated HAP emissions profiles for PM 10 and TOG from the California Air Resources Board's 2 The NONROAD model allocates the total equipment population across a distribution of model years and estimates the emissions associated with each model year. For a given calendar year this analysis is interested in just one engine age/model year representing the average age for each model profile. Therefore the emissions for the model year of interest were scaled back up as if the entire engine population specified in NONROAD were allocated to just this one model year. 6-15 (CARB) Speciation Profile Database for diesel combustion to the PM and TOG emissions factors obtained from the NONROAD model (ARB, 2001). ARB profile #425 was used to speciate PM 10 , and ARB profile #818 was used to speciate TOG. Tables 6-7 and 6-8 present the speciation profiles for PM10 and TOG, respectively. Table 6. 7 PM 10 Speciation Factors Weight Fraction of HAP HAPCAS# PMlO Antimony 7440360 0.000036 Arsenic 7440382 0 .000005 Cadmium 7440439 0.000040 Cobalt 7440484 0 .000011 Chlorine 7782505 0 .000344 Lead 7439921 0 .000042 Manganese 7439965 0.000040 Nickel 7440020 0.000019 Mercury 7439976 0.000030 Phosphorous 7723140 0.000127 Selenium 7782492 0.000010 Table 6.8 TOG Speciation Factors Weight Fraction of HAP HAPCAS# TOG 1,3-butadiene 106990 0.002 2 ,2, 4-trimethy lpentane 540841 0.003 Acetaldehyde 75070 0.074 Benzene 71432 0.02 Cumene 98828 2£-04 Ethyl benzene 100414 0.003 Formaldehyde 50000 0.147 Methanol 67561 3£-04 m-xylene 108383 0.006 Naphthalene 91203 9E-04 n-hexane 110543 0 .002 o-xylene 95476 0.003 Propionaldehyde 123386 0.01 p-xylene 106423 0 .001 Styrene 100425 6£-04 Toluene 108883 0 .015 The final emissions profile for each of the three model rig well type categories was developed by weighing the emission profiles for each rig type (mechanical and electrical) by the 6-16 percentage of we lls of each rig type in each model rig well type category. Appendix F presents the emission factors developed for each of the model rig well type categories for 2002, 2005, and 2008 through 2021. 6.3 Emission Estimation Methodology Using the model rig well type category emission profiles , county-level emission estimates were calculated using the activity data from the TRC dataset. County-level well activity data in terms of total depth (1,000 feet) drilled was obtained by summing the depth of each individual well drilled for each of the three model rig well type categories for each county as described in Section 6.1. Once the total depth drilled by model rig well type category was known and the emission factor profile for each model rig well type category was developed, annual county level emissions for each model rig well type category were estimated by multiplying the total depth drilled (in terms of 1,000 feet) by the emission factors obtained through use of the survey data and the NONROAD model as follows: Epoll-type= (Depth (1,000 feet/yr)) x (EFpoll (tons/1,000 feet)) Where: Epoll-type Depth EFpon Emissions of pollutant for county by model rig well type category (tons/yr) Total depth drilled in model rig well type category by county (1,000 feet/yr) Emission factor of pollutant (tons/1,000 feet) For 2008 through 2021, NOx emission estimates for the 110 counties subject to the Texas Low Emission Diesel (TxLED) program were adjusted downward by 6.2% to account for the effect of the rule. 3 Table 6-9 identifies the counties where this adjustment was made. Table 6.9 TxLED Counties Anderson Denton Johnson Robertson Angelina Ellis Karnes Rockwall Aransas Falls Kaufman Rusk Atascosa Fannin Lamar Sabine Austin Fayette Lavaca San Jacinto Bastrop Franklin Lee San Patricio Bee Freestone Leon San Augustine 3 The TxLED program requirements initiated in February 2006, so these adjustments were not applied to the 2002 and 2005 modeling scenarios. 6-17 Table 6.9 TxLED Counties (Cont.) Bell Fort B end Liberty Shelby Bexar Galve ston Lime stone Smith Bosque Goliad L ive Oak Somervell Bowie Gonza les Madison Tarrant Brazoria Grayson Marion Titus Braz os Gregg Matagorda Travi s Burleson Grimes McLennan Trinity Caldwell Guadalupe Milam Tyler Calhoun Hardin Montgomery Upshur Camp Harris Morris Van Zandt Ca ss Harrison Nacogdoches Victoria Chambers Hay s Navarro Walker Cherokee Henderson Newton Waller Collin Hill Nueces Washington Colorado Hood Orange Wharton Comal Hopkins Panola Williamson Cooke Houston Parker Wilson Coryell Hunt Polk Wise Dallas Jackson Rains De Witt Jasper Red Ri v er Delta Jefferson Refugio For counties subject to TxLED requirements , NO x emissions were estimated as follows: ENox-ty pe = (Depth (1 ,000 fee t/yr)) x (EF Nox (tons/1,000 feet)) x (0 .938) Where: ENox -type Depth EFN ox (0.938) Emissions of NOx for each county by model rig well type category (tons/yr) Total depth drilled in model rig well type category by county ( l , 000 fee t/yr) NOx emission factor (tons /1,000 feet) Adjustment Factor to account for 6 .2% TxLED reduction Total county level annual emissions were then obtained by summing the total emissions for each of the three model rig well type categories for each county. Ozone season daily (OSD) emis sions were calculated by di viding the annual emissions by 365 (days/year). 6-18 6.4 Results 6.4.1 Emission Summary Table 6-10 summarizes the statewide annual criteria pollutant emission estimates for 2002, 2005 , and 2008 through 2021. Table 6-11 summarizes both annual and OSD criteria pollutant emissions by county for the 2008 base year. Appendix G contains detailed tables showing statewide annual emission estimates for each year for all criteria pollutants and HAPs (Appendix G , Table 1), as well as county-level annual and OSD emission estimates for each year for all criteria pollutants and HAPs (Appendix G, Tables 2 and 3 , respectively). The decreasing emissions after 2009 reflecting the falling oil and gas production projections from the EIA dataset for the areas including Texas . As compared to the previous oil and gas study prepared by TCEQ in 2007 (for a 2005 base year), the emission estimates presented in this study reflect a significant decrease in the statewide NO x emission estimate from drilling rig engines for 2005 (42 ,854 tons per year in this study compared to 119 ,647 tons per year in the 2007 study). While not as pronounced, there were also significant decreases in the S02 and CO emission estimates based on this study. For VOC , PM 10 , and PM2 .s, the estimates contained in this study show slightly higher estimates than in the previous study. These differences in the estimates between the two studies can be attributed to the emissions estimation methodologies used in each study. While the previous study was done using a top-down approach, conservative emission estimation assumptions , and the use of AP-42 emission factors , the current study used 2008 survey data on the actual engine parameters ( engine size , hours of operation, and engine load) used in drilling oil and gas wells in 2008 , as well as utilizing the NONROAD model to develop emission factors. 6.4.2 NIF 3.0 Files Once the emissions inventory was completed, NIF 3 .0 area source text-formatted input files were prepared for base years 2002, 2005 , and 2008 . The NIF 3 .0 files were created u sing information provided by TCEQ regarding the correct format and valid code listings for submittal to TexAER (TCEQ 2009a). Prior to submittal to TCEQ, the NIF 3.0 files were pre-processed using EPA 's NIF Basic Format and Content Checker to check for errors and inconsistencies. Additionally, ERG performed a test upload to TexAER to ensure the files were complete and accurate and in a format consistent with the TexAER area source file data requirements . 6-19 Table 6.10 Texas Drilling Rig Estimates (tons/year) Year co NOx PMio PM2.s S02 voe 2002 13,305 35,828 2,552 2,475 4,776 3,631 2005 15,878 42,854 3,036 2,945 5,977 4,337 2008 16,721 55,238 2,543 2,467 956 4,326 2009 16,769 55,457 2,550 2,474 961 4,340 2010 16,336 53,123 2,417 2,344 45 4,182 2011 15,117 48,462 2,319 2,249 44 3,806 2012 14,748 46,253 2,263 2,196 43 3,665 2013 12,008 39,793 1,378 1,337 38 3,413 2014 11,945 39,461 1,372 1,331 38 3,392 2015 11,755 38,837 1,350 1,310 37 3,349 2016 11,558 36,440 1,320 1,280 37 3,320 2017 8,915 34,771 1,118 1,085 36 2,800 2018 6,114 31,282 811 787 35 2,227 2019 6,073 31,127 805 781 35 2,215 2020 6,035 30,771 800 776 35 2,205 2021 3,299 26,063 448 435 33 1,504 6-20 Table 6.11 2008 Annual and OSD County-Level Criteria Pollutant Emission Estimates ., NOx-' ,.NOr PM1r PM1r PMu-PMu-voe-voe- CO-ANN CO-OSD ANN OSD ANN OSD ANN OSD SO~ANN S0-0..~D ANN OSD County .,,;; tonslvr tons/dav tons/vr tons/dAV tons/vr toas/dav tons/vr tons/dav toos/vr ~ u tomlvr - Anderson 2 .03E+Ol 5 .53E-02 5 .94E+Ol l.62E-Ol 3 .IOE +OO 8.47E-03 3 .0lE+OO 8 .21E-03 l .04E+OO 2.83E-03 5 .1 lE+OO l .40E-02 Andrews 2.33E+02 6 .36E-Ol 7 .75 E+02 2 .12E+OO 3 .52E+Ol 9 .61E-02 3.41E+Ol 9 .33E-02 l.37E+Ol 3 .74E-02 5 .64E+Ol 1.54E-Ol Angelina 6 .70E+Ol l .83E-Ol l.93E+02 5 .27E-Ol l.03E+Ol 2 .8 2E-02 l.OOE+Ol 2 .73E-02 3 .26E+OO 8 .91E-03 l.72E+Ol 4 .71E-02 Aransa s 8.80E+OO 2.41E-02 2.75E+Ol 7 .51E-02 l .34E+OO 3 .67E-03 l.30E+OO 3 .56E-03 4.85E -Ol 1.3 2E-03 2 .28 E +OO 6 .23E-03 Archer 9 .32E+OO 2 .5 5E-02 3 .94E+Ol l.08E-Ol l .3 5E+OO 3 .6 8E-03 1.3 lE+OO 3 .57E-03 8.l lE-01 2 .22E-03 2 .05E+OO 5.6\E-03 Atascosa 7 .02E+OO l.92E-02 2 .05E+Ol 5 .61E-02 l .07E+OO 2 .93 E-03 l.04E+OO 2 .84E-03 3.69E -Ol l.OlE-03 l.72E+OO 4 .71E-03 Austin 7 .59E+OO 2 .07E-02 2 .63 E+Ol 7 .20E-02 1.13E+OO 3 .IOE-03 l.lOE+OO 3 .0lE-03 5.13E-Ol l.40E-03 l .8 7E+OO 5.IOE-03 B astrop l.69E+Ol 4 .63E-02 5 .76E+Ol l.57E-Ol 2 .56E+OO 7 .0IE-03 2.49E+OO 6 .8 0E -03 l .04E+OO 2 .85 E -03 4.46E+OO l .2 2E-02 Baylor l.87E+OO 5 .lOE -03 9 .04E+OO 2.47E-02 2 .65 E-Ol 7 .24E-04 2.57E-Ol 7 .02E-04 l.90E-Ol 5 .19E-04 4 .23 E -Ol l .16E-03 Bee 5 .68E+Ol 1.55E-Ol 2 .06E+02 5 .62E-Ol 8 .51E+OO 2 .32E-02 8.25E+OO 2 .25E-02 3 .92E+OO 1.07E-02 l .47E+Ol 4 .0IE-02 Bell 1.42E-Ol 3 .89E-04 6 .28E-Ol l.72E-03 2 .0lE-02 5.49E-05 l .95E-02 5 .32E-05 l .45E-02 3 .97E-05 2 .98E-02 8.14E -05 Bexar 2 .53E-02 6 .92E-05 l.12E-Ol 3 .05E-04 3.57E-03 9.76E-06 3.46E-03 9.47E-06 2 .58E-03 7 .06E-06 5 .30E-03 l.45 E -05 Borden 2 .86E+Ol 7 .80E-02 8 .82E+Ol 2.41E-Ol 4 .39E+OO l.20E-02 4 .25E+OO l.16E-02 1.41£+00 3 .85E-03 7 .32E+OO 2 .00E-02 Bosque 2 .72£+00 7.44£-03 9 .98£+00 2 .73£-02 4 .09E-Ol l .12E-03 3 .97E-Ol 1.08£-03 l.85E-Ol 5 .06£-04 7 .29E-Ol 1.99£-03 Bowie l.35E+OO 3 .68£-03 3 .50£+00 9 .57E-03 2 .09£-01 5 .70E-04 2.03E-Ol 5.53£-04 5 .63E-02 l.54E-04 3.4\E-01 9 .32E-04 Brazoria 4.64£+01 1.27£-01 l.40E+02 3 .84£-01 7 .lOE +OO l .94E-02 6 .89E+OO 1.88£-02 2.44E+OO 6 .65E-03 1.20£+01 3.27E-02 Brazos 2 .17E+Ol 5 .92E-02 9 .57E+Ol 2 .62E-Ol 3 .18£+00 8.69E-03 3 .09E+OO 8.43E-03 l.88E+OO 5 .13E-03 6 .02 E+OO l .64E-02 Briscoe l.48E+OO 4 .04E-03 4.49E+OO l .23E-02 2 .26E-Ol 6 .18£-04 2 .19£-01 6 .00E-04 7.41E-02 2 .02£-04 3 .65E-Ol 9 .9 8£-04 Brooks 9 .58E+Ol 2 .62E-Ol 2 .87E+02 7 .84£-01 l.48E+Ol 4 .03£-02 l.43E+Ol 3 .91E-02 4 .50E+OO l .23E-02 2.45E+Ol 6 .69E-02 Brown l.30E+OO 3 .54E-03 6 .IOE+OO l.67E-02 l.83E-Ol 5 .00E-04 1.78E-OI 4.85E-04 I.32E -OI 3.62E-04 2 .71E-Ol 7.42E-04 Burleson 4.46E+Ol l .22E-OI l .48E+02 4 .04E-Ol 6 .77£+00 l.85E-02 6.57E+OO l.80E-02 2 .65E+OO 7 .23E-03 l.17E+Ol 3.2\E-02 Caldwell l.58E+OO 4 .3 1 E-03 7 .31E+OO 2 .00E-02 2 .25E-Ol 6.14E-04 2 .18E-Ol 5 .96E-04 l .60E-Ol 4 .36£-04 3.78E-Ol 1.03£-03 Calhoun 2 .38£+01 6 .50E-02 7 .79E+Ol 2 .13£-01 3 .61E+OO 9 .87£-03 3 .50E+OO 9.57E-03 l.40E+OO 3.82E-03 6 .21E+OO 1.70E-02 Callahan 2 .58E+OO 7 .06E-0 3 l.22E+Ol 3 .32E-02 3 .65E-Ol 9 .96£-04 3.54£-01 9.67£-04 2 .64E-Ol 7 .21E-04 5.41E-Ol 1.48£-03 Cameron 1.42£+00 3 .89£-03 3 .94E+OO 1.08£-02 2 .20E-Ol 6 .02£-04 2.14E-Ol 5 .84E-04 5 .94E-02 l.62E-04 3 .60E-Ol 9 .84£-04 Carson 9.90£-01 2 .71£-03 5 .12£+00 1.40£-02 1.42£-01 3 .89E-04 l .38E-Ol 3 .77£-04 9 .95E-02 2 .72E-04 2 .67E-Ol 7 .29E-04 Cass 2.22£-01 6 .05E-04 9.77E-Ol 2.67£-03 3 .13£-02 8 .54E-05 3 .03 £-02 8 .28E-05 2 .26£-02 6 .17£-05 4 .63£-02 l.27E-04 Chambers 2 .37E+Ol 6.47E-02 8.97E+Ol 2.45£-01 3 .55£+00 9.69£-03 3.44£+00 9.40£-03 1.68E+o0 4 .60£-03 6 .38£+00 1.74£-02 Cherokee l .52E+02 4 .15E-Ol 4 .40E+02 l .20E+OO 2 .33E+Ol 6 .37£-02 2 .26E+Ol 6 .18E-02 7.46E+OO 2 .04£-02 3 .90E+Ol l.07E -Ol Childress 2 .94E-Ol 8 .04£-04 l .38E+OO 3 .78£-03 4 .15£-02 1.13£-04 4 .03 £-02 l.lOE-04 3.00E -02 8.20£-05 6 .16£-02 1.68£-04 6-21 Table 6.11 2008 Annual and OSD County-Level Criteria Pollutant Emission Estimates (Cont.) fil NOx-' !f NOx-PM10-PM1.-PMl.5" PMu-I< voe-VO(:-., .. CO-ANN CO-OSD ANN OSD H ANN OSD ANN OSD SO.-ANN SOr-OSD ANN OSD County tons/yr tous/dav tons/vr tons/day tons/vr tf)Q/dav tons/vr tous/dav tons/vr tons/dav funlllvr +tous!di.'v "\ Clay l.l2E+Ol 3.06E-02 4 .8 4E+Ol l.32E-Ol l.64E+OO 4.48E-03 l.59E+OO 4 .3 5E-03 9 .2 7E-Ol 2 .53E-03 2.80E+OO 7.66E-03 Cochran l.lOE+Ol 3 .0lE-02 4.45E+Ol l.22E-Ol l.60E+OO 4 .38E-03 l.56E+OO 4.25E-03 8.97E-Ol 2.45E-03 2.47E+OO 6.74E-03 Coke 6 .2 0E+OO l .69E-02 2 .46E+Ol 6.73E-02 9.08E-Ol 2.48E-03 8.80E-Ol 2.41E-03 4 .9 1E-Ol 1.34E-03 1.40E+OO 3.83E-03 Coleman 3 .09E+OO 8.45E-03 l.45E+Ol 3.97E-02 4.36E-Ol l . l 9E-03 4.23E-Ol l.16E-03 3.15E-Ol 8.62E-04 6.47E-Ol l.77E-03 Colorado 2 .83E+OI 7 .73E-02 8 .52E+Ol 2 .33E-01 4 .31E+OO 1.18E-02 4 .18E+OO 1.14E -02 1.53E+OO 4 .18E-03 7.06E+OO 1.93E-02 Comanche 9.49E-02 2.59E-04 4.46E-01 l .22E-03 I .34E-02 3.66E-05 l .30E-02 3.55E-05 9.69E-03 2 .65E-05 1.99E-02 5.43E-05 Concho 5 .29E+OO 1.45E-02 2.49E+Ol 6 .80E-02 7.46E-01 2.04E-03 7 .24E-01 1.98E-03 5.40E-01 1.47E-03 l.l lE+OO 3.02E-03 Cooke 4.07E+OI l.l lE-01 1.18E+02 3 .24E-01 6 .23E+OO 1.70E-02 6.04E+OO l.65E-02 2.09E+OO 5.71E-03 1.0lE+OI 2.77E-02 Coryell 1.27E-Ol 3.46E-04 5 .58E-01 1.53E-03 1.79E-02 4.88E-05 1.73E-02 4 .73E-05 1.29E-02 3.53E-05 2 .65E -02 7 .23E-05 Cottle 1.78E+OI 4 .8 7E-02 5 .34E+OI 1.46E-Ol 2.74E+OO 7 .49E-03 2 .66E+OO 7 .26E-03 8 .56E-Ol 2 .34E-03 4.48E+OO 1.22E-02 Crane 4 .87E+Ol l.33E-Ol l .8 0E+02 4 .93E-Ol 7.25E+OO l .98E-02 7.04E+OO 1.92E-02 3 .38E+OO 9.24E-03 l.16E+Ol 3.17 E-02 Crockett 3 .l lE+02 8.50E-Ol 9.41E+02 2.57E+OO 4.77E+Ol l .30E-Ol 4.63E+Ol l.26E-Ol 1.53E+Ol 4 .l 7E-02 7 .79E+Ol 2 .13E-Ol Crosby 2 .90E+OO 7 .93E-03 l .36E+Ol 3 .73E-02 4 .09E-Ol l.12E-03 3 .97E-Ol 1.08E-03 2.96E-Ol 8.09E-04 6 .07E-Ol l.66E-03 Culberson 3 .59E+Ol 9 .80E-02 1.08E+02 2.95E-Ol 5.53 E+OO l.5 lE-02 5.36E+OO 1.46E-02 1.70E+OO 4.64E-03 9.20E+OO 2.5 IE-02 Dallas 7.73E+OO 2.l lE-02 3 .84E+Ol 1.05E-Ol 1.12E+OO 3.05E-03 l .08E+OO 2.96E-03 7 .73E-01 2 .l lE-03 2.21E+OO 6.03E-03 Dawson 5 .66E+Ol 1.55E-Ol l.63E+02 4.45E-Ol 8.73E+OO 2 .39E-02 8.47E+OO 2 .31E-02 2.52E+OO 6 .8 9E-03 1.43 E+Ol 3 .91E-02 Denton 2 .06E+02 5.62E-01 9 .93E+02 2.71E+OO 2 .99E+OI 8 .16E-02 2 .90E+OI 7 .91E-02 1.99E+Ol 5.44E-02 5 .83E+OI 1.59E-OI DeWitt 1.05E+02 2 .86E-Ol 3 .80E+02 l .04E+OO 1.57E+OI 4.30E-02 1.53E+OI 4 .17E-02 7.06E+OO l.93E-02 2.79E+OI 7 .6 1E-02 Dickens 2.40E+Ol 6 .56E-02 7 .72E+OI 2 .1 lE-01 3.65E+OO 9.96E-03 3 .54E+OO 9.66E-03 l.34E+OO 3 .65E-03 5 .8 4E+OO l.60E-02 Dimmit 4 .50E+OI 1.23E-01 l .66E+02 4.53E-01 6 .7 5E+OO 1.84E-02 6 .55E+OO 1.79E-02 2.96E+OO 8.IOE-03 1.13E+Ol 3.IOE-02 Duval 7 .96E+Ol 2 .17E-OI 2.39E+02 6 .53E-01 1.2 2E+OI 3.35E-02 1.19E+OI 3 .25E-02 3.78E+OO 1.03E-02 2 .02E+OI 5 .53 E -02 Eastland l .52E+OO 4 .16E-03 7.16E +OO 1.96E-02 2.15E-01 5 .8 7E-04 2 .08E-Ol 5.69E-04 1.55E-Ol 4 .2 4E-04 3 . l 8E-O l 8 .70E-04 Ector 2.64E+02 7.21E-01 7 .77E+02 2.12E+OO 4 .06E+Ol l.l lE-01 3.94E+Ol l.08E-Ol 1.23E+OI 3.36E-02 6 .64E+O l 1.81 E-01 Edwards 3 .99E+OI I .09E-01 l.3 IE+02 3.58E-01 6.07E+OO l .66E-02 5.89E+OO 1.61 E-02 2.20E+OO 6.0lE-03 l.OlE+Ol 2 .76E-02 Ellis 2.09E+OI 5 .72E-02 1.04E+02 2 .84E-Ol 3 .03E+OO 8.27E-03 2.94E+OO 8.02E-03 2.IOE+OO 5 .73E-03 5.97E+OO l .63E-02 Erath 8.49E+OO 2 .32E-02 4.44E+Ol l.21E-Ol l.22E+OO 3 .34E-03 l.l 9E+OO 3.24E-03 8.51E-Ol 2.33E-03 2.35E+OO 6.42E-03 Falls 5 .70E-02 l .56E-04 2 .51E-Ol 6 .8 7E-04 8.04E-03 2.20E-05 7.80E-03 2 .13E-05 5.81E-03 l.59E-05 l . l 9E-02 3.26E-05 Fannin 2.84E+OO 7 .77E-03 7 .3 9E+OO 2 .02E-02 4.41E-Ol l .20E-03 4 .28E-Ol l . l 7E-03 1.19E-Ol 3 .24E-04 7.20E-Ol I.97E-03 Fayette 1.1 IE+Ol 3.03E-02 4 .69E+OI 1.28E -01 l.63E+OO 4.46E-03 1.58E+OO 4.33E-03 9 .16E-Ol 2.50E-03 3.02E+OO 8.24E-03 Fisher l.54E+Ol 4.20E-02 5 .25E+O I l .44E-Ol 2 .3 lE+OO 6 .3 IE-03 2.24E+OO 6 .12E-03 9.52E-01 2.60E-03 3.67E+OO 1.00E-02 6-22 Table 6.11 2008 Annual and OSD County-Level Criteria Pollutant Emission Estimates (Cont.) NOx-NOx-PM1r PM1r PMu-PMu-voe- voe- CO-ANN CO-OSD ANN OSD ANN OSD ANN OSD SOrANN SO..OSD ANN OSD County tonlllvr toDi/d.av tonlllvr tonildaY tom/wr tons/day tomlvr toas/d.av tons/yr t -toaalyr .. Foard 7.94£-01 2 .l 7E-03 3 .74E+OO 1.02£-02 1.12£-01 3 .06£-04 1.09£-01 2.97£-04 8 .lOE-02 2 .21£-04 1.66£-01 4.54£-04 Fort Bend 2 .60E+Ol 7 .09£-02 9 .96E+Ol 2 .72£-01 3 .85E+OO 1.05£-02 3 .73E+OO 1.02£-02 l.95E+OO 5 .34£-03 6.66E+OO 1.82£-02 Franklin 1.45E+Ol 3 .96£-02 3 .83E+Ol l.05E-Ol 2 .24E+OO 6.13£-03 2.17E+OO 5.94£-03 6.26£-01 l.7 IE-03 3 .66E+OO 9 .99£-03 Freestone 4.35E+02 l.19E+OO l.22E+03 3 .33E+OO 6 .70E+Ol 1.83£-01 6 .50E+Ol 1.77£-01 2 .04E+O l 5 .56£-02 l.l 1E+02 3.04£-01 Frio 1.91E+Ol 5.21£-02 7.43E+OI 2.03£-01 2 .84E+OO 7 .75 E -03 2.75E+OO 7.52£-03 l.37E+OO 3 .74£-03 4 .77E+OO l .30E-02 Gaines 1.12E+02 3.07E-Ol 3.47E+02 9.48E-Ol l.72E+OI 4 .69E-02 1.66E+OI 4 .55£-02 5 .72E+OO l.56E-02 2 .80E+O l 7 .65E-02 Galveston l .19E+OI 3 .26E-02 4 .1 lE+Ol 1.12E-01 l.81E+o0 4.93E-03 l.75E+O O 4.78E-03 7 .49E-Ol 2 .05E-0 3 3 .15 E+O O 8 .61E-03 Garza 1.40E+OI 3.83E-02 5 .IIE+Ol 1.39E-Ol 2 .09E+OO 5 .70E-03 2.02E+OO 5.53E-03 9 .61E-Ol 2 .63E-0 3 3 .30E+OO 9 .00E-03 Glasscock l .36E+02 3 .72E-Ol 3 .8IE+02 l.04E+OO 2.1 IE+OI 5 .76E-02 2 .05E+Ol 5 .59E-02 5 .78E+OO l .58E-02 3.46E+OI 9.44E-02 Goliad 6.97E+Ol l.91E-Ol 2 .0 9E+02 5.70E-OI 1.06E+Ol 2.91E-02 l.03E+Ol 2 .82E-0 2 3 .70E+OO l.OIE-02 l.75E+OI 4.79E-02 Gonzales 5.35E+OO l.46E-02 l.87E+Ol 5.12£-02 8 .04E-Ol 2 .20E-03 7 .80E-Ol 2 .13E-03 3.50E-Ol 9.57E-04 l .39E+OO 3.79E-03 Gray 2 .33E+OO 6.37£-03 7 .20E+OO l .97E-02 3 .56E-Ol 9.72E-04 3.45E-Ol 9.43E-04 l.20E-Ol 3.29£-04 5 .73E-Ol l.57E-03 Grayson l.07E+Ol 2.91E-02 3.54E+Ol 9 .66E-02 l.62E+O O 4.42E-03 l .57E+OO 4 .28£-03 6.40£-0 1 1.75£-03 2.78E+OO 7.59£-03 Gre2:e: 9 .58E+Ol 2.62£-01 2.97E+02 8.12£-01 l.46E+Ol 4 .00E-02 l.42E+O l 3 .88£-02 5.19E+OO 1.42£-02 2.49E+Ol 6 .81E-02 Grimes 1.33E+Ol 3.64£-02 6.59E+Ol l .80E-Ol l .92E+OO 5 .25£-03 l .86E+OO 5 .09E-03 l .33E+OO 3.64£-0 3 3.79E+OO l.03E-02 Guadaluoe 8.96£-01 2.45E-0 3 4 .29E+OO l.l 7E-02 l.29E-Ol 3 .51£-04 1.25£-01 3.41£-04 9.02E-02 2.47£-04 2.34£-01 6 .38E-04 Hale 3 .22E+OO 8.80£-03 l.58E+Ol 4 .33E-02 4 .59E-01 l .25E-03 4.45E-Ol l.22E-03 3 .26E-Ol 8.92E-04 7 .63E-Ol 2 .08E-03 Hansford 4 .53E+Ol 1.24£-01 1.39E+02 3.80E-01 6.95E+OO 1.90E-02 6.74E+OO 1.84E-02 2 .24E+OO 6 .l l E -03 1.15E+O l 3.14E-02 Hardeman 1.70E+Ol 4.65E-02 5 .35E+Ol l.46E-01 2.6 1E+OO 7 .13E-03 2.53E+OO 6.92E-03 8 .64E-Ol 2.36E-03 4.37E+OO 1.19E-02 Hardin 5 .91E+Ol l.62E-01 l .92E+02 5 .23E-Ol 8.98E+OO 2.45E-02 8.71E+OO 2 .38£-02 3.44E+OO 9.40E-03 l.53 E+o l 4 .18E-02 Harris 1.24E+Ol 3 .38E-02 4.89E+O l l.34E-01 1.84E+OO 5 .02E-03 l.78E+OO 4 .87£-03 9.40£-01 2 .57E-03 3.32E+OO 9 .06E-03 Harrison 5 .79E+02 1.58E+OO 1.8 4E+03 5 .04E+OO 8.82E+Ol 2.41E-01 8.55 E+Ol 2.34E-01 3 .26E+Ol 8 .91£-0 2 1.51E+02 4 .13E-Ol Hartley 5.68E-Ol 1.55E-0 3 2.67E+OO 7 .3 0£-03 8 .0IE-02 2 .19E-04 7 .77E-02 2.12£-04 5.80E-02 l .58E-04 l.19E-01 3.25E-04 Haskell 2.02E+OO 5 .5 1E-03 9.48E+OO 2 .59E-02 2.84E-OI 7 .77£-04 2 .76E-Ol 7 .54E-04 2 .0 6E-01 5 .62E-04 4 .22£-01 1.15£-03 Hemphill 6.43E+02 l.76E+OO l .92E+03 5 .23E+OO 9 .90E+Ol 2 .71E-Ol 9 .61E+Ol 2 .62E-01 3.00E+Ol 8.18E-02 1.64E+02 4.49E-OI Henderson 3 .91E+Ol l .07E-01 I. l l E+02 3.04E-01 6.0IE+OO 1.64E-02 5.83E+OO l .59E-02 l.87E+OO 5 .12E-0 3 1.00E+OJ 2 .74E-02 Hidalgo 2 .27E+02 6 .19E-Ol 6.98E+02 l.91E+OO 3.48E+Ol 9 .5 1£-02 3.38E+Ol 9.23E-02 l.l lE+Ol 3.03E-02 5 .82E+Ol l.59E-Ol Hill 9 .04E+OI 2.47E-Ol 4.49E+02 1.23E+OO 1.31E+Ol 3.57E-02 1.27E+Ol 3.46E-02 9 .05E+OO 2.47E-02 2 .58E+OI 7 .04E-02 Hockley 3 .19E+Ol 8 .71E-02 l.18E+02 3.23E-Ol 4 .77E+OO 1.3 0E-02 4.63E+OO l.27E-02 2 .12E+OO 5 .80E-0 3 8 .00E+OO 2.18E-02 Hood 7 .86E+OI 2 .15 E-Ol 3 .90E+02 l .07E+OO l.13E+Ol 3 .lOE-02 l.lOE+Ol 3.0IE-02 7.86E+OO 2.15E-02 2.24E+OJ 6 .1 2E-0 2 6-23 Table 6.11 2008 Annual and OSD County-Level Criteria Pollutant Emission Estimates (Cont.} NOx-NOx-PM 1.-PM,.-PMu· PMu-voe-voc.:t CO-ANN CO-OSD ANN OSD ANN OSD ANN OSD SOrANN SOrOSD ANN OSD County tons/n' tons/day tons/yr tons/day tons/yr toQ/day tons/yr tons/day tons/yr . .,, tons/day tons/yr toQ!dav Hopkins 3.41E+OO 9 .3 lE-03 9 .llE+OO 2.49E-02 5 .26E-Ol l .44E-03 5 .lOE-01 l.39E-03 1.51E-Ol 4.12E-04 8 .56E-Ol 2 .34E-03 Houston 2.89E+Ol 7.89E-02 8.59E+Ol 2.35E-Ol 4.43E+OO l.2 IE-02 4.29E+OO 1.17E-02 l .48E+OO 4.04E-03 7.44E+OO 2 .03E-02 Howard l .19E+02 3.26E-Ol 3 .36E+02 9 .l 7E-Ol l.85E+Ol 5.04E-02 l.79E+Ol 4 .89E-02 5 .14E+OO l.40E-02 3 .0lE+Ol 8 .23E-02 Hudspeth 4 .12E+OO l .12E-02 l.30E+Ol 3 .55E-02 6 .26E-Ol l.71E-03 6 .0SE-01 l.66E-03 2.2 lE-O 1 6 .05E-04 l.OlE+OO 2 .75E-03 Hutchinson 1.55E+OI 4.24E-02 6 .98E+Ol l.91E-01 2 .24E+OO 6 .l lE-03 2 . l 7E+OO 5 .92E-03 l.42E+OO 3.89E-03 3 .59E+OO 9 .SIE-03 Irion 2 .33E+02 6 .36E-0 1 6 .57E+02 1.79E+OO 3 .60E+Ol 9.83E-02 3.49E+Ol 9 .54E-02 1.0IE+OI 2.76E-02 5 .87E+Ol 1.60E-Ol Jack 1.69E+OI 4 .63E-02 8 .59E+OI 2 .35E-Ol 2.43E+OO 6 .63E-03 2 .35E+OO 6.43E-03 1.71E+OO 4 .66E-03 4.36E+OO 1.19E-02 Jackson 5.69E+Ol 1.56£-01 1.66E+02 4 .53E-0I 8 .70E+OO 2 .38E-02 8.44E+OO 2 .3 IE-02 2 .92E+OO 7.97E-03 1.42E+OI 3 .88E-02 Jasper 2 .20E+OI 6 .02E-02 9 .34E+Ol 2.55E-Ol 3 .25E+OO 8 .88E-03 3 .15E+OO 8 .61E-03 1.81 E+OO 4 .96E-03 6 .05E+OO 1.65E-02 Jefferson 4.90E+OI 1.34E-01 1.84E+02 5 .03E-01 7 .34E+OO 2 .0lE-02 7 .12E+OO 1.95E-02 3.46E+OO 9.44E-03 1.31E+OI 3 .59E-02 Jim Ho!!!! 3.05E+Ol 8 .33E-02 8.78E+Ol 2.40E-Ol 4.71E+OO l.29E-02 4.57E+OO l.25E-02 l .36E+OO 3.70E-03 7 .74E+OO 2 .12E-02 Jim Wells l.IOE+Ol 3.0IE-02 3 .69E+Ol l.OlE-0 l l .67E+OO 4 .56E-03 1.62E+OO 4.42E-03 6.49E-Ol 1.77E-03 2.69E+OO 7.36E-03 Johnson 6.62E+02 1.81E+OO 3 .27E+03 8 .93E+OO 9 .57E+Ol 2 .62E-01 9 .28E+Ol 2 .54E-Ol 6 .58E+Ol 1.SOE-01 l.89E+02 5 .15E-Ol Jones 7 .02E+OO 1.92E-02 3.30E+Ol 9.02E-02 9.91E-Ol 2 .71E-03 9 .61E-Ol 2 .63E-03 7.17E-Ol l.96E-03 l.47E+OO 4 .0lE-03 Karnes 2 .97E+OI 8 .12E-02 1.11E+02 3 .05E-Ol 4.45E+OO l .22E-02 4.32E+OO l.lSE-02 2 .lOE+OO 5 .73E-03 7 .95E+OO 2.17E-02 Kenedy 6.47E+Ol l .77E-Ol l.98E+02 5.40E-Ol 9.94E+OO 2 .72E-02 9.64E+OO 2.63E-02 3 .13E+OO 8.56E-03 1.66E+Ol 4.53E-02 Kent 2 .31E+Ol 6 .30E-02 7.83E+OI 2.14E-01 3.49E+OO 9.54E-03 3.39E+OO 9.25E-03 1.36E+OO 3 .71E-03 5.76E+OO l.57E-02 King 7.56E+OO 2 .07E-02 3 .34E+Ol 9.13E-02 1.08E+OO 2 .96E-03 1.05E+OO 2.87E-03 7.05E-Ol l.93E-03 l.63E+OO 4.45E-03 Kleberg 1.98E+OI 5.42E-02 8.43E+Ol 2 .30E-Ol 2 .95E+OO 8 .06E-03 2 .86E+OO 7.82E-03 1.51E+OO 4 .12E-03 5 .39E+OO 1.47E-02 Knox 2 .79E+OO 7.63E-03 1.l l E+Ol 3 .02E-02 4.09E-01 l .12E-03 3 .97E-0 1 1.0SE-03 2.20E-01 6 .0IE-04 6 .32E-Ol l.73E-03 La Salle 1.07E+02 2 .92E-Ol 3 .04E+02 8 .32E-Ol 1.65E+Ol 4 .52E-02 l.60E+OI 4.38E-02 4.68E+OO l.28E-02 2 .71E+OI 7.40E-02 Lamb 1.62E+OO 4.43E-03 7 .96E+OO 2 .18E-02 2.31E-Ol 6 .30E-04 2.24E-01 6.l lE-04 1.64E-Ol 4.49E-04 3.83E-01 1.05E-03 Lavaca 1.03E+02 2 .SIE-01 3 .14E+02 8 .57E-01 l.57E+Ol 4 .30E-02 1.53E+Ol 4.17E-02 5.49E+OO l.50E-02 2.65E+Ol 7.23E-02 Lee 1.12E+Ol 3 .07E-02 4 .65E+Ol l .27E-01 l .66E+OO 4 .53E-03 1.61E+OO 4.39E-03 9.12E-Ol 2.49E-03 3 .00E+OO 8.20E-03 Leon l.05E+02 2 .86E-01 3 .33E+02 9 . IOE-01 1.59E+Ol 4.36E-02 1.55E+Ol 4 .23E-02 5.91E+OO 1.61 E-02 2.72E+OI 7.43E-02 Liberty 6.19E+Ol 1.69E-01 1.89E+02 5.18E-Ol 9.46E+OO 2 .58E-02 9.17E+OO 2 .51E-02 3 .31E+OO 9 .03E-03 1.60E+OI 4.37E-02 Limestone 3 .16E+02 8.64E-01 9.05E+02 2.47E+OO 4 .86E+OI l.33E-Ol 4 .72E+Ol 1.29E-01 1.53E+Ol 4.17E-02 8.12E+OI 2 .22E-Ol Lipscomb l.45E+02 3 .95E-Ol 6.84E+02 1.87E+OO 2 .12E+OI 5 .SOE -02 2.06E+Ol 5 .63E-02 1.26E+Ol 3.44E-02 4 .02E+Ol l.lOE-01 Live Oak 6 .56E+Ol 1.79E-Ol 2 .02E+02 5 .51E-Ol l.OOE+Ol 2.73E-02 9 .70E+OO 2 .65E-02 3.58E+OO 9.77E-03 . l.67E+OI 4 .58E-02 Loving l.OOE +02 2 .74E-Ol 2 .93E+02 8.0lE-01 1.54E+OI 4.22E-02 l.50E+Ol 4 .09E-02 4.62E+OO 1.26E-02 2.53E+Ol 6.90E-02 6-24 Table 6.11 2008 Annual and OSD County-Level Criteria Pollutant Emission Estimates (Cont.) iii NOx-NOx-PM1r « PM1r PMu-PMu-voe~ voe- CO-ANN CO-OSD ANN OSD ANN OSD ANN OSD SO.-ANN SO....OSD ANN OSD Couaty ,,, tons/vr tons/day tons/vr tons/day tonllvr tons/dav tom/vr tons/dav tons/yr tons/day tons/yr tons/dav Lubbock l.91E+OO 5 .21E-03 8 .97E+OO 2.45E-02 2 .69E-Ol 7 .36E-04 2 .61E-Ol 7 .14E-04 l.95E-0I 5 .32E-04 3.99E-Ol l .09E-03 Lynn 6 .92E+OO l .89E-02 l.92E+Ol 5 .24E-02 l .07E+OO 2 .93E-03 l .04E+OO 2 .84E-03 2 .89E-OI 7.90E-04 l.75E+OO 4 .79E-03 Madison l.06E+Ol 2.89E-02 3.96E+Ol 1.08E-Ol 1.59E+OO 4 .33E-03 l .54E+OO 4 .20E-03 7.41E-OI 2.03E-03 2 .84E+OO 7.77E-03 Marion 2.08E+Ol 5 .70E-02 6.64E+Ol 1.8 lE-O I 3.18E+OO 8.68E-03 3 .08E+OO 8.42E-03 l.17E+OO 3 .2 0E-03 5.44E+OO l.49E-02 Martin 5.45E+02 l.49E+OO l.51E+03 4 .13 E+OO 8.45E+Ol 2 .31 E -01 8 .20E+Ol 2 .24E-Ol 2 .28E+Ol 6.22E-02 l.38E+02 3 .77E-01 Matagorda 9 .69E+Ol 2.65E-01 2.72E+02 7.43E-01 1.49E+Ol 4 .08E -02 l.45E+Ol 3.96E -02 4 .55 E+OO 1.24E -02 2.48E+Ol 6 .77E -02 Maverick 3 .34E+Ol 9 . I IE-02 1.60E+02 4 .37E-Ol 4 .8 3E+OO 1.32E -02 4.68E+OO l.28E-02 3 .12E +OO 8.53E-03 8 .58E+OO 2 .35E -02 McCulloch 3 .16E-02 8 .65E-05 1.49E-Ol 4.07E-04 4.46E -03 l .2 2E-05 4 .33E-03 l . l 8E-05 3 .23E-03 8 .82E-06 6.62E-03 l.81E-05 McLennan 2.20E+OO 6 .0lE-03 7 .53E+OO 2 .06E-02 3.33E-01 9.08E -04 3.23E-Ol 8 .81E-04 l.37E-Ol 3.75E-04 5 .79E-01 1.58E-03 McMullen l .20E+02 3 .28E-Ol 3 .50E+02 9.58E-OI l.85E+Ol 5 .06E-02 l.80E+Ol 4.91E-02 5.49E+OO l .SOE-02 3 .04E+OI 8 .30E-02 Medina 9 .53E-01 2 .60E-03 4.48E+OO l.22E-02 l.34E-Ol 3 .67E-04 l.30E-Ol 3 .56E-04 9 .72E-02 2 .66E-04 l.99E-Ol 5.45E-04 Menard 2 .23E+OO 6 .lOE-03 l .OSE +Ol 2 .87E-02 3 .lSE-01 8.60E-04 3 .0SE-01 8 .34E-04 2.28E-Ol 6.22E-04 4.67E-Ol 1.28E-03 Midland 4 .01E+02 l.lOE+OO 1.13E+03 3 .08E+OO 6 .21E+Ol l.70E-Ol 6 .02E+Ol l.64E-Ol l.71E+Ol 4 .67E-02 l.02E+02 2 .78E-Ol Milam 2 .llE+OO 5 .76E-03 6 .58E+OO l.80E-02 3 . l 8E-Ol 8.69E-04 3 .09E-01 8.43E-04 l.25E-Ol 3.41E-04 5 .07E-Ol l.38E-03 Mitchell 2 .03E+Ol 5 .54E-02 9 .54E+Ol 2.61E-Ol 2 .86E+OO 7 .82E-03 2 .78E+OO 7 .58E-03 2 .07E+OO 5 .65E-03 4 .24E+OO l.16E-02 Montague l.03E+02 2 .81E-Ol 3 .63E+02 9.92E-Ol l.56E+Ol 4 .26E-02 l.51E+Ol 4 .14E-02 6 .16E+OO l.68E-02 2 .68E+Ol 7.33E-02 Montgomery 9 .87E+OO 2 .70E-02 3 .05E+Ol 8 .33E-02 l.51E+OO 4 .12E-03 1.46E+OO 3.99E-03 5 .35E -01 1.46E-03 2 .55E+OO 6 .98E-03 Moore 4.49E+OO l.23E-02 2.14E+OI 5 .85E-02 6.35E-Ol 1.74E-03 6 .16E-01 l.68E-03 4.57E-01 1.25E-03 9.77E-Ol 2 .67E-03 Motley l.51E+OO 4 .1 IE-03 4.48E+OO l .22E-02 2 .31E-01 6 .31E-04 2 .24E-01 6 .13E-04 7 .24E-02 l.98E-04 3.74E-OI l .02E-03 Nacogdoches 3 .90E+02 l.07E+OO l.l5E+03 3.15E+OO 5 .98E+Ol l.63E-01 5.80E+Ol l.59E-OI l.97E+Ol 5 .39E-02 l.0IE+02 2 .75E-OI Navarro l.69E+Ol 4 .63E-02 4 .73E+Ol 1.29E-Ol 2 .60E+OO 7 .l lE-03 2 .53E+OO 6 .90E-03 8 .06E -Ol 2 .20E-03 4 .26E+OO l .16E-02 Newton 9 .90E+OO 2 .70E-02 3 .83E+Ol l.OSE-01 1.48E+OO 4 .04E-03 l.43E+OO 3.92E-03 7.23 E -Ol I .98E-03 2 .68E+OO 7.31 E-03 Nolan l.62E+Ol 4.42E-02 6 .52E+Ol 1.78E-O l 2 .36E+OO 6.45E-03 2 .29E+OO 6 .26E -03 1.3 lE+OO 3 .58E-03 3 .63E+OO 9.93E-03 Nueces 5.79£+01 I .58£-01 l .66E+02 4 .54E-Ol 8 .90E+OO 2.43E-02 8 .63E+OO 2.36E-02 2.84E+OO 7.76E-03 l.47E+Ol 4 .03E-02 Ochiltre e 8 .0LE+OI 2 .l9E-Ol 3 .07E+02 8 .38E-OI l.21E+Ol 3.30E-02 l.l7E+Ol 3 .20E-02 5 .31 E+OO l.45E-02 2 .13E+OI 5 .83E-02 Oldham 6 .87E+OO 1.88E-02 l.90E+OI 5 .20E-02 l.06E+OO 2 .9IE-03 l.03E+OO 2 .82E-03 2.87E-Ol 7.84E-04 l.74E+OO 4.76E-03 Orange l.06E+Ol 2 .91 E-02 4 .67E+OI l .27E-OI l.56E+OO 4 .27E-03 l .52E+OO 4.14E-03 9.16E-01 2.50E-03 2.94E+OO 8.02E-03 Palo Pinto l.72E+OI 4 .70E-02 8 .71 E+OI 2 .38E-01 2.46E+OO 6 .73E-03 2 .39E+OO 6 .53E-03 l.73E+OO 4.74£-03 4.40£+00 1.20£-02 Panola 5 .35E+0 2 1.46E+OO 1.70£+03 4 .64E+OO 8.14E+Ol 2 .23E-Ol 7 .90E+Ol 2 .16E-Ol 3 .00E+OI 8.19E-02 I.39E+02 3 .81E-Ol Parker 6 .86E+OI l.88E-01 3.40E+02 9 .30E-Ol 9.9LE+OO 2 .71E-02 9 .62E+OO 2 .63E-02 6 .87E+OO l .88E-02 l.96E+Ol 5 .35E-02 6-25 Table 6.11 2008 Annual and OSD County-Level Criteria Pollutant Emission Estimates (Cont.) NOx-NOx-PM10-PMur PM:i.5"' PMu· voe~' :,::voe ... CO.ANN CO-OSD ANN OSD ANN OSD ANN OSD SO.-ANN SOrOSD ANN OSD,· County toos/vr tons/du toos/vr toos/dav toos/vr toos/dav tons/vr to.-s/da:v toos/:vr tons/day toos/vr tons/day % Pecos 4 .72£+02 1.29£+00 1.49£+03 4 .06£+00 7 .23£+01 1.98£-01 7.02£+01 1.92£-01 2 .39£+01 6.54£-02 1.21£+02 3.31£-01 Polle 3.25£+01 8.88£-02 1.28£+02 3 .50£-01 4 .83£+00 1.32£-02 4 .69£+00 1.28£-02 2.46£+00 6.73£-03 8.69£+00 2 .37£-02 Potter 6 .71£-01 1.83£-03 3 .16£+00 8 .62£-03 9.47£-02 2.59£-04 9 .18£-02 2.51£-04 6.84£-02 1.87£-04 1.40£-01 3 .83£-04 Reagan 3.77£+02 1.03£+00 1.05£+03 2 .86£+00 5 .84£+01 1.59£-01 5.66£+01 1.55£-01 1.58£+01 4.32£-02 9 .54£+01 2 .61£-01 Real 9.49£-02 2 .59£-04 4.46£-01 1.22£-03 1.34£-02 3 .66£-05 1.30£-02 3.55£-05 9 .69£-03 2.65£-05 1.99£-02 5.43£-05 Red River 1.86E+OO 5.09£-0 3 6 .24£+00 1.70£-02 2.81£-01 7.68£-04 2.73£-01 7.45£-04 l.15E-Ol 3.14£-04 4.78£-01 1.31 E-03 Reeves 7 .84£+01 2 .14£-01 2 .96£+02 8.08£-01 1.18E +Ol 3 .22£-02 l.14E+Ol 3.13£-02 5.13E+OO 1.40£-02 2 .07£+01 5.64£-02 Refugio 6 .89E+Ol 1.88£-01 2 .13£+02 5 .81£-01 l .04E+Ol 2.85£-02 1.0l E+Ol 2 .76£-02 4 .00E+OO 1.09£-02 l.66E+Ol 4 .54£-02 Roberts 2.29E+02 6 .25£-01 7 .06E+02 1.93£+00 3.52£+01 9.61£-02 3.41£+01 9.32£-02 1.12£+01 3.07£-02 5.88£+01 1.61 £-01 Robertson 3 .81£+02 1.04£+00 1.07£+03 2 .93£+00 5 .87£+01 1.60£-01 5.69£+01 1.56£-01 1.79£+01 4 .89£-02 9.76£+01 2.67 £-01 Runnels l .23E+Ol 3 .35£-02 5 .79£+01 1.58£-01 1.73£+00 4 .73£-03 1.68£+00 4.59£-03 1.25E+OO 3.41£-0 3 2 .59£+00 7.08£-0 3 Rusk 5.94£+02 1.62£+00 1.64£+03 4.48£+00 9.16£+01 2.50£-01 8.88£+01 2.43£-01 2 .71E+Ol 7.42£-02 1.52 £+02 4.14£-01 Sabine 1.20£+00 3.27£-03 3.1 lE+OO 8 .50£-03 1.86£-01 5.07£-04 1.80£-01 4.92£-04 5 .00E-02 1.37£-04 3 .03£-01 8.29£-04 San Augustine 3.02£+01 8.24£-02 1.31£+02 3 .58£-01 4.44£+00 1.21£-02 4.30£+00 1.18£-02 2.56£+00 6.99£-03 8.35£+00 2.28£-0 2 San Jacinto 2 .1 lE+Ol 5.77£-02 5.96£+01 1.63£-01 3.25£+00 8.89£-03 3 .16£+00 8.62£-03 9 .98£-01 2.73£-03 5.41£+00 1.48£-02 San Patricio 2.19E+Ol 6.00E-02 7 .51£+01 2 .05E-Ol 3 .32E+OO 9.06£-03 3.22£+00 8.79£-03 1.38£+00 3.76£-03 5.74£+00 1.57£-02 Schleicher 6 .60£+01 1.80£-01 1.90£+02 5.19£-01 1.02£+01 2 .78£-02 9.87£+00 2.70£-02 2.98£+00 8.15£-03 1.66£+01 4.52£-0 2 Scurry 4.61E+Ol 1.26£-01 1.56£+02 4 .27£-01 7 .00E+OO 1.91E-02 6.79E+OO 1.85£-02 2 .66E+OO 7.27£-0 3 1.17£+01 3.20£-0 2 Shackelford 6.53E+OO 1.78£-02 3 .07E+Ol 8.39£-02 9 .21£-01 2.52£-03 8.94£-0 1 2.44£-03 6 .66£-01 1.82£-03 l.37E+OO 3 .73£-03 She lb y 1.50£+02 4 .1 lE-01 5.53 £+02 1.51E+OO 2 .26E+Ol 6 .17£-02 2 .19E+Ol 5 .98£-02 l.03E+OI 2 .81£-02 4.03E+Ol l.lOE-01 Sherman 2 .07E+OI 5 .67£-02 7.43E+Ol 2.03£-01 3 .09E+OO 8.46£-03 3 .00E+OO 8.20£-03 l.39E+OO 3.80£-0 3 4 .87E+OO 1.33£-02 Smith 3.09E+Ol 8.45£-02 1.15£+02 3 .14£-01 4 .64E+OO 1.27£-0 2 4.50E+OO 1.23£-02 2 .15E+OO 5 .86£-03 8.29£+00 2 .26£-02 Somervell 1.12£+01 3 .06£-02 5.55£+01 l.52E-OI 1.62£+00 4.42£-0 3 1.57£+00 4 .28£-03 1.12£+00 3.06£-03 3.19£+00 8.72£-03 Starr 2.27£+02 6.19£-0 1 6 .67£+02 1.82£+00 3.49£+01 9.54£-0 2 3.39E+Ol 9.26£-02 l .04E+Ol 2 .84£-0 2 5.77£+01 1.58£-01 Stephens 1.60£+01 4.37£-02 7 .58£+01 2 .07£-01 2 .26E+OO 6 .17£-03 2 .19£+00 5.99£-03 1.63E+OO 4.45£-03 3.43£+00 9.37£-03 Sterling 4 .61£+01 l.26E-Ol 1.32£+02 3 .61£-01 7 .12£+00 1.95£-02 6 .91£+00 1.89£-02 2 .05£+00 5 .59£-03 1.17£+01 3.18£-02 Stonewall 7 .00E+OO 1.91 E-02 3.29£+01 8.99£-0 2 9 .87£-01 2 .70£-03 9.57£-01 2.62£-03 7 .14£-01 1.95£-03 1.46£+00 4 .00E-03 Sutton 3.03£+02 8.29£-0 1 8 .88£+02 2.43£+00 4 .67£+01 1.28£-01 4 .53E+Ol 1.24£-01 1.41£+01 3 .86£-02 7 .58E+OI 2 .07 £-01 Tarrant 5 .97E+02 l.63E+OO 2 .95£+03 8.07E+OO 8 .62E+Ol 2.36£-0 1 8.36E+Ol 2 .29£-01 5.95E+Ol 1.63£-01 1.70£+02 4.65£-01 Taylor 2 .50E+OO 6.84£-03 1.20E+OI 3 .27£-0 2 3 .54£-01 9.68£-04 3.44£-0 1 9 .39£-04 2.55£-01 6 .96£-04 5.47£-01 1.50£-03 6-26 Table 6.11 2008 Annual and OSD County-Level Criteria Pollutant Emission Estimates (Cont.) &!! NOx-NOx-,.1\'110-PM1r PM:u-PM:u-VQC-voe:- CO-ANN CO-OSD ANN OSD ANN OSD ANN OSD SO,.ANN SOr-OSD ANN OSD County tous/vr tons/day tooslYr tons/day tomlvr tons/day tou/vr tons/day tons/yr tons/dav tons/vr toiWdaY Terrell 5.40E+Ol l.48E-Ol l .73E+02 4.72E-Ol 8.26E+OO 2.26E-02 8 .0lE+OO 2 .l9E-02 2 .83E+OO 7 .73E-03 l.38E+Ol 3 .77E-02 Terrv l.80E+Ol 4 .93E-02 6 .24E+Ol l.7 lE-0 l 2.74E+OO 7.48E-03 2 .66E+OO 7 .26E-03 l.05E+OO 2 .88E-03 4 .67E+OO l .28E-02 Throckmorton 2 .87E+OO 7 .85E-03 l.35E+Ol 3 .69E-02 4 .06E-Ol l.l lE-03 3 .93E-Ol l.07E-03 2 .93E-Ol 8.0lE-04 6 .0lE-01 l.64E-03 Titus l.46E-Ol 3 .98E-04 6.42E-Ol l.75E-03 2.05E-02 5 .6lE-05 l.99E-02 5.44E-05 l .49E-02 4 .06E-05 3.05E-02 8.32E-05 Tom Green 6.31E+OO l.72E-02 2 .50E+Ol 6 .84E-02 9 .23E-Ol 2 .52E-03 8.95E-Ol 2.45E-03 4 .99E-Ol l .36E-03 l.42E+OO 3 .89E-03 Trinity l .30E-Ol 3 .54E-04 5 .72E-Ol l.56E-03 l.83E-02 5 .00E-05 l.78E-02 4 .85E-05 l.32E-02 3 .62E-05 2.71E-02 7.42E-05 Tyler 3 .69E+Ol l.01 E-01 l.58E+02 4 .31E-Ol 5.43E+OO 1.48E-02 5 .27E+OO l .44E-02 3 .08E+OO 8.41E-03 l.OIE+OI 2 .77E-02 Upshur 4 .68E+Ol l.28E-01 1.40E+02 3.83E-Ol 7 .18E+OO l .96E-02 6 .96E+OO l.90E-02 2.42E+OO 6.60E-03 l.21E+Ol 3 .30E-02 Upton 7 .28E+02 1.99E+OO 2 .08E+03 5 .68E+OO l.13E+02 3 .08E-Ol l.09E+02 2.98E-01 3.19E+Ol 8 .71E-02 l .85E+02 5.06E-Ol Val Verde l.1 IE+Ol 3 .02E-02 3 .09E+Ol 8.43E-02 l.71E+OO 4.68E-03 1.66E+OO 4 .54E-03 4 .68E-Ol l.28E-03 2.80E+OO 7 .65E-03 Van Zandt 5.53E+OO l.5 lE-02 l .48E+Ol 4 .05E-02 8 .53E-Ol 2 .33E-03 8.28E-Ol 2.26E-03 2.46E-Ol 6 .73E-04 l.39E+OO 3 .79E-03 Victoria 4.30E+Ol l.l 7E-Ol l.35E+02 3 .68E-Ol 6 .50E+OO l.78E-02 6.30E+OO l.72E-02 2.5lE+OO 6.85E-03 l.05E+Ol 2.88E-02 Walker l.55E-Ol 4 .24E-04 6 .84E-Ol l.87E-03 2.19E-02 5.98E-05 2.12E-02 5.80E-05 l .58E-02 4.32E-05 3.24E-02 8.86E-05 Waller l.26E+Ol 3.46E-02 3 .94E+Ol l.08E-Ol l.92E+OO 5 .23E-03 l .86E+OO 5 .08E-03 7 .3lE-Ol 2.00E-03 3.l lE+OO 8.50E-03 Ward 7 .63E+Ol 2 .08E-Ol 3 .34E+02 9 .l2E-Ol l.l2E+Ol 3 .07E-02 l.09E+Ol 2.98E-02 6.25E+OO l.7lE-02 l.99E+Ol 5.43E-02 Washington 3.45E+OO 9.43E-03 l.70E+Ol 4 .65E-02 4 .98E-Ol l .36E-03 4 .83E-Ol l.32E-03 3.46E-Ol 9.45E-04 9.7lE-Ol 2 .65E-03 Webb 2 .85E+02 7.79E-Ol 8 .66E+02 2.37E+OO 4.38E+Ol 1.20E-Ol 4 .25E+Ol l.l6E-Ol l.38E+Ol 3 .77E-02 7.26E+Ol l.98E-Ol Wharton l.04E+02 2 .85E-Ol 3 .06E+02 8 .36E-Ol l.60E+Ol 4 .36E-02 l.55E+Ol 4 .23E-02 5 .33E+OO 1.46E-02 2.64E+Ol 7.20E-02 Wheeler 6.12E+02 l .67E+OO l.79E+03 4 .89E+OO 9.45E+Ol 2 .58E-Ol 9 .17E+Ol 2.50E-01 2.77E+Ol 7.58E-02 l.56E+02 4 .27E-Ol Wichita l.30E+Ol 3 .54E-02 5.83E+Ol 1.59E-Ol J .85E+OO 5 .04E-03 1.79E+OO 4.89E-03 l .24E+OO 3.39E-03 2 .77E+OO 7 .57E-03 Wilbarger 4 .02E+OO l .lOE-02 l.89E+Ol 5.l6E-02 5 .67E-Ol l .55E-03 5 .50E-Ol l .50E-03 4.lOE-01 l.l2E-03 8.4lE-Ol 2.30E-03 Willacy 4 .72E+Ol l .29E-Ol l .36E+02 3 .71E-01 7 .29E+OO 1.99E-02 7.07E+OO l .93E-02 2.08E+OO 5.69E-03 l.20E+Ol 3 .28E-02 Wilson 3 .46E-Ol 9.45E-04 l.72E+OO 4 .69E-03 4 .99E-02 l .36E-04 4.84E-02 l.32E-04 3.46E-02 9.45E-05 9 .86E-02 2.69E-04 Winkler 5.64E+Ol l.54E-O I 1.87 E+02 5 .IOE-01 8.61E+OO 2 .35E-02 8.35E+OO 2 .28E-02 3 .07E+OO 8 .38E-03 l.46E+Ol 3 .99E-02 Wise l.79E+02 4.89E-01 8.44E+02 2 .31E+OO 2.60E+Ol 7 .l lE-02 2 .53E+Ol 6.90E-02 l.69E+Ol 4 .61 E-02 5 .03E+Ol l.37E-Ol Wood 8 .71E+OO 2.38E-02 2 .95E+OI 8 .07E-02 l .32E+OO 3 .60E-03 l.28E+OO 3.49E-03 5.42E-Ol 1.48E-03 2 .26E+OO 6.18E-03 Yoakum 5.71E+Ol I .56E-01 2.20E+02 6.0lE-01 8 .51E+OO 2 .33E-02 8 .26E+OO 2.26E-02 4.04E+OO 1.lOE-02 1.43E+Ol 3.89E-02 Young 8.21E+OO 2.24E-02 3.86E+OI l.05E-Ol l.16E+OO 3 .16E-03 1.12E+OO 3 .07E-03 8.37E-Ol 2.29E-03 1.72E+OO 4 .69E-03 Zapata 3.43E+02 9.38E-01 1.05E+03 2 .87E+OO 5 .28E+Ol l.44E-Ol 5 .12E+Ol l.40E-01 I .66E+OI 4.54E-02 8 .81E+OI 2 .41E-01 Zavala 5 .19E+OO l.42E-02 2 .71E+Ol 7.41E-02 7.47E-Ol 2 .04E-03 7 .25E-Ol l .98E-03 5 .20E-01 l.42E-03 I .44E+OO 3 .94E-03 6-27 7.0 Conclusions and Recommendations This study presents a comprehensive, statewide 2008 emissions inventory for Texas for drilling rig engines. This inventory was prepared using well drilling activity data obtained through permit records from the TRC, combined with emissions data derived through detailed drilling rig engine data collected through a bottom-up survey effort. Survey data was collected through a phone and email survey which resulted in the collection of 45 completed surveys obtained from 39 different drilling rig contractors and/or oil and gas well operators. These surveys were representative of over 1,500 wells drilled in Texas in 2008, or about 10% of all wells drilled in that year, and covered all of the major oil and gas basins in the state (Andarko, East Texas, Ft. Worth/Bend Arch, Permian, and Western Gulf). The data collected included drilling rig engine sizes (hp), ages, hours of operation, and model year. The 2008 inventory was used as the basis for developing 2002 and 2005 year inventories, as well as projected inventories for 2009 through 2021. As compared to the previous oil and gas study prepared by TCEQ in 2007 (for a 2005 base year), the emission estimates presented in this study reflect a significant decrease in the statewide NOx emission estimate for 2005 (42,854 tons per year in this study compared to 119,647 tons per year in the 2007 study). While not as pronounced, there were also significant decreases in the S02 and CO emission estimates based on this study. For VOC, PM1o, and PM 2.5, the estimates contained in this study show slightly higher estimates than in the previous study. Further improvements to this inventory could be made through the addition of emission estimates for fracturing operations, as well as additional refinement of the activity data used for projected years 2009 through 2021. 7-1 8.0 References ARB, 2001. Speciation Profile Database. Internet address : http://www.arb.ca.gov/ei /speciate/interoptO l .htm Bar-Ilan, Amnon; Friesen, Ron; Pollack, Alison; and Hoats, Abigail , 2007 . WRAP Area Source Emissions Inventory Projections and Control Strategy Evaluation Phase II. Prepared for the Western Governor's Association. September, 2007. Bar-Ilan, Amnon; Grant, John; Parikh, Rajashi; Pollack, Alison; Henderer, Doug; Pring, Daniel; and Sgamrna, Kathleen, 2008 . Development of Baseline 2006 Emissions from Oil and Gas Activ ity in the Denver-Julesburg Basin. Prepared for Colorado Department of Public Health and Environment Air Pollution Control Division. April, 2008. Bar-Ilan, Amnon; Parikh, Rajashi ; Grant, John; Shah, Tejas; and Pollack, Alison, 2008a. Recommendations for Improvements to the CENRAP States ' Oil and Gas Emissions Inventories. Prepared for Central States Regional air Partnership. November, 2008 Bar-Ilan, Amnon; Grant, John; Friesen, Ron and Pollack, Alison, 2009 . Development of Baseline 2006 Emissions from Oil and Gas Activity in the Piceance Basin. Prepared for the Western Governor's Association and the Independent Petroleum Association of Mountain States. January, 2009. Bommer, P , 2008 . A Primer of Oilwell Drilling, A Basic Text of Oil and Gas Drilling, Seventh Edition . The University of Texas at Austin, Petroleum Extension Service. 2008. Energy Information Administration (EIA), 2009. Supplemental Tables to the Annual Energy Outlook 2009 , Updated Reference Case with ARRA, Data Tables 113 and 114. Data released April 2009. Washington, D.C . Internet address: http ://www.ei a .do e.g o v/oiaf/a eo /supplem ent/stimulus/r e gionalarra .h tml Pollack, Alison; Russell , James ; Grant, John; Friesen, Ron; Fields, Paula; and Wolf, Marty, 2006 . Ozone Precursors Emission Inventory for San Juan and Rio Arriba Counties , New Mexico. Prepared for New Mexico Environment Department. August, 2006. Russell, James and Pollack, Alison, 2005 . Oil and Gas Emissions Inv entories for the Western States . Prepared for Western Governor's Association. December, 2005. Texas Commission on Environmental Quality (TCEQ), 2007 . Emissions from Oil and Gas Production Facilities, 2007. Prepared by Eastern Research Group , Inc . August 31 , 2007. Texas Commission on Environmental Quality (TCEQ), 2009 . New Oil and Gas SCCs . Data provided by Greg Lauderdale, TCEQ. June 2 , 2009. Email communication from Greg Lauderdale, TCEQ to Mike Pring, Eastern Research Group, Inc. 8-1 Texas Commission on Environmental Quality (TCEQ), 2009a. NIF 3.0 Formatting for TEXAER. Data provided by Greg Lauderdale, TCEQ. June 24, 2009. Email communication from Greg Lauderdale, TCEQ to Mike Pring, Eastern Research Group, Inc. Texas Railroad Commission (TRC), 2009a. Summary of Drilling, Completion and Plugging Reports Processed for 2002. Accessed June 5, 2009. Internet address: http://www.rrc. state. tx. u s/ data/ drilling/ drillingsummary/2002/ ogdc02an. pdf Texas Railroad Commission (TRC), 2009b . Summary of Drilling, Completion and Plugging Reports Processed for 2005. Accessed June 5, 2009. Internet address: http://www.rrc .state .tx.us/data/drilling/drillingsummaiy/2005 /ogdc05an.pdf Texas Railroad Commission (TRC), 2009c . Summary of Drilling, Completion and Plugging Reports Processed for 2008 . Accessed June 5, 2009. Internet address : http ://www.rrc.state.tx.us/dat a/drilling/drilling summary/2008 /annual2008.pdf U.S. EPA, 2005. User's Guide for the Final NONROAD2005 Model. EPA-420-R-05-013 . U.S. Environmental Protection Agency, Office of Air and Radiation. December. U.S . EPA, 2005a . Conversion Factors for Hydrocarbon Emission Components. EPA-420-R-05 - 015. U.S. Environmental Protection Agency, Office of Air and Radiation. December. 8-2 Appendix A -Approved Data Collection Plan 5608 Parkcrest Drive, Suite 100 Austin, TX 78731 MEMORANDUM TO: Greg Lauderdale (TCEQ) FROM: Rick Baker, Mike Pring (ERG) DATE: April 3, 2009 SUBJECT: Work Order# 582-7-83985-FY09-01, Deliverable 2b-Final Data Collection Plan This document serves as the final deliverable for Task 2 of the Work Order, and includes the results of ERG's review of existing activity and emissions data, and presents a Data Collection Plan which identifies the proposed approach for collecting the information needed to develop a comprehensive emissions inventory for land-based drilling rig engines in the state of Texas in 2008. In addition, as described in the Work Plan, we have included our recommendations on how to proceed with the Texas oil and gas drilling activity emissions estimation project. The methodology used to develop the 2008 emissions inventory will be based on the 2005 emissions inventory ERG completed for TCEQ in 2007 , but will expand on that effort by improving the analysis and data collection of both activity data and emissions data. ERG will conduct the data collection survey as per the proposed Data Collection Plan and as approved by TCEQ . 1.0 Review of Existing Studies, Data, and Industry Websites Under Task 2, ERG has conducted a literature review and evaluated existing information and studies pertinent to the development of a comprehensive oil and gas drilling activity emissions inventory for the state of Texas for the year 2008. The results of this research is discussed below in two parts , the first being a review of existing studies that address estimating emissions from oil and gas drill rig operations, and the second being the results of our review of existing Texas data available from government and industry websites and publications. A-1 1.1 Review of Existing Studies As mentioned above, the goal of this project is to improve upon the 2005 emissions inventory ERG completed for TCEQ in 2007 for drill rig engines by obtaining more highly resolved activity data, as well as more accurate emissions information. Over the last several years , numerous studies have been conducted in the western states to develop area source emission estimates for oil and gas sources, with subsequent studies improving upon the data collection methodology and emission estimation approaches in prior studies. The relevant studies ERG has identified are provided in Table 1. Table 1. Existing Drill Rig Engine Studies Report Geographic Coverage Publication Date Oil and Gas Emission Inventories for the Western WRAP States December, 2005 States (WRAP Phase I) Ozone Precursors Emission Inventory for San Juan San Juan and Rio August, 2006 and Rio Arriba Counties , New Mexico Arriba Counties, New Mexico Emissions from Oil and Gas Production Facilities Texas August, 2007 WRAP Area Source Emissions Inventory WRAP States September, 2007 Projections and Control Strategy Evaluation Phase II Development of Baseline 2006 Emissions from Oil Denver-Julesburg April , 2008 and Gas Activ ity in the Denver-Julesburg Basin Basin, Colorado Recommendations for Improvements to the CENRAP States November, 2008 CENRAP States ' Oil and Gas Emissions Inventories Development of Baseline 2006 Emissions from Oil Piceance Basin, January, 2009 and Gas Activity in the Piceance Basin Colorado A-2 As a result of a review of the ex isting literature , ERG has been able to develop a firm understanding of the types of equipment currently used by industry for different drilling acti v ities , as well as basic approaches to surveying and compiling emissions estimates . Based on this re v iew, ERG anticipates organizing our survey based on rig type (drilling rigs vs. completion/workover rigs), rig engine application ( draw works engines, mud pump engines , and engines for general rig power), whether the rig is mechanical or electrical, well depth, and wellbore type (vertical , horizontal). Engine size (hp) will al so be critical in our analysis , but the parameters listed above will dictate the v arious engine siz es we anticipate seeing . For example , many workover and completion rigs may be powered by a single engine at less than 600 hp , while rigs used on deep ( over 15 ,000 feet) horizontal wells may require four or five engines , ranging in size from 500 to 1,000 hp each. In addition to process information, example surveys and survey questions were included in several studies , and ERG anticipates formulating the survey used for this project utilizing examples provided in these reports. It should be noted that these existing studies were comprehensive in nature, inclusive of all emission sources found at oil and gas exploration and production locations. While well drilling was included as an emission source, this source category was not a major focus of these efforts. As such, many of the surveys u sed in these studies were sent to the oil and gas producers themselves, and not directly to the owners and operators of the drill rigs, who are typically contracted by the producers to drill the well . Once a gi ven well is completed, the drilling contractor will move on to the next well. Therefore , ERG anticipates focusing our survey efforts on the drilling contractors themselves , with less emphasis on the production companies as has been done previously. A-3 Of the reports listed in Table 1, the CENRAP report appears to be the most relevant for this study as Texas is one of the CENRAP states covered under the report, and the report also provides "default" activity data and emission factors for the five major oil and gas basins in Texas (Andarko, East Texas, Fort Worth, Permian, and Western Gulf). While ERG anticipates developing specific activity data and emissions data from our survey efforts as part of this project, the CENRAP report may be useful for gap-filling and/or validation depending upon the results of our survey activities. 1.2 Review of Existing Activity Data The primary source of activity data to be used to compile the 2008 drill rig emissions inventory will come from the Texas Railroad Commission (RRC). ERG has contacted the RRC and obtained a copy of the "Drilling Permit Master and Trailer" database, which contains information on every application to drill for an oil or gas well in Texas since 1976, including American Petroleum Institute (API) number, date approved , location (county), wellbore profile , well depth , spud-in date, and well completion date. ERG is currently in the process of translating this database into Access for ease of use in estimating emissions. This data will allow us to allocate emissions spatially (aggregated at the county level), as well as temporally (based on spud-in date and well completion date for each individual well). Use of this database will result in a more highly refined dataset than was used in development of the 2005 emissions inventory, which was based on total depth drilled by county by wellbore type , with drilling times estimated from the "worst case" well for each county/wellbore-type combination. In addition , by obtaining the complete dataset , ERG will be able to analyze activity data for multiple years. As described in the work plan, ERG has concerns regarding the representativeness of activity data for 2008 given the extreme volatility in the market that year. Once the data has been properly compiled, ERG will consult with TCEQ and make a final recommendation as to the base year for this inventory effort . Regardless of which base year is chosen, the RRC data will be used to backcast the base year inventory to develop the 2002 and 2005 prior year inventories based on drilling permit records for those years. ERG anticipates developing 2009 through 2021 projected inventories using the base year inventory and forecasting future activity based on US DOE Energy Information Administration projections of A-4 oil and gas production for the Southwest and Gulf Coast regions from the Annual Energy Outlook 2009. 1.3 Review of Industry Websites Using information available on the International Association of Drilling Contractors (IADC) website , we were able to identify many of the larger drilling contractors in Texas (while there may be non-IADC members with significant drilling activities in Texas , we did not identify any during our review). A review of the websites for these larger contractors provided useful information regarding the drilling rig fleets in use in Texas , and we were able to easily assimilate a dataset with specific equipment information on over 225 drill rigs. A few examples of this type of information can be found at the following drill rig operator websites: a) http://www. gwdri Hing . com/services/ri glist.htm b) http://ww w.pioneerdrlg .com/HTML/RigF le et.html c) http ://www.rowancompanies .com/fw /mai n/L and-Rig-Fleet-61 .html This effort was not exhaustive , and if additional information is needed to gap-fill or supplement our survey findings , there is additional information that can be obtained online. For example, Appendix A contains an example "spec sheet" for a specific rig used by Pioneer Drilling, including specific makes and models of both the draw works engines and mud pump engines. ERG will compile this information to the extent possible prior to conducting the survey in order to familiarize ourselves with the engine makes and models we are likely to encounter through the survey. 2.0 Data Collection Plan By obtaining and translating the RRC "Drilling Permit Master and Trailer" database, we will have highly resolved data on all drilling activity that occurred in Texas during the base year. In addition to wells that were started and finished during the base year, we will also have data on drilling activities that commenced during the year preceding the base year (but finalized during the base year), as well as data on wells that were started during the base year but were not A-5 completed until the following year. Therefore, we feel we have obtained the best activity data available to use as the basis for the base year inventory . As we will have obtained the activity data needed to estimate emissions from the RRC database , the primary focus of our data collection and survey activities will be on obtaining real data from rig operators who were actively drilling in Texas in 2008. The goal of this survey will be to develop a series of "model rig profiles" for different rig types , well depths , and geographic locations (basin-specific profiles are preferred). Our proposed survey methodology for obtaining this information is provided below. 2.1 Participant Recruitment In order to encourage survey response , stakeholder support for the study will be sought. At the current time , ERG has consulted with contacts at the University of Texas , Southern Methodist University, the Texas Railroad Commission, and the IADC in an effort to obtain an understanding of well drilling practices, and to assist us in encouraging stakeholder participation. The IADC provided helpful information on industry practices, but their organization does not endorse or participate in any survey activities , so further contribution from them may be limited to feedback on our draft survey materials and/or survey approach . In addition to those sources we have already contacted, ERG anticipates encouraging additional stakeholder participation by contacting the following trade associations and local organizations: a) Texas Oil and Gas Association (TxOGA) b) Texas Independent Producers and Royalty Owners Association (TIPRO) c) Independent Petroleum Association of America (IPAA) d) Petroleum Equipment Suppliers Association (PESA) e) The Barnett Shale Energy Education Council (BSEEC) If possible, ERG will attempt to provide information regarding the study and survey to trade associations before administering the survey to promote cooperation with the study and to A -6 identify potential survey participants. We will prepare a draft survey for peer review by members of the Petroleum Engineering Department at the University of Texas to obtain feedback prior to implementation. ERG will also request trade associations and stakeholders help distribute a letter of introduction about the project on TCEQ letterhead to the owners and operators of drill rigs. 2.2 Mail and Phone Surveys At this point we do not have a specific list of target respondents, but in general , will seek to find willing participants through our planned communication with the trade groups as described above, as well as searches through business listings and directories obtained from such sources as USA Data. Once we have identified a comprehensive listing of likely drilling rig operators, ERG will obtain the services of a survey contractor to execute this portion of the Data Collection Plan. ERG will train the survey contractor staff in conducting phone surveys of drill rig operators , providing background in the purpose of the study and familiarizing staff with industry terminology they may encounter. Once trained, the survey contractor will initiate the survey, first by phone calls to targeted respondents, then potentially by follow-up with phone , mail or fax surveys (as needed). Respondents will be asked to specify their preferred survey response mode, although phone surveys will be encouraged in order to reduce incomplete responses and errors. Upon completion of the first week of phone surveys (and at regular intervals thereafter), ERG will review and audit the results of the phone surveys to confirm that we are contacting participants willing to provide us the needed information over the phone ( or willing to continue with the mail survey), and determine if adjustments need to be made to the survey or survey method in order to ensure sufficient response for proper stratification of our model rig profiles. The survey itself will focus on collecting the following information for representative, or average (based on a particular basin or drilling depth), drill ing operations : a) The number of engines on a rig b) Engine make, model , model year, and size (hp) c) Average load for each engine d) Engine function (draw works , mud pumps, power) A-7 e) Actual engine hour data for well completion (total hours) t) Actual engine fuel use data for well completion (total fuel use) g) Engine fuel type ( and sulfur content for diesel fuel) h) Engine-specific emission factors (based on manufacturers' or vendor data) or actual test data if available i) Well location (county, API #) j) Total well drilling time (actual number of drilling days) k) Total well completion time (number of days needed for well completion activities) l) Well depth Depending on how responsive the survey participant are to the phone survey, and what level of aggregation they have data available, we may request "average" data for their rigs, or specific examples based on actual data for specific wells drilled in the base year. ERG will first attempt to obtain all the required information via the phone survey, but it is expected that specific information may more readily be obtained by following up with a mail survey. Appendix B presents an example cover letter that will be included with the mail survey, and Appendix C provides an example of the types of information that will be requested. ERG will periodically review the mail survey responses to see if adjustments are needed in order to obtain a sufficient response rate by checking that all fields/basins are being covered, ensure all wellbore types are included, and check that the survey adequately covers the range of well depths included in the RRC drilling permit dataset. 2.3 Field Observations Once ERG has obtained initial responses to our phone and/or mail surveys and with approval from the TCEQ project manager, ERG will attempt to obtain permission for site visits to active drilling sites through survey participation and stakeholder contacts. ERG's protocol for conducting on-site visits includes a standardized data collection form, such as that presented in Appendix D . This form essentially requests the same information as requested during the phone/mail survey, but adds additional contact information and site visit date. On-site observations of drill rig engine operation and specifications will be used to verify the data A-8 collected in the mail and phone surveys, and to attempt to establish equipment load factors and any other adjustment factors deemed necessary . Site visits will be coordinated in advance , obtaining the site location, name of contact, and date/time for each visit. Site contacts will be called one business day in advance to confirm the time and location for the visit , as well as to determine any site-specific safety or operation requirements. For example, it is expected that active drilling sites will require steel-toed boots, hard hat, and safety glasses before entry. ERG representatives will adhere to all company requirements while on site. If necessary, the TCEQ Project Representative shall obtain an official letter on TCEQ letterhead explaining the purpose of the study to be presented to site foremen or other company representatives as requested. Once on site , each engine will be assigned a unique identifier, and data collection will involve an inspection of each engine located on site to collect the following information: a) Make and model, model year, and size b) A description of how each unit is used ( obtained from the site foreman) c) Typical Fuel usage information (gallons per day over the course of the drilling activity) d) Typical operating schedule (hours per day over the course of the drilling activity) e) Typical operating load if available The on-site data collected will be recorded using the standard reporting form such as that provided in Appendix D . ERG will attempt to arrange for visits to multiple locations/fleets for field observations , and will seek to arrange visits to different types and sizes of rigs , with a preference for a geographical distribution reflective of the well drilling data obtained from the RRC (as feasible given the project resources). Preference will be given to companies operating multiple drill rigs in order to improve data collection efficiency. A-9 2.4 Confidentiality Confidentiality will be stressed to participants participating in the study, and will be addressed in the survey cover letters and/or phone questionnaire scripts. ERG is particularly sensitive to the privacy of individuals and businesses. Therefore all interviews and data collection efforts will begin with a guarantee of privacy, anonymity, and confidentiality. To ensure survey respondent's rights to privacy, respondents will be informed of the research purpose, the kinds of questions that will be asked, and how TCEQ may use the results of the study. Confidentiality will be maintained by eliminating names from interview records, stripping all respondent-identifying characteristics from study datasets. In addition, all project staff will be given explicit training regarding confidentiality protocols and commitments. 3.0 Emissions Calculation Methodology Once the Data Collection survey is complete, ERG will develop emission estimates for model rig fleets which we will then apply to the population of wells from the RRC dataset. It is anticipated that model rig fleets will be stratified according to: a) Well location (basin, as identified by County) b) Well depth (based on RRC data) c) Well type (vertical, horizontal) While these parameters are provided in the RRC dataset, and based on our review of available literature and operator interviews appear to be the most critical parameters in terms of · differentiating wells for emission estimation purposes, we may encounter other variables that provide additional distinction between our model rig fleets based on our survey results. For example, we anticipate the total hp of each rig profile to vary by well depth, and although rig power information is not provided in the RRC data, it will be critical in estimating emissions. Once we have compiled the survey data into model rig fleets, an average emissions profile will be developed for an average well in that fleet. The emissions profile will be developed for each model rig fleet using a combination of emission and deterioration factors obtained through our survey, EPA's NONROAD model, and/or AP-42 emission factors. For HAPs, emission factors will be obtained from the SPECIATE database, and/or AP-42. A-10 Each well in the RRC dataset will then be assigned to a specific model fleet , and emissions will be calculated for each well base on scaling emissio ns from the model fleet to each individual well based on the ratio of the actual well depth for th at well to the model fleet average well depth. For calculating daily emission estimates (for purposes of ozone-season daily estimates), the total emissions for each wellbore will be evenly divided by the total number of days between spud date and completion date , as obtained by the RRC dataset. The end result will be an estimate of the actual emissions for each well for each day of the drilling period . 4.0 Recommendations ERG recommends that TCEQ proceed with the drill rig engine emission estimation project as described above. By obtaining the RRC well permit database in electronic format , the activity data we now have available provides us with a much greater level of geographical and spatial resolution for emission estimates than was available when ERG compiled the 2005 oil and gas emissions inventory. In addition , our literature review has indicated that the "state of the art " emissions estimation approaches and methodology have continued to be refined over the last few years as regional , state , and local agencies have become increasingly aware of the magnitude of emissions from the sources associated with oil and gas exploration and production. Subsequent studies of emissions from these sources make use of previous studies , and build upon those with further refinement of the acti v ity and emission factor data used in the estimates. ERG anticipates being able to continue this evolution for estimating emissions from drill rig engines in Texas. The next challenge in this process will be to continue to solicit support from stakeholders , namely, the trade associations representing oil and gas drill rig operators , as well as the operators themselves . Through data available on the IADC website , we have obtained contact information for many of the major drill rig owners and operators in Texas. While we could proceed to contact them directly at this point, we feel it will be beneficial to the ultimate success of this project to obtain the endorsement and support from the industry as a whole through the trade associations if possible . A-1 1 APPENDIX A EXAMPLE OF DRILLING RIG INFORMATION AVAILABLE ONLINE A-12 APPENDIXB ADV AN CED LETTER TO DRILL RIG OWNERS/OPERA TORS ---on TCEQ letter head (distributed via fax &/or trade associations) Dear Drill Rig Manager OR <Mr./Ms . LAST NAME>: The Texas Commission on Environmental Quality (TCEQ) requests your help. We are asking for your voluntary participation in a study about engines used in the drilling of new and/or recompleted oil and gas wells in Texas during 2008. The study will involve rig owners sharing information regarding the operating practices (such as hours of operation) and rig configuration (such as the number and size of engines) in their fleet. This information will provide a better understanding of how drilling rig operations are conducted under real-world practices . TCEQ contracted with Eastern Research Group (ERG), an independent research organization, to administer this study. We urge you to participate -the results will improve the accuracy of TCEQ's emissions estimates for drilling rigs across the state. Prominent trade associations are supporting this study, encouraging their membe rs to pa1ticipate, including the [TxOGA , IPAA. etc ... ] These organizations represent the interests of oil and gas exploration and production companies at the local, state , and national levels and recognize the value of the study to industry as well as to government. Your participation is both voluntary and completely confidential. ERG guarantees the confidentiality of all participants in this study. This means the information your company provides will be used for statistical purposes only. Responses will be kept confidential and will not be disclosed in identifiable form to anyone other than ERG employees or agents without your consent. E very ERG employee with access to identifying information will sign a confidentiality agreement. This agreement guarantees that we will not disclose any information that may identify you, such as your address, contact information or worksite locations, unless required by law. The study involves 3 easy steps. 1. First, the person most knowledgeable about your business' drilling rig operations will be asked to participate in a short phone survey about the typical rig configurations and engine numbers and types used to drill wells in Texas in 2008 . In most cases , this survey will take ten to fifteen minutes . 2. Second, after completion of the phone survey, ERG may send you a written survey requesting more detailed information about operating practices you employed in drilling wells in Texas during 2008. In order to minimize the amount of data we are requesting from any one participant, we would request data for a select number of drilling operations , most likely requesting information on 2-3 examples for a particular well- depth, oil field or basin, and well type. However, we would be willing to accept as much data as made available to us , and can also accept existing data and query it to meet our A-13 needs if you have existing data that would be helpful , but is not currently in a format consistent with our survey. 3. Third, after completion of the surveys, ERG may ask for permission to visit one of your active drilling sites. Pending your approval , an ERG representative will travel to an active well site and collect information on each engine found on-site . This data includes make , model , year, load , and engine clock hour readings and fuel usage. Only a small percentage of companies will be asked to participate in on-site field data collection. Again, we appreciate your assistance in this important study . If you have any questions , please call Greg Lauderdale in the Air Quality Division ofTCEQ at 512-239-1433 . To contact the independent research firm conducting the study, call the survey project manager, Rick Baker at 512-407-1823 , or email him at ric k.b aker @e rg .com. Thank you in advance , {TCEQ Signature authority } A-14 APPENDIXC DRILL RIG SURVEY QUESTIONS Part 1. General Site Information 1. Name of Company: 2. Well API #: 3. Contact Name: 4. Number of engines on site: 5. Well Type (Vertical , Horizontal): 6. Well Depth: 7. Total Well Drilling Duration (days): 8. Fuel Type (and sulfur content for diesel fuel) Part 2. Engine-Specific Information (for each eng in e) Engine Use Average Average Average Engine (Drawworks , Make/ Model Engine Operating ID Mud Pump, Model Year HP Fuel Use Schedule Engine Power) (gallons) (hours) Load(%) A-15 APPENDIXD FIELD DATA COLLECTION FORM Part 1. General Site Information 1. Name of Company: 2 . Company ID : 3. Well API #: 4. Site Personnel Contact Name: 5 . Site Personnel Title: 6 . Site Personnel Phone #: 7 . Number of engines on site : 8 . Well Type (Vertical, Horizontal) 9 . Well Depth: 10. Total Well Drilling Duration (days): 11. Fuel Type (and sulfur content for diesel fuel) 12. Date of site visit: Part 2. Engine-Specific Information (for each engine) Engine Use Average Average Average Engine (Draw works, Make/ Model Engine HP Fuel Use Operating Engine ID Mud Pump, Model Year Schedule Load Power) (gallons) (hours) (%) A-16 Appendix B -Survey Letter EASTERN RESEARCH GROUP , INC . Dear Owner/Operator: Eastern Research Group (ERG), an independent research organization, is conducting a study on drilling rig engine emissions for the State of Texas for calendar year 2008. ERG is conducting this study with the support of the Texas Independent Producers and Royalty Owners Association (TIPRO) and the Texas Oil & Gas Association (TXOGA). These organizations represent the interests of oil and gas exploration and production companies in Texas and recognize the value of the study to industry as well as to government. We are asking for your voluntary participation in this study of oil and gas wells that were drilled in Texas during 2008 . The study will involve sharing information regarding the operating practices (such as the hours of operation) and rig configuration (such as the number and size of engines) used during well drilling. Your participation is voluntary and completely confidential, individual wells do not need to be identified. The information your company provides will be used for statistical purposes only in order to develop county-level estimates and will not be republished or disseminated for other purposes . Responses will not be disclosed in identifiable form to anyone other than ERG employees or agents . The attached Excel workbook contains our study questions. We are seeking basin specific rig profiles to complete a typical well in the Andarko, Bend Arch-Fort Worth, East Texas, Permian, and Western Gulf basins. For each basin, we would like one profile for a vertical well, and a second profile for a horizontal/directional well. If you operate in multiple basins in Texas, please complete one worksheet for each basin and well type that you are familiar with. For your convenience, the county/basin assignments are included in the workbook in the "Counties by Basin" worksheet. An example of a completed worksheet is also provided. Your expertise is valued; please include comments or clarifications! Your response is requested by June 5, 2009. Completed forms may be submitted via email to Len Boatman at llboatman@ gmail.com, or via fax to 512-579-0315. For further information or assistance in completing this form , please call Len Boatman at 512-579-0315. We appreciate your assistance in this important study. If you have any questions on the study, please feel free to contact me at (919) 468-7840, or via email at mike .pring@ erg.com. Sincerely, ,4£4 Mike Pring Senior Environmental Engineer Eastern Research Group, Inc. B-1 DRILL RIG SURVEY QUESTIONS Part I. General Site Information Owner/Operator: Owner/Operator Contact Name: Owner/Operator Contact Phone: Please use county or basin averages for each question. l. Well Locations ( county or basin) 2 . Well Type (vertical, horizontal, directional) 3 . Typical Well Measurement Depth (feet) 4 . Typical Well Drilling Duration (days) 5 . Typical Number of engines on site 6. Typical Rig Fuel Use (gal/day) 7 . Typical Workover/Completion (hours) 8. Typical Workover/Completion Engine Size (HP) 9. Fracing; Yes/No; Duration (days) Part 2. Drill Rig Engine-Specific Information (for each engine on a typical rig). Engine Function Typical Typical Typical Typical Engine Typical Engine Typical Engine (Draw works, Mud Make and Model Engine On-time time under load Pump , Power) Model Year Size (HP) (hr/day) (hr/day) Load(%) C-1 Appendix D -Survey Data Table D.1 Survey Data -Horizontal and Directional Wells #of ~ Engine wells Total Total On-time covered Make Engine Well Engine (hours/ Survey by Well Engine Engine and Model Size Drilling On-time 1,000 Average ID survey Well Type Depth ID Function Model Year (HP) Days (boors) feet) Load% (All) Electric D200a 5 Directional 10 ,150 1 Rig Cat 3512 2006 1192 .5 40 960 94.58 65 (All) Electric D200a 5 Directional 10 ,150 2 Rig Cat 3512 2006 1192 .5 40 960 94.58 65 (All) Electric D200a 5 Direc tional 10 ,150 3 Rig Cat 3512 2006 1192 .5 40 960 94.58 65 Dl80 5 Horizontal 8,000 1 Drawworks Cat 3406 1985 400 22.5 540 67 .50 62 .5 D180 5 Horizontal 8,000 2 Drawworks Cat3406 1985 400 22.5 540 67.50 62 .5 D180 5 Horizontal 8,000 3 Mud Pump Cat 399 1985 1260 22 .5 540 67.50 75 Dl80 5 Horizontal 8 ,000 4 Mud Pump Cat 399 1985 1260 22.5 540 67.50 75 Dl80 5 Horizontal 8 ,000 5 Generator Cat 3406 400 22.5 540 67 .5 0 80 D180 5 Horizontal 8 ,000 6 Generator Cat3406 400 22.5 540 67.50 80 Cat D81 33 Horizontal 9 ,500 1 Drawworks 3412B 1985 475 13 .5 324 34.1 l 25 .5 Cat D81 33 Horizontal 9 ,500 2 Drawworks 3412B 1985 475 13 .5 162 17 .05 25.5 Cat D8l 33 Horizontal 9,500 3 Mud Pump 3508B 2005 950 13 .5 162 17 .05 25 .8 Cat D81 33 Horizontal 9,500 4 Mud Pump 3508B 2005 950 13 .5 162 17 .05 25.8 D8l 33 Horizontal 9 ,500 5 Generator Cat 3306 1985 270 13.5 162 17 .05 60 D-1 Table D.1 Survey Data -Horizontal and Directional Wells (Cont.) #of Engine wells Total Total On-time covered Make Engine Well Engine (hours/ Survey by Well Engine Engine and Model Size Drilling On-time 1,000 Average ID survey Well Type Depth ID Function Model Year (HP) Days (hours) feet) Load% D8l 33 Horizontal 9,500 6 Generator Cat 3306 1985 270 13.5 162 17 .05 60 (All) Electric D50a 34 Horizontal 10,109 1 Rig Cat3508 2006 950 16 384 37.99 60 (All) Electric D50a 34 Horizontal 10 ,109 2 Rig Cat 3508 2006 950 16 384 37.99 60 (All) Electric Dl 19 20 Horizontal 11,500 l Rig Cat 3512 2006 1192 .5 19 456 39 .65 60 (All) Electric Dl 19 20 Horizontal 11,500 2 Rig Cat 3512 2006 1192 .5 19 456 39 .65 60 D97 9 Horizontal 13,000 l Drawworks Cat 379 1984 550 45 1080 83 .08 40.5 D97 9 Horizontal 13 ,000 2 Drawworks Cat 379 1984 550 45 1080 83 .08 40.5 D97 9 Horizontal 13 ,000 3 Mud Pump Cat 3508 1995 900 45 1080 83.08 55.8 D97 9 Horizontal 13 ,000 4 Mud Pump Cat 399 1989 1250 45 324 24 .92 55 .8 Detroit D97 9 Horizontal 13 ,000 5 Generator Series 60 2002 400 45 540 41.54 60 Detroit D97 9 Horizontal 13 ,000 6 Generator Series 60 2002 400 45 540 41.54 60 (All) Electric Cat D50c 3 Horizontal 14 ,900 1 Rig 3512C 2006 1478 67 1608 107.92 40 (All) Electric Cat D50c 3 Horizontal 14 ,900 2 Rig 3512C 2006 1478 67 1608 107 .92 40 (All) Electric Cat D50f 11 Horizontal 17,668 1 Rig 3512C 2006 1478 72 1728 97 .80 40 D-2 Table D.1 Survey Data -Horizontal and Directional Wells (Cont.) #of Engine wells Total Total On-time covered Make Engine Well Engine (hours/ Survey by Well Engine Engine and Model Size Drilling On-time 1,000 Average ID survey Well Type Depth ID Function Model Year (HP) Days (hours) feet) Load% (All) Electric Cat D50f 11 Horizontal 17 ,668 2 Rig 3512C 2006 1478 72 1728 97 .80 40 Horizontal/ Detroit Dla 14 Directional 10 ,000 1 Drawworks Series 60 2008 470 21 504 50.40 49.4 Horizontal/ Mud Pump # Detroit Dla 14 Directional 10 ,000 2 l 16V2000 2008 1,205 21 504 50.40 35 .5 Horizontal/ Mud Pump# Detroit Dla 14 Directional 10 ,000 3 2 l6V2000 2008 1,205 21 504 50.40 35.5 Horizontal/ Drawworks/ Detroit Dla 14 Directional 10 ,000 4 Swivel Motor Series 60 2008 470 21 504 50.40 49.4 Horizontal/ Detroit Dla 14 Directional 10 ,000 5 Generator # 1 Series 60 2008 470 21 252 25 .20 90 Horizontal/ Detroit Dla 14 Directional 10 ,000 6 Generator # 2 Series 60 2008 470 21 252 25 .20 90 Horizontal/ Detroit Dlb 18 Directional 10,000 1 Drawworks Series 60 2008 470 21 504 50.40 49.4 Horizontal/ Mud Pump# Detroit Dlb 18 Directional 10 ,000 2 1 16V2000 2008 1,205 21 504 50.40 35 .5 Horizontal/ Mud Pump# Detroit Dlb 18 Directional 10,000 3 2 16V2000 2008 1,205 21 504 50.40 35 .5 Horizontal/ Drawworks/ Detroit Dlb 18 Directional 10 ,000 4 Swivel Motor Series 60 2008 470 21 504 50.40 49.4 Horizontal/ Detroit Dlb 18 Directional 10 ,000 5 Generator # 1 Series 60 2008 470 21 252 25 .20 90 Horizontal/ Detroit Dlb 18 Directional 10 ,000 6 Generator # 2 Series 60 2008 470 21 252 25.20 90 Horizontal/ Dl62a 7 Directional 11 ,335 l Drawworks Cat C-18 2005 600 34 816 71.99 60 D-3 Table D.1 Survey Data -Horizontal and Directional Wells (Cont.) # of Engine wells Total Total On-time covered Make Engine Well Engine (hours/ Survey by Well Engine Engine and Model Size Drilling On-time 1,000 Average ID survey Well Type Depth ID Function Model Year (HP) Days (hours) feet) Load% Horizontal/ Dl62a 7 Directional 11 ,335 2 Drawworks Cat C-1 8 2005 600 34 8 16 71.9 9 60 Horizontal/ Dl62a 7 Directional 11 ,335 3 Mud Pump Cat 3508 2005 1300 34 40 8 35 .99 80 Horizontal/ D162a 7 Directional l l ,335 4 Mud Pump Cat 3508 2005 1300 34 408 35 .99 80 Horizontal/ Dl62a 7 Directional 11 ,335 5 Generator Cat C-15 2005 485 34 408 35 .99 60 Horizontal/ D162a 7 Directional 11,335 6 Generator Cat C-15 2005 485 34 408 35.99 60 CatD- S51 10 Horizontal 8,692 l Drawworks 353 1975 450 17.5 420 48 .3 2 43 CatD- S51 10 Horizonta l 8,692 2 Drawworks 353 1975 450 17 .5 420 48 .32 43 Cat D S51 10 Horizontal 8,692 3 Mud Pump 398 1984 825 17 .5 210 24 .16 66 .2 Cat D S51 10 Horizonta l 8,692 4 Mud Pump 398 1984 825 17.5 210 24 .16 66 .2 Cato S51 10 Horizontal 8 ,692 5 Generator 3412 1998 450 17 .5 210 24 .16 40 CatD S5l 10 Horizonta l 8 ,692 6 Generator 3412 1998 450 l 7.5 210 24 .16 40 (All) Electric DI 1 119 Horizontal 10 ,570 l Rig Cat 3512 2006 1476 19 456 43 .14 50 (All) Electric Dll 119 Horizontal 10,570 2 Rig Cat 3512 2006 1476 19 456 43.14 50 D-4 Table D.2 Survey Data -Vertical Wells<= 7,000 feet Engine Total Total On-time # of wells Engine Well Engine (hours/ Survey covered Well Well Engine Engine Make and Model Size Drilling On-time 1,000 Average ID by survev TvPe Depth ID Function Model Year (HP) Davs (hours) feet) Load% D80 37 Vertical 1,000 1 Drawworks Cummins 1990 450 3 10 30.00 59 D80 37 Vertical 1,000 2 Mud Pump Cat 343 1985 400 3 10 30.00 49.4 Drawworks and Mud Cummins D150 10 Vertical 1,8 50 1 Pump KT450 1980 500 2.5 10 13 .51 50 Dl50 10 Vertical 1,8 50 2 Generator Deutz 19 80 50 2.5 10 13.51 20 Draw D74 48 Vertical 2,200 l Cat 3406 1990 470 2 24 21.82 60 Mud pump D74 48 Vertical 2,200 2 Cat 3408 1990 470 2 15 13.64 80 Generator D74 48 Vertical 2,200 3 25 2 24 21.82 25 Draw D51 72 Vertical 2,500 1 Cat 3406 1992 425 2 24 19 .2 0 80 Mud pump D51 72 Vertical 2,500 2 Cat 3406 1992 425 2 24 19.20 50 Generator John D51 72 Vertical 2,500 3 Deere 2000 80 2 12 9 .60 20 Cummins Dl72 6 Vertical 3,300 1 Drawworks 400 1985 400 6.5 24 47.27 75 Cummins Dl72 6 Vertical 3,300 2 Mud Pump 400 1985 400 6.5 24 47 .27 75 Perkins 4 Dl72 6 Vertical 3,300 3 Generator Cylinder 1995 48 6 .5 24 47 .27 77 .5 Draw D72 41 Vertical 3,700 1 Detroit 60 2006 470 10 24 64.86 65 D-5 Table D.2 Survey Data -Vertical Wells<= 7,000 feet (Cont.) Engine Total Total On-time # of wells Engine Well Engine (hours/ Survey covered Well Well Engine Engine Make and Model Size Drilling On-time 1,000 Average JD by survey Type Depth ID Function Model Year (HP) Days (hours) feet) Load% Mud Pump C ummins D72 4 1 Vertical 3,700 2 350 2002 350 10 24 64.86 70 Mud pump Cummins D72 41 Vertical 3,700 3 350 2002 350 10 24 64 .86 11 Generator D72 41 Vertical 3 ,700 4 Cat3404 2006 280 10 24 64.86 50 Dll3 23 Vertical 4 ,200 1 Drawworks Cat 3408 1982 489 6 24 34 .29 52 .65 Dl 13 23 Vertical 4,200 2 Mud Pump JD 600 2008 600 6 24 34 .29 73.9 Dl 13 23 Vertical 4 ,2 00 3 Generator Cat 3304 1985 97 6 24 34 .29 65 S23 13 Vertical 4,500 1 Mud Pump 1 Cat 353 350 11 24 58 .67 77 D etroit S23 13 Vertical 4 ,500 2 Drawworks Series 60 400 11 24 58.67 Detroit S23 13 Vertical 4,500 3 MudPump2 Series 60 330 11 - John S23 13 Vertical 4,500 4 Generator Deere 80 11 24 58.67 S3 16 Vertical 4 ,900 I Generator Cat3406 2002 475 11 40.8 2 37 .5 S3 16 Vertical 4 ,900 2 Drawworks Cat3406 2002 475 11 40.82 3 7 .5 Detroit S3 16 Vertical 4 ,900 3 Mud Pump Series 60 2000 500 11 20.41 75 Detroit S3 16 Vertical 4 ,900 4 Mud Pump Series 60 2000 500 11 20.4 1 75 D-6 Table D.2 Survey Data -Vertical Wells<= 7,000 feet (Cont.) Engine Total Total On-time # of wells Engine Well Engine (hours/ Survey covered Well Well Engine Engine Make and Model Size Drilling On-time 1,000 Average ID by survey Type Depth ID Function Model Year (HP) Days (hours) feet) Load% Dl41 14 Vertical 5,000 1 Drawworks Cat3406 1988 425 10 24 48.00 65 Dl41 14 Vertical 5,000 2 Mud Pump Cat 3503 1988 375 10 5 10 .00 67 .5 Dl41 14 Vertical 5,000 3 Mud Pump Cat3406 1992 425 10 24 48.00 67.5 Detroit D141 14 Vertical 5,000 4 Generator Diesel 1990 250 10 12 24 .00 75 Dl 519 Vertical 5,000 1 Drawworks Cat C-15 2007 425 5 24 .00 49.4 Mud Pump # Dl 519 Vertical 5,000 2 l Cat C-15 2007 425 5 24 .00 35 .5 Mud Pump# Dl 519 Vertical 5,000 3 2 Cat C-15 2007 425 5 24 .00 35.5 Drawworks/ Dl 519 Vertical 5,000 4 Swivel Motor Cat C-15 2007 425 5 24.00 49.4 Detroit Dl 519 Vertical 5,000 5 Generator Series 60 2007 470 5 24 .00 90 Dl 18 25 Vertical 5,000 1 Drawworks Cat 3408 2005 550 12 24 57 .60 27 Detroit Dl 18 25 Vertical 5,000 2 Mud Pump Series 60 2007 550 12 24 57 .60 90. Detroit Dl 18 25 Vertical 5,000 3 Generator Series 60 2007 350 12 24 57 .60 75 Dl39 14 Vertical 5,200 1 Drawworks Cat 3406B 1993 400 8 24 36 .92 32 Dl39 14 Vertical 5,200 2 Drawworks Cat 3406B 1993 400 8 24 36.92 32 D-7 Table D.2 Survey Data -Vertical Wells<= 7,000 feet (Cont.) Engine Total Total On-time # of wells Engine Well Engine (hours/ Survey covered Well Well Engine Engine Make and Model Size Drilling On-time 1,000 Average ID by survey Type Depth ID Function Model Year (HP) Days (hours) feet) Load% Dl 39 14 Vertical 5,200 3 Mud Pump Cat 353E 1985 435 8 3 4 .62 85 Dl39 14 Vertical 5,200 4 Mud Pump Cat 353E 1985 435 8 24 36.92 85 Dl 39 14 Vertical 5,200 5 Generator Cat 3306B 1993 400 8 12 18.46 85 Dl39 14 Vertical 5,200 6 Generator Cat 3306B 1993 400 8 12 18.46 85 Dl63 8 Vertical 6,000 1 Drawworks Cat V71 1965 700 10 24 40.00 50 Dl63 8 Vertical 6,000 2 Drawworks Cat V71 1965 700 10 24 40 .00 50 D163 8 Vertical 6 ,000 3 Mud Pump Cat V379 1975 600 10 24 40 .00 75 D163 8 Vertical 6,000 4 Mud Pump Cat V379 1975 600 10 24 40 .00 75 Dl63 8 Vertical 6,000 5 Generator Cat 3306 1975 175 10 24 40 .00 75 (A ll) Electric Detroit Dl52 4 Vertical 6,500 1 Rig Series 60 2008 425 14 24 51.69 70 (All) E lectric Detroit Dl52 4 Vertical 6,500 2 Rig Series 60 2008 425 14 24 51.69 70 Detroit D70 50 Vertical 3,000 1 Drawworks 8V-92 1989 475 8.5 24 68 .00 40.4 D70 50 Vertical 3,000 2 Mud Pump Cat3406 1989 425 8.5 24 68 .00 48.8 John Deer D70 50 Vertical 3,000 3 Generator 4 cylinder 1989 50 8.5 24 68 .00 80 D-8 Table D.3 Survey Data -Vertical Wells> 7,000 Feet Engine Total Total On-time # of wells Make Engine Well Engine (hours/ Survey covered Well Well Engine Engine and Model Size Drilling On-time 1,000 Average ID by survey Type Depth ID Function Model Year (HP) Days (hours) feet) Load% D142 19 Vertical 7,500 1 Drawworks Cat 3406 2005 400 20 480 64 .00 34 .6 D142 19 Vertical 7 ,500 2 Drawworks Cat3406 2005 400 20 480 64 .00 34.6 D142 19 Vertic a l 7,5 00 3 Mud Pump Cat 3412 2006 650 20 240 32 .00 73 .1 D142 19 Vertical 7 ,500 4 Mud Pump Cat C-18 2006 600 20 240 32.00 73.1 D142 19 Vertical 7,5 00 5 Generator Cat3406 2000 400 20 240 32 .00 45.5 D142 19 Vertical 7,500 6 Generator Cat 3406 2000 400 20 240 32 .00 45 .5 D35 114 Vertical 8,300 1 Drawworks Cat 353 1970 450 12 288 34 .70 52.4 D35 114 Vertical 8,300 2 Drawworks Cat 353 1970 450 12 288 34 .70 52.4 D35 114 Vertical 8,300 3 Mud Pump Cat 398 1997 800 12 288 34 .70 45 .3 D35 114 Vertical 8,300 4 Generator Cat3408 2000 350 12 144 17 .35 80 D35 114 Vertical 8,300 5 Generator Cat3408 2000 350 12 144 17 .35 80 (All) Electric D200 9 Vertical 9,550 1 Rig Cat 3512 2006 1192.5 30.5 732 76.65 65 (All) Electric D200 9 Vertical 9,550 2 Rig Cat 3512 2006 1192 .5 30.5 732 76.65 65 D-9 Table 0.3 Survey Data -Vertical Wells> 7,000 Feet (Cont.) Engine Total Total On-time # of wells Make Engine Well Engine (hours/ Survey covered Well Well Engine Engine and Model Size Drilling On-time 1,000 Average ID by survey Type Depth ID Function Model Year (BP) Days (hours) feet) Load% (All) E lectric D200 9 Vertical 9 ,550 3 Rig Cat 3512 2006 1192.5 30.5 732 76 .65 65 D 83 36 Vertical 9,750 I Drawworks Cat C-15 2004 475 15 .5 186 19.08 45 .3 D 83 36 Vertical 9,750 2 Drawworks Cat C-15 2004 475 15.5 186 19.08 45 .3 D83 36 Vertical 9,750 3 Mud Pump Cat 398 1975 970 15.5 186 19.08 52.4 D83 36 Vertical 9,750 4 Mud Pump Cat 398 1975 970 15.5 186 19 .08 52.4 D83 36 Vertical 9,750 5 Generator Cat 3406 19 95 435 15 .5 186 19 .08 80 D 83 36 Vertical 9,750 6 Generator Cat 3406 1995 435 15 .5 186 19 .08 80 (A ll ) E lectri c S12 12 Vertical 10,000 1 Rig Cat3512 1192 .5 17 408 40.80 65 (All) Electric S12 12 Vertical 10 ,000 2 Rig Cat 3512 1192.5 17 408 40 .80 65 Cat 3408 D206 2 Vertical 10,000 1 Drawworks DITA 475 17 .5 420 42.00 24 .25 Cat 3408 D206 2 Vertical 10 ,000 2 Drawworks DITA 475 17 .5 420 42.00 24.25 Cat D206 2 Vertical 10,000 3 Mud Pump D399PC 1200 17 .5 420 42.00 24.25 Cat D206 2 Vertical 10,000 4 Mud Pump D399PC 1200 17 .5 420 42.00 24.25 D-10 Table D.3 Survey Data -Vertical Wells> 7,000 Feet (Cont.) Engine Total Total On-time # of wells Make Engine Well Engine (hours/ Survey covered Well Well Engine Engine and Model Size Drilling On-time 1,000 Average ID by survey Type Depth ID Function Model Year (HP) Days (hours) feet) Load% D206 2 Vertical 10 ,000 5 Generator Cat 3406 425 17 .5 210 21.00 100 D206 2 Vertical 10,000 6 Generator Cat3406 425 17.5 210 21.00 100 D191 3 Vertical 10,000 1 Drawworks Cat C-13 2006 410 15 360 36 .00 67.5 D191 3 Vertical 10,000 2 Drawworks Cat C-13 2006 410 15 360 36 .00 67.5 Dl91 3 Vertical 10 ,000 3 Mud Pump Cat C-15 2006 500 15 360 36.00 67 .5 D191 3 Vertical 10 ,000 4 Mud Pump Cat C-15 2006 500 15 360 36 .00 67 .5 D191 3 Vertical 10,000 5 Generator Cat C-15 2006 500 15 360 36 .00 80 D191 3 Vertical 10,000 6 Generator Cat C-15 2006 500 15 360 36 .00 80 D37 IO 1 Vertical 10,300 l Drawworks Cat 353 1981 450 13 .5 324 31.46 45 .5 D37 101 Vertical 10 ,300 2 Drawworks Cat 353 1981 450 13 .5 324 31.46 45 .5 D37 101 Vertical 10,300 3 Mud Pump Cat 379 1981 550 13 .5 324 31.46 36 .9 D37 101 Vertical 10,300 4 Mud Pump Cat 379 1981 550 13 .5 324 31.46 36 .9 D37 101 Vertical 10,300 5 Generator Cat 3406 1995 425 13.5 162 15.73 90 D37 101 Vertical 10 ,300 6 Generator Cat3406 1995 425 13.5 162 15.73 90 D-11 Table D.3 Survey Data -Vertical Wells > 7,000 Feet (Cont.) Engine Total Total On-time # of wells Make Engine Well Engine (hours/ Survey covered Well Well Engine Engine and Model Size Drilling On-time 1,000 Average ID by survey Type Depth ID Function Model Year (HP) Davs (hours) feet) Load% D1 90 3 Vertical 10 ,500 1 Drawworks Cat C-15 2005 475 30 720 68.5 7 67 .5 D190 3 Vertical 10 ,500 2 Drawworks Cat C-15 2005 475 30 720 68 .57 67.5 Dl 90 3 Vertical 10,500 3 Drawworks Cat C-15 2005 475 30 720 68.57 67 .5 D190 3 Vertical 10 ,500 4 Mud Pump Cat 399 1200 30 720 68 .57 67 .5 D190 3 Vertical 10,500 5 Mud Pump Cat 399 1200 30 720 68.57 67 .5 D190 3 Vertical 10 ,500 6 Generator Cat 3412 1000 30 360 34.29 62 .5 D190 3 Vertical 10,500 7 Generator Cat 3412 1000 30 360 34 .29 62.5 D121 12 Vertical 10 ,800 1 Drawworks Cat C-15 2004 485 32 .5 780 72 .22 27 .2 D121 12 Vertical 10 ,800 2 Drawworks Cat C-15 2004 485 32 .5 780 72.22 27 .2 Cat D121 12 Vertical 10,800 3 Mud Pump D399TA 2004 1200 32.5 780 72 .22 35 .5 Cat D121 12 Vertical 10 ,800 4 Mud Pump D 399TA 2004 1200 32.5 780 72 .22 35 .5 0121 12 Vertical 10,800 5 Generator Cat C-15 2004 485 32.5 390 36.11 35 D121 12 Vertical 10,800 6 Generator Cat C-15 2004 485 32 .5 390 36.11 35 D162 8 Vertical 11 ,500 I Drawworks Cat C-18 2005 600 25 600 52.17 60 D-12 Table D.3 Survey Data -Vertical Wells> 7,000 Feet (Cont.) Engine Total Total On-time # of wells Make Engine Well Engine (hours/ Survey covered Well Well Engine Engine and Model Size Drilling On-time 1,000 Average ID by survey Type Depth ID Function Model Year (BP) Days (hours) feet) Load 0/o Dl 62 8 Vertical 11 ,500 2 Drawworks Cat C-18 2005 600 25 600 52.17 60 D162 8 Vertical 11 ,500 3 Mud Pump Cat3508 2005 1300 25 300 26 .09 80 Dl62 8 Vertical 11 ,500 4 Mud Pump Cat 3508 2005 1300 25 300 26.09 80 Dl62 8 Vertical 11 ,500 5 Generator Cat C-15 2005 485 25 300 26 .09 60 Dl 62 8 Vertical 11,500 6 Generator Cat C-15 2005 485 25 300 26 .09 60 Detroit D215 1 Vertical 12 ,200 1 Mud Pump 2000 2008 1205 16 384 31.48 60 Detroit D215 1 Vertical 12,200 2 Mud Pump 2000 2008 1205 16 384 31.48 60 Detroit D2 15 1 Vertical 12,200 3 Drawworks Series 60 2008 470 16 384 31.48 50 Detroit D2 15 1 Vertical 12,200 4 Drawworks Series 60 2008 470 16 384 31.48 50 D etroit D215 1 Vertical 12,200 5 Generator Series 60 2008 470 16 192 15 .74 50 Detroit D215 1 Vertical 12,200 6 Generator Series 60 2008 470 16 192 15 .74 50 (All) Electric Cat D50b 16 Vertical 12 ,211 1 Rig 3512C 2006 1478 21 504 41.27 40 (All) Electric Cat D50b 16 Vertical 12 ,211 2 Rig 3512C 2006 1478 21 504 41.27 40 D-13 Table 0.3 Survey Data -Vertical Wells> 7,000 Feet (Cont.) E ngi ne Tota l T o ta l On-time # of w ells M ake E ngine Well E ngin e (h ou rs / S urv ey cove re d Well Well E ngine E ng ine an d M odel S ize Drill ing On-ti me 1,000 Av erage ID by s urvey Type Depth ID F unction Model Year (HP) Da ys (hours) feet) L oad% (A ll ) Electric Cat D 50d 6 Vertical 12 ,483 1 Rig 3512C 2006 147 8 22 528 42.30 40 (All ) E lectric Cat D 50d 6 Vertical 12 ,483 2 Rig 3512C 2006 1478 22 528 42 .30 40 (All ) Electric Cat D50g 9 Vertical 17 ,778 1 Rig 35 12C 2006 1478 55 1320 74.25 40 (All) Electric Cat D50g 9 Vertical 17,778 2 Rig 3512C 2006 147 8 55 1320 74 .25 40 (All) Electric Cat D50e 10 Vertical 17 ,970 I Rig 3512C 2006 1478 84 2016 112 .19 40 (A ll ) E lectric Cat D 50e 10 Vertical 17 ,970 2 Rig 3512C 2006 1478 84 20 16 112 .19 40 D-14 Appendix E -Total Drilling Depth by County by Model Rig Well Type Category (see file "TCEQ Drilling Rig Engine Report_Appendices.xls") Table F.1 Emission Factors for Vertical Wells> 7,000 Feet Emission Factor (ton/1,000 feet) Pollutant 2002 2005 2008 2009 2010 2011 2012 2103 2014 201S 2016 2017 2018 2019 2020 2021 co 2.07E-O l 2 .06E-Ol l.50E -Ol l.49E-Ol l.49E-Ol l.45E-O l l.45E-Ol l.l lE-01 l.l lE-01 l.ll E-01 l.lOE-01 9 .82E-02 6 .44E-02 6.42E-02 6.41E-02 3.55E-02 NOx 4 .6 1E-Ol 4.60E-Ol 4 .15E-Ol 4 .1 4E-Ol 4.l l E-01 3.88E-Ol 3.88E-O l 3.62E-Ol 3.62E-O l 3.61E-Ol 3.42E-O I 3.38E-O l 2 .99E-O l 2 .98E-OI 2 .98E-Ol 2.52E-O l PMIO 4 03E-02 4.02E-02 2.32E -02 2.32E-02 2.27E-02 2.27E-02 2.27E-02 l.31E-02 I JOE-02 l .3 0E-02 l .2 7 E-02 1.2 0E-02 8.29E-03 8.27E-03 8.25E-03 4 .3 I E-03 PM2.5 3.9 1E-02 3.90E-02 2.25E-02 2 .25E-02 2.20E-02 2 .20E-02 2.20E-02 l.27E-02 l.26E-02 l.26E-02 l .2 4E-02 l.16E-02 8.04E-03 8.02E-03 8.00E-03 4 .18E-03 S02 5.92E-02 5.92E-02 6.25E-03 6.25E-03 2.97E-04 2 .97E-04 2.97E-04 2.73E-04 2.73E-04 2.73E-04 2 .73E-04 2.73E-04 2 .73E-04 2.73E-04 2.73E-04 2.58E-04 TOG 5.61 E-02 5.59E-02 3.85E-02 3 .85E-02 3.82E-02 3 .74E-02 3 .73E-02 3.I I E-02 3.l lE-02 3.l lE-02 3.IOE-02 2.82E-02 2 .0 9E-02 2.08E-02 2.08E-02 l .29E-02 voe 5.52E-02 5.SOE-02 3.79E-02 3.79E-02 3.76E-02 3.68E-02 3.67E-02 3.07E-02 3.06E-02 3.06E-02 3.05E-02 2.78E-02 2.05E-02 2.05E-02 2.05E-02 l.27E-02 Formaldehyde 8.25E-03 8.22E-03 5.67£-03 5.66£-03 5.62E-03 5.50E-03 5.49E-03 4.58E-03 4.58E-03 4.57£-03 4.56E-03 4 . I 5E-03 3.07E-03 3.07E-03 3.06E-03 I .89E-03 Methanol l.68E-05 I .6 8E-05 l.16E-05 l.1 5E-05 1. I 5E-05 l .12 E-05 1.1 2E-05 9.34E-06 9 .33E-06 9.32E-06 9.3 I E-06 8.47E-06 6.26E-06 6.25E-06 6.24E-06 3.86E-06 Benzene l.1 2E-03 l.12E-03 7.70E-04 7.69E-04 7.63E-04 7.48E-04 7.46E-04 6.23E-04 6.22E-04 6.2 1E-04 6.20E-04 5.65£-04 4.17E-04 4 .17 E-04 4.16E-04 2.57E-04 Aceta ld ehvde 4 .12E-03 4 .l l E-03 2.83E-03 2.83E-03 2.81 E-03 2.75E-03 2.74E-03 2.29E-03 2.29E-03 2.28E-03 2.28E-03 2.08E-03 I .53E-03 l.53E-03 l .53E-03 9 .45E-04 Naohthalene 5.05E-05 5.03E-05 3.47E-05 3.46E-05 3.44E-05 3.36E-05 3.36 E-05 2.80E-05 2.SOE-05 2 .80£-05 2 .79E-05 2 .54E-05 l .88E-05 l.88E-05 l.87E-05 l.16E-05 o-xvlene 1.9 1 E-04 l.90E-04 l .31E-04 l.31E-04 l .30E-04 l.27E-04 l.27E-04 l .06E-04 1.06E-04 1.06E-04 l .05E-04 9.60E-05 7.IOE-05 7.08E-05 7 .07E-05 4 .3 7E-05 Cumene 1.12 E-05 l.12E-05 7.70E-06 7.69E-06 7 .63 E-06 7.48E-06 7.46E-06 6.23E -06 6.22E-06 6.21E -06 6.20E-06 5 .65E-06 4 .17 E-06 4.17E-06 4 .16E-06 2.57E-06 Ethvlbenzene l.74E-04 l.73E-04 l.1 9E-04 l.1 9E-04 l.18E-04 l.1 6E-04 l.16E-04 9.66E-05 9.64E-05 9.63E-05 9.62E-0 5 8.75E-05 6.47E-05 6.46E-0 5 6.45E-05 3.99E-05 Stvrene 3.36E-05 3.35E-05 2.3 1 E-05 2.3 1 E-0 5 2 .29E-05 2.24E-05 2 .2 4E-05 l.87E-05 l .87E-05 1.86E-05 1.86E-05 l .69E-05 l .25E-05 1.25E-05 1.25E-05 7.72E-06 o-xv lene 5.61E-05 5.59E-05 3.85E-05 3.85E-05 3.82E-05 3.74E-05 3.73E-05 3.I I E-05 3.l lE-05 3.IIE-05 3.IO E-05 2.82E-05 2.09E-05 2.08E-05 2 .08E-05 I .29E-05 1,3 -butadiene l .07E-04 l.06E-04 7.32E-05 7 .31 E-05 7.25E-05 7. IO E-05 7.09E-05 5.92E-05 5.9 1E-05 5.9 0 E-05 5.89E-05 5.36E-05 3.97E-05 3.96E-05 3.95E-05 2 .44 E-05 m-xvlene 3.42E-04 3.41E-04 2.35E-04 2.35E-04 2.33E-04 2.28E-04 2.28E-04 l .90 E-04 l.90E-04 l .8 9E-04 l .89E-04 1.72E-04 l .27E-04 l.27E-04 1.27£-04 7 .85E-05 Toluene 8.24E-04 8.2 1E-04 5.66E-04 5.65E-04 5.6 1E-04 5.49E-04 5.49E-04 4.58E-04 4.57E-04 4 .57E-04 4.56E-04 4.15E-04 3.07E-04 3.06E-04 3.06E-04 I .89E-04 n-hexane 8.97E-05 8.94E-05 6 .16E-05 6. ISE-05 6.l l E-05 5.98E-05 5.97E-05 4 .98E-05 4.98E-05 4 .97E-05 4.96E-05 4.52E-05 3.34E-05 3.33E-05 3.33E-05 2 .0 6E-05 Propion ald e hyde 5.44E-04 5.42E-04 3.74E-04 3.73E-04 3 .70E-04 3.63E-04 3.62E-04 3.02E-04 3.02E-04 3.0 IE-04 3.0 I E-04 2.74E-04 2.02E-04 2.02E-04 2.02E-04 l .25E-04 2,2 ,4- trime thvloe ntane l .68E-04 l .68E-04 1.1 6E-04 l. l SE-04 l .lS E-04 1.12 E-04 1.12 E-04 9 .3 4E-05 9.33E-05 9.32E -0 5 9.3 1 E-05 8.47E-05 6.26E-05 6 .25E-05 6.24E-05 3.86E-05 Lead l.69E-06 l .69E-06 9 .74E-0 7 9.73E-07 9.52E-07 9.55E-07 9 .53E-07 5.49E-0 7 5.47E-07 5.46E-07 5.35E-07 5.04E-07 3.48E-07 3.47E-07 3.46E-07 1.81 E-0 7 Manganese l.61E-06 l.61E-06 9 .28E-07 9.26E-07 9.06E-07 9.09E-07 9.07E-07 5 .22E-07 5 .2 1E-07 5.20E-07 5.IOE-07 4 .8 0E-07 3.32E-07 3.3 IE-07 3.30E-07 l.73E-07 Mercury 1.21 E-06 1.2 1 E-06 6 .96E-07 6.95E-07 6.80E-07 6.82E-07 6.8 1E-07 3.92E-07 3.9 1E-07 3 .90E-07 3 .82E-07 3 .60E-07 2.49E-07 2.48E-07 2.47E-07 l.29E-07 Nickel 7.66E-07 7.64E-07 4.41E-07 4.40E-07 4 .3 IE-07 4.32E-07 4 .3 1E-07 2.48E-07 2.48E-07 2.47E-07 2.42E-07 2 .28E-07 l .58E-07 l .57E-07 l .57E-07 8.19E-08 Antimony l.45 E-06 I .45E-06 8.35E-07 8.34E-07 8.1 6E-07 8.1 8E-07 8.l 7E -07 4.70E-07 4.69E-07 4.68E-07 4 .59E-07 4 .32E-07 2 .98E-07 2.98E-07 2 .97E-07 l.SSE-07 Arsenic 2.02E-07 2.0IE-07 1.1 6E-07 1.16E-07 l.13E-07 l.1 4E-07 l.1 3E-07 6 .5 3E-08 6 .52E-08 6.SOE -0 8 6.37E-08 6 .00E-08 4 .IS E-08 4 .13E-08 4 .12 E-08 2 .16E-08 Cadmium l.6 1E-06 l.61E-06 9 .28E-07 9.26E-07 9.06E-07 9.09E-07 9.07E-07 5.22E-07 5.21E-07 5.20E-07 5.IOE-07 4 .8 0E-07 3.32E-07 3.3 I E-07 3 .30E-07 l.73E-07 F-1 Table F.1 Emission Factors for Vertical Wells> 7,000 Feet (Cont.) Emission Factor (too/1,000 feet) PoUutant 2002 2005 2008 2009 2010 2011 2012 2103 2014 2015 2016 2017 2018 2019 2020 2021 Coba lt 4.44E-07 4 .42E-07 2 .55E-07 2.55E-07 2 .49E-07 2 .50E-07 2.SOE-07 l.44E-07 l.43E-07 l.43E-07 l.40E-07 l .32E-07 9 .l2E-08 9 09E-08 9.07E-08 4 .74E-08 Phosphorous 5 .1 2E-06 5 .IOE-06 2 .95E-06 2 .94E-06 2.88E-06 2 .89E -06 2.88E-0 6 l .66E-06 l.65E-06 l .65E-06 l .62E-06 l .52E-06 I.OSE-06 1.0S E-06 I.OSE-06 5.48E-07 Selenium 4.03E-07 4 .02E-07 2 .32E-07 2.32E-07 2 .27E-07 2.27E-07 2 .27E-07 l.31E-07 l .30E-07 l.30E-07 l.27E-07 l .20E-07 8.29E-08 8.27E-08 8.25E-08 4 .3 IE-0 8 Chlorine l .39E-05 l .38E-05 7 .98E-06 7.97E-06 7.SOE-06 7 .82E-06 7.SOE-06 4.49E-06 4.48E-06 4.47E-06 4.38E-06 4 .13E-06 2 .85E-06 2.84E-06 2.84E-06 l.48E-06 Table F.2 Emission Factors for Vertical Wells> 7,000 Feet Emission Factor (too/1,000 feet) PoUutant 2002 2005 2008 2009 2010 2011 2012 2103 2014 2015 2016 2017 2018 2019 2020 2021 co 6. I 7E-02 4 .13E-02 3 .1 6E-02 3.09E-02 3.01 E-02 2 .95E-02 2 .93E-02 2 .86E-02 2.78E-02 2.23E-02 2.21E-02 l .39E-02 4 .37E-03 4 .2 I E-03 4 .0SE-03 3 .9 1E-03 NOx 2.21E-OI l.82E-OI 1.49E-Ol l.47E-OI l.33E-O I l.30E-OI 1.12E-OI 8.76E-02 8.28E -02 7.46E-02 7.41E-02 6.20E-02 402E-02 3.97E-02 2 .76E-02 l .36E-02 PMIO 9 .25E-03 6.68E-03 4.46E-03 4.43E-03 4 .00E-03 3.94E-03 3.68E-03 3.37E-03 3.32E-03 2 .66E-03 2.64E-03 l .67E-03 5.39E-04 5.16E-04 4 .94E-04 4 .75E-04 PM2.5 8 .97E-03 6.48E-03 4.33E-03 4.30E-03 3.88E-03 3 .8 3E-03 3 .57E-03 3.27E-03 3 .22E-03 2.58E-03 2 .56E-03 I .62E-03 5.23E-04 5.00E-04 4.79E-04 4 .60E-04 S02 3.06E-02 3 .06E-02 3 .23E-03 3.23E-03 I .53E -04 I .53E-04 l.53E-04 1.53E-04 I .53E -04 1.43E-04 ! .43E-04 1.28E-04 I.I I E-04 I.I I E-04 I.I I E-04 I.I IE-04 TOG 1.43E-02 7.54E-03 6 .72E-03 6.63E-03 6.53E-03 6.44E-03 6 .39E-03 6 .30E-03 6.21 E-03 5.85E-03 5.S IE-03 5.28E-03 4 .68E-03 4.64E-03 4 .6 1 E-03 4 .58E-03 voe l.4 I E-02 7.42E-03 6 .62E-03 6.53E-03 6.43E-03 6.34E-03 6.29E-03 6.20E-03 6.12E-03 5 .76E-03 5.72E-03 5 .20E-03 4.60E-03 4 .57E-03 4.53E-03 4 .51 E-03 Formald ehyde 2.1 I E-03 1.l lE-03 9 .89E-04 9.75E-04 9.60E-04 9.48E-04 9.39E-04 9 .26E-04 9.14E-04 8.60E-04 8.54E-04 7.77E-04 6.88E-04 6.83E-04 6.78E-04 6 .74E-04 Methanol 4.30E-06 2.26E-06 2.02E-06 l.99E-06 l.96E-06 1.93E-06 l.92E-06 1.89E-06 1.86E-06 1.75E-06 1.74E-06 ! .58E-06 1.40E-06 1.39E-06 1.38E-06 1.37E-06 Benzene 2.87E-04 l.51 E-04 l .34E-04 l.33E-04 l.31E-04 l .29E-04 l.28E-04 1.26E-04 l .2 4E-04 l.17E-04 l.16E-04 l .06E-04 9 .3 5E-05 9.28E-05 9 .22E-05 9.16E-05 Aceta ld ehvde 1.0SE-03 5.54E -04 4 .94E-04 4 .8 7E-04 4 .SOE-04 4 .74E-04 4.69E-04 4 .63E-04 4 .57E-04 4 .3 0E-04 4.27E-04 3.88E-04 3.44E-04 3.4 1E-04 3.39E-04 3.37E-04 Naphthalene l.29E-05 6 .78E-06 6 .05E-06 5.97E-06 5.88E-06 5.SOE -06 5.75E -06 5.67E-06 5.59E-06 5.26E-06 5.23E-06 4 .75E-06 4 .21E-06 4 .18 E-06 4.ISE-06 4.12E-06 o -xvlene 4.87E-05 2.56E -05 2 .29E-05 2 .25E-05 2.22E-05 2.19E-05 2 .1 7E-05 2.14E-05 2.I IE-05 l .99E-05 l.97E-05 l .SOE-05 l.59E-05 l.58E-05 l .57E-05 l .56E-05 Cumene 2 .87E-06 l.51E-06 l .3 4E-06 l.33E-06 l.3 IE-06 l.29E-06 I .28E-06 l .26E-06 l.24E-06 I.I 7E-06 1. l 6E-06 l.06E-06 9.35E-07 9 .2 8E-07 9.22E-07 9.!6E-07 Eth y l benzene 4.44E-05 2 .34E-0 5 2.08E-05 2 .0 SE -05 2.02E-05 2.00E-05 1.98E-0 5 l.95E-05 l.93E-05 l.8 IE-05 I .SOE-05 1.64E-05 1.45E-05 1.44E-05 1.43E-05 l.42E-05 Stvrene 8.60E-06 4.52E-06 4.03E-06 3 .98E-06 3 .92E-06 3.87E-06 3.83E-06 3.78E-06 3.73E-06 3.51 E-06 3.48E-06 3 .1 7E-06 2.81E-06 2 .78E-06 2.76E-06 2.75E-06 p-xvlene 1.4 3E-05 7 .54E-06 6 .72E-06 6.63E-06 6.53E-06 6.44E-06 6.39E-06 6 .30E-06 6.2 1E-06 5.85E-06 5.81 E-06 5.28E-06 4 .68E-06 4.64E-06 4 .6 1 E-06 4 .58E-06 1,3-butadi ene 2 .72E-05 l .43E-05 l .28E-05 1.26E-05 l.24E-05 1.22E-05 l.21E-05 l.20E-05 1.18E-05 1.I IE-05 I. IO E-05 1.00E-05 8.89E-06 8.82E-06 8.75E-06 8.?0E-06 m-xylene 8.74E-05 4.60E-05 4 . IO E-05 4.04E-05 3.98E-05 3.93E-05 3.89E-05 3.84E-05 3 .79E-05 3 .57E-05 3.54E-05 3.22E-05 2.85E-05 2.83E-05 2 .S I E-05 2.79E-05 Toluene 2 .I IE-04 I.I I E-04 9.89E-05 9 .74E-05 9.60E-05 9.47E-05 9 .39E-05 9 .26E-05 9.13E-05 8.60E -05 8 .54E-05 7.76E-05 6 .87E-05 6.82E-05 6.77E-05 6 .73E-05 n-hexane 2.29E-05 l .2 1E-05 1.0SE-05 !.06E-05 l.04E-05 l.03E-05 I .02E-05 I .OIE-05 9.94E-06 9 .36E-06 9 .2 9E-06 8.45E-06 7.48E-06 7.43E-06 7.37E-06 7.33E-06 F-2 Table F.2 Emission Factors for Vertical Wells> 7,000 Feet (Cont.) Emission Factor (ton/1 ,000 feet) Pollutant 2002 2005 2008 2009 2010 2011 2012 2103 2014 2015 2016 2017 2018 2019 2020 2021 Propionaldehyde l .39E-04 7 .3 IE-05 6.52E-05 . 6.43E-05 6.33E-05 6.25E-05 6.19E-OS 6 .l l E-05 6 .03E-05 5.67E-OS 5 .63E-OS 5 .1 2E-05 4 .54E-OS 4 .SOE -05 4.47E-05 4 .44E-OS 2,2,4- trimethylpentane 4.30E-OS 2 .26E-05 2 .02E-OS 1.99E-OS l.96E-05 l .93E-05 I .92E-05 l.89E-05 l.86E-05 l.75E-05 l .74E-05 l .58E-05 l.40E-05 l.39E-O S l .38E-05 l.37E-OS Lead 3 .89E-07 2 .8IE-07 l .88E-07 I.86E-07 I .68E-07 l .66E-07 l.SSE-07 l .42E-07 l .39E-0 7 l.12E-07 l.l IE-07 7 .00E-08 2 .26E-08 2 . I?E-08 2 .0?E-08 l.99E-08 Manganese 3.70E-07 2.67E-07 1.79E-07 l.77E-07 I .60E-07 I .58E-07 l.47E-07 I .35E-07 I .33E-07 l.O?E-07 l.06E-07 6.66E-08 2 .1 6E-08 2.06E-08 l.97E-08 l .90E-08 Mercury 2.78E-07 2.00E-07 l .34E-07 I.33E-07 l .20E-07 l.1 8E-07 l.lOE-07 I.OIE-07 9.96E-08 7 .99E-08 7 .91E-08 5.00E-08 l.62E-08 I .55E-08 1.48E-08 l.42E-08 Nickel l.76E-07 l.27E-07 8.48E-08 8.4IE-08 7.60E-08 7.49E-08 6.99E-08 6.4 IE-08 6 .31E-08 5.06E-08 5.0IE-08 3.16E-08 l.02E-08 9.80E-09 9.38E-09 9.02E-09 Antimony 3.33E-07 2.40E-07 l .6 1E-07 l.59E-07 I .44E-07 1.42E-07 l .32E-07 l.21E-07 I .2 0E-07 9 .5 9E-08 9.SOE-08 6.00E-08 I .94E-08 I.86E-08 l.78E-08 l.7 1E-08 Arsenic 4.63E-08 3.34E-08 2 .23E-0 8 2 .2 1 E-0 8 2.00E-08 l .9 7E-08 l .84E-08 l .69E-08 l .66E-08 l .33E-08 l.32E-08 8.33E-09 2.69E-09 2.58E-09 2.47E-09 2 .37E-09 Cadmium 3 .70E-07 2.67E-07 l.79E-07 l.77E-0 7 l .60E-07 l.58E-07 1.47E-07 l .35E-07 l.33E-07 l.07E-07 l.06E-07 6 .66E-08 2. l6E-08 2.06E-08 l.97E-08 l .90E-08 Cobalt l.02E-07 7.35E-08 4 .9 1E-08 4 .87E-08 4.40E-08 4.34E-08 4 .0SE-0 8 3 .7 1 E-08 3 .65E-08 2 .93E-08 2.90E-08 I .83E-08 5.93E-09 5 .67E-09 5.43E-09 5.22E-09 Phos ohorous l.1 7E-06 8.4 8E-07 5.67E-07 5.62E-07 5.08E-07 5.01 E-07 4.67E-07 4.28E-07 4.22E-07 3.38E-07 3.35E-07 2. I 2E-07 6.84E-08 6.55E-08 6.27E-0 8 6 .03E-08 Selen ium 9 .25E-08 6.68E-08 4.46E-08 4.43E-08 4.00E-08 3 .94E-08 3.68E-08 3.37E-08 3 .32E-08 2 .66E-08 2.64E-0 8 I .67E-08 5.39E-09 5. l 6E-09 4 .94E-09 4.75E-09 Chl o rine 3.18E-06 2 .30E-06 l .5 4E-06 l.52E-06 l.38E-06 l.36E-06 I.27E-06 l.16E-06 l.14E-06 9.I?E -07 9.07E-07 5 .73E-07 l .85E-07 l.77E-07 l.?O E-07 I.63E-07 Table F.3 Emission Factors for Directional/Horizontal Wells Emission Factor (ton/1,000 feet) Pollutant 2002 2005 2008 2009 2010 2011 2012 2103 2014 2015 2016 2017 2018 2019 2020 2021 co 1.27E-OI l.09E-OI 7 .77E-02 7 .75E-02 7.72E-02 6.47E-02 6 .45E-02 6.40E-02 6 .38E-02 6 .36E-02 6 .07E-02 2 .66E-02 2 .6 1E-02 2.59E-02 2.58E-02 I .34E-02 NOx 5.20E-OI 5 .22E-OI 4.IIE-01 4.IIE-01 4.00E-01 3.55E-OI 3.37E-O I 2 .5 2E-Ol 2.49E-O I 2.43E-O I 2.24E-OI 2.0 I E-0 1 2 .00E-01 l.99E-OI l.99E-OI I.80E-O I PMIO 2.43E-02 l.97E-02 l.12 E-02 l.1 2E-02 l.06E-02 9.28E-03 9.38E-03 6.75E-03 6.74E-03 6.75E-03 6 .65E-03 3.92E-03 3 .90E-0 3 3.88E-03 3.86E-03 2.?0E-03 PM2.5 2.36E-02 1.91 E-02 l.09E-02 l.08E-02 l.03E-02 9 .00E-03 9.IOE-03 6 .SSE -03 6.54E-03 6 .SSE-03 6.45E-03 3.81E-03 3.79E-03 3.76E-03 3.74E-03 2.62E-03 S02 7.36E-02 7 .36E-02 7 .77E-03 7 .77E-03 3.69E-04 3.69E-04 3 .69E-04 3 .00E-04 3 .00E-04 3 .00E-04 3.00E-04 2 .83E-04 2 .8 3E-04 2 .83E-04 2.83E-04 2 .76E-04 TOG 3.95E-02 3.5 1 E-02 2 .25E-02 2.2SE-02 2 .I ?E-02 l .64E-02 l .53E-02 2.08E-02 2 .06E-02 2 .03E-02 2.00E-02 l .34E-02 l.34E-02 l.33E-02 l.3 3E-02 l.l l E-02 voe 3.89E-02 3.46E-02 2 .22E-02 2 .2 1 E-02 2.14E-02 l.62E-02 l.SOE-02 2.0SE-02 2 .03E-02 2.00E-02 1.97E-02 l.32E-02 l.32E-02 l.3IE-02 1.3 IE-02 l.09E-02 Fonnaldehvde 5.8 1 E-03 5.17E-03 3.3 1 E-03 3.30E-03 3 .20E-03 2 .42E-03 2.25E-03 3.07E-03 3 .04E-03 2 .98E-03 2 .95E-03 l .98E-03 I .97E-0 3 l.96E-03 l.96E-03 l.63E-03 Methanol l. I 8E-05 l.OS E-05 6.75E-06 6.74E-06 6.52E-06 4 .93E-06 4 .58E-06 6 .25E-06 6 .1 9E-06 6.08E-06 6.0 IE-06 4 .03E-0 6 4 .01 E-0 6 4 .00E-06 3.99E-06 3.33E-06 Benzene 7.90E-04 7.03E-04 4 .SOE-04 4.49E-04 4 .35E-04 3.29E-04 3.0SE-04 4 .l ?E-04 4 .13E-04 4 .06E-04 4 .01 E-04 2 .69E-04 2.68E-04 2 .67 E-04 2 .66E-04 2 .22E-04 Acetaldehvde 2 .90E-03 2 .58E-03 1.65E-03 l .65E-03 l .60E-03 1.21E-03 l.1 2E-03 I .53E-03 1.52E-03 I .49E-03 1.47E-03 9.88E-04 9 .84E-04 9 .8 1 E-04 9 .79E-04 8 .16 E-04 Na phtha lene 3 .55E-05 3.16E-05 2 .03E-05 2.02E-05 l .96E-05 l.48E-05 l.37E-05 I .88E-05 l .86E-05 I .83E-05 I .80E-0 5 1.2 1 E-05 l .20E-05 I .20E-05 I .20E-05 9 .99E-06 F-3 Table F.3 Emission Factors for Directional/Horizontal Wells (Cont.) Emission Factor (ton/1,000 feeO Pollutant 2002 2005 2008 2009 2010 2011 2012 2103 2014 201S 2016 2017 2018 2019 2020 2021 o-xvlene I .34E-04 1.19E-04 7 .66E-05 7 .63E-05 7.39E -0 5 5.59E-05 5.19E-05 7.09E-05 7.02E-05 6 .90E-05 6 .82E-05 4 .57E-05 4 .55E-05 4 .54E-05 4 .53E-05 3.78E-05 Cumene 7.90E-06 7 .03E-06 4 .50E-06 4.49E-06 4 .35E-06 3 .29E-06 3 .05E-06 4 .17 E-06 4 .13E-0 6 4 .0 6E -06 4 .0IE-06 2 .69E-06 2 .68E-06 2 .67E-06 2 .66E-06 2 .22E-06 Eth vlbenze ne 1.22E-04 l .09E-04 6.98E-05 6 .96E -0 5 6.74E-05 5 09E-05 4.73E-05 6.46E-05 6 .40E-05 6 .29E-05 6 .22E-05 4 .17E-05 4.15E-05 4 .14E-05 4 .13 E-05 3.44E-05 Stvrene 2 .37E-05 2 .I I E-05 l.35E-05 l .35E-05 l .30E-05 9 .86E-06 9.16E-06 l.25E-05 l .24E-05 l .22E-05 1.20E-0 5 8.07E-0 6 8.03E-06 8 .0IE-06 7.99E-06 6 .66E -06 o-xvlene 3 .95E-05 3.5 I E-05 2 .25E-0 5 2 .25E-0 5 2 . I 7E-05 l .64E-0 5 l.5 3E-05 2 .08E-05 2 .06E-05 2 .03E-05 2.00E-05 l.34E-05 l .34E-05 l.33E-05 l .33E-05 I.I I E-05 1,3-butadiene 7.50E-05 6.68E -05 4.28E-05 4.27E-05 4.13E-05 3 . I 2E-05 2.90E-05 3 .96E-05 3 .92E-05 3.85E-05 3.81 E-05 2 .55£-05 2 .54E-05 2.54E-05 2.53E-05 2 .I I E-05 m-xvlene 2.4 1E-04 2 .14 E-04 I .37E-04 1.37E-04 l .33E-04 I .OOE-04 9 .3 1 E-05 1.27£-04 l .26E-04 l.24E-04 l .22E-04 8.20E-05 8.16£-05 8.14E -05 8.12E-05 6.77E-05 Toluene 5.80E-04 5.17E-04 3 .3 1 E-04 3 .30E-04 3.20E-04 2.42E-04 2 .24£-04 3 .06£-04 3.03E-04 2.98E-04 2 .95£-04 1.98E-04 1.9 7£-04 I .96E-04 l .96E-04 l.63E-04 n-hexa ne 6 .32£-05 5.62£-05 3 .60E-05 3.59E-05 3.48£-05 2.63E-05 2 .44£-0 5 3.33E-05 3.30£-05 3 .25E-05 3.2 1£-05 2 .15£-0 5 2 .14£-05 2.14E-05 2 .13E-05 l.78E-05 Prooi o na ldehvde 3 .83E-04 3.41E-04 2.18E-04 2.18£-04 2 .I I E-04 l .59E-04 I .48E-04 2.02E-04 2.00E -04 l .97E-04 l.94E-04 1.30E-04 1.3 0£-04 I .29E-04 1.29E-04 1.08E-04 2,2,4- trimethvloentane l .18E-04 l.05E-04 6 .75E-05 6 .74E-05 6.52E-05 4.93E-05 4 .58E-0 5 6.25E-05 6.19E-05 6 .08E-05 6 .0lE-05 4 .03£-05 4.01 E-05 4 .00E-05 3.99E-05 3 .33 E-05 Lead l .02E-06 8.28E-07 4.71E-07 4.70E-07 4.46E-07 3 .90E-07 3.94E-07 2.84E-07 2 .83E-07 2.84E -07 2.79E-0 7 l.65E-07 I .64E-07 l.63E-07 l.62E-07 l.14 E-07 Man~a nese 9 .73£-07 7.89£-07 4.49£-07 4.47£-07 4 .25£-07 3.71 E-07 3 .75£-07 2 .70£-07 2 .70£-07 2.70E-07 2 .66E-07 1.57£-07 l.56E-07 I .55E-07 1.54£-07 I.O SE-07 Mercury 7.30£-07 5.91 E-07 3.37£-07 3 .35£-07 3. 19E-07 2 .78£-07 2 .8 1E-07 2 .03£-07 2 .02E-07 2 .03£-07 1.99£-07 1.18£-07 1.1 7£-07 l.1 6E-07 1.16£-07 8.1 I E-08 Ni cke l 4 .62E-07 3.75E-07 2 .13E-07 2.12£-07 2.02E-07 l.76E-07 1.78£-07 l.28E-07 l .28E-07 l.28E-07 1.26£-07 7.45E-08 7.42£-08 7 .37£-0 8 7.33£-08 5.14£-08 Antimony 8 .76£-07 7.IOE-07 4 .04£-07 4 .02E-07 3.82E-07 3.34E-07 3.38£-07 2.43E-07 2.43£-07 2.43E-0 7 2 .39£-07 1.41 £-07 1.41£-07 1.40£-07 1.39£-07 9 .74£-08 Arsenic l.22E-07 9 .86£-08 5.6 I E-08 5.59£-0 8 5 .3 I E-08 4 .64£-0 8 4 .69£-08 3.38£-0 8 3 .37E-08 3.38E-08 3.32E-0 8 1.96£-08 1.95£-08 I .94E-08 1.93£-08 1.35£-08 Cadmium 9.73£-07 7 .89£-07 4.49£-07 4.47£-07 4.25£-07 3.71£-07 3 .75£-07 2.70£-07 2 .70£-07 2.70£-07 2.66£-07 1.57£-07 l .56E-07 1.55£-07 I.54E-07 l.08E-07 Cobalt 2 .68E-07 2 . I 7E-07 1.23E-07 1.23E-07 1.17 £-07 l .02E-07 l.03 E-07 7.43E-08 7.41 E-08 7.43E -08 7.3 1 E-08 4 .32E-0 8 4.29E-08 4 .27E-08 4 .24E-08 2.98E -0 8 Phosohorous 3 .09 E-06 2 .50E-06 l .43E-06 I .42E-06 1.35£-06 1.18E-06 l .19E-06 8.57E-07 8 .56E-07 8 .58E-07 8.44E-07 4.98E-07 4 .96E-07 4 .93E-07 4 .90E-07 3 .44£-07 Selenium 2.43E-07 1.97£-07 1.1 2£-07 1.12E-07 I .06E-07 9 .28E-08 9 .38E-08 6 .75E-08 6 .74£-08 6 .75£-08 6.65£-08 3 .92£-08 3 .90£-08 3.88£-08 3 .86E-08 2 .70 E-08 C hlorine 8.37E-06 6 .78E-06 3 .86E-06 3.85E-06 3.65E-06 3. I 9E-06 3.23E-0 6 2 .32E-06 2 .32E-06 2 .32E-06 2 .29E-06 l .35E-06 I .34 E-06 1.33£-0 6 1.33£-06 9 .31 E-07 F-4 Appendix G -Annual and OSD County-Level Emission Estimates (Criteria Pollutants and HAPs, 2002, 2005, 2008-2021) (see file "TCEQ Drilling Rig Engine Report_Appendices.xls") TOTAL Infrared Imaging SEP -Part I Draft Work Plan TOT AL Petrochemicals, Inc. TOT AL Refinery Port Arthur, Texas Prepared by: Sage Environmental Consulting, LP July 2007 SAGE ENVIRONMENTAL CONSULTING "Friendly Service, No Surprises!" TABLE OF CONTENTS Section 1 Introduction and Background ............................................................................................. 1-1 Section 2 Project Resources .................................................................. Error! Bookmark not defined. 2 .1 ProjectTeam ................................................................................................................... 2-l 2.2 Training ............................................................................. Error! Bookmark not defined. 2 .3 Equipment. ........................................................................ Error! Bookmark not defined. 2.2.1 Ta sk 1 -Preparation and Training ....................... Error! Bookmark not defined. 2.2 .2 Task 2 -Part I oflnfrared Imaging SEP .............. Error! Bookmark not defined. 2.2.3 Task 3 -Part II oflnfrared Imaging SEP ............. Error! Bookmark not defined. 2 .2.4 Task 4 -Infrared Imaging SEP Report ................ Error! Bookmark not defined. Section 3 Part I : Imaging Plan .............................................................. Error! Bookmark not defined. 3 .1 Imaging Every Regulated Component... ........................... Error! Bookmark not defined. 3 .2 Method 21 Monitoring .................................................................................................... 3-3 3 .3 Part I Schedule ................................................................................................................ 3-3 Section 4 Preliminary Part II Work Plan ........................................................................................... .4-4 Section 5 Reporting and Documentation ............................................................................................ 5-1 LIST OF APPENDICES Consent Decree Scope of Work Sage LDAR Qualifications Statement FLIR ThermaCAM® GasFindIR Camera Appendix A Appendix B Appendix C Appendix D Appendix E Additional M21 Monitoring Via Unit Schedule Coordination Alternate Monitoring Plans Sage Environmental Co ns ulting J uly 2007 TOTA L Petrochemicals, In c. TOTAL Infrared Im aging Part I Work Plan Draft Internal Ve rs ion SECTION 1 INTRODUCTION AND BACKGROUND TOT AL Petrochemicals, Inc . (TOT AL) has negotiated a Consent Decree with the US EPA/DOJ. One element of that Consent Decree is to implement a Supplemental Environmental Project titled "Passive, Infrared Imaging of Refinery Equipment and Components and Follow-Up Actions " (Infrared Imaging SEP). This is a work plan developed by TOTAL and Sage Environmental Consulting, LP (Sage) to describe the approach planned for the Infrared Imaging SEP. The scope of work for the Infrared Imaging SEP , as negotiated in the Consent Decree, has been attached as Appendix A of this work plan. The scope of work is divided into two parts . Part I involves infrared imaging of every regulated component, except for difficult-to- monitor and unsafe-to-monitor components. In addition to the imaging work, Method 21 monitoring is required for a total of 1000 components , which should consist of up to 500 components where leaks were detected by infrared imaging and the balance where infrared imaging did not detect a leak. The Consent Decree requires that Part I be completed within six months after entry of the Consent Decree. This work plan provides details for the planned execution of Part I of the Infrared Imaging SEP . Part II of the Infrared Imaging SEP requires imaging of every component in VOC or HAP service . The Consent Decree requires that Part II be completed within two years after entry of the Consent Decree . This work plan provides a preliminary plan for Part II for completeness , but a final work plan for Part II will be developed at completion of Part I. The remainder of this document presents the work plan in the following major sections: • Project resources o Project team o Training o Equipment • Imaging plan • Preliminary plan for Part II • Reporting and documentation. Sage En vironm ental Co nsulting July 2007 1-1 TOTA L P etrochemicals, In c. TOTAL Infrared Imag ing Part I Work Plan Draft Internal Version SECTI O N 2 PROJECT RESOURCES TOT AL has provided for the resources needed to complete the Infrared Imaging SEP Part I work, including skilled personnel, training, and state-of-the-art equipment. 2.1 Project Team This subsection presents the personnel selected for the project team. TOT AL has selected Sage to provide the primary imaging staff to carry out the Infrared Imaging SEP, in coordination with TOTAL Port Arthur Refinery environmental staff. See Appendix B for additional details on Sage staff and their LOAR experience . The following personnel and their roles are planned for this work: Person Robert Fisher Brett Kriley Scott Muller David Ranum Buzz Harris VinhDo Organization TOT AL Port Arthur Sage Beaumont Sage Austin Sage Austin Sage Austin Sage Austin Role TOTAL Project Manager Client Service Manager Sage President and Agency Liaison Sage Project Manager and Imaging Leader Technical Consultant Imaging Team Member Brett Kriley will serve as the Client Service Manager for this project. Brett will not be involved in the daily work on the infrared imaging project, but he will review work products and plans and be available as a resource to TOTAL to help resolve any problems which might arise. Scott Muller, the President of Sage, will act as the Corporate Sponsor for this work. Scott will also serve as a liaison to TCEQ staff in Austin to encourage their participation and to shepherd any requests for waivers that might be needed. David Ranum will serve as the Sage Project Manager and the field leader of the imaging w ork. David has worked in the fugitive emissions area since the early 1980s. He has worked on many bagging projects to measure mass emissions from fugitive leaks, initially to develop correlation equations and emission factors and , more recently, to demonstrate the detection limits of optical imaging . He has managed an LOAR program for a gas plant in West Virginia, and he has consulted on LOAR program development in the US and abroad. He has conducted well over a hundred LOAR audits, including about 100 Consent Decree audits for petroleum refineries . He has participated in most public demonstrations of Smart LOAR including: ~ API funded demonstration of the Sandia fiber laser at a Texas refinery in February 2002 ; Sage En vironmental Co nsulting Feb ru ary 2005 2-1 Wes tlake Ch emical Co rporatio n TOTAL Infrared Im aging Part I Work Plan Draft Intern a l Ve rs io n );., HARC/TNRCC funded demonstration of the CO 2 laser at an olefins production plant in Texas in August 2002; and );., TCET/TCEQ funded five-camera demonstration at two olefins using facilities in Texas in January/February 2004. In addition , David has assisted with several demonstrations of optical imaging funded by private companies. Two of these demonstrations were long term tests occurring at refineries in Texas and lasting from six months to one year. In addition to his LDAR specific work, he has worked on a variety of environmental measurement projects , including Fourier Transform Infra-Red (FTIR) open-path and closed- cell monitoring. His combination of experience with infrared instrumentation and broad knowledge of LDAR make him an outstanding choice for this work. That choice is furthered by his associate degree in electronics and a MacGyver-like ability to make field repairs and keep instrumentation on line and functioning properly. Graham E. "Buzz" Harris will be a technical consultant for the Infrared Imaging SEP. Buzz is a Chemical Engineer with 37 years experience. He began his career as a process engineer at the Texaco Port Arthur refinery, not far from the TOTAL site. He began working in the fugitive emissions area since 1976 when he joined Radian Corporation. He was a key figure in the development of EPA Method 21 and the b agging method used to quantify mass emission rates. He has worked in developing correlation equations , emission factors , and regulatory support for most Federal LDAR rules. He has consulted on LDAR program development in the US and abroad. He has conducted well over a hundred LDAR audits , including nearly 100 Consent Decree audits for petroleum refineries. He has participated in nearly every public demonstration of Smart LDAR as well as with 5 demonstrations of optical imaging funded by private companies. The earliest of these demonstrations occurred in June 2000 at a refinery in Louisiana. One long term test occurred at a refinery in Texas over a period of 6 months from late 2003 to mid-2004. Three more demonstrations occurred during 2006 , one at a Texas refinery, one at a Texas chemical plant, and one at a Texas site that included both refinery and chemical plant units in the test. In summary, Buzz Harris is widely respected as an LOAR expert, and is consistently called to participate in panels on Smart LDAR at conferences and workshops. He has a strong background in environmental research and will be able to help guide the Infrared Imaging SEP to achieve meaningful results. Vinh Do holds a BS in Chemical Engineering from the University of Texas in Austin. Vinh worked for Sage as an intern while still at the University and has a year of full time experience since graduation. Vinh began working with David and Buzz on LDAR audits shortly after graduation, and he has completed 11 LDAR audits to date. In addition, Vinh has been working solo to provide quarterly QA checks on the LDAR program at a Midwest refinery. Vinh has also spent several months ons ite at refinery assisting the LDAR program with a retagging effort. Vinh offers the cost-effectiveness of a relatively junior engineer, good LDAR experience, and good skills with computers and gadgets (such as the Archos Sage En vironm ental Consulting July 2007 2-2 TOTAL P etroc hemicals, Inc. TOTA L Infrared Imag ing Part I Work Plan Draft Internal Vers ion video recorder that will be used to record the infrared imaging from this demonstration). This combination should provide a significant contribution to the success of the Infrared Imaging SEP. 2.2 Training The staff planned for the Infrared Imaging SEP is very experienced in LDAR in general and hav e participated in many optical imaging demonstrations. David Ranum has extensive experience in using FTIR as an environmental measurement technique , including open-path monitoring like fence line surveys . This solid base of experience will be augmented by specific training on the FLIR ThermaCAM® GasFindIR camera. An instructor from the Infrared Training Center will come to the TOTAL refinery ( or a meeting room in the area outside the refinery) to conduct a 5-day Level 1 thermography training course . The fee for this course is good for up to 15 attendees, so all Sage staff who could potentially work on this project can be trained, as well as TOTAL staff. TCEQ and EPA Region VI personnel could also be invited to attend this course if there is excess capacity. This course will cover the general theory of infrared thermography, but there will also be time for practical field work as well. Since all attendees will be primarily interested in imaging fugitive leaks, we should be able to focus more practical time in that area than is normally available when attending the course at a training center. 2.3 Equipment The primary equipment for the Infrared Imaging SEP will include: • One FLIR ThermaCAM® GasFindIR camera with accessory lenses ; • Archos video recorder with capacity to record a full day of imaging ; • TV A-1 OOOB portable analyzer for making Method 21 measurements ; and • An intrinsically-safe data logger that can hold the master equipment list for a unit and record time stamps for each regulated component at the time it was imaged. Sage has purchased the FLIR GasFindIR™ camera that will be used for this project. A FLIR brochure with specifications for this imager has been attached as Appendix B . This FLIR camera has been the standard for SmartLDAR work since the TCEQ/HARC multi-camera shootout in 2004. An Archos v ideo recorder is supplied along with the FLIR camera. These digital video recorders (DVR) are available from several manufacturers and with different memory capacities. The Archos recorder will be used initially and upgraded, if needed, to accommodate up to 10 hours of video capacity. The DVR files will be downloaded at the end of each day to the hard drive on a Sage laptop computer and burned to DVD weekly for backup and archiving . Sage En vironmenta l Cons ulting July 2007 2-3 TOTA L Petrochemicals, In c. TOTA L Infrared Imag ing Part I Work Plan Draft In te rna l Ve rs ion r Sage owns several intrinsically-safe dataloggers , including two Symbol M-9060 PocketPCs and four Palm Tungsten e2 personal data assistants (PD As). All of these dataloggers have the capability to upload an Excel file with the m aster equipment list (in route order) for a process unit, which will be followed to assure im ag ing every regulated component. The Infrared Imaging SEP may use one of these existing dataloggers or a new intrinsically-safe datalogger with equivalent capabilities. Sage Environmental Consulting July 2007 2-4 TOTAL Petroc hemicals, Inc. TOTA L Infrared Imag ing Part I Work Plan Draft Int ernal Version SECTION 3 PART I: IMAGING PLAN This section w ill present the detailed plans for conducting the Part I imaging of every regulated component. The discussion includes the approach for infrared imaging, for Method 21 measurements , and for scheduling the work. 3.1 Infrared Imaging Sage plans to comply with the requirements of Part I by following a master component listing in route sequence through each unit. To demonstrate that each regulated component has been imaged , we plan to record the output of the infrared camera on an Archos video recorder and to log the time that each regulated component is imaged. An intrinsically safe electronic datalogger, such as the Symbol Pocket PC model MC-9060 or Palm Tungsten e2 , will be loaded with the master component list for the unit to be imaged. The time setting on the datalogger, the GasFindIR camera, and the Archos video recorder will be synchronized each morning. At the closest approach to each regulated component, the camera will hold a still image for about 3 seconds and a time stamp will be entered into the datalogger that will correspond to the time on the Archos video recorder. The records could then be queried for the image of any regulated component by looking up the date and time it was imaged in the datalogger files and selecting that date/time on the video records. We may also be able to add voice recording capability so that the tag number can be read off while the component is imaged. This approach will be more time consuming than a general infrared imaging scan, because of the need to follow the master component list rather than just conducting a general scanning survey . We have used an estimated productivity of 1000 components per IO-hour work day for the Part I work. Approximately two hours out of each work day will be spent on overhead tasks , including: >-Warm up and electronic checks on the camera; >" Daily demonstration of camera sensitivity in accordance with the proposed EPA Alternate Work Practice; >-Downloading the master component list for the subject unit to the datalogger; >-Travel to the unit, check in, and authorization to work; >-End of day review of components imaged as leakers with the site LDAR crew to facilitate repair attempts; >-Upload of data from the datalogger and the Archos video recorder >-Cleaning and minor maintenance on the camera; and Sage En vironmental Consulting July 200 7 3-1 TO TA L Petrochemicals, In c. TOTAL Infrared Imag ing Part I Wo rk Plan Draft Internal Ve rsion ~ Daily report to refinery staff on components imaged, leaks found and any problems encountered. The planned field work to image all regulated components in Part I will require a team of two people for an estimated 11 weeks. A two person team for imaging is needed for safety and to relieve eye strain, with one person operating the infrared camera and the other operating the datalogger at any given time. We anticipate the field team changing roles at least once per hour to relieve the eye strain from closing one eye and looking through the camera eyepiece with the other. Safety issues occur when the camera operator moves with limited visibility of tripping hazards , and the second team member will need to act as a spotter. The planned effort would spend about 2 days of imaging work per process unit to complete the Part I requirements. Sage plans to use David Ranum and Vinh Do as the Part I field team . The team will work 5-day weeks of 10 hours per day, or an estimated 550 labor hours for each team member. Best practices for identifying leaks using infrared imaging are still in the developmental phase. One approach calls for imaging each component three times during a moving survey: once when approaching the component, once when beside it, and once when moving away from it. Since the background can have an impact on the ability to image a leak, this approach allows each component to be imaged from several directions with different backgrounds, thereby increasing the opportunity to detect a leak if one is present. A side benefit of this approach is that all components on lines with regulated components will be imaged during completion of Part I work, including connectors and non-regulated components. A plot plan of each unit will be marked to indicate the areas with regulated components imaged in Part I. Another emerging best practice for imaging is to pause on each component. The basis of this approach is that leaks are detected with the infrared imager when the eye detects motion in the field of view , such as an image like smoke wafting away from a component with the wind. If the camera operator makes a continuous walking survey or continuously pans from a fixed position, there is much apparent movement in the field of view that may prevent the operator from noticing the moving plume from a leak. Observation points (OP) are another concept that may prove to be a best practice when infrared imaging becomes the primary leak detect ion method for a site. The OP concept is that a series of positions can be defined from which a number of regulated components can be effectively imaged. The OP locations can be defined by GPS or land-based beacon coordinates or by grids on a plot plan. The camera operator would proceed to each OP and image a set of regulated components associated with that OP . The time required to effectively image the components visible from each OP could be noted as they are set up , and that time could be used as a QC check for subsequent imaging surveys at that OP . Sage plans to blend all these potential best practices into our approach for Part I. We will follow the master equipment list route and imaging each component on the approach, when S age En vironmental Consulting July 2007 3-2 TOTAL Petro che micals, In c. TOTAL Infrared Im aging Part I Work Plan Draft Intern al Version closest , and when moving away . We plan to pause on each regulated component at closest approach for several seconds to allow the data logger to record a time stamp. We will also experiment with the concept of observation points by trying to establish a set of OPs for one process unit. 3.2 Method 21 Monitoring Part I also requires "concurrent" infrared imaging and Method 21 monitoring for all components where infrared imaging detects a leak (up to a total of 500). Infrared non-detect components also need to be monitored to round out to 1000 total components imaged by infrared and monitored by Method 21 . Sage plans to perform Method 21 on all accessible infrared-detected leaks and to temporarily mark each leaking component with fluorescent surveyors' tape . A list of all leaking components identified during the infrared survey will be compiled each day and sent to the site LOAR team. The site LOAR team will locate the leaks from the Sage leak list and affix the site leaker tag and, if feasible , make a first attempt at repair or begin the repair process . Sage plans to perform Method 21 on imager non-detect components at a rate of about one component for every 15 minutes of survey time. This approach will spread the Method 21 data for non-detects over a wide area of the regulated components surveyed. More than 1700 imager non-detect components should be monitored in this approach if our estimates of survey pace are correct, and it should go beyond the Consent Decree required 1000 Method 21 monitoring ev ents for any conceivable case. 3.3 Imaging Schedule The Consent Decree sets the schedule for Part I work at 6 months after the date of entry. Sage estimates that Part I work will require 11 weeks of imaging, which is less than half of the 6 month allowance (24 weeks). The planned survey speed provides some flexibility in the approach to meeting the Consent Decree deadline . Sage plans to do imaging every other week, which allows time for the refinery to catch up on repairs . The infrared surveys may image 5000 regulated components in a week, along with 15 ,000 connectors on lines with regulated components . Even if the leak rate is very low (0.1 % for example), 20 leaks might be found that need to have a first attempt within 5 days and be repaired within 15 days. Some weeks we might find 50 or even 100 leaks. And those 20 to 100 leaks from the infrared imaging project will be in addition to the normal leaks being detected by the site LOAR team. This could put a severe strain on the maintenance group. While the Consent Decree language does allow the possibility of asking EPA Region 6 for additional time to make repairs , that might not waive TCEQ repair requirements , and should be considered as a last resort . Sage plans to initially perform infrared imaging every other week and to adjust that schedule as neces sary to meet the 6 month deadline. Sage En vironmental Co nsulti ng July 200 7 3-3 TOTA L Petrochemicals, In c. TO TA L Infrared Im aging Part I Work Plan Draft In ternal Versio n SECTION 4 PRELIMINARY PART II WORK PLAN The Part II work involves imaging every component with potential to leak VOC or HAP compounds. This work will be done in a similar manner to Part I, except that no master component route will be followed and no time stamp will be recorded for each component. The imaging will be done in continuous survey mode with the intent to image each component during the approach, at closest approach, and while moving away. We will not attempt to pause on each component, but rather to proceed with a slow continuous survey unless we see possible indications of a leak . The unit plot plans marked up with the areas imaged in Part I will be used to guide the Part II survey . Different colored markers will be used to distinguish Part II coverage and for elevated coverage . A total facility plot plan will also be used to show off-unit areas imaged in Part II. David Ranum w ill continue as the Project Manager for Part II and will be in the field to kick off the new surveys . Vinh Do will take over the field lead for Part II and a second person with similar LDAR experience will be selected to assist him. The productivity for Part II surveys should be significantly higher, and we have assumed 3000 components per day coverage . Unfortunately , there are no precise estimates of the numbers of non-regulated components. Based on our experience , the total non-regulated component population might range from 6 to 10 times the number of regulated components. This would include connectors and all heavy liquid components , as well as non-conventional components (sight-glasses , manways , meter bodies , exchanger heads , etc .). In addition, the tank farms , utilities , and all interconnecting pipe racks will need to be imaged. We roughly estimate Part II to require 18 weeks for a two-person team to complete, but we would like to reserve the right to review that estimate after completion of Part I work. This represents about 3 days per process unit. There is considerable flexibility in schedule for Part II. Sage would initially plan to perform imaging on alternate weeks to allow time for repairs . Based on early experience in Part II , the schedule may be extended even more (within the constraint of completing the work within two years of entry of the Consent Decree). Sage En viro nm ental Cons ulting July 2007 4-4 TOTAL P etrochemicals, In c. TOTA L Infrared Im aging Part I Work Plan Draft Internal Ve rs ion SECTION 5 REPORTING AND DOCUMENTATION The results of Part I and Part II work will be documented in a report at the conclusion of Part II work. The report will include: >" Detailed description of the Infrared Imaging SEP as implemented; >" Description of any problems encountered in completing the Infrared Imaging SEP and the solutions thereto ; >" Itemized list of all eligible Infrared Imaging SEP costs; >" Certification that the Infrared Imaging SEP has been fully implemented pursuant to the provisions of this Consent Decree; >" Description of the environmental and public health benefits resulting from the implementation of the Infrared Imaging SEP , with a quantification of the benefits and pollutant reductions , if feasible ; and >" Listing of all components for which leaks were imaged with the infrared camera, along with Method 21 readings for those components. The report will be drafted within 30 days following completion of Part II imaging work. Two weeks will be allocated to TOT AL for review and comment on the report. The comments will be addressed and the report finalized within two weeks to meet the 60-day requirement in the Consent Decree. While the Consent Decree only requires a report at the conclusion of both Parts I and II , Sage plans to prepare a Part I report for internal use while the work is still fresh. The Part I report will include all the elements described above as they apply to Part I. This draft report will be held until the completion of Part II and assembled into the complete SEP report at that time. Sage En vironmental Co ns ulting July 200 7 5-1 TOTAL P etrochemicals, Inc. TOTA L Infrared Im aging Part I Wo rk Plan Draft Internal Versio n APPENDIX A CONSENT DECREE SCOPE OF WORK TOT AL Infrared Imaging Project -SCOPE OF WORK Consent Decree Requirement TOT AL shall implement a "Passive, Infrared Imaging of Refinery Equipment and Components and Follow-Up Actions" project ("Infrared Imaging SEP"). Schedule Part I -within six months after the Date of Entry* of this Consent Decree Part II -as soon as practical after the Date of Entry* of this Consent Decree but in no event more than two years after the Date of Entry. *Date of entry will be sometime in the next 3 months; however, TOTAL wou ld like to implement Part I ASAP. Part I Scope of Work • TOTAL shall conduct passive, infrared imaging of all Refinery components subject to the LDAR rules at 40 C.F.R. Part 60, Subpart GGG, Part 61, Subparts J and V, and Part 63 , Subparts F, H , and CC. This requirement shall not apply to components that are difficult or unsafe to monitor with the infrared imaging equipment. An estimate of existing TOT AL components regulated under these programs is provided in Table 1-SAGE • TOT AL shall monitor, in accordance with Method 21, at least 1,000 Refinery components imaged concurrently with such imaging. -TOTAL LDAR Contractor • The 1,000 components subject to concurrent imaging and Method 21 monitoring, shall include any component imaged from which the imaging detects emissions, up to a maximum of 500 such components. The remaining 1,000 components subject to concurrent imaging and Method 21 monitoring shall consist of components from which the imaging does not detect emissions , and the number of such components shall be the greater of (1) 500, or (2) the difference between 1,000 and the number of Sage Environmental Consulting July 2007 1 TOTAL Petrochemicals, In c. TOTAL Infrared Im aging Part I Work Plan Draft Internal Version I Work Plan components imaged from which the imaging detects emissions. -SAGE/TOTAL LDAR Contractor • TOTAL shall repair, in accordance with the LDAR requirements , any component found to be leaking under the standards set by the LDAR regulations and Method 21. -TOTAL Part II Scope of Work • TOT AL shall conduct passive infrared imaging of all Refinery components and operations not so imaged pursuant to Part I of the Infrared Imaging SEP. -SAGE EPA Deliverable • Within 60 days after the date set for completion of Phase II of the Infrared Imaging SEP, TOTAL shall submit a Infrared Imaging SEP Completion Report . The Infrared Imaging SEP Completion Report shall contain the following: (i) a detailed description of the Infrared Imaging SEP as implemented; (ii) a description of any problems encountered in completing the Infrared Imaging SEP and the solutions thereto; (iii) an itemized list of all eligible Infrared Imaging SEP costs ; (iv) a certification that the Infrared Imaging SEP has been fully implemented pursuant to the provisions of this Consent Decree ; and (v) a description of the environmental and public health benefits re sulting from the implementation of the Infrared Imaging SEP , with a quantification of the benefits and pollutant reductions , if feasible. -SA GE • Report submission shall be signed by an official with knowledge of the Infrared Imaging SEP and contains the certification statement set forth -TOTAL: o "I certify under penalty of law that I have personally examined and am familiar with the information submitted herein and that I have made a diligent inquiry of those individuals immediately responsible for obtaining the information and that to the best of my knowledge and belief, the information submitted herewith is true, accurate , and complete. I am aware that there are significant penalties for submitting false information, including the possibility of fine and imprisonment." Sage Environmental Co ns ulting July 200 7 2 TO TA L Petrochemicals, Inc. TO TA L Infrared Imag ing Pa rt I Work Plan Draft Internal Ve rsion I Work Plan EPA Dictated Work Plan for Part I. • TOT AL must retain the services of an experienced camera operator to conduct this examination, and TOT AL and EPA must agree that the selected operator is qualified for the job. TOT AL and EPA shall agree in writing (in advance) on the imaging camera used for this Project. In conducting Part I of this Project, the camera must be operated within allowed specifications, ranges of tolerance, and/or conditions prescribed by the manufacturer and/or operator for proper operation in a petroleum refinery. • For any component that a Method 21 examination indicates emissions of volatile organic compounds at a rate or level greater than the applicable LDAR limit, TOTAL must comply with all applicable requirements of this Consent Decree and the LDAR regulations . • If TOT AL timely and properly completes the steps above, and if TOT AL then concludes that the components requiring correction or repair cannot be accomplished on the applicable regulatory or Consent Decree schedule, consistent with regular operation of the Refinery , then TOT AL may request from EPA Region 6 an extension in the time allowed to complete the requirement. Such request must be made in writing and explain with particularity the need for additional time and must provide for as short a schedule as practicable, consistent with orderly completion of repairs and operation of the Refinery . • TOT AL shall give EPA Region 6 at least three weeks advance notice of the date on which the use of the infrared camera imaging and/or Method 21 monitoring pursuant to this Project will commence . Consistent with all established Refinery safety procedures and prerequisites , TOT AL shall allow representatives of EPA Region 6 and NEIC to attend, at any and all times, with the individuals ( contractors and/or employees) conducting preparatory work and/or the camera imaging and LDAR monitoring required under Part I of this Project. Sage En vironmental Co nsulting July 2007 3 TOTAL Petro chemicals, In c. TOTA L Infrared Imaging Part I Work Plan Draft Internal Vers ion I Work Plan EPA Dictated Work Plan for Part II. • In addition to the camera imaging and monitoring required in Part I above , TOT AL must examine each Refinery component that contains or can contain volatile organic compounds (other than the components subject to the LOAR regulations) with a passive, infrared imaging camera. TOT AL is not required to examine Refinery components on a component by component basis , so long as the examination is conducted by an operator and with a camera that meets the requirements of Part I and such operator follows suitable procedures for examining the areas to be imaged under this Part of the Project. Consistent with these terms, TOTAL may examine Refinery components from selected vantage points that allow areas within the Refinery to be examined as a whole. TOT AL is not required to number each individual component while examining Refinery components under Part II of the Project, so long as the examination is completed in a fashion that allows for effective use of the examination and any recording of it in performing the work called for by this Consent Decree. • TOT AL will provide EPA the same notice and opportunity to participate with the work under Part II of this Project that it provides for the work under Part I. • TOT AL must eliminate the emissions identified by Part II of this Project unless either: 1) such emissions are allowed by law; or 2) TOTAL and the United States agree, in writing, that the elimination of a particular emission source is impracticable because it is inherent in the proper design, construction, and operation of the Refinery. Nothing in the Consent Decree, however, bars any other option available to the United States to eliminate such an emission or emission source. • Nothing in this Consent Decree is intended to limit or disqualify TOTAL , on the grounds that information was not discovered and supplied voluntarily, from seeking to apply EPA's Audit Policy or any state audit policy to any violations or non- compliance TOT AL discovers during the course of any investigation, audit, or enhanced monitoring that TOT AL is required to undertake for Part II of this Project. Sage Environmental Co nsulting J uly 2007 4 TO TA L Petrochemicals, Inc. TOTA L Infrared Imag ing Part I Wo rk Plan Draft Internal Version I Wo rk Plan Table 1 -TOTAL Regulated Component Count Unit Part 1 Count* Crude Unit No . 1 2 ,125 Crude Unit No . 2 1,457 Naphtha HOS/Reformer 3 ,710 Sulfolane (HON) 9 ,223 BTX (HON ) 2,048 Distillate Hydrotreater No. 1 786 Distillate Hydrotreater No . 2 1 ,028 Resid Solvent Extraction 22 FCCU 4,499 Alkylation Unit 3 ,303 Condensate Splitter 2,326 Toluene Disproportionation (HON) 2,229 Sat Liquids 1,626 Fuel Gas Treater/Amine Unit 334 Sour Gas Recovery Compressors 1,044 Fuel Gas Recovery Compressors 133 lsomerization 1,390 Sour Water Stripper 116 SRU Complex 59 Refract ionation 2 ,339 Jet Treater 253 CoQen 213 Transporation Fuels Blend inQ 449 Tank Farm (HON) 6 ,046 Tank Farm 3,719 Marine Terminal 1 ,126 Marine Terminal (HON) 619 Truck LoadinQ 262 Total 52,484 *Count includes connectors for HON regulated equipment. Sage Environmen tal Consu lting Ju ly 2007 S TOTA L P etrochemicals, In c. TOTAL Infrared Imaging Part I Work Plan Draft Internal Ve rsion I Wo rk P lan INTRODUCTION APPENDIXB SAGE LOAR QUALIFICATIONS STATEMENT Sage Environmental Consulting, LP (Sage) is an environmental engineering and consulting company offering regulatory compliance, permitting, and remediation assistance . The professional services we provide cross a wide spectrum of environmental programs and media such as air quality , hazardous and solid waste, water quality , hazardous materials , and petroleum storage activities. While we offer a broad range of services , our specialty is air permitting and compliance programs for industry. Air permitting and compliance assistance work comprised approximately 80% of our total revenue in the last three years. At Sage, we believe that every project is an opportunity to earn your trust, based on a quality product done in a cost effective manner, with friendly service and no surprises. We have a culture that builds trust and loyalty among employees and clients. Our customers have confidence in our ability to deliver. Sage currently has offices in Dallas, Austin, Houston, Midland and Beaumont, Texas as well as Baton Rouge , Louisiana, Atlanta, Georgia, Washington, D .C., Denver, Colorado, San Francisco, California, and Tulsa, Oklahoma. Our experienced personnel have performed work both nationally and internationally. Auditing and compliance services offered by Sage Environmental include LDAR compliance assistance . Sage Environmental personnel are nationally recognized for their work in all facets of LDAR including auditing, program development, monitoring plan development, mass emission studies , and personnel training. The remainder of this statement of qualifications for LDAR work includes: » A listing of LDAR services provided; » A listing of LDAR staff with a brief description of experience ; and » Example project summaries. If you need more specific information, please contact either: G. E. "Buzz" Harris or David Ranum (512)773-8556 (512)968-8906 buzz@ sageenvironmental.com davidr@ sageenvironmental.com Sage En vironmental Co ns ulting July 2 00 7 Work Plan 1 TOTAL Petrochemicals, In c. TOTA L Infrared Imag ing Part I Work Plan Draft Internal Ve rs ion I LEAK DETECTION AND REPAIR (LOAR) SERVICES ~ LOAR Program Audits o Third-party Consent Decree audits o Third-party HRVOC audi ts (Texas ) o Custom Audits • Verification of component inventories • Spotting monitoring problems • Shadow monitoring • Identification of routing problems • Report reviews • Answers to compliance questions. • Open-end line control • Proper sample station design ~ Smart LOAR o Design of optical imaging demonstrations and special studies o Mass emission measurement to define sens itivity of optical imaging o Infrared imaging survey work o Rule interpretation for Smart LOAR o Design of hybrid infrared/M21 leak detection programs ~ LOAR Program Enhancements o Development of an LOAR Compliance Plan o Identification and Responsibilities of Key Program Personnel o Management of the LOAR Contractor o Developing an in-house LOAR Training Program o Important LOAR QA/QC Procedures o Key LOAR Program Metrics ~ LOAR Program Development o Starting an LOAR Program from "scratch" o Equipment Leak Emission Estimates o Basic LOAR Program Elements o Complying with basic reporting requirements o Valuable Program Enhancements o LOAR Data Management Systems o Effective Staffing Techniques ~ Training o Method 21 (Classroom & Practical) o LOAR Regulations o Consent Decree Annual Tra ining o Refinery Operations o LOAR Equipment Considerations o Analyzers o Monitored components o Smart LOAR o How to pass a Regulatory Audit o Fugitive Emission Estimation o Quality Assurance/Management Systems ~ Mass Emission Measurement o Bagging to develop Emission Factors & Correlation Equations o Bagging to support SmartLDAR demonstrations Sage Environmental Consu lting July 2007 TOTAL Petrochemicals, Inc. TJrAL Infrared Imaging Part I Work Plan Draft Internal Version I Work Plan KEY PERSONNEL Graham E. "Buzz" Harris Buzz Harris is a Chemical Engineer with 37 years experience in industry and consulting. He began his career as a process engineer at the Texaco Port Arthur refinery, where he spent six years rotating through responsibility for all the major refining process categories. He joined Radian Corporation in 1976, where he worked 29 years before joining Sage in 2005 . He has spent the last 31 years in consulting to the refining and petrochemicals industries. Buzz played a lead role in the fugitive emission studies that established the monitoring protocol, correlation equations , and emission factors for refineries and SOCMI facilities. He has been continuously involved in LDAR equipment leaks issues for 30 years, in projects ranging from bagging, training, database , regulatory development, and auditing. In recent years, LOAR audits have become nearly his full-time job, having completed more than 100 LOAR audits over the last five years . Buzz has also been active in supporting the development of new LOAR technologies, such as Smart LOAR. He has played a part in most public demonstrations of infrared imaging of equipment leaks, and has participated in several private demonstrations. Buzz is active in development and presentation of training materials related to LOAR, and is a lecturer at LOAR University. He has presented several dozen papers on LOAR at workshops and meetings and has chaired several LOAR-specific workshops. He is regular participant on expert panels to field audience questions on LOAR and Smart LDAR. David Ranum David has over 28 years experience in a variety of areas within the environmental field. These areas include instrumentation system design, air toxics monitoring programs , fugitive emission programs, design and installation of continuous emission monitoring systems (CEMS) and mobile air monitoring systems, maintenance of infrared air monitoring systems (FTIR) and numerous projects related to LOAR. In the LOAR area, David participated in several key bagging projects that eventually led to the development and enhancement of refinery emission correlation equations. He has initiated LOAR programs both here and abroad as well as managed a large scale refinery tagging inventory project. David provides training on a variety of LOAR issues to refinery LOAR staff and participates in symposiums dealing with topics of interest to the LOAR community. David currently serves as a member of an LDAR audit team that has conducted LOAR audits at over 100 refinery and petrochemical plants across the U.S. Davi d has served as the audit leader on 16 LOAR audits. David is participating as part of a three-person team of LOAR experts in a comprehensive assessment of LOAR for a major oil company site. Sage Environm ental Consulting July 2 007 Work Plan TOTAL Petroc hemicals, Inc. TdrAL Infrared Imaging Part I Work Plan Draft Internal Vers ion I Erin Badough Erin holds a Masters in Environmental Engineering from Texas Tech University and has four years experience in environmental consulting. Erin has worked on a variety of permitting and emission inventory projects , in addition to her LDAR work. Erin began working with the LDAR audit team in 2006 and has completed 13 refinery Consent Decree audits to date . She has worked in both the compliance/recordkeeping/reporting position and the field monitoring/tagging/OEL position. Erin has also participated in a bagging study to measure emission rates to quantify the sensitivity of Smart LDAR applications in petroleum refinery. Vinh Do Vinh holds a BS degree in Chemical Engineering from the University of Texas in Austin. Although a recent graduate , he worked as an intern at Sage prior to graduation, was a co-op at a petrochemical facility in Texas, and worked in a research position at the University. Since graduation, he has worked in a number of fields, but has specialized in LDAR auditing. Vinh has completed 12 LDAR audits to date , including Consent Decree audits of refineries and HRVOC audits of refinery and chemical facilities in Texas. Vinh has worked on a bagging project that involved cross-checking the results of Smart LDAR, Method 21 , bagging, and the Hi-Flow™ sampler. Vinh is also the site lead for doing quarterly shadow monitoring for a Midwest petroleum refinery. Catherine Barry Catherine was a zoology major at Texas Tech University who now has about 1.5 years experience in environmental consulting. She has participated in six LDAR audits, filling both the office and field roles. Catherine has also been the site lead for a major study to determine which streams are applicable to LDAR rules at a Texas petrochemicals facility. She worked with Aspen modelers to take major stream composition data and fit it to the more detailed lines on piping and instrumentation diagrams. She set up a database to manage the stream data and a variety of spreadsheets to present the results, including cells that make rule applicability decisions based on stream composition and header data about the unit. Kyle Brzymialkiewicz Kyle is a recent Chemical Engineering graduate from the University of Texas in Austin. Kyle has split his time between LDAR audits and BWON work. He has completed 4 LDAR audits and has been trained on both the office (rule compliance/recordkeeping/reporting) and field (comparative monitoring/component identification/open-ended line/sample systems) work. Sage Environm ental Consulting July 2007 Work Plan TOTA L Petroc hemicals, In c. T04rAL Infrared Im aging Part I Work Plan Draft Internal Vers ion I Judah Fontenot Judah has over 16 years of technical and regulatory experience with a variety of Environmental air quality issues. Judah managed leak detection and repair (LDAR) programs at several petroleum refineries and chemical plants, including direct responsibility for technician monitoring , valve repair (including drill and tap procedures), delay of repair, management of change, recordkeeping and reporting, compliance auditing and database management. Judah is based out of the Dexter Field Services Beaumont office . Dexter is an independent company with the same ownership as Sage. Judah was a Sage employee before Dexter was founded, and he can be available for Sage projects through subcontract. Sage En vironmental Co nsulting July 2 00 7 Work Plan TOTA L Petroc hemicals, In c. TJrAL Infrared Imag ing Part I Work Plan Draft Int ernal Ve rs ion I REPRESENTATIVE PROJECT EXPERIENCE LOAR Auditing Refinery Consent Decree Audits The US EPA and DOJ have been negotiating Consent Decrees (CD) with the oil companies operating refineries in the US . All these Consent Decrees include a requirement for an LDAR audit every two years , and half those audits must be third-party. Sage is the leading provider of refinery Consent Decree audits , with over 100 completed to date . The scope of work for Consent Decree audits includes: )l> Performing comparati ve monitoring; )l> Re viewing records to ensure monitoring and repairs were completed in the required periods; )l> Reviewing component identification procedures , ta gging procedures , and data management procedures; and )l> Observing LDAR technicians ' calibration and monitoring techniques . Sage has performed CD LDAR audits that ranged from two people for two days up to four people for two weeks, depending on the size of the refinery and the depth of comparative monitoring. A typical audit includes a staff of three people for a week. After safety orientation, each audit begins with a kic k off meeting to communicate the planned activities. The work then splits into two parallel tracks: office and field. The office work includes a detailed re view of rule compliance, recordkeeping, and reporting . Several checklists are used to guide the office review and provide cons istency in our audits . One checklist is for NSPS VV compliance, which both NSPS GGG and Refinery MACT refer to for the detailed compliance activities. We also use an overall audit checklist to track other inquiries into records and reports. We try to do as much of the record re views electronically as possible , using Excel and Acces to leverage our ability to review thousands of records in the time it would take to review dozens of paper records. The field work is built around comparative monitoring, where we will typically select three process units as subjects. A target monitoring goal is set for each unit based on its size and the historical claimed leak rate . The component subset is field selected in a semi-random manner, starting in one comer and monitoring one out of each four components , for example, if the target were 25 %. This approach spreads the components to be monitored over the whole unit , which helps the selected subset to be representative of the overall unit. This approach also involves a physical survey of the whole unit , which allows component identification, open-ended line control, and sample systems flushing control to be ev aluated . Component identification is evaluated by trying to justify each component without an LDAR tag as being a utility, a heavy liquid, a non-monitored component type , or other exempt stream/component. Anomalies in tagging are reviewed with operations and LDAR staff, and any that appear to have been overlooked from the LDAR inventory are documented. Each missing cap, plug, or blind is Sage Env iro nm ental Co ns ulting July 200 7 Wo rk Plan TOTA L Petrochemicals, Inc. T<JTA L Infra red Im aging Part I Wo rk Plan Draft In ternal Ve rs ion I evaluated to see if it is in hydrocarbon service and whether or not it is controlled by a double block valve system; each OEL compliance issue is documented . Sample points are reviewed to see if they include flushing control by closed-loop, closed-purge, or closed-vent. Any sample points that do not include flushing control are checked with operators to see if they are routine , and any uncontrolled routine sample points are documented. The CD audits also include observation of the site LDAR team. This includes observations of calibration and review of instrument calibration/certification records. Several technicians are also observed in the course of monitoring and any repair attempts they are allowed to make. Sage prepares a spreadsheet with all findings documented before leaving the site. A closing meeting is held to explain findings and comparative monitoring agreement. Sage has gathered data from over 100 similar facility audits and developed benchmarks for a number of LDAR program criteria, including: OEL control, accuracy of component identification, comparative monitoring agreement, percent of components on delay of repair, percent of valves designated as difficult to monitor, percent of valves designated unsafe to monitor, and LDAR staffing levels/effectiveness. A preliminary report is repaired within two weeks following the field audit. The client reports back with any challenges to the audit findings, which are generally worked out over a conference call. Sage then prepares a final audit report saved in a signed/certified Adobe pdf format. HRVOC Audits The Texas Commission on Environmental Quality (TCEQ) has adopted special regulations for the Houston-Galveston area that focus on reducing emissions of highly reactive VOC ( ethylene, propylene, and butylenes). The HRVOC rules include an annual third-party audit requirement , which focuses on comparative monitoring to verify site leak rates . The HRVOC audits also include a review of tagging of leaking equipment, QA/QC analyses of monitoring data, and a review of calibration records . Sage typically staffs HRVOC audits with two people for a period of 3 to 10 days . The time- determining factor is the comparative monitoring . The TCEQ sets a minimum number of valves to be monitored based on valve population and claimed leak rate. The comparative monitoring is to be done randomly from the set of all HRVOC valves at the facility. Two random selection schemes have been used: random component selections from the HRVOC master valve list and random grid selections from a geographic division of process areas. Sage has used both random selection criteria. The random component selection approach is preferred where the number of components to be monitored is low and the location/description information in the database is sufficiently detailed to allow quick location of each component. The random grid approach works as an alternative when larger numbers of components must be monitored and when location/description information is not sufficiently detailed to locate individual components in a reasonable amount of time. HRVOC audits include a closing meeting with all findings at the conclusion of the audit and quick report generation. Sage Environmental Cons ulting July 2007 Work Plan TOTAL P etrochemicals, In c. TdTAL Infrared Imaging Part I Work Plan Draft Internal Version I Specialty LDAR Audits In addition to conducting complete program audit , Sage provides specialized LDAR audit assistance. Specialty audits are often driven by the client rather than a regulation. The facility may have discovered a group of overlooked components , so Sage is hired to take a broader look at component identification accuracy to check for additional problems. Another common specialty audit focuses only on monitoring quality , while others might focus only on recordkeeping issues . Consent Decree (EPA-DOJ Negotiations) Sage has assisted several refineries with expert advice on their Consent Decree negotiations , cost assessments , responses and compliance, in the area of LDAR. LDAR Program Implementation and Enhancements Starting a New LDAR Program -Sage staff have helped clients start several LDAR programs from scratch. One such program was for a gas plant that triggered NSPS KKK. Sage staff have also helped petroleum refineries in Europe and Asia develop cost-effective LDAR programs. These projects start with a review of any applicable regulations , LDAR program objectives and scope of work, field procedures , safety procedures , and criteria for tagging (e.g . process stream applicability). Facility P&IDs/PFDs are marked up to indicate VOC Gas , Light Liquid and Heavy Liquid streams and are backed up with detailed stream composition information. The marked up P&IDs are used to assist in the physical tagging of components. Once components are tagged, the fugitive emissions database is ready to be populated and monitoring routes created . LDAR Best Practices -Sage staff have helped a number of clients identify the best ways to approach LDAR. We typically document program strengths in our audits, and we have provided a corporate tabulation of those strengths to several clients. Sage staff provided consulting to a chemical facility client in Louisiana who chose to explore LDAR best practices as a beneficial environmental project. That work involved visiting and surveying successful programs at 8 facilities and two contractor facilities. Sage is currently providing two of the three experts involved in a comprehensive assessment of a major refinery LDAR program. LDAR Retagging/Tag Verification -Sage staff have provided key services to clients who need to establish or improve the basis of component identification . One such study that is currently under way at a Texas petrochemicals site is focused on fundamental analyses of stream composition to decide which need to be included in the LDAR program. This detailed study involves on-site Sage staff working with modelers to translate primary stream composition data to the diversity of lines on P&IDs. Both database and spreadsheet tools have been used to manage the vast array of data, which involve multiple feed possibilities. Stream compositions have been assigned to every line on the P&ID using both a worst case composition for applicability determination and an average composition for emission inventories. In another project, Sage staff performed extensive QA/QC of flagging , tagging , and documentation of components for a complete retagging effort for a refinery struck by Hurricane Katrina. Sage En vironmenta l Co ns ulting July 200 7 Wo rk Plan TOTA L Petrochemicals, In c. T&A L Infrared Imaging Part I Work Plan Draft Internal Ve rsion I LDAR Bagging Studies Sage staff were involved in the original and follow-up studies to develop EPA emission factors used to convert Method 21 screening results into emission rates and the emission factors developed from the correlation equations . These landmark studies include : ~ The original refinery measurements done in the late 1970s ; ~ The original SOCMI measurements done in the early 1980s; ~ The original gas plant measurements done in the mid-1980s; ~ The CMA funded work done in the late 1980s; and ~ The API/WSP A refinery study done in the early 1990s . Sage staff members have also performed bagging to develop site-specific correlation equations for a number of facilities. Smart LDAR Demonstration Studies Sage staff hav e been involved in most of the large public demonstrations of infrared imaging, which is also known as Smart LDAR, including: ~ API funded demonstration of the Sandia Laboratory-developed fiber laser at a Texas refinery in February 2002; ~ HARC/TNRCC funded demonstration of the CO2 laser at an olefins production plant in Texas in May 2002 ; ~ HARC/TNRCC funded demonstration of the CO2 laser at an olefins production plant in Texas in August 2002 ; ~ TCET/TCEQ funded five-camera demonstration at two olefins using facilities in Texas in January/February 2004. Sage staff have also worked with clients in a number of private demonstrations of Smart LDAR. One of these was a long-term application of Smart LDAR to several project units in a Texas refinery that included EPA NEIC involvement. Another is in a Texas refinery that negotiated the test as part of their Consent Decree . Another private demonstration involved cross checks of infrared imaging , Method 21 , bagging , and the Hi-Flow™ Sampler. The Hi-Flow™ Sampler was originally de v eloped as a powered dilution probe by GRI to extend the measurement capability to very large leaks. Sage staff designed and built the second generation prototype of the Hi-Flow™ Sampler for GRI. It has now been commercialized by JW Bacharach as a quick alternativ e to bagging . Sage Environmental Co ns ulting July 200 7 Work Plan TOTAL Petrochemicals, In c. T!JTAL Infrared Im aging Part I Work Plan Draft Internal Vers ion I APPENDIXC FLIR THERMACAM® GasFindlR CAMERA See attached file in Adobe pdf. Sage Environmental Consulting July 2007 Work Plan TOTAL Petrochemicals, In c. TJl'AL Infrared Im aging Part I Work Plan Draft Internal Version I APPENDIXD ADDITIONAL M21 M O NITORING VIA UNIT SCHEDULE CO O RDINATION There are potential advantages to scheduling the infrared surveys just before or after the scheduled Method 21 monitoring is done by the site LDAR team. This will generally work best for smaller units where both the infrared imaging and Method 21 work can be completed within a few days. The advantages and disadvantages of before and after scheduling are discussed below. Infrared Surveys Just After Site Method 21 This combination will be ideal during the early work when we are working to perfect our ability to see all possible leaks . The Method 21 monitoring crew will have hung leaker tags for equipment above the leak definition, so the infrared crew can spend extra time on each marked leaker to see if it is possible to image the leak. Simultaneous Method 21 readings will be captured by the infrared imaging crew so that we can be sure that the leak rate has not changed since the site monitoring due to repair attempts or other factors. The additional efforts to image a leak on each tagged leaker will include: • Varying the imaging distance; • Varying the background; • Trying angles from above and below the tagged leaker; • Using custom settings on the camera to optimize sensitivity; and • Allowing both of the survey crew to try all the above. When a leak can be imaged, both crew members will attempt to achieve the image again in a normal survey mode. The factors to be evaluated during this experiment will include distance, background, camera settings, walking vs. stopped, and panning vs. still imaging of the component. These types of experiments will accomplish several objectives: • Extend training on how to effectively identify leaks with infrared imaging; • Develop a large volume of contemporaneous Method 21 vs. imaging data points; and • Concentrate a group of data points for Method 21 leaks in the area that could potentially be imaged by infrared. Infrared Su rveys Just Before Site Method 21 Once we have completed a few units using the above technique, we can begin to perform infrared surveys just prior to scheduled Method 21 monitoring by the site. The infrared imaging team will then try to detect leaks with no visual cues (i.e., leaker tags) of which are likely to leak. Once the site Method 21 monitoring has been completed, the imaging team will return to try to image all tagged leakers that were not detected in the initial imaging survey. It is expected that Sage En vironm ental Co ns ulting July 200 7 Work Plan TOTA L Petrochemicals, In c. T~L Infrared Imaging Part I Work Plan Draft Internal Vers ion I many Method 21 leakers will not be visible with infrared imaging. Any Method 21 leaks that can be imaged with extra effort (as described in the imaging after Method 21 section) will be evidence of imperfections in the survey technique and/or camera settings, and these learnings will be used to improve technique/settings. This before Method 21 experiment will accomplish several objectives: • Critical test of survey technique; • Extend training on how to effectively identify leaks with infrared imaging; • Develop a large volume of contemporaneous Method 21 vs. imaging data points; and • Concentrate a group of data points for Method 21 leaks in the area that could potentially be imaged by infrared. Application of Contemporaneous Method 21 and Infrared Surveys There are 28 process units at the TOTAL Port Arthur refinery, and 13 of those units have around 1000 or fewer components. These smaller units would be the primary targets for contemporaneous surveys: Unit Distillate Hydrotreater No. 1 Distillate Hydrotreater No. 2 Resid Solvent Extraction Fuel Gas Treater/Amine Unit Sour Gas Recovery Compressors Fuel Gas Recovery Compressors Sour Water Stripper SRU Complex Jet Treater Cogen Transportation Fuels Blending Marine Terminal (HON) Truck Loading Components 786 1,028 22 334 1,044 133 116 59 253 213 449 619 262 This list provides enough candidates for units where both surveys can be completed within a calendar week. If scheduling of these small units does not meet the infrared survey needs, it may also be possible to perform contemporaneous surveys on a single route out of a larger unit. A few units will be done with the site Method 21 monitoring done first to provide training on effective infrared leak detection. After that, a few units will be done with the infrared survey just prior to scheduled Method 21 monitoring to test the effectiveness of the infrared survey procedures. It may also be useful to perform some of the Part II infrared surveys contemporaneous to site LOAR monitoring. There will be less feedback on infrared survey effectiveness in Part II, since Sage Environmental Consulting July 2007 Work Plan TOTAL Petro chem icals, In c. TJ?;iL Infrared Imaging Part I Work Plan Draft Internal Version I most of the emphasis will be on imaging non-regulated components. It may provide some longer term input on unit leak rates with Method 21 and infrared imaging . Additional Data Collection Sage plans to collect additional data about each component imaged as a leak by infrared or discovered as a leak by Method 21 during contemporaneous surveys. The list of possible data to be collected includes but is not limited to: • Method 21 Results • Date and Time • Technician and instrument ID (TVA and Camera) • Camera Observation Distance o Distance at first detection o Farthest distance detectable • Lighting o Bright sun o Cloudy bright o Heavy overcast o Shadow o Other -describe • Temperature • Wind Speed o Wind speed in an open area from weather station data o Estimated wind speed at the component • Strong wind • Breeze • Swirling • Still • Other -describe • Precipitation o None o Fog o Drizzle o Rain • Component Service o Gas/Vapor o Light Liquid o Heavy Liquid o Not Regulated • Component Type • Component Subtype , • Component Size • Component Tag# • Component GPS Location ( if available) Sage En vironmental Cons ulting July 2007 Work Plan TOTAL Petrochemicals, In c. rJIAL Infrared Imag ing Part I Work Plan Draft Internal Version I • Operating Temperature • Operating Pressure • Material Composition. Sage Environmental Cons ulting July 20 0 7 Work Plan TOTAL Petrochemicals, In c. T~L Infrared Imaging Part I Work Plan Draft Intern al Version I APPENDIXE ALTERNATE MONITORING PLANS Most Federal and State environmental rules include provisions to allow a site to propose an alternate monitoring plan (AMP) in place of the approach specified in the rule . This appendix discusses several potential AMPs for infrared imaging: • LDAR for regulated components (assuming the EPA Alternate Work Practice (AWP) has not been finalized or the TCEQ has not yet accepted the A WP); • Cooling tower leak detection; and • External floating roof tank seal gaps. Each of these is discussed below. LDAR for Regulated Components An alternate monitoring plan (AMP) for LDAR will not be necessary if the EPA Alternate Work Practice in 40 CFR 60 .18 is finalized and accepted by TCEQ. It might be necessary to develop an AMP for infrared imaging of regulated components if TCEQ is slow to accept the EPA A WP or if the final EPA A WP includes some unacceptable conditions . The contemporaneous infrared and Method 21 monitoring data should provide a large volume of information about the detection limits of infrared imaging and how to carry out an effective infrared survey. If necessary, these data can be used to structure a white paper that could be submitted as a request for an AMP to EPA and/or TCEQ. Cooling Tower Leak Detection The standard test for leaks from cooling water return lines is the El Paso method, which uses a stripper to remove any volatile hydrocarbons from the cooling water and a portable analyzer to measure the hydrocarbon concentration. Infrared imaging will be conducted at the same time that the El Paso test is performed, ideally several times for several different cooling towers. While the El Paso test is being done , the imaging team will attempt to image hydrocarbons evaporating from the El Paso test setup as well as the cooling water return inlet to the cooling tower and the plumes from the cooling tower fans. The key will be to see if the infrared can image a leak that is detected by the El Paso test, so the infrared team should be called out to survey the cooling towers every time an El Paso test finds a leak. Data will be collected showing the relative ability to detect leaks by the El Paso test and infrared imaging . If the data looks promising, a white paper will be prepared that could be used as part of a submittal to TCEQ requesting an AMP for cooling towers. Sage En viro nmental Co ns ulti ng J uly 2007 Wo rk Plan TOTAL Petroch em icals, In c. TJ2iL Infrared Imag ing Part I Work Plan Draft Internal Ve rsion I External Floating Roof Tank Seal Gaps Infrared surveys will be conducted before , during , and after traditional seal gap measurements are made on external floating roof tanks . Surveys conducted before traditional measurements will show the potential for infrared to detect significant areas of leakage in a manner that is unbiased by gap measurements . During traditional gap measurements , the technician will be instructed to call out any gaps found above the level of significance so that the infrared operator can attempt to imaging the leak and capture video that ties gap size to a leak image . Surveys after traditional gap measurements will allow the infrared team to optimize their viewing angles to try to detect any significant gaps that could not be imaged before/during traditional measurements. There is much informal information indicating that infrared can image leaks from floating roof tank seals . The experiments described above could provide information to establish the relati ve sensitivity of gap seal measurement vs. infrared imaging . The relative levels of sensitivity shown by this data could lead to varying AMP proposals: • If gap seal measurement is more sensiti ve , the white paper might propose the use of infrared surveys more frequently than current requirements for gap tests as an AMP ; or • If the infrared imaging is more sensitive , the white paper might establish the leak image parameters that would trigger a need for seal repair as part of an AMP performed at the current frequency for gap seal tests. The white paper will include the camera settings and survey parameters needed to achieve results that match those of the demonstration tests. Sage Enviro nm e ntal Co nsulting July 200 7 Wo rk Plan TOTAL Petrochemicals, In c. TJ?,n Infrared Im aging Part I Work Plan Draji Intern al Vers ion I Evaluating HAP Trends: A Look at Emissions, Concentrations, and Regulation Analyses for Selected Metropolitan Statistical Areas Regi Oommen, Jaime Hauser, Dave Dayton, and Garry Brooks Eastern Research Group, Inc. (ERG, Inc.), 1600 Perimeter Park Dri ve, Morrisville, NC 27560 Regi .Oommen@erg.com ABSTRACT EPA' s annual Trends Report1 is tasked with characterizing the state of air quality for the nation. Most of the reports in the past focused on criteria pollutant trends for emissions and concentrations; few analyses were conducted for hazardous air pollutants (HAPs) due to the limited amount of data available. Since the passage of the Clean Air Act Amendments in 1990, much time and resources have been directed at quantifying HAP emissions and concentrations and regulating HAP emission sources. Historical concentration and emissions data were retrieved from EPA for select metropolitan statistical areas (MSAs) spanning from 1990 to 2003, for the purpose of evaluating trends for specific HAPs. Within the last 10 years, EPA has implemented several air regulations to reduce stationary and mobile source HAP emissions, and these reductions should correspond to reductions in ambient monitoring concentrations. Annual and seasonal trend graphs were generated to evaluate possible correlations between the imposition of HAP regulations and reductions in HAP emissions and ambient concentrations. Targeted HAPs for this study include: benzene, ethylbenzene, toluene, xylenes (total), acetaldehyde , formaldehyde, and some metal compounds. INTRODUCTION Under earlier versions of the Clean Air Act ( 1960, 1963, 1977), the primary legislative focus from the United States Environmental Protection Agency (EPA) was on criteria pollutants (lead, NOx, S02, CO, PM, and VOCs). Extensive work on source characterization, control device options, and monitoring took place under these Acts. The vast monitoring network of ambient air instruments across the nation is used to assess the nation's air quality. These findings are reported by EPA in its annual Trends Report. However, due to limited availability of data, hazardous air pollutant (HAP) trends were not calculated. Since the passage of the 1990 Clean Air Act Amendments (CAAA),2 EPA has spent considerable time and resources in establishing federal regulations to reduce emissions for HAPs. The goal of this study is to review HAP ambient monitoring, emissions, and regulatory data from the last 14 years across ten metropolitan statistical areas (MSAs) with the purpose of characterizing HAP trends at each of these MS As, and across the nation. POLICY-RELEVANT QUESTIONS In this type of study, it was important to develop conclusions based on the available data. To guide our analyses, we asked three policy-relevant questions: 1. What are the HAP concentration trends? 2. Have HAP-specific federal regulations been effective at reducing ambient concentrations? 3. Do HAP emissions show a decline due to HAP-specific federal regulations? To answer these three questions, we focused our study on a selected number of HAPs, specific Metropolitan Statistical Areas (MSAs), and a study period from 1990 to 2003. Detailed information is described below. Pollutants of Interest The 1990 CAAA shaped early monitoring programs. The amendments emphasized collecting, reporting, and regulating HAPs (also called air toxics). Air toxics are those pollutants known or suspected to cause cancer or other serious health effects. Currently, 188 HAP categories (with over 700 subspecies) are regulated under the Clean Air Act.3 These HAPs may contribute to a wide variety of adverse ecosystem and health problems, including cancer and noncancer effects. Noncancer effects include neurological effects, reproductive effects, and developmental effects. Emissions from multiple sources , including major stationary, area, and mobile sources, result in population exposure to these air toxics compounds. In some cases the public may be exposed to an individual air toxic. More typically, however, people experience exposures to multiple air toxics from many emission sources. Exposures result not only from the direct inhalation of air toxics , but also from multi-pathway exposures such as drinking water contaminated from airborne deposition of HAP-laden particles , deposition on skin, and various routes to ingestion in contaminated food. Several EPA programs have been built around subsets of the total HAPs , such as the 112( c )( 6) program,4 the 112(k) program,5 and the core HAPs designated by EPA under the National Air Toxics Assessment (NATA).6 For this study, we targeted the following HAPs: HAP Type Cancer Effect Noncancer Effect Acetaldehyde Carbonyl X X Benzene voe X X Cadmium Metal X X Ethylbenzene voe X X Formaldehyde Carbonyl X X Lead Metal X Mercury Metal X Toluene voe X Xylenes (total) voe X Benzene, ethylbenzene , toluene, acetaldehyde , and formaldehyde do not have multiple isomers or species, and are also considered their own pollutant group . For pollutants that have multiple isomers or species , such as the metallic HAP compounds, averages were computed. For the individual xylene species, the isomer concentrations were summed to compute a total xylene value . Each of the targeted HAPs has corresponding cancer and/or noncancer toxicity factors . MSAs of Interest The initial list ofMSAs targeted comes from ERG's work operating EPA's Urban Air Toxics Monitoring Program (UATMP). For this study, we applied the MSA boundaries for year 2003, as designated by the Office of Management and Budget (OMB).7 An MSA is defined by the counties associated with the MSA, as listed by the U .S. Census Bureau designations.7 For example, Camden County, NJ (FIPS = 34007), in which CANJ (AQS site ID= 34-007-0003) is a UATMP monitor in that county, is part of the Philadelphia-Camden-Wilmington, PA-NJ-DE-MD MSA. According to the 2003 U.S. Census Bureau, ten other counties are part of this MSA: • New Castle County, DE (FIPS = 10003); • Chester County, PA (42029); • Cecil County, MD (24015); • Delaware County, PA (42045); • Burlington County, NJ (34005); • Montgomery County, PA (42091); • Gloucester County, NJ (34015); • Philadelphia County, PA ( 42101) • Salem County, NJ (34033); • Bucks County, PA ( 42017); In 2004, several state agencies with large MSAs participated in the UATMP. Previous year-end reports limited the geographic area to the monitor, thus limiting the number of years for constructing a trend. For the 2004 report , the trends analyses portion increases from the participating monitor to the monitors within the MSA, thereby potentially increasing the amount of study years available. Of the ten MSAs ERG chose, six have monitors participating in the 2004 UATMP. Each of the six monitors also represents one of EPA's ten regions. The remaining four MSAs represent the four EPA regions not chosen from the UATMP report. The MSAs for this study are as follows (2004 UATMP MSAs are denoted with an *): • Region 1: (*) Boston-Cambridge-Quincy, MA-NH MSA • Region 2: (*) New York-Northern New Jersey-Long Island, NY-NJ-PA MSA • Region 3: (*) Philadelphia-Camden-Wilmington, PA-NJ-DE-MD MSA • Region 4: (*) Tampa-St. Petersburg-Clearwater, FL MSA • Region 5: (*) Detroit-Warren-Livonia, MI MSA • Region 6: Dallas-Fort Worth-Arlington, TX MSA • Region 7: (*)St.Louis, MO-IL MSA • Region 8: Denver-Aurora, CO MSA • Region 9: Los Angeles-Long Beach-Santa Ana, CA MSA • Region 10: Seattle-Tacoma-Bellevue, WA MSA It should be noted that although the Dallas , TX MSA and Denver, CO MSA are not participating in the 2004 UATMP , they were participants of previous UATMP years. Each MSA in this study showed moderate to substantial increases in population and vehicle miles traveled (VMT) during the time period considered (Table 1 ). Time Period of Interest Our time period for this study spanned from 1990 to 2003. The first HAP emission inventory developed by EPA was for the 1990 base year to coincide with the passage of the 1990 CAAA. HAP emission inventories were also developed for the 1996, 1999 , and 2002 base years, thus providing emissions data before and after several regulations from the CAAA were implemented. Specifically over the last 10 years, EPA has implemented several air regulations to target stationary and mobile source HAP emissions, and these reductions should correspond to reductions in ambient monitoring concentrations and emissions. This time period also captures the period where a number of federal, state, and local agency HAP monitors and networks were placed or expanded across the nation, including the UATMP, PAMS , and Pilot City Monitoring data sets. The time period also does not conflict with EPA's plans for calculating HAP trends. Beginning in 2004, EPA established a HAP monitoring network of 22 sites called the National Air Toxics Trends Subsystem (NATTS), which is to serve a similar function as the well- established criteria pollutant monitoring network. METHODOLOGY In calculating trends for this study, ERG retrieved three types of information from EPA: 1) HAP ambient monitoring data ; 2) HAP emissions data; and 3) implemented federal stationary and mobile source rules. Ambient Monitoring Data The primary data sources for the HAP ambient monitoring data were from the EPA historical archive (HA)8 and the Air Quality Subsystem (AQS).9 The HA contained nationwide HAP data from 1990-2000, while the AQS data contained state/local/tribal-submitted data for 2001-2003 . Under contract to EPA , ERG compiled, supplemented, and quality-assured the three data sources into a single comprehensive database. The concentrations were standardized to micrograms per cubic meter (µg/m3). Additional quality assurance /quality control (QA/QC) checks were performed on a subset of the entire data set for approximately 30 HAPs. To evaluate trends, ERG chose to calculate annual and seasonal MSA averages using a modified approach to an EPA-approved procedure. 10 The following steps were performed: 1. Calculate pollutant group averages . As described earlier, the metal compounds were averaged , while the xylene species were summed together. 2. Calculate valid daily site ave rages from the pollutant group averages. Most of the data in the merged database were daily samples, and no adjustments were needed . For sub- daily data (hourly, 3-hour, 6-hour, etc.), a minimum of 18 hours of sampling data within a day was needed to establish a valid daily average . Thus , if a site had seventeen 1-hour concentrations in a particular day, the average of those concentrations would not be considered a valid daily average. 3. Calculate valid seasonal site averages from th e valid daily s ite averages . Each season is assumed to have 91 days. If samples were collected l-in-6 days , then up tol5 samples can be collected per season . Some sites sampled with less frequency , such as 1-in-12 days , which is less than 8 samples per season. For a site to have a valid seasonal average, a minimum of seven valid daily averages is needed. 4 . Calculate seas onal MSA averages from the valid seasonal site averages . The valid seasonal averages for each site within the MSA were averaged together. 5. Calculate valid annual site averages from th e valid seasonal site ave rages. An annual average is the average of the valid seasonal averages. A minimum of two seasons is needed to compute a valid annual average. 6 . Calculate annual MSA averages from the valid annual site averages. The valid annual averages for each site within the MSA were averaged together. Table 2 summarizes the number of sites by time period and pollutant which were used in this study. For the MSAs of interest, lead compound monitoring sites were the most prevalent for the 1990 to 1994 and the 2001 to 2003 time periods ( 110 and 84 sites , respectively). Conversely, acetaldehyde monitoring was the lowest in the 1990 to 1994 time period (9 sites), while mercury monitoring was the lowest for the 2001 to 2003 time period (36 sites). It should be noted that HAP ambient monitoring sampling methods were not consistent during the entire study period, as monitoring methods have improved over time . However, the data used for this analysis represent the best data available. No adjustments were made to account for differences in monitoring methods. Emissions Data Data from the National Emissions Inventory (NEI) 11 for base years 1990 and 2002 were retrieved from EPA for the targeted HAPs . Using an approach similar to that used for the concentration data, total MSA emissions were calculated using the following steps: 1. Retrieve emissions from NE! for base years 1990 and 2002. Emissions data for 1990 were at the county-level , but still delineated between stationary (point sources and area nonpoint sources) and mobile sources . Emissions data for 2002 contained stationary source data at the facility-and county-level. 2. Calculate county-level emissions by HAP. Emissions for each base year were summed to the county-level by targeted HAP. Stationary and mobile source emission types were retained. 3. Calculate MSA emissions by HAP. Using the MSA-county designations, the MSAs of interest were summed by HAP and emission type. Similar to the ambient monitoring trends, emission estimation methodologies/models have improved over the study period . However, no adjustments were made to account for these differences. Implemented HAP Regulations The final component for the trends analyses involves identifying implemented HAP regulations. Federal air regulations for stationary and mobile source HAPs were researched for applicability and for implementation dates (i.e ., when sources need to comply). These dates were compiled for over sixty regulations which affect our time period. All legislation corresponded to the passing of the 1990 CAAA. Specifically, Titles I, II and III of the 1990 CAAA contain legislation to reduce HAP emissions from stationary and mobile sources: • Under Title I, NSPS and NAAQS Programs, Solid Waste Combustion MACT Regulations and National Volatile Organic Compound Emission Standards (NVOCES) were two of several sub- programs to be enacted; • Under Title II, Mobile Sources Program, the following sub-programs were to be enacted: 1. Motor Vehicle Emission Standards (also called Tier I and Tier II); 2 . Fuel and Fuel Additives (including Prohibition of leaded gasoline); 3 . Aircraft Emission Standards; and 4. Clean-Fuel Vehicles. • Under Title III, NESHAP Program, the following sub-programs were to be enacted: 1. National Urban Air Toxics Strategy; 2. NESHAP Standards (post-1990); A. 112(c)-Specific regulations for 8 HAPs; B. 112(d) -Specific regulations for 170+ MACT source categories; C. 112(f)-Residual Risk Program; and D . 112(k)-Specific regulation for 30+ HAPs. 3. State Programs; and 4. Accidental Release Prevention Program. Although not considered for this study, regulations for Title IV and Title V will reduce HAPs indirectly: • Under Title IV , Acid Rain Program, electric-generating units using coal were required to install scrubbers to reduce criteria pollutant emissions, including particulate matter. Consequently, metallic HAP concentrations should decrease accordingly. Phase I of this program was to take place in 1995, while Phase II was to take place in 2000. • Under Title V, Permitting Program, state agencies issue operating permits to facilities limiting · maximum potential emissions. These limits, typically for criteria pollutants, may indirectly reduce HAP emissions. Of the specific sub-programs listed above , only the Solid Waste Combustion MACT (Section 129), the National VOC Emission Standards (NVOCES, Section 183), the Motor Vehicle Emission Standards (Section 202), Fuel and Fuel Additives (Section 211 ), and over forty Section 112( d) NESHAPs have federal regulations implemented from 1990 to 2003. Reductions due to Title V were not considered , as they were implemented at the state-level. To identify federal stationary source regulations for the above sub-programs, ERG used the 2002 NEI for point and area nonpoint sources for each MSA. In these inventories , MACT codes are identified for each facility (in the point inventory) or source category (in the area nonpoint inventory). Since each MSA is unique in its emission source makeup , each MSA is subject to different stationary source regulations. Since 1990, seventy-three of 143 MACT source categories promulgated have been implemented. Mobile source rules are generally for the entire country ( e.g. -National Low Emissions Vehicles) or for specific MSAs (e .g. -Reformulated Gasoline for some ozone nonattainment areas). NVOCES categories , such as architectural surface coating, consumer products, and autobody refinishing, typically are found in all areas. Table 3 is a summary of the CAAA federal regulations that were implemented during our study period. Sixty-four HAP-specific regulations were implemented during our study period; forty-four were implemented between 1995 and 2001. While it's difficult to definitively conclude that concentrations decreased due to the implementation of certain regulations, it's useful to analyze concentrations pre-and post-implementation to conclude an apparent effect on emissions. RESULTS The combination of the ambient monitoring data, emissions data, and implementation dates of stationary and mobile source rules were the basis for our trends analysis. The following sections describe the concentration and emissions trends for each MSA. Tables 4a-i provide an emissions and concentration trends summary by HAP and MSA . Due to availability of ambient monitoring data, we chose to average 1990-1994 concentrations and 2002-2003 concentrations. To evaluate a trend, we compared the average concentrations from two time periods. For each MSA and HAP , there were 57 combinations which had concentration values during both of these time periods; of those, over 85% of the HAPs measured across the ten MS As presented a decrease in their HAP concentrations. These sub-time periods overlap with the NEI baseyear (1990-1993) and latest year (2002) emissions inventory. When comparing emission estimates from the 1990 NEI and the most recent 2002 NEI, HAP emissions for each MSA decreased substantially; total emissions across the MSAs decreased from 580,000 tpy to 270 ,000 tpy (53% reduction). An interesting observation in this study was the relationship between reducing emissions and the apparent effect on concentrations. More than half of time period comparisons in emissions and average concentration (30 of 57) realized percentage reductions within 20% of each other, with one as close as 1 %; the Los Angeles MSA total xylene emissions decreased by 73%, while average concentration decreased by 74% (Table 4i). Regulation impact analyses figures were constructed for each MSA and pollution group, and are posted at Eastern Research Group's FTP site 12 due to space limitations for this paper. However, for this paper, we have included two figures per MSA. Implemented regulations are coded in the figures using the graph key from Table 3. Boston MSA • The Boston MSA experienced a 7% increase in population and a 74% increase in vehicle miles traveled (VMT) from 1990 to 2003. This MSA 'participated in the winter-oxygenated program from 1992 to 1996 and the reformulated gasoline program during the study period. • Although there were increases in population and VMT during the study period, the emissions for all the pollutants of interest decreased from 30% (acetaldehyde) to 84% (mercury). The VOC and metal HAPs decreased in their average concentrations, ranging from 4 7% ( ethylbenzene) to 94% (total xylenes). Acetaldehyde and formaldehyde concentrations, in contrast, increased during our study period ( +640% and+ 300%, respectively). • The Boston MSA phased out of the winter-oxygenated fuel program in 1996, but still participates in the reformulated gasoline (RFG) program. According to Figures 2 and 3, acetaldehyde and formaldehyde concentrations appeared to increase after the implementation of RFG Phase II and the POTW MACT. Since emissions for these HAPs have decreased substantially, this may suggest that they are forming as secondary pollutants . Research has shown increases in carbonyl concentrations due to implementations of the RFG Program (Phase I and Phase II).13 New York City MSA • The New York MSA experienced an 11 % increase in population and a 29% increase in VMT from 1990 to 2003. This MSA participated in the winter-oxygenated program and the reformulated gasoline program during the study period . • Although there were increases in population and VMT during the study period, the emissions for all the pollutants of interest decreased from 29% (total xylenes) to 84% (mercury). Similarly, all the pollutants of interest decreased in their average concentrations, ranging from 24% ( cadmium) to 95% (mercury). • Benzene concentrations in the New York MSA decreased, as shown in Figure 4, after implementation of mobile source rules (winter-oxygenated fuel and reformulated gasoline). The federal rules targeting stationary sources (Degreasing, Gasoline Distribution Stage I, etc.) did not appear to reduce benzene concentrations. • Mercury concentrations appeared to decrease after implementation of the Petroleum Refineries MACT , Reformulated Gasoline Phase II program, and the Large Municipal Waste Combustors MACT (Figure 5). Philadelphia MSA • The Philadelphia MSA experienced a 6% increase in population and a 57 % increase in VMT from 1990 to 2003. This MSA participated in the winter-oxygenated program and the reformulated gasoline program during the study period. • Although there were increases in population and VMT during the study period, the emissions for all the pollutants of interest, except for cadmium, decreased from 49% (lead) to 71 % (mercury). Cadmium emissions increased 110%. All the pollutants of interest, except cadmium, decreased in their average concentrations, ranging from 65 % (benzene) to 99 % (lead). Average cadmium concentrations increased from 0.45 ng/m 3 to 4 .6 ng /m3 . • Closer examination of the emissions data indicates a possible error in the 2002 area nonpoint emission estimates for three combustion categories in the Philadelphia MSA: industrial boilers using residual oil , institutional/commercial heating using residual oil , and industrial boilers using bituminous and lignite coal. The total cadmium emissions for these three categories in the Philadelphia MSA increased from 0 .038 tons per year in 1990 to 5.7 tons per year in 2002 , which matches the large increase in cadmium emissions . • Cadmium compound concentrations appeared to increase throughout the study period in the Philadelphia MSA (Figure 6); however, limited or no data are available from 1998-2000. There was one site (AQS ID= 42-045-0002) which measured cadmium in both time periods. Average concentrations increased from 0.45 ng/m3 in the early time period to 4 .3 ng/m3 in the later time period, which matches the trend in Table 4c. • As shown in Figure 7, lead compound concentrations appeared to decrease substantially after implementation of the Secondary Lead Smelter MACT and the Gasoline Distribution Stage I MACT. Tampa Bay MSA • The Tampa Bay MSA experienced a 22 % increase in population and a 73 % increase in VMT from 1990 to 2003 . This MSA does not participate in either the winter-oxygenated program or the reformulated gasoline program . • Although there were increases in population and VMT during the study period, the emissions for all the pollutants of interest decreased, ranging from 22 % (benzene) to 96% (cadmium). Lead was the only HAP to have a 1990-1994 average calculated, and that concentration decreased by 61 %. Limited or no data were available for the other HAPs during the 1990-1994 time period. • According to Figure 8, lead compound concentrations appeared to decrease overall during the study period , most notably after the Secondary Lead Smelting MACT. • Although toluene concentrations have decreased during the study period (Figure 9), there is limited toluene data in the Tampa MSA for the last five years , thereby making it difficult to establish a trend . Detroit MSA • The Detroit MSA experienced a 6% increase in population and a 29% increase in VMT from 1990 to 2003. This MSA does not participate in ei ther the winter-oxygenated program or the reformulated gasoline program. • Although there were increases in population and VMT during the study period, the emissions for all the pollutants of interest, except cadmium and lead, decreased ranging from 32% (benzene) to 79 % (mercury). Cadmium and lead emissions increased by 36 % and 67 %, respectively. Concentrations for the VOC HAPs and for lead decreased during the study period, ranging from 9% (ethylbenzene) to 39 % (lead). Limited or no data were available for the acetaldehyde, cadmium, formaldehyde , or mercury during the 1990-1994 time period. • Closer examination of the cadmium emissions data shows a large cadmium emission source , Perma-Fix of Michigan, reporting emissions at 1.50 tons in 2002. This facility is not accounted for in the 1990 NEI, thereby explaining the increase in MSA emissions. It is assumed that this facility was not operational in 1990 or the emissions were below reporting thresholds. If those emissions are removed, then the emissions decrease by 53 %. • Closer examination of the 2002 lead emissions shows that over 17 tons are emitted from two oil- fired utility boilers, Detroit Edison Greenwood Energy Center and St. Clair/Belle River Power Plant. In 1990, the entire emissions from oil-fired utility boilers for the Detroit MSA is 0.21 tons , suggesting that the 1990 estimates are too low. • Lead concentrations in Detroit appeared to decrease steadily during the study period (Figure 10). The biggest effect appears to be related to the implementation of the Large Municipal Waste Combustors MACT. • Although total xylene concentrations had little variance throughout the 1990s (Figure 11), it is unclear how stationary source rules affected xylene concentrations due to the limited data availability of xylene measurements from 1997-2000, when several regulations were implemented. Dallas MSA • The Dallas MSA experienced a 40% increase in population and a 36% increase in VMT from 1990 to 2003. This MSA participated in the reformulated gasoline program during the study period. • Although there were increases in population and VMT during the study period, the emissions for all the pollutants of interest decreased from 36% (total xylenes) to 83% ( cadmium). All the pollutants of interest decreased in their average concentrations, ranging from 36% (benzene and lead) to nearly 100% (mercury). Limited or no data were available for acetaldehyde, cadmium, or formaldehyde during thel990-1994 time period . • Benzene concentrations in Dallas show a downward trend (Figure 12), primarily in response to implementation of Tier 1 Mobile Standards. • Mercury compound concentrations appeared to have decreased substantially with the implementation of the Reformulated Gasoline Phase 1 Program (Figure 13). However, according to the NEI, mercury emissions from Hazardous Waste Combustors decreased by 97% from 1996 to 2002 for this MSA, most likely as a result of impending regulations . St. Louis MSA • The St. Louis MSA experienced a 6% increase in population and a 38% increase in VMT from 1990 to 2003 . This MSA participated in the reformulated gasoline program during the study period. • Although there were increases in population and VMT during the study period, the emissions for all the pollutants of interest decreased from 46% ( acetaldehyde) to 89% (lead). All the pollutants of interest, except acetaldehyde, ethylbenzene, and formaldehyde decreased in their average concentrations, ranging from 21% (toluene) to nearly 89% (total xylenes). Average acetaldehyde, ethylbenzene, and formaldehyde concentrations increased 79%, 9%, and 222%, respectively . • Overall , cadmium compound concentrations in the St. Louis MSA appeared to have decreased during the study period (Figure 14). The implementation of the Reformulated Gasoline Phase 2 Program and the Primary Lead Smelting MACT coincide with these reductions. However, no implemented regulations explain the increases and decreases in the 1996, 1997, and 1999 concentrations. • Total xylene concentrations in the St. Louis MSA declined dramatically in apparent response to several implemented stationary and mobile source regulations targeting VOCs (Figure 15). However, the lack of xylene data measurements between 1995 and 2000 limit the certainty of these conclusions . Denver MSA • The Denver MSA experienced a 39% increase in population and a 75% increase in VMT from 1990 to 2003. This MSA participated in the winter-oxygenated program, but not the reformulated gasoline program during the study period. • Although there were increases in population and VMT during the study period, the emissions for all the pollutants of interest decreased, ranging from 11 % (lead) to 97% (mercury). Cadmium and lead were the only HAPs to have 1990-1994 averages calculated, and those concentrations decreased by 90% and 54%, respectively. Limited or no data were available for the other HAPs during the 1990 to 1994 time period. • As shown in Figure 16, over the last four years, acetaldehyde concentrations appeared to decrease after implementation of mobile source rules (winter-oxygenated fuel program and the National Low Emissions Vehicle Program Phase II). • For the cadmium trend (Figure 17), no implemented stationary source regulations were identified in the Denver MSA which affected cadmium concentrations. To understand this decline, we reviewed the NEI and Toxic Release Inventory 14 from 1990-1994 for cadmium emissions . One facility, Asarco, Inc. Globe Plant, which is a cadmium refining and cadmium oxide production plant reported emissions in 1990 as 0.20 tpy. By 1994 , the emissions decreased to 0.078 tpy, a 61 % decrease in emissions . Emissions at this plant through 2002 remain constant. It's likely that the decrease in cadmium emissions from this plant contributed to the decrease in ambient cadmium concentrations . Los Angeles MSA • The Los Angeles MSA experienced a 14% increase in population and a 16% increase in VMT from 1990 to 2003. This MSA also participated in the winter-oxygenated program and the reformulated gasoline program during the study period. • Although there were increases in population and VMT during the study period, the emissions for all the pollutants of interest decreased from 40% ( acetaldehyde) to 81 % (mercury). Similarly, all the pollutants of interest decreased in their average concentrations, except for cadmium and formaldehyde, ranging from 24% (acetaldehyde) to 85% (lead). Average cadmium concentrations increased from 0 .78 ng/m3 to 3 .79 ng/m3, while formaldehyde concentrations increased by 65%. • There was one site (AQS ID= 06-037-1103) which measured cadmium in both time periods. Average concentrations increased from 0.95 ng/m3 in the early time period to 3.8 ng/m 3 in the later time period, which is similar to the MSA concentration increase presented in Table 4c. Cadmium emissions, however, decreased by 51 %. This observation suggests that most likely the emission inventories are incorrect, and need to be further investigated. • Ethylbenzene concentrations in the Los Angeles MSA declined steadily in apparent response to several implemented stationary and mobile source regulations targeting VOCs (Figure 18). • Formaldehyde concentrations have steadily increased during the study period (Figure 19). This is most likely due to the implementations of the RFG Program (Phase I and Phase II), which creates formaldehyde secondarily. This trend was observed in the Boston MSA. Seattle MSA • The Seattle MSA experienced a 23% increase in population and a 27% increase in VMT from 1990 to 2003. This MSA participated in the winter-oxygenated program from 1992-1996, but not the reformulated gasoline program. • Although there were increases in population and VMT during the study period, the emissions for all the pollutants of interest decreased ranging from 25% ( ethyl benzene and total xylenes) to 91 % ( cadmium and mercury). Lead was the only HAP to have a 1990-1994 average calculated, and that concentration decreased by 96%. Limited or no data were available for the other HAPs during the 1990 to 1994 time period . • Over the last three years, formaldehyde concentrations appeared to have increased, noticeably after the implementation of the Publicly Owned Treatment Works MACT (Figure 20). However, formaldehyde data prior to 2001 are limited or unavailable, thus making it difficult to characterize a trend. • During the study period, lead concentrations appeared to have decreased (Figure 21). After implementation of the Petroleum Refineries and Aerospace Manufacturing MACTs, concentrations decreased substantially. Interestingly, lead concentrations increased after the prohibition of leaded gasoline. CONCLUSIONS Nine HAPs were analyzed for MSAs across the United States. Each MSA was chosen from one of EPA 's ten regions. ERG used a database consolidated from EPA 's Historical Archive and from the Air Quality Subsystem to calculate annual average concentrations. Emissions for each HAP were retrieved from EPA's National Emissions Inventory, 1990 to 2002. Information on federal regulations were researched from the 1990 Clean Air Act Amendments (CAAA). Three policy-relevant questions were used to guide our study, and we answer these questions below: • What are the hazardous air pollutant (HAP) concentration trends? When comparing concentrations between 1990-1994 and 2002-2003, over 85% of the MSA-HAP combinations measured across the ten MSAs realized a decrease in their HAP concentrations, while less than 15% realized an increase. This observation would suggest that most HAPs had a decreasing trend during the study period. For example, lead compound concentrations decreased in all ten MSAs (range 36% to 99%), while benzene decreased in seven (range 19% to 79%). However, acetaldehyde, cadmium compounds, ethylbenzene, and formaldehyde each had at least one MSA that computed an increasing trend . Additionally, more than half of the percentage reduction comparisons for concentrations and emissions (30 of 57) were within 20% of each other, with one as close as 1 % ( e.g., Los Angeles total xylene emissions: 73 % decrease in emissions, 74% decrease in average concentration). • Have HAP-specific federal regulations been effective at reducing ambient concentrations? Sixty-four HAP-specific regulations were implemented between 1992 and 2003. During that time period, most HAP concentrations decreased, suggesting a correlation between the two . The most effective regulations on pollutant types, based on visual inspection of the regulation impact analysis figures , were: 1. VOCs: Reformulated Gasoline Phase I, VOC rules, Printing/Publishing MACT, Tier 1 Mobile Source Standards, Reformulated Gasoline Phase II 2 . Carbonyls: Reformulated Gasoline Phase I , National Low Emissions Vehicle Program Phase II , Pharmaceuticals Production 3. Metals: Prohibition of Leaded Gasoline, Aerospace Manufacturing MACT, Petroleum Refineries MACT, Reformulated Gasoline Phase II , Large Municipal Waste Combustors MACT, Secondary Lead Smelter MACT, Stage I Gasoline Distribution MACT, Primary Lead Smelter MACT • Do HAP emissions show a decline due to HAP-specific federal regulations? When comparing emission estimates from the 1990 NEI and the most recent 2002 NEI, HAP emissions for each MSA decreased substantially. Total HAP emissions across the ten MSAs decreased from 580,000 tpy to 270,000 tpy (53% reduction). Emissions in the Los Angeles MSA decreased the most among the MSAs (69% reduction, 86,000 tpy). For the HAPs, mercury emissions realized the highest percent reduction (80%), while toluene emissions realized the highest mass reduction (140 ,000 tpy). Between 1991 and 2001 , over 40 HAP-specific regulations were implemented, suggesting that HAP emissions declined due to these regulations . Using the above observations , the implementation of HAP-specific federal regulations coincides favorably with reductions in emissions and ambient concentrations for benzene, ethylbenzene, lead compounds, mercury compounds, toluene , and xylenes. REFERENCES 1. U .S . EPA. Latest Finding on Air Quality: 2002 Status and Trends. OAQPS. EPA 454/K-03-001. August 2003. Internet address: http ://www.epa.gov /airtrends/2002 airtrends final.pd[ 2. U.S. EPA. Clean Air Act Amendments. OAQPS. lnternet address: http ://www.epa.gov/air/oag caa.html/ 3. U.S . EPA . The Original List of Hazardous Air Pollutants. Internet address : http://www.epa.gov/ttn/atw/origl89.html 4. U .S. EPA. Notice of Source Category Listings for Specific Pollutants: Section 112(c)(6). Internet address : http ://www.epa.gov/ttn/atw/112c6/112c6fac.html 5. U.S. EPA. Air Toxics Strategy: Overview. Internet address: http://www.epa.g ov /ttn/atw /urban/urbanpg .html 6. U.S. EPA . The National-Scale Air Toxics Assessment. Internet address: http://www.epa.gov/ttn/atw/nat a/ 7. U.S. Census Bureau . Metropolitan and Micropolitan Statistical Areas, 2003. Internet address: http://www.census.gov/population/www/estimates/metroarea.html 8. U.S. EPA. Historical Archive of Ambient Monitoring Data. Data retrieved from Mr. Jawad Touma, U.S. EPA. 9. U.S. EPA. About the AQS Subsystem. Internet address: http://www.epa.gov/air/data/ag sdb.html 10. Sonoma Technologies , Inc. (STI). Database Overview: Cleaning and Averaging. Presentation by Dr. Michael McCarthy, STI. Presented to the Workshop on Air Toxics Data Analysis . Rosemont , IL. June 2-3 , 2004. Internet address: http://www .ladco.org/toxics/ AT%2 0presentations %2 0pdf/Database preparation.pd[ 11. U.S. EPA . National Emission Inventories for the U.S. Internet address: http://www .epa.gov/tt n/ chief/net/index.html 12. Eastern Research Group , Inc. FTP site: ftp://ftp.erg.com/outgoing/Trends/ 13 . Northeast States for Coordinated Air Use Management (NESCAUM). RFG/MTBE: Findings and Recommendations. NESCAUM. August 1999. lnternet address: http://www.nescaum.org/pdf/MTB E PH2 /Ph2swnm .pdf 14 . U .S. EPA. Toxic Release Inventory (TRI) Program. Internet address: http://www.epa.gov/tri/ KEYWORDS Hazardous Air Pollutants (HAPs) HAP Concentration Trends Regulation Analysis HAP Emission Trends Metropolitan Statistical Areas Ambient Air Monitoring Ambient Concentration Trends Table 1. Population and Vehicle Miles Traveled (VMT) Profiles for Each MSA MSA MSA %Change 1990 MSA 2003 MSA % Change Winter-Oxygenated Population Population inMSA VMT VMT inMSA Time Period MSA Reformulated MSA in 1990 in 2003 Population (thousands) (thousands) VMT Implemented Gasoline Desi2nation Boston MSA 4 ,133 ,895 4 ,439 ,971 +7% 18 ,730 ,000 32 ,600 ,000 +74% 1992-1996 Opt-In NewYorkMSA 16 ,863 ,671 18,640 ,775 + 11 % 82 ,100 ,000 I 06,000 ,000 +29% 1992-2000 Required Philadelphia MSA 5,435 ,550 5,772 ,947 +6% 24 ,000 ,000 37 ,600 ,000 +57 % 1992-1996 Required Tampa Bay MSA 2,067 ,959 2 ,531 ,908 +22 % 12 ,300 ,000 21 ,300 ,000 +73 % NA NA DetroitMSA 4 ,248 ,699 4,483,853 +6% 28 ,600,000 36,800,000 +29% NA NA Dallas MSA 3,989 ,294 5,589 ,670 +40 % 29 ,300,000 39 ,800 ,000 +36% NA Opt-In St. Louis MSA 2,599 ,893 2 ,759 ,440 +6% 16,500,000 22,800 ,000 + 38 % NA Opt-In DenverMSA 1,650 ,489 2 ,301 ,116 +40 % 9 ,910,000 17,400 ,000 +75 % 1992-2003 NA Los Angeles MSA 11 ,273,720 12 ,829,272 + 14% 91 ,500,000 106 ,000 ,000 + 16% 1992-2003 Required Seattle MSA 2 ,559 ,136 3,141 ,777 +23 % 19 ,200,000 24 ,400,000 +27 % 1992-1996 NA Table 2 . Number of Ambient Monitors Used Fo r Trends Analysis Time MSA Period Boston MSA 1990-1994 2002-2003 NewYorkMSA 1990-1994 2002-2003 Philadelphia 1990-1994 MSA 2002-2003 Tampa Bay 1990-1994 MSA 2002 -2003 Detroit MSA 1990-1994 2002-2003 Dallas MSA 1990-1994 2002-2003 St. Louis MSA 1990-1994 2002-2003 D enver MSA 1990-1994 2002 -2003 Los Angeles 1990-1994 MSA 2002-2003 Seattle MSA 1990-1994 2002-2003 TOTAL 1990-1994 2002-2003 1 ACET = acetaldehyde B ENZ = benzene CAD = cadmium compounds ACET BENZ CAD AZ 8 3 AZ 8 3 AZ 1 1 2 1 0 9 2 2 2 0 0 5 0 0 7 0 0 3 1 0 2 0 0 1 4 4 6 0 0 2 9 7 39 3 1 0 -4 2 5 0 4 .___ 14 8 2 2 1 -5 6 0 0 0 .___ 0 1 2 2 0 -7 7 2 0 0 .___ 8 4 2 0 7 -4 4 0 0 4 -3 3 8 6 3 -7 I 0 0 0 -2 5 24 11 19 -54 41 ETHYL = ethylbenzene FORM = formaldehyde LEAD = lead compounds 2 A = Number of ambient monitors used for ana lysis 3 B = Number of common monitors between time periods 8j 0 1 1 0 0 0 0 0 1 0 3 POLLUTANT1 ETHYL FORM LEAD AZ 8 j AZ 8 " AZ 8 j 1 1 1 1 2 1 4 2 3 5 0 1 0 14 2 14 9 10 2 2 2 2 18 4 5 2 7 0 0 0 0 3 2 0 5 4 2 2 0 0 3 2 7 7 7 2 0 0 0 24 6 7 3 11 1 0 1 0 23 8 4 2 12 0 0 0 0 7 3 3 1 5 4 3 6 5 12 6 6 6 8 0 0 0 0 4 1 0 2 8 17 8 11 8 110 35 50 39 MERC = mercury compounds TOL = toluene XYL = total xylene 75 MERC TOL XYL A' 8 , AL 8 " A' B" 0 0 3 1 2 1 -2 4 4 4 0 5 0 5 0 - 7 14 14 0 0 2 2 2 2 - 6 5 5 0 0 0 0 0 0 - 1 0 0 0 0 2 2 2 2 2 7 7 1 0 2 0 2 0 - 4 8 7 8 0 2 0 2 0 4 4 4 0 0 0 0 0 0 - 1 3 3 3 1 8 6 6 4 -I 7 7 0 0 0 0 0 0 - 6 0 0 16 1 24 11 21 9 -34 52 51 Table 3. Implemented Federal Regulations from 1990 Clean Air Act Amendments , 1992-2003 Graph Implementation Targeted Key Regulation Date HAPs 1 a Winter-Oxygenated, Season I 1 1/1/1992 V,C,M b Winter-Oxygenated, Season 2 l l/l /1993 V,C,M C Winter-Oxygenated, Season 3 I l/1 /1994 V,C,M d Reformulated Gasoline (RPG) -Stage I 1/1/1995 V,C,M e Winter-Oxygenated, Season 4 11 /1/1995 V,C,M f Coke Ovens 12/3 1/1995 V g Prohibition of Leaded Gasoline for Motor Vehicles 1/1/1996 M h Chromium Electroplating 1/25/1996 V i Industrial Cooling Towers 3/8/1996 NA i Final phase-in of Ti er I Standards 8/1/1996 V ,C k Dry Cleaners 9 /23 /1996 NA I Winter-Oxygenated, Season 5 11 /1/1996 V,C,M m Magnetic Tape (surface coating) 12/15 /1996 NA n Shipbuilding and Ship Repair (surface coating) 12/16/1996 V 0 Polymers and Res ins Manufacturing I 7/31 /1997 NA p Polymers and Resins Manufacturing IV 7/3 1/1997 V,M q Winter-Oxygenated, Season 6 11 /1/1997 V ,C ,M r Wood Furniture (surface coating) 11/21/1997 V,C s Deg reasing Organic C leaners 12 /2/1997 V t Gasoline Distribution Stage I 12/15 /1997 V,C u Secondary Lead Smelting 12/23 /1997 M V National Low Emissions Vehicle Program -Stage I 8/1/1998 V,C w Petroleum Refineries 8/18/1998 V ,C ,M X Aerospace Manufacturing (surface coating) 9/1 /1998 V ,C,M y Winter-Oxygenated, Season 7 11 /1/1998 V ,C ,M z National VOC Emission Standard for Consumer Products 12/1 0/1998 V,C A National VOC Emission Standard for Autobody 1/1/1999 V,C Refini sh ing B Hazardous Organic NESHAP 5/12/1999 V,C C Printing and Publishing (surface coating) 5 /30/1999 V ,C ,M D California Low Emissions Vehicle Program -Stage I 8/1/1999 C E National VOC Rule for Architectural Surface Coating 9/13 /1999 V,C F Marine Vessel Loading 9 /19/1999 V G Primary Aluminum Manufacturing 10/7/1999 V H Winter-Oxygenated, Season 8 11 /1 /1999 V ,C,M I Reformulated Gasoline (RPG) -Stage II 1/1/2000 V,C,M J Off-Site Waste Recovery Operations 2/1/2 000 NA K National Low Emissions Vehicle Program -Stage II 8/1/2 000 V,C L Winter-Oxygenated, Season 9 1 1/1/2000 V,C ,M M Municipal Waste Combustors -Large Units 12/19/2000 C ,M N Pulp and Paper I 4 /15 /200 I V,M 0 Pulp and Paper II 4/16/2001 V,M p Primary Lead Smelting 6 /4 /2001 M Pl Steel Pickling -HCI Process 6 /22 /2001 NA Q Pharmaceuticals Production 9/21/2001 V,C,M R Flexible Polyurethane Foam Production 10/8/2001 V s Winter-Oxygenated, Season I 0 1 1/1/2001 V,C,M T Ferroalloys Production 11/21/2001 NA u Mineral Wool Production 6 /1/2002 NA V Polyether Polyols Production 6 /1/2002 NA w Phosphate Fertilizer Production 6 /10/2002 NA X Phos phoric Acid Manufacturing 6/10/2002 M y Portland Cement Manufacturing 6/14/2002 V,C ,M z Wool Fiberglass Manufacturing 6 /14/2002 V,C Table 3. Implemented Federal Regulations from 1990 Clean Air Act Amendments, 1992-2003 (Continued) Graph Implementation Targeted Key Regulation Date HAPs 1 0 Natural Gas Transmi ssio n and Storage 6/17/2002 V,C I Oil and Natural Gas Production 6/17/2002 V,C,M 2 Generic MACT 6/29/2002 M 3 Hospital , Medical , Infectious Waste Incinerators 9/15 /2002 M 4 Publicly Owned Treatment Works 10/26/2002 V,C,M 5 Winter-Oxygenated, Season 11 11/1/2 002 V,C,M 6 Polymers and Re si ns Production III 1/2 0/2003 V,C,M 7 Secondary Aluminum Production 3/24/2003 V,C,M 8 Hazardous Waste Combustion 9/30/2003 M 9 Winter-Oxygenated, Season 12 11/1/2 003 V,C,M 10 Pesticide Active Ingredients Manufacture' 12/23 /2003 V 1 = NA: Not Applicable; V = VOC HAPs; C = carbonyl HAPs; M = metal HAPs 2 = The implementation date for this MACT, although occurring in 2003, would be considered part of the winter 2004 time period , and was not be considered for this study. Table 4a. Acetaldehyde Emission (tpy) and Concentration (µg/m 3) Comparison % Change 1990-1994 2002-2003 1990 2002 in Average Average % Change in MSA Emissions Emissions Emissions Concentration Concentration Concentration Boston MSA 1,100 790 -30 % 2 .8 ± 0 .5 20.4 ± 5 .3 +630% N ew York MSA 3 ,100 1,300 -57 % 4 .2 ± 1.3 1.9 ± 0.1 -55 % Philadelphia MSA 1,200 620 -50 % 3.4 ± 0 .5 1.0 ± 0.2 -72 % Tampa Bay MSA 540 360 -34% NA 2 .1 ± 0.1 NA Detroit MSA 1,200 630 -47% NA 1.8 ± 0.1 NA Dallas MSA 1,200 570 -54 % NA 1.8 ± 0 .1 NA St. Loui s MSA 820 450 -46% 2 .6 ± 1.2 4 .6 ± 0.4 +79% DenverMSA 660 440 -33 % NA 2 .5 ± 0.2 NA Lo s Angeles MSA 2,400 1,400 -40% 4.7 ± 0.3 3 .6 ± 0.3 -25 % Seattle MSA 1,100 600 -44 % NA 1.7 ± 0 .1 NA Table 4b. Benzene Emission (tpy) and Concentration (µg/m 3) Comparison % Change 1990-1994 2002-2003 1990 2002 in Average Average % Change in MSA Emissions Emissions Emissions Concentration Concentration Concentration Boston MSA 6 ,300 2,200 -64% 3 .9 ± 0.6 0 .8 ± 0.1 -80% NewYorkMSA 17 ,000 7,500 -55 % 3 .2 ± 0 .2 1.4 ± 0 .1 -59% Philadelphia MSA 6,000 2,600 -57% 3 .6 ± 0 .3 1.3 ± 0 .1 -65 % Tampa Bay MSA 3 ,100 2,400 -22 % NA NA NA Detroit MSA 6 ,500 4 ,400 -32% 4 .2 ±0.5 3.4 ± 1.2 -19% Dallas MSA 7 ,900 2,800 -64% 1.2 ± 0 .1 0 .8 ± 0 .1 -36 % St. Loui s MSA 4 ,400 2,300 -47% 5 .2 ± 2 .2 1.4 ± 0 .1 -72 % DenverMSA 2 ,8 00 1,900 -32 % NA 2 .8 ± 0 .2 NA Los Angeles MSA 20,000 4 ,200 -79 % 9 .0± 0 .5 2 .3 ± 0 .1 -74 % Seattle MSA 5 ,8 00 4 ,300 -26% NA 1.4 ± 0.2 NA Table 4c. Cadmium Compound Emission (tpy) and Concentration (ng/m 3) Comparison % Change 1990-1994 2002-2003 1990 2002 in Average Average % Change in MSA Emissions Emissions Emissions Concentration Concentration Concentration Boston MSA 1.0 0.4 -62 % NA 2 .1 ±0.2 NA New York MSA 3 .7 0.9 -75 % 5 .1 ±0.4 3 .9 ± 0 .3 -24 % Philadelphia MSA 2 .9 6 .3 +110% 0 .5 ± 0 .1 4 .6 ± 0 .5 +910% Tampa Bay MSA 9 .0 0.3 -97 % NA 5 .0 ±0.8 NA Detroit MSA 1.7 2 .3 36% NA 1.3 ± 0 .2 NA Dallas MSA 4 .7 0 .8 -83 % NA 3 .0 ± 0 .3 NA St. Louis MSA 8.7 2 .7 -69 % 16.3 ± 3 .2 3.4 ± 0.5 -79 % Denver MSA 0.4 0 .2 -54 % 31.7±8.4 3.2 ±0.6 -90 % Los Angeles MSA 2 .9 1.4 -51 % 0.8 ± 0 .1 3 .8 ± 1.1 +390 % Seattle MSA 1.0 0 .1 -91 % NA 2.0 ± 0 .3 NA Table 4d. Ethylbenzene Emission (tpy) and Concentration (µg/m 3) Comparison % Change 1990-1994 2002-2003 1990 2002 in Average Average % Change in MSA Emissions Emissions Emissions Concentration Concentration Concentration Boston MSA 2 ,600 1,100 -58 % 1.0 ± 0.1 0 .5 ± 0 .1 -47 % NewYorkMSA 8,400 4 ,200 -50 % 2.1±0.1 0 .7 ± 0 .1 -65 % Philadelphia MSA 3,400 1,300 -60 % 1.6 ± 0.2 0 .5 ± 0 .1 -66 % Tampa Bay MSA 1,600 1,100 -27 % NA NA NA Detroit MSA 3,300 1,800 -44 % 1.4 ± 0 .2 1.3 ± 0 .3 -9 % Dallas MSA 3,500 1,500 -57 % 0.7 ± 0 .1 0 .3 ±0.1 -64 % St. Loui s MSA 2,100 1,100 -47 % 0 .8 ± 0.4 0 .8 ± 0.1 +9% DenverMSA 1,300 780 -38 % NA 1.6 ± 0.2 NA Lo s Angele s MSA 7,600 1,900 -75 % 3.9 ± 0.3 1.5 ± 0 .1 -61 % Seattle MSA 2,300 1,700 -25 % NA NA NA Table 4e. Formaldehyde Emission (tpy) and Concentration (µg/m 3) Comparison % Change 1990-1994 2002-2003 1990 2002 in Average Average % Change in MSA Emissions Emissions Emissions Concentration Concentration Concentration Boston MSA 3,700 1,800 -51 % 3.9±0.8 15.0 ± 4 .8 +300 % NewYorkMSA 10,000 4 ,000 -62 % 6.5 ± 2.4 3 .2 ± 0.3 -52 % Philadelphia MSA 4 ,300 2 ,100 -51 % 4 .2 ± 0 .3 1.7 ± 0 .5 -61 % Tampa Bay MSA 1,700 1,100 -38 % NA 3 .4 ± 0.4 NA Detroit MSA 4 ,100 1,700 -59 % NA 4 .0 ± 0 .7 NA Dallas MSA 4 ,300 1,800 ~59 % NA 3.8 ± 0.3 NA St. Louis MSA 2,700 1,300 -53 % 4.1 ± 1.7 13.0 ± 1.3 +220 % DenverMSA 2,200 1,100 -51 % NA 2.8 ± 0 .2 NA Los Angeles MSA 8,000 4 ,700 -41 % 3.3 ±0 .2 5.4 ± 0.3 +65 % Seattle MSA 3,200 1,900 -41 % NA 2.6± 0 .6 NA Table 4f. Lead Compound Emission (tpy) and Concentration (ng/m3) Comparison % Change 1990-1994 2002-2003 1990 2002 in Average Average % Change in MSA Emissions Emissions Emissions Concentration Concentration Concentration Boston MSA 15 .0 7 .0 -54% 47 .6 ± 2.7 9 .0 ± 0.7 -81 % NewYorkMSA 86.0 22 .3 -74% 109 .6± 16 .6 10 .9 ± 1.5 -90 % Philadelphia MSA 69.8 35.6 -49% 848 .0 ± 113 .6 11.7 ± 0.9 -99 % Tampa Bay MSA 21.8 7 .2 -67 % 612.8 ± 83 .9 237 .0 ± 43 .0 -61 % Detroit MSA 19 .0 31.7 +67% 24.9 ± 1.8 15 .2 ± 0.9 -39 % Dallas MSA 38. l 22.9 -40% 124 .2 ± 8.7 79 .3 ± 8.5 -36 % St. Louis MSA 223 .1 23 .7 -89% 785.1 ± 77.7 293 .8 ± 60 .1 -63 % DenverMSA 7 .7 6.9 -11 % 71.3 ± 4 .1 32 .9 ± 5.0 -54 % Los Angeles MSA 63 .5 28.4 -55 % 125.4 ± 14 .2 19 .0 ± 1.9 -85 % Seattle MSA 16.3 3.7 -78 % 116 .5 ±19.7 4.4 ± 0 .3 -96 % Table 4g. Mercury Compound Emission (tpy) and Concentration (ng/m3) Comparison % Change 1990-1994 2002-2003 1990 2002 in Average Average % Change in MSA Emissions Emissions Emissions Concentration Concentration Concentration Boston MSA 3.4 0.5 -84% NA 0 .9±0.J NA New York MSA 7.6 1.3 -84 % 36.4 ± 3.2 1.8 ± 0 .1 -95 % Philadelphia MSA 4.4 1.3 -71% NA 2.3 ±0.2 NA Tampa Bay MSA 1.3 0.2 -87% NA 2 .3 ± 0 .3 NA Detroit MSA 2.5 0 .5 -79% NA 2.2 ±0.2 NA Dalla s MSA 1.8 0.5 -70% 842 .9 ± 124.5 0.9 ± 0.1 -99.9% St. Louis MSA 2 .3 0 .7 -70% 10.3 ± 0.9 2.4 ± 0.4 -77% DenverMSA 1.2 0 .0 -97% NA 2.2 ± 0 .3 NA Los Angeles MSA 5.6 1.1 -81% 7 .7 ± 0 .5 2 .3 ±0.5 -70% Seattle MSA 1.5 0 .1 -91% NA 0.8 ± 0.1 NA Table 4h. Toluene Emission (tpy) and Concentration (µg/m 3) Comparison % Change 1990-1994 2002-2003 1990 2002 in Average Average % Change in MSA Emissions Emissions Emissions Concentration Concentration Concentration Boston MSA 18,000 6,200 -66% 9 .2 ± 1.6 3 .7 ± 0.4 -60% NewYorkMSA 57 ,000 28,000 -50% 12 .1 ± 0.7 4.8 ± 0 .3 -6 1% Philadelphia MSA 25,000 7,600 -70% 12 .0 ± 1.6 3.4 ± 0.3 -72 % Tampa Bay MSA 9,700 6,300 -35% NA NA NA Detroit MSA 25 ,100 12,000 -53% 7.9± 0 .9 5.3 ±0.6 -33% Dallas MSA 24 ,000 9.000 -63 % 3.2 ± 0.5 1.7 ± 0 .2 -47% St. Louis MSA 14 ,000 6,500 -53% 4 .5 ± 1.2 3.6 ± 0 .3 -21% DenverMSA 8,300 5,200 -37% NA 8.4 ± 1.3 NA Los Angeles MSA 54,000 17 ,000 -68% 24 .3 ± 2.0 8.9 ± 0 .3 -64% Seattle MSA 16 ,000 11 ,000 -36% NA NA NA Table 4i. Total Xylenes Emission (tpy) and Concentration (µg /m3) Comparison % Change 1990-1994 2002-2003 1990 2002 in Average Average % Change in MSA Emissions Emissions Emissions Concentration Concentration Concentration Boston MSA 11 ,000 4 ,300 -60% 9.3 ±2.2 0.5 ±0.1 -94% New York MSA 35,000 25,000 -29% 2.1 ±0.1 0 .8 ± 0.1 -63% Philadelphia MSA 15 ,000 5,200 -66% 6.8 ± 0.7 0 .7 ± 0.1 -89% Tampa Bay MSA 6,200 4,300 -30% NA NA NA Detroit MSA 15,000 7,800 -50% 1.8 ± 0.2 1.1 ± 0.2 -38% Dallas MSA 15,000 9,500 -36 % 0 .9±0.1 0.3 ±0.1 -70% St. Louis MSA 9,000 4,600 -49% 12 .9 ± 6.4 1.5 ± 0.2 -89% D enverMSA 5,400 3,200 -41% NA 2.2 ± 0.3 NA Los Angeles MSA 33,000 8,800 -73 % 19 .8±2.1 5.2 ± 0.4 -74% Seattle MSA 9,100 6,900 -25% NA NA NA I / _____ _r-- 1 l.. , .. 1 \ Dalla<J-Ft. WDftn, TX Ms.A ~ I n111pa-st. Pl!let'!<b ~..is.A 0 12:i Z,:, 50(, 7"./J 1.0JC -c::=--==-----=====-----~11., Figure 1. Metropolitan Statistical Areas ln This Stu dy Each MSA repres en ts an EPA Region . The Boston, New York City, Philadelphia, Tampa , Detroit, and St. Louis MSAs are all participants in EPA's 2004 Urban Air Toxics Monitoring Program. Boston-Cambridge-Quincy, MA-NH MSA Average Annual Acetaldehyde Concentrations (1990-2003) 40 Jz,~J D,EJ I J 35 30 ~ 25 I a 2. C: :8 20 I! E ., " C: 0 15 0 l 10 -------.--.---------------/1~--------i :/ ~-----··-/ffl y i .. . . :r. ~ y y " • -----------~-----------------l 1990 1991 1992 1993 1994 1995 1996 1997 1998 1999 2000 2001 2002 2003 Year Figure 2. Boston MSA Acetaldehyde Regulation Impact Analysis After the implementation ofRFG Phase II (graph key= I) and the POTW MACT (gra ph key= 4), ace taldehyde concentrations appeared to have increased in the Boston MSA. Boston-Cambridge-Quincy, MA-NH MSA Average Annual Formaldehyde Concentrations (1990-2003) 30 ~ ~ ~ [:] ~~ ~ ~ 25 20 .; E a 2. C: .2 15 f E ., : : " C: 0 0 : : 10 •• t • yy • 0+--~-------~-------~-------~-------~--- 1990 1991 1992 1993 1994 1995 1996 1997 1998 1999 2000 2001 2002 2003 Year Figure 3. Boston MSA Formaldehyde Regulation Impact Anal ys is Formaldehyde concentrations in the Boston MSA were steady throughout the 1990s . After the implementation of the Large Municipal Waste Combustors MACT (grap h key = M) and POTW MACT (gra ph key= 4), concentrations appeared to have increase d. New York-Northern New Jersey-Long Island, NY-NJ-PA MSA Average Annual Benzene Concentrations (1990-2003) s ~-----------------------------------~ ~ [!] ~ ~ ~ ~ I w,x Jv ,z;AI D,~,Fl ,H,11 . : : : : ~ . . . . . . . . . . . . 4 +---------------~--~-~-------i-----.------.-----------.---~------j 0 +--~-----·----'-,---·---·---·---·~~·-.. --~"'-· ------·~· _. __ ____. 1990 1991 1992 1993 1994 1995 1996 1997 1998 1999 2000 200 1 2002 2003 Year Figure 4. New York City MSA Benze ne Regulation Impact Analysis Benzene concentrations in the New York MSA appeared to have decreased after imp lementation of mobile so urce rules : winter-oxygenated fuel (graph keys = a-c) and reformu lated gaso lin e (graph key = d). Rules targeting statio nary sources did not appear to reduce benzene concentrations . 50 40 .;;- New York-Northern New Jersey-Long Island , NY-NJ-PA MSA Average Annual Mercury Compound Concentrations (1990-2003) ~ ~ ~ [:] ~ ~~ ~ ~ [!] [!] 8 1 30 +-------'"-..----l:----,--+--1--1------!--±ir-\T---!---~--.------...-j .s C: 0 ~ c • g 20 +---------!--~,------------,---l'-!--+'<-~----------+-i 0 0 10 +-------------~-----"'-----~-----1--\--'"--~--;---.a...; .. •• .. + ,. 0+---------------------------------------; t t 1990 1991 1992 1993 1994 1995 1996 1997 1998 1999 2000 2001 2002 2003 Year Figure 5. New York City MSA Mercury Regulation Impact Analysis Mercury concentrations appeared to have decreased after implementation of the Petroleum Refi neries MACT (graph key= w), Reformulated Gasoline Phase II program (graph key= I), and the Large Municipal Waste Combustors MACT (graph key = M). ] Philadelphia-Camden-Wilmington, PA-NJ-DE-MD MSAAverage Annual Cadmium Compound Concentrations (1990-2003) -----·--·-·-----··--··------·---------- 8 !4+--------,_ _ ___,_ __ ___,_ _________ _, ___ _,_ _ _, _ _,,,... __ ....,._ __ _._. C 0 ~ c ~3+------------------------------~-+--------< C 0 u • • 1990 1991 1992 1993 1994 1995 1996 1997 1998 1999 2000 2001 2002 Year Figure 6. Philadelphia MSA Cadmium Compounds Regulation Impact Analysis • 2003 Cadmium compo und concentra tion s appeared to have increased throughout th e study period in th e Philadelphia MSA, however, limited or no data is avai lab le from 1998-2000 . 1500 1350 1200 1050 ;:;- E 900 a -=-C 0 750 ~ c .. u 600 C 0 u 450 300 1990 Philadelphia-Camden-Wilmington, PA-NJ-OE-MO MSA Average Annual Lead Compound Concentrations (1990-2003) 1991 1992 1993 1994 1995 1996 1997 1998 1999 2000 2001 Year 2002 Figure 7. Philadelphia MSA Lead Compounds Regulation Impact Analysis 2003 Lead compound concentrations appeared to have decreased substantia ll y after implementation of the Secondary Lead Smelt er MACT (graph key = u) and the Gasoline Distribution Stage I MACT (graph key= t). Ta mpa-S t . Peters burg-Clearwater, FL MSA Average Annual Lead Compound Concent rations (1990-2003) 1500 -··------------ 0 ~ ~ y I 3 I 7 1350 1200 1050 ;;;- ! 900 "' .!:. C: 0 750 ~ C: .. " 600 C: 0 0 450 300 150 y y y yy y 0 1990 199 1 1992 1993 1994 1995 1996 1997 1998 1999 2000 2001 2002 2003 Year Fig ur e 8. Tampa MSA Lead Regulation Imp act Analys is Lead compound concentration s appeared to hav e decreased overa ll during the study period, most notabl y after the Secondary Lead Smeltin g MACT (graph key = u). Tampa-St. Petersburg-Clearwater, FL MSA Average Annual Toluene Concentratio ns (1990-2003) 8----------------------------------------~ ~5 ~-------------------.;.----j-.;.--1'>-.--.---;--------.;.-.---~ ; \i ~4~------------------------~--------------4 I 1 83+--------~,---:~\: -~ 2 +------------+--~\. _ _,__,_____, ~ j 1990 199 1 1992 1993 1994 1995 1996 1997 1998 1999 2000 200 1 2002 200 3 Year Figure 9. Tampa MSA Tolu ene Regul ation Impact Anal ys is Limited tolue ne data in the Tampa MSA for the last fi ve years limits the conclus ion that concentrations are continu ing to dec rease . Detroit-Warren -Livonia, Ml MSAAverage Annual Lead Compou nds Concentrations (1990 -2003) 36 ~-------------------------------------- 0 QJ ~ 1v13 11 1 I 32 -l-__j__-----~---------'=='-----'=;:::!_------~::::'---~~=~='-_J! 28 +---+l\._,,____ ______ --'f~-~--------+----------"--------"--'------"------l ~/~ i 24 +---¥--1--'<--I-\V______....__"" _ ____;___i. == ,, v~~. -~_________;~ .s. 20 +-----------lr-----.11_ ""___..:,-..h...,/C.--+------l-----,1 __ ~-~=--=-----1-~~=,___-1--~~--------'---l ~ f"'~ 11 1 16 +------------t-----~----i---------i---------i-=-+1-"'-~-dtc-i-: __c;..,..---------4 g N u 12 +----------------_..;_ ____ --,; ________ _;._ ___ ___;.._.;.___;__----i 8 _,__ _____________________________________ _J 4+----------------~----~--------~---~~~-~ • • ••• o+-----------~--------------------------~ • 1990 1991 1992 1993 1994 1995 1996 1997 1998 1999 2000 2001 2002 2003 Year Figure 10. Detroit MSA Lead Regul atio n Imp act Analys is Lead concentrations in Detroit appeared to have decreased steadily during the stud y period . The biggest affect appears to be the imp lementation of the Large Municipal Waste Combustors MACT (graph key= M). Detroit -War ren-Livonia, Ml MSA Average An n ual Xylenes (m-,p-,o-) Co n ce ntra tions (1 990-200 3) 4 ~ 1,,s,t!~ El ~ ~ 3.5 3 f 25 Cl 2. i\ C 0 2 ~ \ " .. T u C 0 1.5 u \T~ L---: ~ t / . . . . -r I l 0.5 t t t t t t tt 0 1990 1991 1992 1993 1994 1995 1996 1997 1998 1999 2000 2001 2002 2003 Year Figur e 11. Detroit MSA Xy le nes (to ta l) Regul ati o n Impa ct Anal ys is Although tota l xy lene concentrations had little variance throughout the 1990s, it's un sure how stationary source ru les affected xylene concentrations due to the limited data availabi lity of xy lene measurements from 1997-2000, when several regulations were imp lemented. Dallas-Fort Worth-Arlington , TX MSA Average An nua l Benzene Concentrations (1990-2003) 3 .5 ··-.. -·-··---------·--·--·---··-··-............... -................. ____ ~ QJ ~I X !z ,AI CI E! I I K I 1v ,o,1 I 4 I 3 2 .5 .;- E DI 2 2. C 0 ~ 1: .. 1 .5 " C 0 u 0 .5 " 0 " " " " " " " " " 1990 1991 1992 1993 1994 1995 1996 199 7 1998 1999 20 00 2001 2002 200 3 Year Fig ure 12. Dallas MSA Be nze ne Regul atio n Imp act A nalys is Benzene concentrations in Da ll as show a downward trend , apparently in re sponse to imp lementation of Tier I Mobi le Standards (graph key = j). Dallas-Fort Worth-Arl ington, TX MSA Average Annual Mercury Compound Concentrations (1 990-2003) 1400 1200 ~ [!] ~ [!] 1000 .;-~ / \ E DI 8 00 ..:. \ V I\ C ~ ~ C " 600 u \ C 0 u ~ 400 \ 200 )-T T _l l l 1~ ... ... ... -... 0 1990 199 1 1992 1993 1994 1995 1996 1997 1998 1999 2000 2001 2002 2003 Year Figure 13. Dalla s MSA Me rcury Regula ti on Imp act Analys is Mercury compound concentrations appear to have decrease substantially with the imp lementation of the R eformulated Gasoline Ph ase I Program (graph key= d). However, acco rding to the NEI, mercury emi ssions from Haza rdous Waste Combustors decrease d by 97% from 1996 to 2002 fo r th is MSA, mo st like ly as a re sult of impending regulations (graph key = 8). St. Louis, MO-IL MSA Average Annual Cadmium Compound Concentrations (1990-2003) 45 40 35 30 ;:, E ci> .':. 25 C: ~ ~ C: 20 .. ... C: 0 0 15 10 5 ,. • 0 1990 1991 1992 1993 1994 1995 1996 1997 1998 1999 2000 2001 2002 2003 Year Figure 14. St. Louis MSA Cadmium Regulation Impact Analysis Overall , cadmium compound concentratio ns in the St. Louis MSA appeared to have decreased during the study period. The impl ementatio n of the Reformulated Gasoline Phase 2 Program (graph key= I) and the Primary Lead Sme ltin g MACT (graph key= P) coincide with these reductions. However, no impl emented regulations exp lain the increases in the 1996 , 1997, and 1999 concentrations . 27 24 21 18 ;:, 1 .:. 15 C: 0 "' ~ C: 12 .. " C: 0 0 9 6 3 0 1990 St. Louis, MO-IL MSA Average Annual Xylenes (m-,p-,o-) Concentrations (1990-2003) I o,11 41 s 1 I~ • 199 1 1992 1993 1994 1995 1996 ~:. ~- •• • • 1997 1998 Year :::~ .. • • • • f-•• t t t t • tt 1999 2000 2001 2002 Figure 15. St. Louis MSA Xy lenes (total) Regulation Impact Analysis 2003 Total xylene concentrations in the St. Louis MSA declined dramatically from 1990 to 2003 , apparently in response to several implemented stationary and mobi le source regulations targeting VOCs (graph keys= d, p, r, t, w, x, z, A-C , E, F, I, Q). However, lack of xy lene measurements between 1995 and 2000 limit the certai nty of these conclusions . .;- E 7 6 5 !4 C i C B 3 C 0 " 0 1990 Denve r-Aurora , CO MSA Average Annual Acetaldehyde Con centrati ons (1990-2003) ~ ~ ~ ~[Q2] [!] !y,z,AI~ ~ ~ ~ ~ \ f\ 1~: . . f1 • • • • • • • • •• • • • • • 1991 1992 1993 1994 1995 1996 1997 1998 1999 2000 200 1 2002 2003 Year Figure 16. Denve r MSA Acetald ehyde Regul ation Imp act Anal ys is Ove r the last four years , acetalde hyde concentrations appeared to have decreased afte r implementation of mobile so urce ru les : winter-oxygenated fuel program (graph ke ys= L, S, 5) and th e Nationa l Low Emissions Vehicle Program Phase II (grap h key = K). Denver-Aurora , CO MSA Average Annual Cadmium Compound Concentrations (1990 -2003) 72 ~ ~ ~ ~ ~ ~ 64 0 ~ ~ ~ ~ ~ 56 48 .. E a, .S 40 C 0 ~ C 32 " u C 0 0 24 16 / I I \[ I \ : : I !\ / \ 8 0 '--i ~ ~ ~ . . -T ~ ::r -~ . . --~ ;, ;, ;, ;, ;, ;, ;, " ;, .L ;, ;, ; 1990 1991 1992 1993 1994 1995 1996 1997 1998 1999 2000 2001 2002 2003 Year Figure 17 . De nve r MSA Cadmium Regulatio n Impac t Anal ys is No imp leme nte d statio nary source regulations were iden tified in the Denver MSA which apparent ly affec ted cadmium co nce ntrations . According to TRI, cadmium emissions from Asarco, Inc . Glo be Pla nt decreased from 0 .198 tp y in 1990 to 0.077 tpy in 1994 , a 61 % decrease. Cadmiu m emis sions remained steady for this p lant through the 2002 NEI. ;;, E Los Angeles-Long Beach-Santa Ana, CA MSA Average Annual Ethylbenzene Concentrations (1990-2003) 7-r-----------------------------------------, ~ [:J I I I P I q,r,t I w,~ ll y,z,AI E,F I ~,11 QJ I S I 1 14,517191 6+---+----------------~------~------------~~____, 5+--+---------,....--~---------...... -------~-~---a-------<-~--->-< ~4 -l--+--.,...-=-+'s,..;_--------.;._--;__;__;__;_;__ __ ;--_ _;_ __ _;__~_;.....;._~ C 0 ~ 3 3~~--i ---+~~~~~~~~~--~+~~~-~~-~-+--~~-~~--W 8 ( I 2 -l--------_;_--t---t---_;_----=:_-~---!:-----=-~---:1:-:-..::::,;.-d:___;---!---:--_;__;_----!--{ 0 +---~--~--·---·---·---"---·--·-~·--·-·--·~·--~--·--·--·-·--!· 1990 1991 1992 1993 1994 1995 1996 1997 1998 1999 2000 200 1 2002 2003 Year Figure 18. Los Angeles MSA Ethylbenzene Regulation Impact Analysis Eth y lb enze ne conce ntration s in the Los An ge le s MSA appeared to hav e declin ed steadil y in re spon se to seve ral impleme nted stationa ry and mo bil e source re gulation s targetin g VO Cs (gra ph ke ys= a-L). i Los Angeles-Long Beach-Santa Ana, CA MSA Average Annual Formaldehyde Concentrations (1990-2003) 9-r---------------------------------------~ 7 +--------+---------------+----+--!---i--+---,,--....,....-:-----:---!----!-; ~5 -l--------_;_--;---;--+--,i.---:--=-_;_~l,-',:;....--.;.i--:--1.-.;r-.---i---;J.-_;___;..c::....;~ C 0 ~ 1 4+--------------~----~----------~-~~-----~ u C 0 (.) 2+--------......---------------e--,------,....--;--~--,....---~~----......--~ t • • • t • • t ... t t t t ... t • 0+---~-~--~----------~--~-------------~--~ 1990 1991 199 2 1993 1994 1995 1996 1997 1998 1999 2000 200 1 2002 2003 Year Figure 19. Los Angeles MSA Formaldehyde Regulation Impact Analysis Formaldehyde conce ntrations have ste adil y increased during th e study period . Thi s is most likely du e to th e implementation of th e Refo rmulated G as oline Ph ase I Pro gra m (graph key= d). 6 5 4 I 2. C: ,g 3 ~ C: .. " C: 0 t) 2 0 1990 Seattle-Tacoma-Bellevue, WA MSA Average Annual Formaldehyde Concentrations (1990-2003) ~ ~ ~ ~[!] [:] I X I z,AI E I ~ El ~ I I V I I I 1~· I . . . . . . . . . . . . . . . . . . : I " " " " " ... " " " " " " I 1991 1992 1993 1994 1995 1996 1997 1998 1999 2000 2001 2002 2003 Year Figure 20. Seattle MSA Formaldehyde Regulation Impact Anal ys is Over the last three years, formaldehyde concentrations have appeared to have increased, noticeably after the implementation of the Publicly Owned Treatment Works MACT (graph key= 4). However, forma ld ehyde data prior to 2001 is limited or unavailable, thus making it difficult to characterize a trend . Seattle-Tacoma-Bellevue, WA MSA Average Annual Lead Compound Concentrations (1990-2003) 325 300 275 lae'. ''.:;gl-----~~ b a C 250 225 f 200 O> £ C: 175 ,g ~ 150 C: .. " C: 125 0 / V J I .. I 1\ t) 100 75 50 25 \ \ \ 0 t t t tt .i. .i. 1990 199 1 1992 1993 1994 1995 1996 1997 1998 1999 2000 2001 2002 2003 Year Figure 21. Seattle MSA Lead Regulation Impact Analysis During the study period, lead concentrations appeared to have decreased. After implementation of the Petroleum Refi neries and Aerospace Man ufacturing MACTs (graph keys =wand x, respectively), conce ntrations decreased substantially. Interestingly, lead concentrations apparently increased after the prohibition of leaded gasoline (graph key = g). ·ERG RESPONSE TO CITY OF FORT WORTH'S FORMAL QUESTIONS ERG Response to City of Fort Worth's Formal Questions As part of the requirements outlined in the Request for Qualifications, the ERG Team is providing written responses to eight questions posed by the City of Fort Worth. We understand that answers to our questions will be considered by the Committee as part of the selection process. Below, we re-state the question (in bold italics), followed by our written response (normal typeface). Thank you for the opportunity of considering the ERG Team to provide technical support in this air quality study. We will be happy to elaborate on any responses during the interview. To aid in your review, we have added a list of abbreviated terms below. Abbreviations AERMOD AMS API ATSDR cfm CFR CV DQI EPA ERG FB FLIR H2S HAP HRVOC IR kg/hr km lb/hr MDL M/WBE NATA NCTR NOx PM ppm QAPP REL RFQ RHC RPD scf TCEQ TO TRC TVA voe June 24 , 2010 AMS/EPA Regulatory Model American Meteorological Society American Petroleum Institute Agency for Toxic Substances and Disease Registry cubic feet per minute Code of Federal Regulations Coefficient of Variation Data Quality Indicators Environmental Protection Agency Eastern Research Group Fractional Bias Forward-Looking Infrared Camera Hydrogen sulfide Hazardous air pollutant Highly-reactive volatile organic compound Infrared kilogram per hour kilometer pound per hour Method Detection Limit Minority and Women Business Enterprises National-scale Air Toxics Assessment North Central Texas Regional Oxides of Nitrogen Particulate Matter parts per million Quality Assurance Project Plan Relative Exposure Limit Request for Qualifications Robust Highest Concentrations Relative Percent Difference standard cubic feet Texas Commission on Environmental Quality Toxic Organic Texas Railroad Commission Toxic Vapor Analyzer Volatile Organic Compound Page 1 of 14 ERG Response to City of Fort Worth's Formal Questions Question 1 -How does your proposed study take one hour or instantaneous measurements into account versus various exposure levels over a 24 hour period or longer? Will your testing include FLIR cameras? If so how? Please list each type of sampling proposed and the impact that it is designed to assess. Disparate Time Measurements (instantaneous or 1-hour vs. 24-hour period or longer) ERG is experienced in comparing disparate measurements to various exposure levels. It is important to properly compare an exposure level to a concentration value or average at the same time period. For example, it is not appropriate to compare a 24-hour (short-term) concentration to a chronic (long-term) exposure level, and vice versa. We have demonstrated this capability and understanding of disparate time measurements in our work for EPA's Air Toxics Data Analysis project. In this project, we compiled an archive of over 26 million hazardous air pollutant (HAP) records, spanning 30+ years across the entire United States. This archive consisted of several types of time-period measurements (1-hour, 3-hour, 4-hour, 6-hour, 12-hour, and 24-hour), and ERG was tasked with evaluating each HAP against their respective exposure levels. Typically, most exposure levels are 24-hour (daily) in nature, but some HAPs also have sub-daily exposure levels. For example, benzene has a Relative Exposure Level (REL) over a time-period of six hours. In this situation, we were able to average six 1-hour concentrations or two 3-hour concentrations to accompany any six-hour data measurements in the archive, and develop a frequency in which the six-hour benzene average was greater than its REL. However, most short-term or acute exposure levels are 24-hours . In the above work for EPA, we required that to be considered a valid 24-hour average, at least 18 of the 24 hours must have a valid measurement. Thus, a valid 24-hour measurement could be comprised of at least eighteen I-hour measurements, six 3-hour measurements, five 4-hour measurements, three 6-hour measurements, or two 12-hour measurements. In the proposed study, we would work with the City to determine if this approach, or a modified approach would meet their needs. Another time-period that the City may want to consider would be monthly, seasonal, and/or quarterly averages . These averages could then be compared to intermediate-term exposure levels (typically over periods from 15-days to 364 days). Finally, annual averages can be developed by averaging a minimum number of monthly, seasonal, or quarterly averages. These averages can be compared to chronic exposure levels. Currently, we are supporting the data analyses component of EPA' s Schools Air Toxics Initiative. Daily (24-hour) concentration values are compared to sample screening levels (i.e., the level at which significant risk is observed for short-term exposure), and estimated long-term concentration averages are compared to long-term comparison levels, such as for cancer and/or noncancer effects. FLIR Cameras Yes, our testing will include FLIR cameras. The ERG/Sage team believes that it is important that all potential point sources be screened via the FLIR camera for several reasons: 1) if this is not done, the community will be dissatisfied over what will be perceived as an incomplete effort, 2) homeowners affected by un-sampled sources will ask why "their" neighborhood was not tested, and 3) the point source results will have a direct impact on the ambient air and modeling efforts so it is critical that they be as inclusive as possible. Because the number of potential sources is large (approximately 1,600 wells, perhaps a hundred June 24 , 2010 Page 2 of 14 ERG Response to City of Fort Worth's Formal Questions compressor stations, several gas processing facilities and many miles of gas pipelines), it will be necessary to quickly distinguish the bad actors from the good . The IR camera is ideally suited for this purpose. Large numbers of equipment can be quickly surveyed by the camera to detect dangerous leaks. Using the IR camera, investigators can screen well pads in a matter of minutes; small compressor stations in under half an hour; and medium sized gas conditioning facilities ( containing dehydrators, storage tanks , compressors, piping and incinerators) in less than 4 hours. The only exception to the 100 % screening practice will be gas pipelines. Because the pipelines are relatively new and contain no external moving parts, they pose the lo w est risk of leakage among the identified point sources . Given time and resource concerns, we feel the interests of the project will be best served b y visiting a percentage of accessible pipelines with the IR camera once the other sources hav e been surveyed. Currently we plan to field two IR Camera teams for this project. Each camera team will be equipped with a Toxic Vapor Analy zer (TVA) to perform Method 21 screening on selected natural gas service components . All point source measurements will be instantaneous. The IR camera will quickly detect the large leaks (> 10 ,000 ppm) that can present safety and health concerns. The TV A is much more sensitive and can detect v ery small hydrocarbon leaks that will not be seen by the camera. June 24, 2010 Page 3 of 14 E RG Respon se t o City of F o rt W orth's Formal Q uestions Question 2 -The first bullet and section A of the Scope of Services description in the RFQ describes the City's desire to quantify actual emissions being released from sources involved in natural gas operations. In 1 page or less, please summarize your firm's proposed approach to collect the data sought in A.l) and A.2) of the desired Scope of Services. (This response may refer to information presented in your firm's qualifications package.) As part of this discussion, please describe what specific pollutants will be quantified under this task of the project and what units will be used to quantify emissions released (e.g., lb/hr, sci, etc.). Point Source Type Emissio n Rate Determinatio n Wells Selected equipment leaks found with the IR camera will be sampled with the High-Flo ® Sampler to determine emission rates as methane in cfm. Canister samples will be collected from selected leaks to obtain hydrocarbon-speciated (VOCs , HAPs, and HRVOC) leak rates (kg/hr). Valves, Connectors at Leaks detected by the IR camera of valves and connectors will be Compressor Station sampled with the High-Flo® Sampler to determine emission rates as and Gas Processing methane in cfm. Canister samples will be collected from selected Facilities equipment leaks to obtain hydrocarbon-speciated (VOCs , HAPs, and HRVOC) leak rates (kg/hr). Emission data will also be collected with the High-Flo® Sampler (cfm) from selected non-leaking equipment and equipment leaking below the detection limit of the IR camera (<10 ,000 oom). Compressors Compressor leaks detected by the IR camera leaks will be sampled with the High-Flo® Sampler to determine emission rates as methane in cfm if the leak area is accessible . Canister samples will be collected from selected vent leaks to obtain hydrocarbon-speciated (VOCs , HAPs , and HRVOC) leak rates . A subset of safely accessible compressor vents will be tested for NOx and H2 S emissions using a portable combustible gas detector and portable flow measurement devices (kg/hr). Storage Tanks and Leaks detected by the IR camera from tank hatch covers, pressure relief Dehydrator Vents devices, and still vents will be sampled with the High-Flo® Sampler if accessible, to determine emission rates as methane in cfm. Canister samples will be collected to obtain hydrocarbon-speciated (VOCs, HAPs, and HRVOC) leak rates (kg/hr). Gas Transmission Emissions from natural gas transmission line leaks found by the IR Lines camera will be measured with the High-Flo® Sampler (cfm). Canister samples will be collected from a selection of gas line leaks to obtain hydrocarbon-speciated (VOCs , HAPs, and HRVOC) leak rates (kg/hr). June 24 , 2010 Page 4 of 14 ERG Response to City of Fort Worth's Formal Questions Question 3 -Which air dispersion models are you proposing to utilize for this study and why? How many data points are required to model atmospheric dispersion to ensure that the results are statistically significant? Dispersion Model Selection While we have demonstrated capability in a number of dispersion models, we believe only one model is necessary for this analysis , AERMOD (AMS/EPA Regulatory Model). This is based on the following reasons: a) AERMOD is U .S. EPA preferred air dispersion model for near-field (Appendix W to 40 CFR Part 51 , Guideline on Air Quality Models , http ://www.epa.gov/ttn/scram/guidance/guide/appw 05.pdf, Page 68253); b) AERMOD is widely accepted and used in the scientific and regulatory community; c) The study domain falls within the distance limits of AERMOD (50 km or -30 miles) d) AERMOD supports multiple source types (vents, stacks, area sources for piping) e) Special meteorological circumstances are not at issue in this case ( complex wind flows, stagnation, complex terrain); therefore, alternate models, such as CALPUFF, are unnecessary; f) AERMOD needs only a single meteorological station, along with upper air data to execute, unlike grid models; and, g) Ozone modeling is too costly and is evaluated on a regional level ; thus , it is not considered part of the work scope . Data Points We interpret data points, in this context, to mean simultaneous observations of air quality data and meteorological observations. The number of observations, although important, is not the critical issue. The priority is having air quality and meteorological data taken immediately downwind of the emission sources. This requires well-sited air quality instruments. That said, we consider 25 or more downwind observations from at least one monitor in the area to be ideal. This is based on the number of observations used to calculate the fractional bias . Fractional bias is a statistic used to evaluate general model performance. The general expression for the fractional bias (FB) is given by: FB = 2 (PR-OB) (PR+OB) OB and PR refer to the averages of the observed (OB) and predicted (PR) highest 25 values. The same expression is used to calculate the FB of the standard deviation where OB refers to the standard deviation of the 25 highest observed values and PR refers to the standard deviation of the 25 highest predicted values . In addition to the average and standard deviation, the fractional bias can be determined based on the 25 largest values, the robust highest concentrations (RHC). Negative values denote over-prediction and positive values denote under-prediction. A value of+/-0.67 denotes model predictions off by a factor of 2 . June 24, 2010 Page 5 of 14 ERG Response to City of Fort Worth's Formal Questions Question 4 -Pursuant to the Request for Qualifications, a goal of 10% utilization for minority and women business enterprises (MIWBE) has been established for this project. As a reminder, MIWBEs must be registered by the North Central Texas Regional Certification Agency and must be located in the marketplace or doing business in the marketplace at the time of bid opening or during negotiations related to proposals. Please clarify your proposed MIWBE subcontractor and the proposed parts of the proposed work plan that they are anticipated to complete. ERG and Sage will be using the services of Hicks & Company to assist in the point source testing, ambient air sampling, and communication and outreach tasks . Hicks & Company is registered as a minority and women business enterprises (M/WBE) by the North Central Texas Regional (NCTR) Certification Agency, and is currently doing business in the Fort Worth metropolitan area. Hicks & Company is currently providing environmental management and compliance support for the State Highway 161 and North Tarrant Express transportation p rojects. Specifically, we will u se Hicks & Company personnel as field technicians in the point source IR camera surveys , Method 21 screening, and canister collection activities , as well as for communication and outreach activities once data collection and data analysis have been completed. Hicks & Company personnel are experts in the community education and awareness area, and have presented training on this subject the USA, England, and Africa. We are attaching Hicks & Company 's NCTR certification. NCTRCA Women-Owned Business Enterprise Certification June 24, 2010 Hicks & Company Enviro A.rche olo g ical Consultants Woman-Owned Business Enterprise ba., 111«1 will, 11M Aa;<""Y an Amdnil ._, rJ.l!ned by 11M, NCTRCA M/WllF. polk:l<s & pro«dun:s •nd is llfrfflt a,rtifi<d to prnldt 1trvlct{s) I• lh• followills areas: 541710 , 541910; 541618; 924110 ; Research and Develcpment [n the Physical , Engineering , and life Sciences: Marl<.eting Research and Public Opin ion Poil'ng; Other Management Consulting Services; This Certification ill valid beginnin J une 2010 a nd supene.ded aay regl~trallon or listing previously lssm,d. 'l'his rerdOullon most be updated a!lllnally by ,ubn1is,ilon ot un Annual Update Affidavtl. At any time there ls a d1ange lo ownership or con trol of th~ Orm, ootifiuliou u1ust be made immedi•t<:ly h> the Nor:tls Ccntnd Tuu Regional Culif,c•lfon Ag,m cy. Certill<ate expira.llo,.___.c..Ju'-'-n--"-e------~20_1_1 _ Cer1Jncallon Admln.istrator Issued date June ____ ,2()~ CEllTfHCA'lION NO. WFWB45539Y0611 Page 6 of 14 ERG Response to City of Fort Worth's Formal Questions Question 5 -The study scope includes anticipating emissions from full build out of the Barnett Shale in the City of Fort Worth. How do you intend to go about defining the baseline condition as well as determining what full build out would encompass? Please discuss total number of pad sites, well heads, and production rates as well the sources for information to be used to formulate your response. Since the point source sampling effort will be surveying all potential leak sources with the IR camera and determining emission rates from most of the leaks found, it is expected that sufficient emission data will be collected to develop average emission factors for the following point sources : • Wet Gas Wells • Dry Gas Wells • Wet Gas Compressor Station Valves • Dry Gas Compressor Station Valves • Wet Gas Compressor Station Connectors • Dry Gas Compressor Station Connectors • Wet Gas Compressors • Dry Gas Compressors • Storage Tanks • Glycol Dehydrators Stations • Wet Gas Transmission Lines • Dry Gas Transmission Lines Applying these emission factors to the estimated quantities of full build out equipment types and services should provide a reasonable estimate of potential future emissions. The total number of pad sites, well heads , and current production rates can be obtained from the Texas Railroad Commission (TRC) database . Recently , TCEQ has developed a comprehensive equipment-level inventory of all oil and natural gas source types in the Barnett Shale, which includes Tarrant County. This data is anticipated to be publically available . Anticipated future activity will be obtained from energy statistics available through the US Energy Information Administration, or from drilling and production projections from trade groups or other available resources such as Baker Hughes. Additionally, surveys of the owners and operators can be used to augment future activity for the full build-out. The ERG Team is experienced in preparing, coordinating, and distributing surveys of this nature, especially within the State of Texas. June 24, 2010 Page 7 of 14 ERG Response to City of Fort Worth's Formal Questions Question 6 -The biggest challenge in success/ ully completing this study is to convince a skeptical public that this study is fair, objective and provides results that are credible. How will your project plan accomplish this? The ERG team has extensive ex perience working on projects where community members are very concerned about local air pollution le vels , y et are skeptical of studies that have attempted to characterize air quality . We fully appreciate that a goal of this project is not only to provide the City of Fort Worth a scientifically defensible assessment of air quality impacts from oil and gas production activities, but also to ensure that the study results stand up to the scrutiny of any potential critics. If awarded this task, the ERG team will work closely with City officials to develop an outreach and communications plan designed to meet these goals. While the extent of our proposed outreach and communications efforts will ultimately depend on project resources and other considerations , we share below some guiding principles that typically factor into our site-specific outreach and communications strategies . Project Planning Phase: Build Trust When proposing the most effective outreach and communications strategies, ERG first works with its clients to determine exactly who is meant by "the community." This can be the public at large , specific environmental groups or activists, elected officials, and others. ERG will work directly with City officials to characterize the local community and understand their concerns , background, and perceptions, which will help inform subsequent outreach activities. ERG will also consult with City officials up front to determine who will be the "voice of the project" and under what circumstances the contractor will be expected to communicate directly with community members and other interested parties . A key aspect to building trust is meeting directly with all stakeholders and interested parties. Should project resources allow, ERG will encourage scheduling a few such meetings or public availability sessions early in the project to introduce these community members to the scope of the project and the project team and to solicit input on the proposed sampling and modeling protocols. Opening the lines of communication at the earliest stages of the project helps provide community members a sense of ownership in the future work and lets them know that their opinions and input are truly valued. It also helps in setting realistic expectations. The ERG team recognizes that community members sometimes have requests that go beyond the intended scope of work for a project. However, our experience is that community members still appreciate the opportunity to offer input, even if their specific recommendations cannot always be adopted . During these initial communications, ERG will document the community members ' various expectations of the project. Through consultation with City officials , we will ensure that community members are fully aware of which expectations fall within the scope of the anticipated work. Another aspect of building trust with the community is fully disclosing , from the project onset, the ERG team's past working relationships and describing our technical qualifications. During initial meetings with community members and stakeholders, ERG will emphasize that we are a company that works almost exclusively for public agencies, and rarely working for private industry . For more than 25 years, ERG has researched virtually every type of industrial air pollution source , including numerous projects evaluating air quality impacts from oil and gas production activities . We therefore have developed extensive technical expertise for the source of interest, but we have no financial or June 24, 2010 Page 8 of 14 ERG Response to City of Fort Worth's Formal Questions professional ties to the oil and gas exploration industry. We can also share with interested community members sample projects that demonstrate our qualifications. For instance, EPA entrusts ERG's laboratory with conducting extremely high-profile monitoring projects, including multiple nationwide programs and measuring air quality impacts in the Gulf region following Hurricane Katrina and the recent oil spill. We can also describe the air monitoring we conducted for the Agency for Toxic Substances and Disease Registry (ATSDR) that revealed potential public health hazards associated with oil and gas exploration activity in Illinois. Our monitoring projects with ATSDR are particularly notable because they often involved placing ambient air monitoring equipment directly at community members' households-and sometimes inside their households. These projects required very close coordination with community members. The ERG team can provide these and many other examples of our work on high profile projects, with the intent of assuring community members that we are well suited to help the City of Fort Worth answer its pressing questions regarding local air quality. Ultimately, the initial communications-which will follow the specifications in our outreach and communications plan-are designed to build trust with the community. We fully appreciate that this trust must be earned, not assumed, and that lack of trust has the potential to erode at the credibility of our findings, no matter how scientifically defensible they may be. Our outreach and communications specialists and technical staff all strive to build the necessary foundations with community members such that they view our project team as a trusted source of information. Project Implementation Plan: Maintain Trust Throughout the testing and monitoring program, the ERG team will engage in additional outreach activities to keep City officials and the community informed of progress and to maintain trust with all interested parties. First, we will ensure that we keep a strong, visible presence throughout the project; several options are available for doing so, and the ERG team will work with City officials to determine which options best suit their needs. Examples of these options include: holding periodic update meetings to keep interested parties up-to-date on progress; launching a project website where we post weekly updates on field activities and other important project milestones; and ensuring quick response to all information requests from City officials . Through these and other options, we will communicate our continued commitment to meet project goals and answer community questions . Second, we will discuss with City officials options to have interested parties actually witness some of ERG's field activities. This could be accomplished by giving people tours of the monitoring sites or even allowing observers present at certain emission testing events, provided that activity does not violate any aspects of our health and safety plan. We have found that allowing community members an opportunity to see our work in progress can generate more trust and confidence in the overall process. Finally, further options exist for demonstrating the credibility of our work. Our quality assurance project plan will list the specific quality control approaches adopted, as well as identify specific data quality objectives that must be met in terms of the accuracy and precision for various measurements. Should City officials be interested in pursuing further means for demonstrating data validity , additional options are available (e.g., having an external group of independent experts review and comment on draft products or sending duplicate samples to a competitor's laboratory to characterize measurement accuracy) but these supplemental options involve additional costs that will have to be considered. June 24, 2010 Page 9 of 14 ERG Response to City of Fort Worth's Formal Questions Question 7 -In order to make defensible conclusions from the study that would apply city wide, a s ignificant number and variety of sites and sources distributed geographically will need to be evaluated. How will the contractor balance the need to evaluate a significant number of sites and sources with the short sampling window allotted for this study? Ambient Air Monitoring With re spect to being able to make defensible conclusion s based on the ambient monitoring data, two separate but distinc t questions mus t be considered: 1) Is the data itself appropriate to the study objectives and defensible? 2) is the data representativ e of the study area. Con s ideration #1. Is th e da ta itself appropriate to th e study o bjecti ves and defensible? For m easurement of Air Toxics and Carbonyl compounds, ERG 's procedure for performing sampling and analysis are appropriate for the envisioned survey. Our procedures are conducted in strict accordance with the guidelines detailed in EPA Compendium of Methods T0-15 and T0-11 A , which ERG was instrumental in developing for EPA and in accordance with the quality specifications presented in our Category 1 EPA Approved Quality As surance Project Plan (QAPP) for the EPA National Monitoring Programs. Our QAPP presents Data Quality Indicators (DQI) that will be used as a metric to qualify and defend the data generated : 1) Certification -Can th e sample collection equipment co llect samples that are unbia sed ? All sampling systems used for this study will be "Certifi ed " to shown that they have the ability to prov ide unbiased samples prior to being deployed . 2) Detectability -I s the analy ti cal me thodology sensitive enough to meas ure th e con centration ra nges exp ected during th e s tudy? ERG 's offers some of the lowest experimentally determined Method Detection Limits (MDL) available . For the target compounds of interest, our MD Ls are lower than the associated risk values (i .e ., for both risk screening and health risk determination). 3) Precision -I s the me thod prec ise? A collocated sample will be collected for 10 percent of the sampling episodes . These collocated samples and the primary counterpart samples will be analyzed and compared to each other to determine the a s sociated percent Coefficient of Variance (%CV). The determined %CV will be assessed to determine if it meets the specification set forth in ERG 's EPA Approved QAPP. 4) Bias (or accuracy) -I s th e method able to p rovide data that do es not systematically deviate from th e tru e con centrati on ? For both T0-15 and T0-1 lA, ERG is regularly audited for accuracy through the analy si s of "Blind Performance Evaluations Samples" prov ided by EPA/OAQPS . This audit process prov ides a measurement of ERG's analytical accuracy ex pressed as Relative Percent Difference (RPO). Our determined RPO will be asses sed to determine if it meets the specification set forth in ERG 's EPA Approved QAPP. Conside ration #2. Is the data representative of th e s tu dy area? The goal here is to be able to generate a measurements data set that provides a representative cross- section assessment of emiss ion types and sites that can be used to assess emission rate/totals and associated risk on a city wide basis . To do this , ERG will determine/perform the following : June 24 , 2010 Pa ge 10 of 14 ERG Response to City of Fort Worth's Formal Questions 1) What are the applicable emission source types involved? 2) Based on any available data (i .e ., permit information, AP-42 information, past measurements data, etc.) determine each source types potential for emissions and rank them from highest to lowest. 3) Using similar past data, determine the sheer numbers of each source type and rank them from highest to lowest. 4) Use the 2 rankings to determine which source types provide the most potential for emissions/risk. 5) Screen a subset of each source type using the IR camera to identify appropriate candidates for testing based on emissions (i.e ., the greater the emissions level viewed -the higher the potential as a candidate). 6) Select a minimum of 2 sites in each source test. 7) Measure the total VOC emissions from each candidate site as methane using the API bagging approach of the Hi-flow approach (Initial -before speciated sampling and analysis begins). 8) Using the total VOC as methane data, conduct modeling to determine the potential for transport . 9) Using annual and seasonal (i.e ., August and September for the last 3 years) wind speed and wind direction data from the closest National Weather Service station to generate wind roses to determine the most likely predominate wind direction that will be encountered during the study . 10) Establish down wind monitoring sites, at a distance consistent with any applicable set-back ordinances, from each source type site to be studied. 11) Collect time integrated 24-hour samples (i.e ., from midnight to midnight) on a l-in-3 day frequency . 12) Measure the total VOC emissions as methane from emission type site studies using the API bagging approach of the Hi-flow approach (Final -after speciated sampling and analysis ends). This approach will provide a data set that is representative of the variety of source types and emissions rates (with an emphasis on potential worst case), and produce a data set with a population large enough to characterize emissions and risk potential on a city-wide basis . Point Source Testing The ERG/Sage team considers that defensible conclusions about point source emissions in the Fort Worth metropolitan area can only be derived from a study that inspects all potential natural gas point sources via IR camera. This "Phase I" screening tool will ensure that a comprehensive cross-section of sources are ultimately tested based on location, and based on leak rate profiles (such as high, medium, or low) as discussed in our proposal. In determining the number of sources needed to provide a statistically robust sampling size, we would draw upon the results of our initial screening effort (Phase 1 ). Conducting an IR camera survey of all potential point sources of hydrocarbon leaks is quick, scientifically sound , and considered essential to holding the confidence of the Fort Worth community. Conversely, an incomplete survey could result in weakened ambient air monitoring and modeling results and a discouraged community. The IR camera is an effective tool for surveying large areas and finding big leaks fast. To save time , two IR camera teams are proposed with each team assigned specific survey grids. All accessible wells , natural gas June 24, 2010 Page 11 of 14 ERG Response to City of Fort Worth's Formal Questions processing facilities, and compressor stations within the assigned grids will be visited and surveyed for emissions. The IR camera helps you find large leaks, but it does no t tell you how much is leaking. In order to determine how much is leaking , the component's emission rate needs to be measured. Emission rate measurements are possible in minutes with the High-Flo ® sampler and to the extent possible, emission rates from leaking components will be determined using this device. However, some components are going to be too large or located in spots inaccessible to the High-Flo ® sampler. For these components , a Method 21 screening value plus the EPA screening correlation factors will be relied upon to quickly derive estimated emission rates. June 24, 2010 Page 12 of 14 ERG Response to City of Fort Worth's Formal Questions Question 8 -If there is some need to reduce the scope of the proposed study because of cost or time constraints, how would you identify what pieces of the study would be eliminated and what pieces would be retained? If cost and/or time restraints become issues for the City, then we can offer several broad areas of the proposed study that the City may want to revisit from the original Request for Qualifications. These considerations are listed below: Ambient Monitoring Considerations For any study of this nature Technical Objectives (i.e., what are the goals that are trying to be achieved through this study) must be established at the on-set. This allows Data Quality Objectives (i.e., how good does the data need to be to meet the needs of the data users in accomplishing the Technical Objectives). Typically, in a study of this nature, multiple Technical Objectives will be identified. The ideal situation would be to make scope reductions that would still allow all of the determined Technical Objectives to be met, still with an acceptable level of confidence in the conclusions. In the case of this study, ERG would consider two primary elements. Element #1 would be the possibility of reducing the frequency of sample collection (i.e., change over to a 1-in 6 day). In this , ERG would have to determine if the change would result in a data set population that was still representative and reasonable to use to accomplish the Technical Objectives of the study. Elem ent #2 would be the possibility ofreducing the number of Technical Objectives. At first assessment, all of the multiple Technical Objectives initially identified typically appear to be equal in importance. However, if assessed further in a prudent and objective manner, they usually can be prioritized . When the prioritization is complete, work related to the Technical Objective of highest importance would be conducted. This approach would continue for each of the other identified Technical Objectives in order of priority until the available funding level or associated time constraint was reached. For example, the RFQ appears to place a priority on benzene, methane, ethane , and VOC from wells, gathering stations, and compressor stations, so the City may consider postponing evaluation of NOx and PM emissions, as well as emissions from mobile sources. These elements would be considered separately and in combination to achieve the most beneficial final produce/approach achievable . Dispersion Modeling Considerations Element #1: Remove air dispersion modeling component. This is based on the premise that collection of high-quality ambient air quality and meteorological data of the highest quality is the most important. It is necessary to give the community immediate feedback on what they are actually being exposed to. Dispersion modeling is theoretical and could likely confuse the public, without thorough explanations and context. That said, the air dispersion modeling is probably the least costly part of the study; so, the amount of savings are not likely extraordinary. Elem ent #2: Limit the number of proposed sites . Although several areas of the city are affected by the industry, it is most cost-effective to intensely study just a handful of sites, while getting a representative sample across the various phases of the gas drilling and production cycle . Pick a representative site for each, utilizing existing information gathered from TCEQ activities. June 24, 2010 Page 13 of 14 ERG Response to City of Fort Worth's Formal Questions Element #3: Conduct air dispersion modeling in a "regulatory" mode. This analysis is probably the least costly, and would involve conducting air dispersion modeling in a mode similar to what industrial facilities do for permits. Model "permissible" or permitted emissions from the facilities, along with TCEQ model-ready meteorological data. This analysis could be conducted both on a local level (i.e., pick a worst-case facility based on emission levels or prior monitored concentrations). This is not a "real-world" analysis. This analysis provides an estimate of what the maximum impacts could be. This analysis eliminates collecting field measurements (assuming emission inventory data are already available and reasonably quality-assured). The downside of this approach is the modeling analysis will most likely overestimate impacts, due to the conservative modeling assumptions. However, if conservative results obtained using worst-case assumptions are below concentrations of concern, a large degree of confidence is achieved that the public is not being subjected to overly adverse air quality. Point Source Testing Considerations Reductions to the scope for the proposed point source characterization effort would be recommended in the following order: Element #1: Do not survey transmission lines. As newer equipment is installed in the field, the use of older transmission lines has been reduced. Newer transmission lines are expected to have minimal leaking components. Therefore, emissions from this category may be insignificant relative to other sources. Element #2: Do not collect emission rate data from components in which the IR camera does not detect a leak. Although component count is important, the emissions from components with no observed leaks (based on the IR screening) may be insignificant relative to other sources. Element #3: An alternative to conducting an IR camera ground survey of all point sources, survey only a statistically determined representative sample of point sources and extrapolate the results to the entire population. Additionally, we can use EPA's most recent National-scale Air Toxics Assessment (NATA) modeling results to identify census tracts in the Fort Worth and surrounding areas where the cancer and/or noncancer risk is elevated. June 24 , 2010 Page 14 of 14 Page 1 of 1 Hendrix, Marty From: Wallach, Tyler Sent: Friday, August 06, 2010 4 :16 PM To: Hendrix, Marty Cc: Gange, Michael Subject: Contract CS 40631 Marty, Can someone place a note on this contract stating that it may contain confidential or proprietary information , and to consult legal before releasing? Thank you , Tyler Wallach Assistant City Attorney City of Fort Worth 1000 Throckmorton Street , 3rd Floor Fort Worth , Texas 76102 (817) 392-6259 (817) 392-8359 Fax This message and all attachments are confidential and are intended solely for the use by the individual or entity to which they are addressed . This communication may contain material protected by the attorney-client privilege. Any review, use, distribution , forwarding , printing or copying by persons other than the intended recipients is strictly prohibited . If you believe this email was sent to you in error, please notify the sender by replying to this transmission or by calling Tyler Wallach at 817-392-6259 and delete this message or any copy . Unless expressly stated in this email, nothing in the message should be construed as a digital or electronic signature. 8/6/2010